Digital Commons Network^™

Studies Of Nanoparticles From A Group Of Uniform Materials Based On Organic Salts (Gumbos), Aaron Tesfai

LSU Doctoral Dissertations

Tesfai, Aaron, B.S., B.A., University of Missouri, Columbia, 2003 Doctor of Philosophy, Spring Commencement 2010 Major: Chemistry Studies of Nanoparticles from a Group of Uniform Materials Based on Organic Salts (GUMBOS) Dissertation directed by Professor Isiah M. Warner Pages in dissertation, 101. Words in abstract, 271. Ionic liquids (ILs) are defined as organic salts composed of ions with melting points at or below 100 °C. ILs have gained considerable attention because of their desirable properties such as low volatility, high thermal stability, and tunability. GUMBOS are an emergent class of organic salts, many of which are ionic liquids (ILs). However, …

Effects Of Bondline Thickness On Nonlinear Interfacial Fracture Of Bonded Adhesive Joint, Gefu Ji

LSU Doctoral Dissertations

A number of existing and emerging industrial applications are dependent on layered substrates through adhesive bonding. The interfacial fracture of adhesively bonded structures is a critical issue for its extensive applications to a variety of modern industries. In the recent two decades, cohesive zone models (CZMs) have been receiving intensive attentions for fracture problems of adhesively bonded joints due to its fairly simple and accurate predictive ability. In CZMs the nonlinear interfacial fracture behaviors are described by the traction-separation laws (also referred to as cohesive laws). The cohesive laws represent the local constitutive behavior, instead of the global parameter, such …

Data Transfer Scheduling With Advance Reservation And Provisioning, Mehmet Balman

LSU Doctoral Dissertations

Over the years, scientific applications have become more complex and more data intensive. Although through the use of distributed resources the institutions and organizations gain access to the resources needed for their large-scale applications, complex middleware is required to orchestrate the use of these storage and network resources between collaborating parties, and to manage the end-to-end processing of data. We present a new data scheduling paradigm with advance reservation and provisioning. Our methodology provides a basis for provisioning end-to-end high performance data transfers which require integration between system, storage and network resources, and coordination between reservation managers and data transfer …

Augmented Breast Tumor Classification By Perfusion Analysis, Bruce Yu-Sun Lin

LSU Doctoral Dissertations

Magnetic resonance and computed tomography imaging aid in the diagnosis and analysis of pathologic conditions. Blood flow, or perfusion, through a region of tissue can be computed from a time series of contrast-enhanced images. Perfusion is an important set of physiological parameters that reflect angiogenesis. In cancer, heightened angiogenesis is a key process in the growth and spread of tumorous masses. An automatic classification technique using recovered perfusion may prove to be a highly accurate diagnostic tool. Such a classification system would supplement existing histopathological tests, and help physicians to choose the most optimal treatment protocol. Perfusion is obtained through …

The Interdependence Of Modality And Theory Of Mind, Danielle Rachel Alfandre

LSU Doctoral Dissertations

Modality is traditionally defined as the expression of possibility or necessity. In English, modality is expressed by the modal auxiliaries such as can, would, should, or might; adjectives and adverbs such as possible, necessary, maybe, and absolutely; or phrasal verbs such as going to or have to. Theory of Mind (ToM) is broadly defined as the ability to attribute thoughts and beliefs to other people. ToM is usually expressed using propositional attitude verbs such as think as in Mary thinks that it will rain. Hegarty (2006, 2010) proposes that propositional attitude verbs are covertly modalized and can be analyzed using …

Exploring The Impacts Of Wiki Collaborative Technologies Within The English Writing Environment, Valarie D. Dufrene

LSU Doctoral Dissertations

The use of technology in the writing classroom has been a staple since the early-1990’s when the personal computer made its way onto the desks of teachers and students across America. Since that time, the challenge has been for educators to incorporate the most recent technologies in an effort to stimulate student writing. This study examined the effects the use of a web-based wiki technology can have on the writings of high school students. The primary goal of this study was to explore how the web-based collaborative technology in Google Docs and used in a secondary English IV classroom can …

The Weakening Of Branch Predictor Performance As An Inevitable Side Effect Of Exploiting Control Independence, Christopher Joseph Michael

LSU Doctoral Dissertations

Many algorithms are inherently sequential and hard to explicitly parallelize. Cores designed to aggressively handle these problems exhibit deeper pipelines and wider fetch widths to exploit instruction-level parallelism via out-of-order execution. As these parameters increase, so does the amount of instructions fetched along an incorrect path when a branch is mispredicted. Many of the instructions squashed after a branch are control independent, meaning they will be fetched regardless of whether the candidate branch is taken or not. There has been much research in retaining these control independent instructions on misprediction of the candidate branch. This research shows that there is …

Investigation Of A Classroom-Based Reading Intervention Strategy For Older Elementary Students With Poor Decoding Skills, Shara Brinkley

LSU Doctoral Dissertations

Using a response to intervention framework, this study investigates the efficacy of a classroom-based intervention for struggling readers with decoding deficits in the upper elementary grades. Twenty two students in the fourth and sixth grades from four classrooms in low-performing schools received either a short 20-minute intervention delivered by their teacher or access to the lessons for an equivalent amount of time but no teacher instruction. Using three orthographic patterns, the 24 lessons consisted of a series of ten minimally contrasted words differing by one letter. The students in the experimental group decoded the words using a visual alphabet (Phonic …

Experimental And Analytical Study Of The Surface Texturing Enhanced Lubrication Elements, Yifan Qiu

LSU Doctoral Dissertations

Surface texturing is a method that modifies the frictional surface of a nominally flat tribocomponent by shallow patterns. It is found that with added patterns to the surface of a mechanical face seal or thrust bearing, their tribological performance improves, i.e. both friction and wear rate decrease. The current research concentrates on the analysis of hydrodynamic effect responsible for the performance enhancement of the spiral groove patterns and dimples on mechanical seal-like structures and the experimental evaluation of the tribological behavior of these structures. Surface textures considered are: dimple texture and spiral groove pattern. In the research on the dimple …

Retention And Transport Of Mercury And Nickel In Soils, Lixia Liao

LSU Doctoral Dissertations

Nickel (Ni) is one of many trace metals widely distributed in the environment. High concentrations of Ni in soils and aquifers have been observed worldwide, causing several potential human health impacts. Better understanding of Ni transport in soils and aquifers is necessary to assess and remediate insitu environmental contamination. The movement of Ni in soils and aquifers is highly dependent on adsorption-desorption reactions in the solid phase. In this study, kinetic batch, sequential extractions, and miscible displacement experiments were conducted to investigate the effect of several of environmental factors including soil type, reaction time and competing ions, on the fate …

Integration Of Paleotempestology With Coastal Risk And Vulnerability Assessment: Case Studies From The Dominican Republic And Nicaragua, Devyani Kar

LSU Doctoral Dissertations

Hurricanes account for a significant portion of damages, injuries, and fatalities in the Caribbean. The Dominican Republic has had 3 major hurricane strikes in this century resulting in loss of lives for thousands of people and billions of US $ in economic loss. Major hurricanes had been relatively infrequent in north-eastern Nicaragua’s modern history until Hurricane Felix, a Category 5 storm, made landfall in the north-east in 2007. It caused 130 confirmed deaths and brought devastation to many villages. These events highlight a need for re-evaluation of hurricane risk based on a more comprehensive and long-term hurricane history. Using paleotempestological …

The Relationship Between Social Skills And Challenging Behaviors In Children With Autism Spectrum Disorders, Jonathan Wilkins

LSU Doctoral Dissertations

The autism spectrum disorders (ASD) are among the most serious and debilitating conditions with onset in early childhood. Deficits in social interaction skills are considered to be the hallmark set of symptoms and are given the most weight in current diagnostic systems. Although not considered among the core symptoms of ASD, challenging behaviors in the form of physical aggression, property destruction, and self-injury also commonly occur. Challenging behaviors of this nature are a salient feature of ASD because of their potential to cause harm to self and others as well as limit a child’s access to opportunities in community and …

Readiness For Lifelong Learning Of Volunteers Affiliated With A 4-H Youth Development Program In The Southern Region Of The United States, Kenneth Kimani Kungu

LSU Doctoral Dissertations

The purpose of this study was to explore and determine the level of readiness for lifelong learning of volunteers affiliated with a 4-H youth development program in the southern United States. Based on a literature review, readiness for lifelong learning was conceptualized as incorporating aspects of response to triggers for learning, self-directed learning readiness, and a readiness to overcome deterrents to participation in learning. The Readiness for Lifelong Learning Survey, a 75 item Likert-type scale, was developed and administered online to 1815 adult volunteers who had provided usable emails in a enrollment database system. The final response count was 277 …

The Effect Of Directed Attention Score Study Procedures On Music Majors' Error Detection In Three-Part Instrumental Music, Amanda Lynn Schlegel

LSU Doctoral Dissertations

The purpose of this study was to determine the effects of directing participant (N = 60) attention to one voice in three-part homophonic and polyphonic instrumental music on music majors’ detection of pitch and rhythm errors. Directed attention participants studied one voice prior to studying the entire score through either visual or aural methods. Visual group participants (n = 20) studied the voice of directed attention (VDA), which was color highlighted, in silence. Aural group participants (n = 20) studied the VDA in a three-phase treatment: sight-singing the VDA, using a piano and their own singing to correct any errors …

Improving Software Quality Using An Ontology-Based Approach, Yixin Luo

LSU Doctoral Dissertations

Ensuring quality in software development is a challenging process. The concepts of anti-pattern and bad code smells utilize the knowledge of reoccurring problems to improve the quality of current and future software development. Anti-patterns describe recurring bad design solutions while bad code smells describe source code that is error-free but difficult to understand and maintain. Code refactoring aims to remove bad code smells without changing a program’s functionality while improving program quality. There are metrics-based tools to detect a few bad code smells from source code; however, the knowledge and understanding of these indicators of low quality software are still …

The Effect Of A Planned Instructional Program On The Empathy Levels Of Registered Nurses At A Metropolitan Hospital In Southern Louisiana, Deborah K. Charnley

LSU Doctoral Dissertations

The professional nurse’s role focuses on two distinct provisions of expert care involving the science and art of caring for patients. Nurses must attain and maintain a high level of scientific, clinical expertise. In addition, nurses must continuously seek to understand, relate to and connect with the patients with whom they work whether it is at the hospital bedside or in other arenas where healthcare services are provided. The nurse plays a critical role in supporting patients through their most vulnerable times by empathizing and understanding where they are and where they want and need to be from a physiological …

The Influence Of A State Law Enforcement Training Academy On Future Performance Of Law Enforcement Officers In A Southeastern State Of The United States, Cary Allen Caro

LSU Doctoral Dissertations

This dissertation examines the influence of the state police law enforcement academy on the performance of commissioned officers in the field training officer (FTO) program in a state in the Southeastern region of the United States. The law enforcement training academy is paramount in preparing cadets for the roles, responsibilities, and activities that graduates assume independently in the field. As such, it is important to understand the value added to future performance in the field through adequate preparation in the training academy. This dissertation analyzes a sample of officers in the Southeastern region of the United States and explores the …

Dynamic Acromiohumeral Interval Changes During Scapular Plane Arm Motions, Melissa Deen Thompson

LSU Doctoral Dissertations

This purpose of this dissertation is to explore changes in the acromiohumeral interval during dynamic motion in the scapular plane. All of the experiments were completed in the Football Operations Athletic Training Room at Louisiana State University. The first experiment which investigated dynamic acromiohumeral interval changes in baseball players during a loaded and unloaded scaption exercise from 0°-75°, has been accepted for publication by the Journal of Shoulder and Elbow Surgery (in press, 2010). The mean acromiohumeral interval (AHI) for unloaded and loaded scaption decreased significantly (p<.001) from the arm at the side until 45° and loaded scaption narrowed AHI at 60° (p=.005) and 75° (p=.003). The second experiment investigates AHI and scapular upward rotation (SUR) changes in baseball and softball players during scaption exercises from 0°-75°. Significant load related narrowing of the AHI at 45°(p=.005), 60°(p=.001), and 75°(p<.001) and a significant load-position interaction (p=.001) at 0° and 75°was observed for all subjects. No gender differences in SUR or AHI were found. AHI and SUR displayed moderate positive correlations at 30° for both the unloaded scaption (r=.648, p=.001) and the loaded scaption (r=.445, p=.038) however, no significant relationships were present at 0°, 45°, 60° or 75°. The third experiment compared dynamic acromiohumeral interval and scapulohumeral rhythm changes in trained and untrained females during scaption exercises from 0°-90°. In general, AHI was maximal with the arm at the side and declined significantly (p<.001) during arm elevation until 60°, but increased significantly (p<.001) between 60° and 90°. Significant load related narrowing of the AHI at all positions (p<.05), a more negative SUR at 0° (p<.001) and a more positive SUR at 90° (p=.009) was observed for all subjects. Female athletes had significantly stronger external rotators (p<.001), larger overall AHI (p=.003) and more SUR (p=.008) than untrained females. Significant positive correlations (p<.05) between AHI and SUR were observed at 0°, 30°, and 60° during both loaded and unloaded scaption.

Study Of Microstructure Effect On The Thermal Properties Of Yttria-Stabilized-Zirconia Thermal Barrier Coatings Made By Atmospheric Plasma Spray And Pressing Machine, Monica Bohorquez De Silva

LSU Doctoral Dissertations

Thermal barrier coatings (TBCs) are used in gas turbine engines to achieve a higher working temperature and thus lead to better efficiency. Yttria-Stabilized-Zirconia (YSZ), a material with low thermal conductivity, is commonly used as the top coat layer to provide the thermal barrier effect. In this dissertation the thermo-physical properties of a variety of TBCs samples made out of different fabrication techniques were investigated and compared. The first set of samples was fabricated using a pressing machine device to fabricate 0.5 inch diameter disk shaped YSZ-Al2O3 samples. The YSZ-Al2O3 powder mixture was made of 0, 1, 2, 3, 4 and …

The Influence Of Program Participation In Business Education Courses On Standardized Test Performance Among Secondary Students In Louisiana, Debra A. Wilkerson

LSU Doctoral Dissertations

The primary purpose of this study was to compare the academic achievement, as measured by scores on the English and math portions of the Graduate Exit Examination (GEE), of public high school students in Louisiana by whether or not they were identified as business education students. The GEE is a high-stakes test that is administered to high school students in Louisiana. Students must pass specific portions of the test to obtain a diploma. Academic achievement data on the GEE was obtained from the Louisiana Department of Education. The sample for the study was all 10th and 11th grade students enrolled …

The Effects Of Aging And Unilateral Vestibular Disorders On The Kinematic Performance Of Vestibular Rehabilitation Exercises And Physical Function, Micah Leslie Bradshaw Klumpp

LSU Doctoral Dissertations

The overall purpose of this study was to evaluate the effects of unilateral vestibular disorders and aging on functional performances of activities of daily living and vestibular rehabilitation exercises by examining the correlations among actual and perceived functional measures, the kinematic measurement differences among young healthy adults, older healthy adults, and older adults with unilateral vestibular deficits, and the correlations between kinematic and functional measures. Perceived and actual functional abilities and kinematic variables were compared for young controls, older healthy controls, and patients with unilateral vestibular hypofunction with no previous vestibular rehabilitation. In older adults, better strength, balance, coordination, and …

Relationship Between Dissimilar Cognitive Styles, Use Of Coping Behavior And Use Of Learning Strategies, Chevanese Latoya Samms

LSU Doctoral Dissertations

Research on teacher learning styles and teaching styles have explained that teachers inadvertently mirror their own styles as they teach (Sternberg, 1994; Zhang, 2002) and as such apply teaching strategies that fit personal preference. With this one-style-fits-all approach, students’ individual differences are often ignored and teaching methods are rarely varied to accommodate (McKeachie, 1995) the student. This relationship between one’s preferred style and his or her teaching style may also influence student learning (Zhang, 2001) based on findings which pointed out that students who had similar styles like those of their instructors were more comfortable with the techniques the instructor …

"Do It For Me, My Dear": Structuration And Relational Dialectics Among Mother-Daughter Dyads In Lebanese Arranged Marriages, Khaled Nasser

LSU Doctoral Dissertations

This research applied a two-step triangulation approach to the study of mother-daughter communication in arranged marriages among the religious Sunnis of Beirut, Lebanon. Combining the theory of structuration and relational dialectics in one theoretical framework, the study investigated the role of mother-daughter interactions in the socialization of the daughter into the marital experience. The study investigated the process of marital socialization by first surveying 199 mother-daughter dyads, representing 398 individuals. In the second step, in-depth interviews were conducted with 12 families (three interviews per dyad), randomly selected out of the 199 surveyed pairs. The dyadic data analysis of the surveys …

The Evolution Of Freeze Tolerance In A Historically Tropical Snail, Alice B. Dennis

LSU Doctoral Dissertations

Geographic range differences among species may result from differences in their physiological tolerances. In the intertidal zone, marine and terrestrial environments intersect to create a unique habitat, across which physiological tolerance strongly influences range. The snail Melampus bidentatus occurs in coastal salt marshes in the western Atlantic and Gulf of Mexico. I have used sequence data from one mitochondrial (CO1) and two nuclear markers (histone H3 and a mitochondrial carrier protein, MCP) to identify three cryptic species within Melampus bidentatus, and to infer their relationships to other Melampus. To identify microhabitat differences between two cryptic species, I modeled their distributions …

Quantum Light For Quantum Technologies, William Nicholas Plick

LSU Doctoral Dissertations

In this thesis we will theoretically investigate three potentially useful physical systems, after first developing the theoretical framework necessary for studying them. First, we will study the multiphoton absorption properties of maximally path entangled number (N00N) states. This is directly relevant to quantum lithography, and beating the Rayleigh diffraction limit. Next, we will develop a new scheme for quantum interferometry: dubbed coherent-light boosted super-sensitive quantum interferometry, which has the potential to reach below the shot noise limit for high photon fluxes, and requires no esoteric detection protocol, or technological elements that have yet to be developed. Finally we propose a …

Target Eccentricity Effects For Defensive Responses, Taegyong Kwon

LSU Doctoral Dissertations

Defensive actions involving goal-directed responses to visual stimuli presented in different parts of the viewing field commonly include movements either toward (TOWARD) or away from (AWAY) the actual stimulus. One can categorize the type of defensive movements by outcome or the level of stimulus-response (S-R) compatibility, where a congruent response corresponds to a response in the TOWARD condition and an incongruent response corresponds to a response in the AWAY condition. In an effort to better understand defensive responses, which have received less attention in the literature than offensive movements regardless of their importance in combative situations, we studied the responses …

Computer Simulation Of Ion-Induced Nucleation In The Presence Of Single Ions And Ion Pairs, Samuel Keasler

LSU Doctoral Dissertations

Atmospheric aerosol particles play an important role in climate and human health. Despite their importance, the mechanisms of their formation are still poorly understood. Ion-induced nucleation may play a role in the process, but details are lacking about how the nucleation rate depends on the size, charge, and number of ions in the cluster. In order to better understand the role that ions might play in new particle formation, we have performed a series of AVUS-HR simulations of the water nucleation in the presence of both single ions and ion pairs. These simulations have shown that the location of the …

The Illumination Of E. E. Cummings' Poetry In J. A. C. Redford's "Love Is The Every Only God", Amy Louise Aucoin

LSU Doctoral Dissertations

The choral work love is the every only god, composed by J. A. C. Redford, was published in 2001, placing it among the initial choral concert works published in the twenty-first century. love is the every only god is a song cycle for divisi mixed chorus with piano accompaniment based on six poems by E. E. Cummings. The work is organized into six movements with two interludes and lasts approximately twenty-five minutes. Beyond his regard for the art of poetry and care in choosing a text, Redford sees himself as an illuminator of the text, providing the listener with a …

A Study Of The Interactions Of Lipid Bilayers And Dendrimers Using Small Angle X-Ray Scattering And Freeze Fracture Transmission Electron Microscopy, Derek R. Dorman

LSU Doctoral Dissertations

Lipids are fundamental to all life forms, a key component of cell walls, and essential to proper respiratory function. They are amphiphilic molecules and readily form bilayers. Dendrimers are designer molecules that can be tailored to provide a variety of endgroup moieties, sizes, and charges. The interaction of liposomes and dendrimers can provide information on how medicine interacts with cells and an array of unique structures can be imagined from their assembly into superstructures. Polypropylenimine tetraamine (DAB-Am) and 1-directional arborol dendrimers have been studied in different molar concentrations with 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) bilayers. One-directional arborols are amphiphilic dendrimers with a hydrophilic …

Crossroads And Signposts: The Ada Amendments Act Of 2008, Jeannette Cox

School of Law Faculty Publications

Although the apparent purpose of the 2008 amendments to the Americans with Disabilities Act (ADA) is solely to broaden the ADA 's protected class, the manner in which the amendments achieve this purpose erodes the statute's explicit textual support for understanding persons with disabilities as a politically subordinated minority. The amendments also strengthen the statutory link between the biological severity of a person's disability and that person's right to sue for ADA accommodations. Accordingly, for some courts, the amendments will reinforce the perception that the ADA differs from traditional civil rights law.

Federal courts' understanding of the ADA 's relationship …