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The Roles Of Silanes As Coupling Reagents And In Deoxygenative Alkylations, Andrea S. Dupre

LSU Master's Theses

Silane reagents play important roles in many areas of organic synthesis. This is primarily due to the ability of silanes to bond to more ligands than the traditional four to become hypervalent (i.e. penta- or hexavalent). This hypervalency causes the silicon center to become more Lewis Acidic and causes the formation of carbon nucleophiles from organosilane ligands. These nucleophiles have been used to perform many cross-coupling reactions with organohalide reagents. The research presented in this thesis reports the utility of silane reagents in cross-coupling reactions of Grignard reagents with alkyl halides. This cross coupling was desirable because the silane should …

Thermohydrodynamic Analysis Of Compressible Gas Flow In Compliant Foil Bearings, Zhengchun Peng

LSU Master's Theses

This thesis deals with the development of mathematical models and numerical schemes for simulating the hydrodynamic pressure and temperature rise of compliant foil bearings lubricated by a thin gas film in between its compliant bearing surface and the rotating shaft. The model accounts for the compressibility of gas, the compliance of the bearing surface, and the interaction between the pressure field and temperature field of the gas film in the bearing system. Numerical solutions obtained over a fairly large range of operating speeds show excellent agreement with existing experimental data from both load performance test and bearing temperature measurement. A …

A Biooptical Model Of Irradiance Distribution And Photosynthesis In Seagrass Canopies, Richard C. Zimmerman

OES Faculty Publications

Although extremely vulnerable to coastal eutrophication, seagrasses represent important structuring elements and sources of primary production in shallow waters. They also generate an optical signature that can be tracked remotely. Accurate knowledge of light absorption and scattering by submerged plant canopies permits the calculation of important plant- and ecosystem-level properties, including rates of photosynthesis, vegetation abundance, and distribution. The objectives of this study were to develop a realistic, yet simply parameterized two-flow model of plane irradiance distribution through a seagrass canopy submerged in an optically active water column, to evaluate its performance against in situ measurements, and to explore the …

A Multilevel Discontinuous Galerkin Method, Jay Gopalakrishnan, Guido Kanschat

Mathematics and Statistics Faculty Publications and Presentations

A variable V-cycle preconditioner for an interior penalty finite element discretization for elliptic problems is presented. An analysis under a mild regularity assumption shows that the preconditioner is uniform. The interior penalty method is then combined with a discontinuous Galerkin scheme to arrive at a discretization scheme for an advection-diffusion problem, for which an error estimate is proved. A multigrid algorithm for this method is presented, and numerical experiments indicating its robustness with respect to diffusion coefficient are reported.

A Schwarz Preconditioner For A Hybridized Mixed Method, Jay Gopalakrishnan

Mathematics and Statistics Faculty Publications and Presentations

In this paper, we provide a Schwarz preconditioner for the hybridized versions of the Raviart-Thomas and Brezzi-Douglas-Marini mixed methods. The preconditioner is for the linear equation for Lagrange multipliers arrived at by eliminating the ux as well as the primal variable. We also prove a condition number estimate for this equation when no preconditioner is used. Although preconditioners for the lowest order case of the Raviart-Thomas method have been constructed previously by exploiting its connection with a nonconforming method, our approach is different, in that we use a new variational characterization of the Lagrange multiplier equation. This allows us to …

Quantifying Habitat Quality Of Larval Bay Anchovy (Anchoa Mitchilli) In Chesapeake Bay By Linking An Individual-Based Model With Spatially-Detailed Field Data, Aaron Thomas Adamack

LSU Master's Theses

Larval bay anchovy (Anchoa mitchilli) habitat quality in Chesapeake Bay was predicted using an individual-based model applied to spatially-detailed field data from Rilling and Houde (1999). Habitat quality was predicted using the ratio of instantaneous mortality rate to instantaneous growth rate. Model predictions of habitat quality were compared to field estimates of habitat quality derived from the spatially-detailed field data. Three sets of one-day simulations were performed to estimate larval growth and mortality rates throughout Chesapeake Bay during June and during July 1993. Field-based simulations used field data to estimate the model inputs of water temperature, zooplankton densities, and the …

Denoising Techniques - A Comparison, Sarita Veera Dangeti

LSU Master's Theses

Visual information transmitted in the form of digital images is becoming a major method of communication in the modern age, but the image obtained after transmission is often corrupted with noise. The received image needs processing before it can be used in applications. Image denoising involves the manipulation of the image data to produce a visually high quality image. This thesis reviews the existing denoising algorithms, such as filtering approach, wavelet based approach, and multifractal approach, and performs their comparative study. Different noise models including additive and multiplicative types are used. They include Gaussian noise, salt and pepper noise, speckle …

Supply Chain Models For An Assembly System With Preprocessing Of Raw Materials, Mohammad Anwar Ashek Rahman

LSU Master's Theses

An assembly line that procures raw materials from outside suppliers and processes the materials into finished products is considered in this research. An ordering policy is proposed for raw materials to meet the requirement of a production facility, which, in turn, must deliver finish products in a fixed quantity at a fixed time interval to the outside buyers. Two different types of raw materials, ‘unfinished’ and ‘ready-to-use’, are procured for the manufacturing system. The ‘unfinished raw materials’ are turned into ‘processed raw materials’ after preprocessing. In the assembly line, the ‘processed raw materials’ and the ‘ready raw materials’ are assembled …

The Phylogenetic Underpinnings For Spatial Patterns Of Morphological Disparity: Analyses Using Strombid Gastropods, Jared M. Latiolais

LSU Master's Theses

Attempting to understand the relationship between morphological and taxonomic diversification has become a central concern of both paleobiology and ecology. Ordinating species in morphospace provides a visual representation of trends in form. In morphospace analysis, each axis of a graph represents a quantitative measure of a morphological trait or combination of traits found in a group of closely related organisms. How species fill open morphospace provide some insight into the history of adaptive radiations. Furthermore, if we map species' positions in morphospace onto an independently derived phylogenetic hypothesis, we should be able to detect trends in morphological divergence along different …

Establishment Of A Callus Culture And Measurement Of Seasonal Changes In Secondary Compound Production In Eucommia Ulmoides Oliver, Erica Deshay Gray

LSU Master's Theses

Eucommia ulmoides Oliver (Eucommiaceae) contains many secondary metabolites, including the lignan pinoresinol di-O-β] glucoside (PG) and the iridoid glycoside aucubin (AU), which have been shown to have anti-hypertensive, antioxidant, and hepatoprotective biological properties. The main objective of this research was to create a new agricultural crop in Louisiana for maintaining healthy blood pressure levels. This was done by: 1) determining the seasonal changes in the concentrations of PG and AU in four-year-old E. ulmoides trees in cultivation in Baton Rouge, Louisiana using Thin Layer Chromatography and High Pressure Liquid Chromatography (HPLC) and 2) determining production of secondary metabolites of E. …

Influences On State-Level Policies For Wildfire Risk Reduction, Marios Anastasis Valiantis

LSU Master's Theses

Wildland fires are part of the United State’s history and culture. The human dimension of State wildland fire management, - the relationship of people and wildland fire in America- is an important and driving force in how federal and state agencies respond to wildland fire, now and in the future. In many ways, the critical element for the management of wildland fire is the management of people, communities, and organizations. Explosive growth in the wildland-urban interface puts entire communities, their associated infrastructure and the socioeconomic fabric that holds communities together at a high risk from wildland fire. Year after year …

Use Of Dea To Evaluate Non-Linear And Imprecise Information In Construction Contractor Performance, Gerald H. Williams, Timothy R. Anderson

Engineering and Technology Management Faculty Publications and Presentations

This paper explores the use of Data Envelopment Analysis as a tool to evaluate the efficiency of building construction projects in Oregon where the inputs, including, "reported information" available prior to pricing and contractor selection is imprecise or at least, cannot be entirely or accurately captured by exogenous measures. This work builds on prior work in the field that evaluated missing, imprecise or non-existent information in DEA models and has broad application to the service sector of the economy where information is the prime input in the system.

Snow-Patch Influence On Soil Biogeochemical Processes And Invertebrate Distribution In The Mcmurdo Dry Valleys, Antarctica, Michael N. Gooseff, John E. Barrett, Peter T. Doran, Andrew G. Fountain, W. Berry Lyons, Andrew N. Parsons, Dorota L. Porazinska, Ross A. Virginia, Diana H. Wall

Geography Faculty Publications and Presentations

The McMurdo Dry Valleys is the largest of the ice-free areas in Antarctica. Precipitation events in excess of 1 cm of snow accumulation are rare. During the winter, snow is transported by strong katabatic winds blowing from the polar plateau, and deposited into the lee of topographic features (e.g., stream channels and other topographic depressions). At the start of the austral summer (early October), as much as 10% of the valley soils may be covered by distributed snow patches. Because liquid water is the primary driver of biological, physical, and chemical processes in this polar desert, quantifying fluxes of water …

Simplicity Of Ultragraph Algebras, Mark Tomforde

Dartmouth Scholarship

In this paper we analyze the structure of C*-algebras associated to ultragraphs, which are generalizations of directed graphs. We characterize the simple ultragraph algebras as well as deduce necessary and sufficient conditions for an ultragraph algebra to be purely infinite and to be AF. Using these techniques we also produce an example of an ultragraph algebra which is neither a graph algebra nor an Exel-Laca algebra. We conclude by proving that the C*-algebras of ultragraphs with no sinks are Cuntz-Pimsner algebras.

Tracers Of Wood Smoke, M. A. K. Khalil, R. A. Rasmussen

Physics Faculty Publications and Presentations

Smoke from wood burning is a significant source of air pollution in many parts of the world. When several sources simultaneously cause air pollution, it is often difficult to determine how much comes from wood burning. Woodsmoke has unique chemical characteristics that can be used as indicators, including elemental composition, particularly potassium and chlorine, the ratios of organic and elemental carbon, and gases such as methyl chloride. This paper deals with formulating and applying the chemical mass balance approach incorporating both gas- and aerosol-phase tracers to a study carried out at Olympia-Lacey in Washington. In this study, three types of …

The Impact Of Pollution On Stellar Evolution Models, Aaron Dotter, Brian Chaboyer

Dartmouth Scholarship

An approach is introduced for incorporating the concept of stellar pollution into stellar evolution models. The approach involves enhancing the metal content of the surface layers of stellar models. In addition, the surface layers of stars in the mass range of 0.5-2.0 M_☉ are mixed to an artificial depth motivated by observations of lithium abundance. The behavior of polluted stellar evolution models is explored assuming the pollution occurs after the star has left the fully convective pre-main-sequence phase. Stellar models polluted with a few Earth masses (M_⊕) of iron are significantly hotter than stars of the …

Estimating Watershed Biodiversity: An Empirical Study Of The Chesapeake Bay In Maryland, Usa, Junko Morimoto, Helena Voinov, Matthew A. Wilson, Robert Costanza

Institute for Sustainable Solutions Publications and Presentations

There has been increasing demand for rigorous methods for evaluating biodiversity, one of the ecosystem services that sustains and fulfills human life. After carefully examining the literature, we found three key points that should be taken into account when we evaluate biodiversity. The first point is that any "indicator species" tends to be a leaky target of biodiversity. The second point is that "buffering" that is useful for representing the ecological concept of boundaries should have scientific meanings. The third point is that a "watershed" that integrates most natural processes is advantageous as the spatial range for evaluation. Based on …

Ordering Genetic Algorithm Genomes With Reconstructability Analysis, Stephen Shervais, Martin Zwick

Complex Systems Faculty Publications and Presentations

The building block hypothesis implies that genetic algorithm effectiveness is influenced by the relative location of epistatic genes on the chromosome. We find that this influence exists, but depends on the generation in which it is measured. Early in the search process it may be more effective to have epistatic genes widely separated. Late in the search process, effectiveness is improved when they are close together. The early search effect is weak but still statistically significant; the late search effect is much stronger and plainly visible. We demonstrate both effects with a set of simple problems, and show that infonnation-theoretic …

Modeling Intracranial Fluid Flows And Volumes During Traumatic Brain Injury To Better Understand Pressure Dynamics, Wayne W. Wakeland, James Mcnames, Mateo Aboy, D. Hollemon, Brahm Goldstein

Complex Systems Faculty Publications and Presentations

See additional files below for the Presentation.

We describe a computer model of intracranial pressure (ICP) dynamics that evaluates clinical treatment options for elevated ICP during traumatic brain injury (TBI). The model uses fluid volumes as primary state variables and explicitly models fluid flows as well as the resistance, compliance, and pressure associated with each intra - and extracranial compartment (arteries and arterioles, capillary bed, veins, venous sinus, ventricles, and brain parenchyma). The model evaluates clinical events and therapies such as intra - and extra-parenchymal hemorrhage, cerebral edema, cerebrospinal fluid drainage, mannitol administration, head elevation, and mild hyperventilation. The model …

Leading Learning Through Imposition Of Leadership Learning Standards, Raymond D. Jorgensen

USF Tampa Graduate Theses and Dissertations

This study explored the impact of an imposed standards movement on attitudes and behaviors of a team of line leaders. A case method was employed to describe, to explain, and to draw conclusions about results of standards imposition. Standards were designed and implemented by an executive leadership team frustrated with lack of effective leadership practices of a line leaders team under their supervision. The investigation took an historical perspective, chronicling the story of the company, emerging leadership challenges, and executive leadership responses leading up to the research.

The line or team leaders of an educational software company served as participants. …

A Hierarchical Approach To Computer-Aided Design Of Quantum Circuits, Marek Perkowski, Martin Lukac, Pawel Kerntopf, Mikhail Pivtoraiko, Michele Folgheraiter, Yong Woo Choi, Jung-Wook Kim, Dongsoo Lee, Woong Hwangbo, Hyungock Kim

Electrical and Computer Engineering Faculty Publications and Presentations

A new approach to synthesis of permutation class of quantum logic circuits has been proposed in this paper. This approach produces better results than the previous approaches based on classical reversible logic and can be easier tuned to any particular quantum technology such as nuclear magnetic resonance (NMR). First we synthesize a library of permutation (pseudobinary) gates using a Computer-Aided-Design approach that links evolutionary and combinatorics approaches with human experience and creativity. Next the circuit is designed using these gates and standard 1*1 and 2*2 quantum gates and finally the optimizing tautological transforms are applied to the circuit, producing a …

Distress Under Duress: The Relationship Between Campus Climate And Depression In Asian American College Students, Christine M. Cress, Elaine Kimiko Ikeda

Educational Leadership and Policy Faculty Publications and Presentations

Student perceptions of negative campus climate were predictive of Asian American students’ depression levels in spite of students’ entering proclivities toward depression and in spite of varying institutional types. In addition, these findings were consistent whether individual Asian American perceptions of campus climate were entered into the equation or whether institutional levels of campus perceptions (which included all racial and ethnic groups) were entered into the equation. Therefore, higher education institutions that are perceived by students to discriminate against individuals based on race or ethnicity, gender, sexual orientation, or disability may put their Asian American students at risk for severe …

Investigating The Urban Heat Island Effect With A Collaborative Inquiry Project, Linda Acha George, William G. Becker

Environmental Science and Management Faculty Publications and Presentations

Modification of the earth's surface through urbanization can have a dramatic impact on local climate. A phenomenon known as the Urban Heat Island (UHI) effect, which is a measure of the near-surface air temperature contrast between urbanized and adjoining rural areas, can be evaluated with readily available instruments. Students in an undergraduate general education science course study this phenomenon in the Portland, Oregon area through a collaborative research project. This inquiry project includes background content and literature review, preliminary studies, development of research questions, experimental design and implementation, data analysis and report writing. This project successfully enables students to collaboratively …

Source Motion Mitigation For Adaptive Matched Field Processing, Lisa M. Zurk, Nigel Lee, James Ward

Electrical and Computer Engineering Faculty Publications and Presentations

Application of adaptive matched field processing to the problem of detecting quiet targets in shallow water is complicated by source motion, both the motion of the target and the motion of discrete interferers. Target motion causes spreading of the target peak, thereby reducing output signal power. Interferer motion increases the dimensionality of the interference subspace, reducing adaptive interference suppression. This paper presents three techniques that mitigate source motion problems in adaptive matched field processing. The first involves rank reduction, which enables adaptive weight computation over short observation intervals where motion effects are less pronounced. The other two techniques specifically compensate …

Finite-Time Singularity Versus Global Regularity For Hyper-Viscous Hamilton-Jacobi-Like Equations, Hamid Bellout, Said Benachour, Edriss S. Titi

Faculty Articles, Papers, and Other Scholarship

The global regularity for the two- and three-dimensional Kuramoto-Sivashinsky equations is one of the major open questions in nonlinear analysis. Inspired by this question, we introduce in this paper and family of hyper-viscous Hamilton-Jacobi-like equations parametrized by the exponent in the nonlinear term, p, where in the case of the usual Hamilton-Jacobi nonlinearity, p = 2. Under certain conditions on the exponent p we prove the short-time existence of weak and strong solutions to this family of equations. We also show the uniqueness of strong solutions. Moreover, we prove the blow-up in finite time of certain solutions to this family …

Assessing Sample Bias And Establishing Standardized Procedures For Weighting And Expansion Of Travel Survey Data, Fahmida Nilufar

LSU Master's Theses

Recent household travel surveys are encountering problems with non-response, non-coverage, non-reporting, and even incorrect or incomplete reporting of trips. In addition, data from survey samples are affected by the social, and economic conditions of the respondents, as well as the survey instrument used to collect the data. As a result, household travel survey data are invariably associated with some level of bias. These threats to the integrity of the data are often ignored while analyzing the sample survey data. However, considering the importance of information derived from such surveys, it is necessary that the survey must provide an accurate reflection …

Block-Level Discrete Cosine Transform Coefficients For Autonomic Face Recognition, Willie L. Scott, Ii

LSU Doctoral Dissertations

This dissertation presents a novel method of autonomic face recognition based on the recently proposed biologically plausible network of networks (NoN) model of information processing. The NoN model is based on locally parallel and globally coordinated transformations. In the NoN architecture, the neurons or computational units form distributed networks, which themselves link to form larger networks. In the general case, an n-level hierarchy of nested distributed networks is constructed. This models the structures in the cerebral cortex described by Mountcastle and the architecture based on that proposed for information processing by Sutton. In the implementation proposed in the dissertation, the …

No Child Left Behind And The Louisiana School Accountability System: A Comparative Study Of Accountability Systems, Rani Coleman

LSU Master's Theses

In the educational field, accountability is one of the key issues in the media. No Child Left Behind (NCLB) has made a definite impact in the political and social realm of society. However, many people do not understand what it fully means to education on all levels. The aim of this thesis is to compare and contrast the Louisiana School Accountability System with the new Federal government's No Child Left Behind. Of key interest in this comparative study is: long-term goals, flagging methods, disaggregation of subgroups, starting out - index/proficiency rate, modification/corrective plans, number of tests, indicators, and high stakes …

Field Validation Of Bentazon Phytoremediation, Sajida Begum

LSU Master's Theses

Phytoremediation with black willow (Salix nigra) was conducted in 1996 by planting trees at a density of 2000 trees/hectare at BASF Corporation in a shallow groundwater plume containing low levels of bentazon. In this project, the roots, stems,and leaves of the black willow plants were extracted and analyzed to see if bentazon from the ground water was taken up by the plants. Different extraction procedures such as liquid-phase extraction and solid-phase extraction were compared. Final determination using different analytical techniques such as GC-MSD, GC-ECD, and HPLC with UV detection for the isolation and analysis of bentazon residues from the plant …

Synthesis, Characterization, And Application Of Water-Soluble Chiral Calix[4]Arene Derivatives In Spectroscopy And Capillary Electrokinetic Chromatography, Kim Hamilton

LSU Doctoral Dissertations

This dissertation is an account of the synthesis, characterization, and application of novel water-soluble chiral calixarenes in spectroscopy and capillary electrophoresis. It is divided into four sections. The first part describes the synthesis and nuclear magnetic resonance (NMR) characterization of four p-t-butylcalix[4]arenes bearing L-amino acid moieties on their lower rims (CX4-AA). The structure and conformation of the derivatives have been determined using one- and two-dimensional NMR techniques. Proton and carbon-13 spectra show that the derivatives are tetra-substituted and adopt a cone conformation. The preparation and characterization of silica-bonded calixarene stationary phases for capillary electrochromatography is also reported in Chapter 2. …