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Examining The Evolution Of Phosphagen Kinases: A Study Of A Dimeric Arginine Kinase From Sea Urchin (Strongylocentrotus Purpuratus) Eggs, Brenda Christine Held

USF Tampa Graduate Theses and Dissertations

The phosphagen kinases are a family of enzymes that catalyze the reversible phosphorylation of specific phosphagens using ATP as the phosphate donor. The evolutionary relationships between the enzymes in this family have been studied for over 30 years and yet aspects of the relationships remain unclear. Here, arginine kinase from Strongylocentrotus purpuratus eggs was purified to homogeneity and analyzed for physical and kinetic characteristics as well as its sequence homology with other phosphagen kinases. The results indicate that dimeric arginine kinase from S. purpuratus eggs evolved from a dimeric creatine kinase after dimeric creatine kinase evolved from a monomeric arginine …

Development Of Biocompatible Multi-Drug Conjugated Nanoparticles/Smart Polymer Films For Biomedicinal Applications, Kerriann R. Greenhalgh

USF Tampa Graduate Theses and Dissertations

It has been reported by the American Burn Association that 4,000 people die every year due to burn injury. After survival of the initial trauma, the next major obstacle that must be overcome is combating bacterial infection, the primary cause of mortality for burn victims (Chapter 1). The polyacrylate nanoparticle drug delivery system was created to provide a water-based solution for delivery of highly lipophilic antimicrobials; such as N-thiolated β-lactams, however, with the success of this system for these antimicrobials, it was extended towards other, commercially-available water-soluble antimicrobials through acrylation of the drug monomers, including those with observed bacterial resistance …

The Relationships Between Students’ Perceptions Of School Climate, Attitudes Towards School, And Substance Use Among Early Adolescents, Jason D. Hangauer

USF Tampa Graduate Theses and Dissertations

This study investigated the relationships between early adolescent substance use and perceptions of school climate and attitudes towards school using self-report data from a sample of 443 middle school students. The present study examined school climate and attitudes towards school comprehensively in order to identify important relationships between these classes of variables and multiple types of substance use in early adolescents. The results of the study include that the model of school climate consisting of six factors (fairness, order and discipline, parental involvement, sharing or resources, student interpersonal relations, and student-teacher relations) accurately predicted 11% of the variance in middle …

Essays On Multiple Identities And Motivated Consumption: Exploring The Role Of Identity Centrality On Self-Brand Connections, Tracy R. Harmon

USF Tampa Graduate Theses and Dissertations

This dissertation consists of three essays on the role of identity centrality in the formation of consumer self-brand connections. It contributes to a better understanding of how consumers negotiate multiple identities in the marketplace when making brand choices. This is significant as much of the research on the self-concept and consumer behavior has focused on isolated self-dimensions or have examined single consumer identities in isolation.

Theoretically grounded in identity process theory (Breakwell 1986), which suggests individuals construct their identity through multiple identity motives influencing identity centrality, enactment, and affect; this dissertation addresses these gaps by answering two specific questions: 1) …

Barium Strontium Titanate Films For Tunable Microwave And Acoustic Wave Applications, Venkataramanan Gurumurthy

USF Tampa Graduate Theses and Dissertations

The composition-dependent Curie temperature and bias-dependant dielectric permittivity of Barium Strontium Titanate (BST) makes it very attractive for tunable application in the RF/Microwave regime. In this research work, the performance of BST varactors fabricated on the conventional Pt/Ti/SiO2/Si bottom electrode stack were compared with those fabricated using chemical vapor deposited Nanocrystalline Diamond (NCD) as the diffusion barrier layer instead of SiO2. The varactors fabricated on NCD films displayed much better symmetry in capacitance-voltage behavior and better overall quality factors than varactors fabricated on SiO2. The improvement in performance can be attributed to existence of stable interfaces in the devices fabricated …

A Gis-Based Inventory Of Terrestrial Caves In West-Central Florida: Implications On Sensitivity, Disturbance, Ownership, And Management Priority A Gis-Based Inventory Of Terrestrial Caves In West-Central Florida: Implications On Sensitivity, Disturbance, Ownership, And Management Priority, Grant L. Harley

USF Tampa Graduate Theses and Dissertations

Active cave management, which represents any continuous action to conserve, restore, or protect a cave environment, is virtually non-existent in west-central Florida. This study focuses on developing an inventory to rank terrestrial caves in west-central Florida by management priority. A GIS-based cave inventory system, including a cave sensitivity index and cave disturbance index, were used as a tool to gain an understanding of the management priority of west-central Florida caves. The inventory was applied to 36 terrestrial caves in west-central Florida, which demonstrated a wide range of sensitivity and disturbance. The results show that by relying solely on sensitivity and …

Marriage, Sin And The Community In The Register Of John Chandler, Dean Of Salisbury 1404-17, Byron J. Hartsfield

USF Tampa Graduate Theses and Dissertations

Marriage is a subject of great interest to the social historian. However, the marriage of the average medieval English villager is very poorly documented, as it bears little obvious relationship to the great affairs of state. Searching for information on such difficult subjects, many social historians have recently turned to legal records, learning to sift them for the intimate details of daily life. The Register of John Chandler, Dean of Salisbury 1404-17 preserves a rich variety of cases presented to the church courts of early fifteenth-century Salisbury. The questmen, selected from the most respectable men of each village, presented to …

Le Christianisme « Marginal » Chez Chrétien De Troyes: L’Hérésie Dans Perceval, Melanie Anne Hackney

USF Tampa Graduate Theses and Dissertations

Our perception of the Holy Grail is, for the most part, the result of orthodox views that have dominated literary interpretation. However, the first appearance of the Holy Grail in literature does not conform to the orthodox rules and traditions. In fact, the narrative of Perceval is filled with evidence that points to a very different form of Christianity, one that would have been considered heretical at the time that Chrétien de Troyes was writing it. The twelfth century in France is often called the "Golden Age" of heresies. As Manichaeism and Bogolism swept through the country, they gave birth …

Implementing Differentiated Instruction In Urban, Title I Schools: Effects Of Facilitated Support Groups And Program Fidelity On Student Achievement, Deborah W. Hellman

USF Tampa Graduate Theses and Dissertations

This study presents the results of a mixed methodology study and pilot that investigated the effects of facilitated teacher support groups and differentiated instruction on student achievement at two urban, Title I middle schools. Both general education and students with special needs being served in a collaborative co-taught setting were included in the study. Implications for research to practice and effective inclusive strategies were addressed and the field-tested Differentiated Instruction: Fidelity Implementation Tool (DI: FIT) used to assess teacher fidelity is included. During the first year, the principal investigator developed and field-tested the DI: FIT observation tool, field-tested a facilitated …

The Effectiveness And User Perception Of 3-Dimensional Digital Human Anatomy In An Online Undergraduate Anatomy Laboratory, Amy Joanne Hilbelink

USF Tampa Graduate Theses and Dissertations

The primary purpose of this study was to determine the effectiveness of implementing desktop 3-dimensional (3D) stereo images of human anatomy into an undergraduate human anatomy distance laboratory. User perceptions of 2D and 3D images were gathered via questionnaire in order to determine ease of use and level of satisfaction associated with the 3D software in the online learning environment. Mayer's (2001, p. 184) principles of design were used to develop the study materials that consisted of PowerPoint presentations and AVI files accessed via Blackboard. The research design employed a mixed-methods approach. Volunteers each were administered a demographic survey and …

Mathematical Techniques For The Estimation Of The Diffusion Coefficient And Elimination Constant Of Agents In Subcutaneous Tissue, Lawrence T. Hersh

USF Tampa Graduate Theses and Dissertations

The purpose of this work was to develop methods to estimate the diffusion coefficient and elimination constant for dexamethasone in subcutaneous tissue. Solutions to the diffusion equation were found for different conditions relevant to implantation and injection. These solutions were then used as models for measured autoradiography data where the unknown model parameters were the diffusion coefficient and the elimination constant. The diffusion coefficient and elimination constant were then estimated by curve fitting the measured data to these models. Having these estimates would be of practical importance since inflammation surrounding implantable glucose sensors may be controlled through local release of …

A Paradox Of Diversity: Billions Invested, But Women Still Leave, Rebekah S. Heppner

USF Tampa Graduate Theses and Dissertations

In 2005, women made up 46.4 percent of the United States labor force but only 1.6 percent of Fortune 500 CEOs (Catalyst 2006). Although gains have been made since the passage of the Civil Rights Act in 1964, there is clearly something stopping women from equal representation at the top. Since the late 1980s, businesses have spent billions of dollars on initiatives designed to assist them in dealing with the anticipated increase in the "diversity" of their workplaces (Lubove 1997; Stodghill II 1996; Johnston and Packer 1987). Is there potential for diversity initiatives to help women conquer the "glass ceiling?" …

Numerical Analysis Of Heat Transfer During Jet Impingement On Curved Surfaces, Cesar F. Hernandez-Ontiveros

USF Tampa Graduate Theses and Dissertations

The flow structure and convective heat transfer behavior of a free liquid jet ejecting from a round nozzle impinging vertically on a hemispherical solid plate and a slot nozzle impinging vertically on a cylindrical curved plate have been studied using a numerical analysis approach. The simulation model incorporated the entire fluid region and the solid hemisphere or curved plate. Solution was done for both isothermal and constant heat flux boundary conditions at the inner surface of the hemispherical plate and the constant heat flux boundary condition at the inner surface of the cylindrical shaped plate. Computations for the round nozzle …

Development Of A Method To Determine Vapor Pressure Data Of Low Volatile Chemicals From A Knudsen Effusion Technique, Andrew R. Harshman

USF Tampa Graduate Theses and Dissertations

Vapor pressure data are vital to understanding impacts that substances, specifically pesticides, may exert on the environment. They enter into atmospheric deposition models for such chemicals which determine the fate and transport of these species in the environment. At normal application temperatures (i.e. room temperature) the vapor pressures of many of these chemicals are too low to be determined by conventional means. An isothermal Knudsen effusion technique was designed and developed in our laboratory for such measurements. The effusion mass as a function of time is measured in our technique using a thickness shear mode (TSM) acoustic wave sensor, which …

Modeling Larval Connectivity Among Coral Habitats, Acropora Palmata Populations, And Marine Protected Areas In The Florida Keys National Marine Sanctuary, Christopher John Higham

USF Tampa Graduate Theses and Dissertations

The Florida Keys National Marine Sanctuary (FKNMS) encompasses North America's only living coral barrier reef and the third longest barrier reef in the world, making it a unique national treasure of international notoriety (FKNMS, 2005). Recent evidence of environmental decline within the sanctuary has created a sense of urgency to understand and protect the valuable resources within. This thesis contributed to the understanding of habitat connectivity to aid managers and decision makers in the creation of additional Marine Protected Areas (MPAs) in the FKNMS to help prevent further environmental decline. This research specifically focused on modeling larval transport and larval …

The Association Between Internet Use And Characteristics Of Social Networking For Middle Aged And Older Adults, David L. Hogeboom

USF Tampa Graduate Theses and Dissertations

BACKGROUND: Studies have shown that strong social networks have a positive effect on physical and psychological well-being. Research suggests that Internet use may affect social networks. However it is not clear if Internet use has a positive or negative effect on social networks. One theory suggests that Internet use displaces face-to-face contacts and off line social participation. Another theory suggests Internet use replaces high quality face-to-face ties with weaker online ties. Other studies however suggest the Internet has a positive effect on social networks. Because older adults have shrinking social networks, but may have more discretionary time than other age …

The Impact Of Reward Power On Creativity: Does It Depend On The Nature Of The Reward?, Edward Rickamer Hoover

USF Tampa Graduate Theses and Dissertations

This experiment investigated the influence of reward property and reward power on creative performance. It was hypothesized that the magnitude of reward power would moderate the relationship between reward property and creativity. Fifty undergraduate students (45 females, 5 males, X age = 20.72 years, SD age = 4 years) participated. The experimental design was reward power ($0.00, $0.50, or $2.00 per trial) x reward property (informational vs. controlling undertones in the script) x trials (5). Results demonstrated a positive correlation between intrinsic motivation and creative performance (r = .411, p = .03, n = 50). Hypotheses concerning the moderating influence …

Numerical Modeling And Simulation For Analysis Of Convective Heat And Mass Transfer In Cryogenic Liquid Storage And Hvac&R Applications, Son Hong Ho

USF Tampa Graduate Theses and Dissertations

This work presents the use of numerical modeling and simulation for the analysis of transport phenomena in engineering systems including zero boil-off (ZBO) cryogenic storage tanks for liquid hydrogen, refrigerated warehouses, and human-occupied air-conditioned spaces. Seven problems of medium large spaces in these fields are presented. Numerical models were developed and used for the simulation of fluid flow and heat and mass transfer for these problems. Governing equations representing the conservation of mass, momentum, and energy were solved numerically resulting in the solution of velocity, pressure, temperature, and species concentration(s). Numerical solutions were presented as 2-D and 3-D plots that …

A Case Study Of Governance Of Higher Education In Belize: Implications For Finance And Curricula In Higher Education, Olda R. Hoare

USF Tampa Graduate Theses and Dissertations

The purpose of this case study was to understand governance of higher education in the developing country of Belize by examining how governance affects financial and curricular decision-making in higher education in Belize. The study also examined the role of the market in higher education and its effects on curricular and financial decision-making in higher education. Data were collected from higher education administrators and Ministry of Education officials through semi-structured interviews, and from review of institutional and public documents related to higher education. A major finding of this study is that although the Ministry of Education through the Tertiary and …

The Pedagogy And Politics Of Online Education In Anthropology, Linda J. Hose

USF Tampa Graduate Theses and Dissertations

This dissertation reports on the key findings of an exploratory study of online education in anthropology. The study was designed to collect information on the extent and types of online offerings at four-year and above degree-granting public institutions in the US. It was also designed to report on the teaching strategies and methods that anthropologists employ online, and to inquire into the conditions and institutional structures that encourage or discourage the development of online education in anthropology. Recent growth in online education has been explosive in many disciplines, but little is known about anthropology's participation in the trend, or lack …

Attitudinal Factors Related To Driving Behaviors Of Young Adults In Belize: An Application Of The Precaution Adoption Process Model, Ismael A. Hoare

USF Tampa Graduate Theses and Dissertations

Young adults' risk-taking attitudes, risk perception, and knowledge of road laws and signs influence their driving behaviors. The adoption of risky driving behaviors increases young adults' risk of motor vehicle crashes. The purpose of this study was to increase the understanding of the factors that lead to increased risks of MVC-related mortality and morbidity for young adults in Belize, to provide support for the development of evidence-based programs, and, more importantly, to investigate the relationships involving young adults' risk-taking attitudes, risk perception, and knowledge of road laws and signs and their relation to driving behaviors. The Precaution Adoption Process Model …

Antibody Targeting Of Non Ionic Surfactant Vesicles To Vascular Inflammation, Elizabeth D. Hood

USF Tampa Graduate Theses and Dissertations

Cardiovascular disease (CVD) and particularly atherosclerosis is a leading cause of morbidity in the developed world. Atherosclerosis and the rupture of vulnerable atherosclerotic plaque cause 70% of deaths from CVD. The progression of atherosclerosis has been identified as a pathological inflammatory process. Targeting atherosclerotic drug therapies to inflammatory markers has emerged as an important and growing research area. The adhesion molecule CD44 has been implicated in the onset and build-up of atherosclerotic lesions throughout the course of development. The research in this dissertation is aimed at targeting anti-inflammatory therapy to activated vascular endothelium with directed with an anti-CD44 antibody, IM7, …

High-Stakes Testing In Florida: Media Portrayals And Parental Realities, Jennifer Gilroy Hunsecker

USF Tampa Graduate Theses and Dissertations

In 1998, Florida implemented a system of standardized testing known as the Florida Comprehensive Assessment Test (FCAT). While initially designed as one among many tools to assess student and school progress, the FCAT has become a high-stakes test. Schools whose students fail to meet certain benchmarks are in danger of losing their students to "school choice plans" (which enable parents of children attending failing schools to choose another, more highly rated school) while parents must contend with ever broadening educational policies. The implications of this policy have been far reaching. Textbook makers now market individualized textbooks that teach FCAT content, …

(Dis)Continuity Between Sikhism And Islam: The Development Of Hukam Across Religions, Mark Horowitz

USF Tampa Graduate Theses and Dissertations

The purpose of this study is to analyze the development of the Sikh concept of hukam, which is usually translated as a divine command or order. The concept is prominently featured in the Sikh sacred scripture (Guru Granth) and is an important aspect of daily ritual life for the Sikhs. The goal of this study is to provide initial insight into how the concept developed in the Sikh scriptural tradition, as well as the implications that the concept had for the Sikh community. This paper traces the development of hukam from the concepts origin in the Islamic tradition, the writings …

A Revitalization Strategy For Central New York United Methodist Churches, Robert J. Norrix

ATS Dissertations

No abstract provided.

Raman Spectroscopy Of Inas/Gaas Quantum Dots Patterned By Nano-Indentation, Lindsay K. Hussey

USF Tampa Graduate Theses and Dissertations

Patterns of InAs/GaAs quantum dots (QDs) grown by the combination of nanoindentation technique and molecular beam epitaxy were studied. The resulting QDs tend to preferentially nucleate on indented areas rather than other regions. We studied the strain on the indentations, regions surrounding the indents, and non-indented areas. The QD LO mode for the patterned areas shifts by 7 cm-1 when compared to the non-patterned area. The biaxial strain in the indented areas producing this shift is four times larger than that in non-indented areas, explaining the QD preferential formation within these areas. This larger strain suggests that QDs on the …

The Development Of Leadership Skills Through Diversity Of Student Organizational Leadership, Daniel M. Jenkins

USF Tampa Graduate Theses and Dissertations

The steady increase of racial and ethnic diversity in public universities has provided student leaders with many challenges. However, little is known about the effects of racial and ethnic diversity on the development of these student leaders. This study aims to evaluate the effects of racial and ethnic diversity in college student organizations on the development of student leaders and the perceived value of such diversity on their development. The sample consists of 833 student leaders from Florida's ten public universities who completed online surveys. The questions asked were designed to evaluate their past and present leadership roles and skills, …

Numerical Simulation Of Steady State And Transient Heat Transfer In Microchannels, Phaninder Injeti

USF Tampa Graduate Theses and Dissertations

In this project we studied the effect of different parameters on heat transfer in two-dimensional microchannels, microtubes and also tube-in-block heat exchangers for various engineering applications. These included the use of flow restrictions to enhance local heat or mass transfer rate, enhancement of conjugate heat transfer with discrete heating and magnetic coolers (or heaters) associated with magnetic refrigeration system. The results of this research will help in designing the heating or cooling systems and selection of their appropriate geometrical dimensions and materials for specific applications. Types of problems studied in this project are: steady state analysis of forced convection around …

Virtue And Inquiry, Knowledge And Ignorance: Lessons From The Theaetetus, Jennifer F. Ingle

USF Tampa Graduate Theses and Dissertations

Plato's dialogues are set in fifth century Athens but they are performed for a fourth century audience. The context of his dialogues, then is wider perhaps than other philosophers and because of the difference in periods, it is clear that it is necessary for an audience member to possess knowledge of the events of the previous generation, viz., the fifth century BCE. When its cultural context is taken into account, the Theaetetus can not be read as an attempt by Plato to establish an epistemology in the modern sense of the term. While the characters of the dialogue are searching …

The Principal’S Role In Building Teacher Leadership Capacity In High-Performing Elementary Schools: A Qualitative Case Study, Rahim Jamal Jones

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to explore how public elementary school principals develop teacher leadership capacity within their schools, as well as the effect of this effort on a school's performance. After examining a variety of sources, such as journal articles and web-based search engines, the researcher determined that there was scant information explaining the process principals undergo to create teacher leadership roles in an effort to develop a high-performing school. To accomplish the goals of this study, salient reports in the field of teacher leadership were reviewed. The insights afforded from these reports guided the researcher in developing …