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Reactions Of The Solvent-Stabilized Compound [Moocl_2(Thf)_2] With Aromatic Nitrogen Donor Ligands: Spectroscopic Characterization And Semiempirical Am1* Calculations, Gülşah Kiliçkaya, Başak Doğan, Nursel Acar, Işil Topaloğlu Sözüer

Turkish Journal of Chemistry

Reaction of the solvent-stabilized dioxo-molybdenum(VI) compound [MoO_2Cl_2(THF)_2] with PPh_3 yielded the oxomolybdenum(IV) species [MoOCl_2(THF)_2] (1) by the removal of one oxygen atom as PPh_3O. The complexes [MoOCl_2(=NC_6H_4CN)] 2, [MoOCl_2(CNC_6H_4OH)] 3, [MoOCl_2(=NC_6H_4NH_2)] 4, and [MoOCl_2(=NC_6H_4OCH_3)] 5, were synthesized by the reactions of [MoOCl_2(THF)_2] with XC_6H_4Y (X = NH_2, Y = CN; X= CN, Y = OH; X = Y = NH_2; X = NH_2, Y = OCH_3). All the new compounds were characterized by elemental analyses, and FTIR, UV-Vis, and ^1H- and ^{13}C-NMR spectra. Geometrical parameters and molecular orbital calculations showed that compounds 2-5 are stabilized by a charge transfer between …

A Simple Spectrophotometric Method For The Determination Of Iron(Ii) Aqueous Solutions, M. Jamaluddin Ahmed, Uttam Kumer Roy

Turkish Journal of Chemistry

An ultra-sensitive and highly selective non-extractive spectrophotometric method is presented for the rapid determination of iron(II) at trace levels using 2', 3, 4', 5, 7-Pentahydroxyflavone (morin) as a new spectrophotometric reagent in slightly acidic solution (0.0001-0.0002 M H_2SO_4). The reaction is instantaneous and absorbance remains stable for over 24 h (\lambda_{max} = 415 nm). The molar absorptivity was found to be 6.85 \times 10^4 L mol^{-1} cm^{-1}. Linear calibration graphs were obtained for 0.01-10 \mu g mL^{-1} of Fe^{II}. The stoichiometric composition of the chelate is 1:2 (Fe:morin). Large excesses of over 50 cations, anions, and complexing agents (e.g., tartrate, …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

A Highly Soluble Asymmetric Perylene-Bis (Dicarboximide)-Acceptor System Incorporating A Methylene Bridged Methoxybenzene-Donor: Solvent Dependence Of Charge Transfer Interactions, Rene M. Williams

Turkish Journal of Chemistry

The synthesis and photophysical properties of an asymmetrically substituted perylene-bis(dicarboximide), (PDI), system (1) containing a methylene bridged 4-methoxy-benzene donor and a solubilizing branched C_{13} alkyl chain are described. As compared to most PDIs, the fluorescence of 1 is strongly quenched in polar (but not in non-polar) solvents due to a photo-induced electron transfer process. Transient absorption spectroscopy and time resolved emission in e.g. acetonitrile indicates that upon excitation the radical anion of the PDI is formed with a rate of ca. 3.5 \times 10^9s^{-1}, and the charge transfer state has a lifetime of ca. 3 ns. A Frontier Molecular Orbital …

A Study Of Growth And Breakdown Of Passive Film On Copper Surface By Electrochemical Impedance Spectroscopy, Amtul Naseer, Athar Yaseen Khan

Turkish Journal of Chemistry

Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry were used to investigate the oxide layer formed on a copper disc electrode and the changes that took place when treated potentiostatically in the range of -0.3 V to 0.9 V in aqueous buffer solution of pH 9.2. Equivalent circuits were used to model the response of the electrode, initially at equilibrium to an applied potential. These circuits were proposed for different potential ranges in order to illustrate the Cu/oxide/electrolyte system and its properties in terms of 2 interfaces. A criterion for the applicability of equivalent circuit models was discussed. Changes in the …

A Simple And Efficient One-Pot Multicomponent Synthesis Of \Beta-Acetamido Carbonyl Compounds With Zn(Hso_4)_2 And Co(Hso_4)_2 As Catalysts, Ahmad Reza Momeni, Maryam Sadeghi, Motahareh Hadizadeh

Turkish Journal of Chemistry

Zn(HSO_4)_2 and Co(HSO_4)_2 has been used as efficient catalysts for the preparation of \beta-acetamido carbonyl compounds by Dakin-West reaction.

Electrochemical And Optical Properties Of An Azo Dye Based Conducting Copolymer, Ati̇lla Ci̇haner, Fati̇h Algi

Turkish Journal of Chemistry

The electrochemical and optical properties of a novel conducting copolymer called poly(2,5'-dimethyl-[4-(2,5-di-thiophen- 2-yl-pyrrol-1-yl)-phenyl]azobenzene-co-(3,4-ethylenedioxythiophene)) (poly(1-co-EDOT)) are reported. Electrochemically synthesized poly(1-co-EDOT) based on the azo dye has a well-defined and reversible redox couple (0.37 V vs. Ag/AgCl) with good cycle stability. The copolymer film exhibits high conductivity (13 S/cm) as well as electrochromic behavior (magenta when neutralized and transmissive sky blue when oxidized). Furthermore, electro-optically active copolymer film has a low band gap of 1.79 eV with a \pi-\pi* transition at 555 nm.

An Efficient One Pot Synthesis Of 1,4-Dihydropyridines Using Alumina Sulfuric Acid (Asa) Catalyst, Mustafa Arslan, Cüneyt Faydali, Mustafa Zengi̇n, Mustafa Küçüki̇slamoğlu, Hülya Demi̇rhan

Turkish Journal of Chemistry

An efficient synthetic method for 1,4-dihydropyridines has been developed using 3 or 4 component condensation reactions of aldehydes, 1,3-dicarbonyl compounds, and ammonium acetate in the presence of alumina sulfuric acid catalyst in minimum methanol at reflux temperature. This procedure offers several advantages including high yields, an environmentally friendly procedure, short reaction times, and a simple work-up procedure.

Synthesis, Characterization, And Antibacterial Activity Of Some Transition Metals With The Schiff Base N-(2-Furanylmethylene)-3-Aminodibenzofuran, Aurora Reiss, Stelian Florea, Theodor Caproiu, Nicolae Stanica

Turkish Journal of Chemistry

This paper presents the structure and antibacterial properties of some complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) with a new Schiff base N-(2-furanylmethylene)-3- aminodibenzofuran. The structure of each complex was characterized by spectroscopic methods (IR, UV-Vis, ^1H-NMR, and ESR), conductometric and magnetic data, and thermogravimetric and elementary analysis. According to these data, we propose an octahedral geometry for Co(II), Ni(II), and Cu(II) complexes, and a tetrahedral geometry for Zn(II), Cd(II), and Hg(II) complexes. Antibacterial activity of the ligand and its complexes was tested against selected bacteria. The ligand and all the complexes possess antimicrobial activity, and antimicrobial activity …

Preparation And Characterization Of Magnetic Chitosan Nanospheres, Doina Hritcu, Marcel I. Popa, Nuculina Popa, Vasile Badescu, Vera Balan

Turkish Journal of Chemistry

A method for the preparation of magnetite/chitosan composite nanoparticles was developed. Colloidal magnetite particles (Fe_3O_4 produced by co-precipitation and stabilized in suspension by adding a non-ionic surfactant (Pluronic F127) were subsequently covered with a layer of chitosan (CS) prepared by ionotropic gelation using sodium tripolyphosphate (STPP) as a crosslinking agent. The products were characterized in terms of the following parameters: size distribution and \zeta-potential (by laser diffraction analysis), surface morphology (TEM), composition (FTIR, elemental analysis), magnetic properties (magnetic susceptibility analysis), and concentration of surface functional groups (potentiometric titration). The synthesis parameters were optimized for obtaining uniformly distributed colloidally stable, biocompatible …

Three-Component Process For The Synthesis Of Some Pyrrole Derivatives Under Microwave Irradiation, Farhad Hatamjafari, Nasser Montazeri

Turkish Journal of Chemistry

We report a short and efficient 3-component reaction for synthesis of a series of [1,2-b]pyrrole derivatives from ninhydrin, alkyl propiolates, and simple primary amines under solvent free and microwave irradiation. This method provides a new route to produce pyrrole derivatives in good to excellent yields.

4h-Pyran-4-One Derivatives:; Leading Molecule For Preparation Of Compounds With Antimycobacterial Potential, Demet Us, Ece Gürdal, Barkin Berk, Si̇nem Öktem, Tanil Kocagöz, Berrak Çağlayan, Işil Aksan Kurnaz, Di̇lek Demi̇r Erol

Turkish Journal of Chemistry

A series of 3-hydroxy-6-methyl-2-((4-substitutedpiperazin-1- yl)methyl)-4H-pyran-4-one structured compounds were synthesized by reacting 5-hydroxy-2-methyl-4H-pyran-4-one with suitable piperazine derivatives using Mannich reaction conditions. Antibacterial activities of the compounds for E. coli, S. paratyphi, S. flexneri, E. gergoviae, and M. smegmatis were assessed in vitro by using broth dilution for determination of the minimum inhibitory concentration (MIC). In addition, their inhibitory effects over DNA gyrase enzyme were evaluated using a DNA gyrase supercoiling assay. Among the synthesized compounds; compound 7 showed a 4 \mu g/mL MIC value for M. smegmatis, whereas the other compounds demonstrated moderate to high activity. Those tested in the supercoiling …

Antioxidant And Anticholinesterase Constituents Of Salvia Poculata, Ufuk Kolak, Işil Hacibeki̇roğlu, Mehmet Öztürk, Fevzi̇ Özgökçe, Gülaçti Topçu, Ayhan Ulubelen

Turkish Journal of Chemistry

Two triterpenoids, namely 2\alpha,3\alpha-dihydroxy-24-nor- 4(23),12-oleanadien-28-oic acid (1) and ursolic acid (2); 4 flavonoids, namely 5-hydroxy-7,4'-dimethoxyflavone (3), cirsimaritin (4), eupatilin (5), and salvigenin (6); a diterpenoid, namely sclareol (7); and a steroid, namely \beta-sitosterol (8), were isolated from the aerial parts of Salvia poculata Nab., a Turkish endemic Salvia species. Total phenolic and flavonoid contents of the crude extract were determined as pyrocatechol and quercetin equivalents, respectively. The antioxidant activity of the crude extract and the isolated compounds (2-8) was established using \beta-carotene bleaching, superoxide anion radical, and ABTS cation radical scavenging activity. In addition, the anticholinesterase activity of the crude …

Partial Regeneration Of Ni-Based Catalysts For Hydrogen Production Via Methane Cracking Part Ii: Modeling And Optimization, Reyyan Koç, Erdoğan Alper, Eric Croiset, Ali Elkamel

Turkish Journal of Chemistry

High purity, carbon monoxide-free hydrogen and filamentous carbon can be produced by thermo-catalytic cracking of methane. Carbon filaments continue to grow until the catalyst deactivates because of carbon encapsulation. Regeneration of catalyst is important to maintain a continuous process. Our work on optimization of the partial regeneration method showed that activity of the catalyst can be sustained for longer times by gasifying not all but some extent of the deposited carbon. In the previous work, a kinetic model was developed to be able to understand the reaction mechanism of deactivation of fresh catalyst at the molecular level. The objective of …

Pore Structure And Surface Acidity Evaluation Of Fe-Pilcs, Suna Balci, Eli̇f Gökçay

Turkish Journal of Chemistry

Fe-PILCs via different conditions using smectites from Hancili (Turkey) and Wyoming (USA) were synthesised. Presaturation had little effects on the basal spacing values while it had important effects on thermal stabilities of the products. Products having basal spacing (d_{001}) around 1.30 nm and surface area up to 160 m^2 g^{-1} were obtained. The thermal behaviour, X-ray diffraction (XRD) patterns, and nitrogen adsorption/desorption experiments confirmed that thermally stable and micro-mesoporous products were obtained although at elevated calcination temperature. Delaminated sample with basal spacing value of 2.79 nm was obtained. Surface acidity of clay was enhanced by pillaring. Chemically sorbed pyridine Fourier …

Synthesis And Single Crystal Structure Analysis Of Three Novel Benzoylthiourea Derivatives, Gülten Kavak, Süheyla Özbey, Gün Bi̇nzet, Nevzat Külcü

Turkish Journal of Chemistry

N,N-dimethyl-N' -(2-methylbenzoyl)thiourea, C_{11}H_{14}N_2SO (HL^1), N,N-dibutyl-N' -(2-methylben\-zoyl)thiourea, C{17}H{26}N2SO (HL^2), and N,N-dihexyl-N' -(2-methylbenzoyl) thiourea, C{21}H{34}N2SO (HL^3) were synthesized and characterized by elemental analysis, spectroscopic methods (FT-IR, NMR), and single crystal X-ray diffraction. Compound HL^1 crystallizes in the monoclinic system, space group P21/c, Z = 4. Compound HL^3 also crystallizes in the monoclinic system, space group P21/n, Z = 8 with 2 independent molecules in the asymmetric unit. Compound HL^2 crystallizes in the orthorhombic system, space group Pcnn, Z = 8. In all compounds, molecules form dimers through the strong intermolecular N-H...S hydrogen bonds. Moreover, there are different types of intra- and inter-molecular …

Cover And Contents

Turkish Journal of Chemistry

No abstract provided.

Barriers Encountered During Enrollment In An Internet-Mediated Randomized Controlled Trial, Lorraine R. Buis, Adrienne W. Janney, Michael L. Hess, Silas A. Culver, Caroline R. Richardson

Wayne State University Associated BioMed Central Scholarship

Abstract

Background

Online technology is a promising resource for conducting clinical research. While the internet may improve a study's reach, as well as the efficiency of data collection, it may also introduce a number of challenges for participants and investigators. The objective of this research was to determine the challenges that potential participants faced during the enrollment phase of a randomized controlled intervention trial of Stepping Up to Health, an internet-mediated walking program that utilized a multi-step online enrollment process.

Methods

We conducted a quantitative content analysis of 623 help tickets logged in a participant management database during the enrollment …

The Believing Game In Mathematics: Stories In A Discipline Of Doubt, Shelly Sheats Harkness, Catherin Pullin Lane, Sue Mau, Amber Brass

The Journal of the Assembly for Expanded Perspectives on Learning

Many people view mathematics as a discipline of certainty and rigidity. Answers are either right or wrong, and, when they are wrong, it is easy to play the doubting game. We invite readers into our mathematics classrooms as we story our attempts to play the believing game. We provide a lens into how we suspended our own logic, assumptions, and interpretations until we first tried to "unpack, " understand, and honor our students' logic, assumptions, and interpreta· tions. Within our individual stories, elements of tension, surprise, and wonder emerged as collective themes.

Tau Sleptons And Tau Sneutrino Decays In Mssm Under The Cosmological Bounds, Levent Selbuz, Z. Zekeri̇ya Aydin

Turkish Journal of Physics

We present a numerical investigation of the fermionic two-body decays of tau sleptons \tilde \tau_{1,2} and \tau sneutrino in the Minimal Supersymmetric Standard Model with complex parameters. In the analysis we particularly take into account the cosmological bounds imposed by WMAP data. We plot the CP-phase dependences for each fermionic two-body channel of \tilde \tau_{1,2} and \tau sneutrino and speculate about the branching ratios and total (two-body) decay widths. We find that the phase dependences of the decay widths of the third family sleptons are quite significant which can provide viable probes of additional CP sources. We also draw attention …

Development Of New Chiral Selectors For Liquid Chromatography And Their Performance Relative To Established Chiral Stationary Phases (Csps), Ping Sun

Chemistry & Biochemistry Dissertations - Archive

HPLC with chiral stationary phases (CSPs) has proven to be the most widely applicable and versatile technique for enantiomeric separations. This dissertation discusses new research in three important areas of enantiomeric separations: HPLC method developments for target chiral analytes using the existing CSPs, mechanistic investigations by NMR, and development of new HPLC CSPs. Two classes of commercial chiral stationary phases (cyclodextrin-type and macrocyclic glycopeptide-type) were evaluated by separating specific groups of chiral analytes, including β-lactam compounds and ruthenium(II) polypyridyl complexes. The effects of chiral selector structures, mobile phase compositions, and analyte structures have been examined. For Ru(II) complexes, the newly …

Graduate Catalog And Student Handbook 2009-2010, Nova Southeastern University

Abraham S. Fischler College of Education and School of Criminal Justice Graduate Course Catalogs

No abstract provided.

Effective Practices In Undergraduate Stem Education Part 1: Examining The Evidence, Labov B. Jay, Susan R. Singer, Melvin D. George, Heidi A. Schweingruber, Margaret L. Hilton

Biology Faculty Work

No abstract provided.

Collaboration, Commitment, And Communication: Tales From The Road Of Continuous Performance Improvement, M. Therese Antone, Rsm

Faculty and Staff - Articles & Papers

Performance in higher education is strongly tied to accountability—accountability that goes beyond financial matters and includes assessment of academic achievement. The demands of accountability, both from the faculty and from the institution, are critical performance requirements for the higher education industry. In the past, institutional performance or success was very often measured by endowment, the number of student applications, the rate of matriculation from that application pool, and the graduation rate. Higher education has moved far beyond that for a real assessment of performance.

General Education Survey Of Graduating Seniors: Trends 2002-2009, Umm Institutional Research

Assessment of Student Learning Reports

No abstract provided.

Biology Discipline Assessment Report Spring 2009, Biology Discipline

Assessment of Student Learning Reports

No abstract provided.

Biology Discipline Assessment Plan 2009, Biology Discipline

Assessment of Student Learning Reports

No abstract provided.

Salt River Basin, Daniel I. Carey

Map and Chart--KGS

The Salt River Basin and adjacent Ohio River drainages include over 4,150 square miles in all or parts of 19 counties. The basin contains more than 9,600 miles of streams.

Over 660 miles of streams assessed in the basin by the Kentucky Division of Water do not support designated uses for warm-water aquatic habitat, fish consumption, or primary contact recreation (swimming). Not all streams have been assessed. The percentage of assessed streams not supporting uses was: warm-water aquatic habitat (38 percent); fish consumption (36 percent); primary contact recreation (86 percent). Over 100 miles of streams have been declared special use …

Big Sandy/Little Sandy And Tygarts Creek Basins, Daniel I. Carey

Map and Chart--KGS

Nearly 7,600 miles of streams flow through the basin's 3,440 square miles in 14 counties to the Tug Fork, Big Sandy River, and Ohio River. The Tygarts Creek–Little Sandy River Basin includes 1,160 square miles. The Big Sandy River Basin has 2,285 square miles in Kentucky and 1,950 square miles in West Virginia and Virginia. There are nearly 17,000 acres of wetlands, including water bodies.

Residents draw about 27 million gallons of water per day (mgd) from streams and reservoirs in the basin. About three in five residents are on public water; other households rely primarily on domestic wells. Only …

Kentucky River Basin, Daniel I. Carey

Map and Chart--KGS

The Kentucky River Basin's nearly 7,000 square miles in 42 counties contain 16,000 miles of streams. From a hill in Letcher County 3,250 feet above sea level, and the Kentucky River runs down the Eastern Kentucky Coal Field, Knobs, and Bluegrass Regions to the Ohio River at 420 feet above sea level.

Along the way the river washes rocks laid down as sediments over a period of 150 million years—past the 300-million-year-old sandstone, siltstone, shale, and Camp Nelson limestones at the base of the Kentucky River Palisades in central Kentucky.

Residents draw about 100 million gallons of water per day …