Digital Commons Network^™

Thermochemistry And Kinetics In Pyrolysis And Oxidation Reaction Of Oxygenate Chlorocarbons, Neopentane, And Ortho-Xylene, Hongyan Sun

Dissertations

Thermochemical properties of chlorinated alcohols, chlorinated hydroperoxides and corresponding alkoxy, hydroxy alkyl radicals, peroxy and hydroperoxy alkyl radicals are determined by ab initlo and density functional calculations for modeling and optimization of complex chemical processes for combustion or incineration of chlorinated hydrocarbons. The entropy and heat capacities from vibrational, translational, and external rotational contributions are calculated by statistical mechanics, and the hindered rotational contributions to S^°₂₉₈ and C_p(T)'s are calculated by using direct integration over energy levels of the internal rotational potentials. The values of ΔH_f^°₂₉₈ are determined using isodesmic reactions …

Design And Evaluation Of A List Gathering Tool In A Web-Based Collaborative Environment, Yuanqiong Wang

Dissertations

This research focuses on how to build a "list" structure to combine individual items of information into some sort of structure that converts the individual items of information into a structure of knowledge relative to the problem. Software was designed to provide relationships among and comparisons of the contributions in a "list" structure, so that individual members of a group process will be able to understand the contributions of information made by the group as a whole.

A List Gathering Tool was designed and implemented, which is one component in a Web-based Social Decision Support System (SDSS) Toolkit. Then, a …

Design And Evaluation Of A Voting Tool In A Collaborative Environment, Zheng Li

Dissertations

This dissertation researchdesigned, implemented, and evaluated a Web-based Dynamic Voting Toolfor small group decision-making in a collaborative environment.

In this dissertation, theliterature on voting tools in current GDSS research is presented. Variousvoting theories and methods are analyzed, and the advantages and weaknessesare compared, so as to gain a better understanding of how to apply thesedifferent voting methods to diverse decision-making situations. A briefoverview of scaling theories is also given, with an emphasis on Thurstone'sLaw.

The basic features of someweb-based voting tool implementations are reviewed along with a discussionof the pros and cons of Intemet voting. A discussion of Human DynamicVoting …

Understanding The Origins Of Metastability In Thin Film Growth; Tantalum And The Early Group Vb-Vib Metals, Neme Okechukwu Nnolim

Dissertations

Tantalum (Ta) is a metal that is highly prized for its applications in a variety of industries, including the microelectronics industry, where it is largely used in thin film modifications in order to achieve various electronic, magnetic and structural capabilities in solid-state devices. Ta frequently forms metastable phases, including the well-known ß-phase, during the preparation of thin Ta films by standard film deposition methods such as sputtering and electro-deposition. In order to gain insight into Ta metastable phase formation, the Bain transformation mechanism is studied for Ta and the neighboring body centered cubic (bcc) transition metals in Groups 5 and …

Method For Theoretically Determining The Locus And Location Of The Transmission Zeros In Microwave Filter Networks, Keehong Um

Dissertations

This dissertation presents a theoretical investigation of a practical method to determine quantitatively the locations and loci of complex transmission zeros (TZ's) of positively and negatively cross-coupled RF or microwave bandpass filter networks.

Bandpass filters can be effectively designed by adjusting the locations of TZ's in the complex s-domain. To locate TZ's, this practical method uses chain matrices for subsystems (discrete parts of the network) of the filter network, and can be extended to other types of filters with cross-coupled sections.

An important result is that a complex doublet, triplet and/or quadruplet, (one-, two-, or four-pairs) of TZ's are shown …

Finite Element Modeling Of A Commuter Category Aircraft Seat Under Crash Loading, David William Bowen

Theses and Dissertations

This thesis describes the development and validation of a finite element model of a commuter aircraft seat under crash loading. In particular, this effort has developed an LS-DYNA model of a Beechcraft 1900C low back passenger seat.

Although air travel is one of the safest forms of transportation, crash-related fatalities do occur even in relatively low severity crashes. Many of these fatalities can be traced to the inability of production seats to absorb crash energy. The goal of this research effort is to develop a computational model of a production aircraft seat as a first step towards the development of …

Face Recognition Using Principal Component Analysis, Timothy Kevin Larkin

Theses

Current methods of face recognition use linear methods to extract features. This causes potentially valuable nonlinear features to be lost. Using a kernel to extract nonlinear features should lead to better feature extraction and, therefore, lower error rates. Kernel Principal Component Analysis (KPCA) will be used as the method for nonlinear feature extraction. KPCA will be compared with well known linear methods such as correlation, Eigenfaces, and Fisherfaces.

Growth Of Well-Defined Zno Microparticles By Hydroxide Ion, Ruth Mcbride, Declan Mccormack, John Kelly

Articles

The morphology of the microcrystalline zinc oxide formed by reaction of zinc salts with sodium hydroxide depends critically on the reaction conditions. To understand this, the nature of the solid product has been probed by scanning electron microcopy (SEM) and X-ray diffraction (XRD) and the concentration of zinc remaining in the solution has been determined at regular intervals throughout the reaction. Two general preparative procedures have been followed. The first, which involves simply heating an aqueous solution containing Zn(NO3)2 (0.025 M) and sodium hydroxide (0.375 M) to 101 uC and maintaining it at that temperature for periods of up to …

A Combined Channel-Modified Adaptive Array Mmse Canceller And Viterbi Equalizer, Richard M. Friedman

Theses

In this thesis, a very simple scheme is proposed which couples a maximum-likelihood sequence estimator (MLSE) with a X-element canceller. The method makes use of the MLSE's channel estimator to modify the locally generated training sequence used to calculate the antenna array weights. This method will increase the array's degree of freedom for interference cancellation by allowing the dispersive, desired signal to pass through the array undisturbed. Temporal equalization of the desired signal is then accomplished using maximum-likelihood sequence estimation. The T-spaced channel estimator coefficients and the array weights are obtained simultaneously using the minimum mean square error criteria. The …

A Biologically Inspired Joint Model Using Engineering Methods To Enhance Understanding Of Muscle Activity, Richard Paradiso

Theses

Compliant actuators and control methods have been known to exhibit similarities in human musculoskeletal systems. In order to better understand and improve the effects of force optimization under closed- loop conditions, a physical joint model was constructed with an agonist and an antagonist muscle operating under linear control. Utilizing LabVIEW software, compliant McKibben air muscles and Merlin stretch sensors, the author was able to incorporate a Bang-Bang controller and propose the inclusion of pulse width modulation (PWM) as well as a Proportional-Integral-Derivative (PD) controller to study the reflex loops under various levels of feedback sensitivity. The feedback mechanism, similar to …

Elastic Brain Image Registration Using Mutual Information, Srisheela Devabhaktuni

Theses

Image Registration is the determination of a geometrical transformation that aligns points in one image of an object with corresponding points in another image. The source image is geometrically transformed to match the target image. The geometric transformation can be rigid or non-rigid. Rigid transformations preserve straight lines and angles between straight lines. The basic rigid transformations are rotation, scaling and translation.

In this thesis non-rigid registration using B-splines is the method being used to take into account the elastic change in the brain structure. The B-spline equation is a type of curved transformation that does not preserve the straightness …

Study Of Baroreceptor Sensitivity Index In Chronic Fatigue Syndrome, Diane L. Donnelly

Theses

Although numerous studies evaluate baroreflex response as part of their research protocol, only one was identified as having evaluated continuous baroreceptor response as part of a 70° head-up tilt. It was done by Youde et al. [28] and was limited in that it evaluated only sequences of three beats for lag 0. The limitations of the Youde study [28] are not present in this thesis.

The data for this thesis came from a 70° head-up tilt study performed on chronic fatigue syndrome subjects by LaManca et al. [3] at the East Orange VA Medical Center. Baroreflex was not evaluated as …

An Experimental Study On Network Intrusion Detection Systems, Peng Fu

Theses

A signature database is the key component of an elaborate intrusion detection system. The efficiency of signature generation for an intrusion detection system is a crucial requirement because of the rapid appearance of new attacks on the World Wide Web. However, in the commercial applications, signature generation is still a manual process, which requires professional skills and heavy human effort. Knowledge Discovery and Data Mining methods may be a solution to this problem. Data Mining and Machine Learning algorithms can be applied to the network traffic databases, in order to automatically generate signatures.

The purpose of this thesis and the …

The Influence Of Exercise On Oxygen Uptake In Mild Hypertension, Matthew Joseph Herban

Theses

The amount of oxygen used by muscle cells increase with exercise. The two body systems that influence the amount of oxygen delivered are the cardiovascular system and the pulmonary system. Two groups of patients were studied, those that were mildly hypertensive (but are not taking prescription medication for hypertension) and the control or normal group. The two groups exercised on a bicycle ergometer. Work rate was increased in steps (multiples of thirty watts) until anaerobic threshold (as measured by an ear oximeter) was reached. Heart rate, blood pressure, oxygen uptake and carbon dioxide production were measured during exercise. Their data …

Tree Based Reliable Topology For Distributing Link State Information, Ram Narayan Krishnan

Theses

Finding paths that satisfy the performance requirements of applications according to link state information in a network is known as the Quality-of- Service (QoS) routing problem and has been extensively studied. However, distributing link state information may introduce a significant protocol overhead on network resources. In this thesis, the issue on how to update link state information efficiently and effectively is investigated. A theoretical framework is presented, and a high performance link state policy that is capable of minimizing the false blocking probability of connections under a given update rate constraint is proposed. Through theoretical analysis, it is shown that …

Internet Traffic Over Wide Area Network - Statistical Modeling And Analysis, Yan Yi Lee

Theses

This thesis provides results on trace data collecting and modeling of the Internet traffic over a Wide Area Network. The study is based on extensive data, gathered by tracing the actual packet exchange at the interfaces of devices on the WAN of BCCLS (Bergen County Cooperative Library System). A powerful network monitoring system WhatsUp Gold was employed to monitor the WAN, and logged the byte rates and packet rates sent and received at the interfaces. Different statistical distributions were employed to model the data traces. In comparison with some other statistical models - normal, lognormal, Weibull, and Pareto, which are …

Synthesis And Application Of Novel Chiral Ionic Liquids Derived From Alpha-Pinene, Yun Wang

Theses

Two new chiral ionic liquids of oxazolinium cations derived from a-pinene: 9,9-Dimethyl-4-propenyl-5-propyl-3 -oxa-5-azonia-tricyclo [6.1.1.0 ^2,6] dec-4-ene tetrafluoro borate ([ChIPOZ] [BF₄]) and 9,9-Dimethyl-4-propenyl-5-propyl-3-oxa-5-azonia-tricyclo [6.1.1.0 ^2,6] dec-4-ene hexafluoro phosphate ([ChIPOZ][PF₆]). Both these chiral ionic liquids have been applied in enantiomeric copper-catalyzed 1,4-addition reactions with diethyl zinc. The enantiomeric excess for product using [ChIPOZ][BF₄] is above 70% and for [ChIPOZ][PF₆] is above 30%. Chiral ionic liquids worked as phase transfer catalysts In this reaction.

α-Pinene was used as the "chiral pool" in the synthesis of amino alcohol through a two-step reaction, followed by …

Low Interference Routing For Wireless Ad-Hoc Networks, Mohit Gupta

Theses

In this thesis the primary focus is on the problem of interference between messages. The thesis discusses why the messages are blocked in a system? How adding a message impacts the cost of all other available links, which can be established in the system.

This thesis analyzes how the availability of channels, increase in number of nodes and increase in the transmission range help in increasing the number of messages that can be handled in the network. It is also analyzes how critical is the selection of the maximum transmission range MTR, transmission range TR and required transmission range RTR. …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Task V: Fourth Quarterly Report 06/01/2003-08/30/2003, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the TRP proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with only very sparse experimental data. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics-Task V: Annual Report -Phase Ii 09/01/2002-08/30/2003, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the TRP proposed application. Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with only very sparse experimental data. Scientists have noticed that the concentration of oxygen dissolved in the liquid alloy could control the corrosion rate of steels exposed to Pb or Pb-Bi. At high …

We Are…Marshall, August 29, 2003, Office Of Marshall University Communications

We Are ... Marshall: the Newsletter for Marshall University 1999-2023

No abstract provided.

Volume 39 - Issue 00 - Friday, August 29, 2003, Rose Thorn Staff

The Rose Thorn Archive

The Rose Thorn, Rose-Hulman's independent student newspaper.

Cross-Calibration Of Stroke Disability Measures: Bayesian Analysis Of Longitudinal Ordinal Categorical Data Using Negative Dependence, Giovanni Parmigiani, Heidi W. Ashih, Gregory P. Samsa, Pamela W. Duncan, Sue Min Lai, David B. Matchar

Johns Hopkins University, Dept. of Biostatistics Working Papers

It is common to assess disability of stroke patients using standardized scales, such as the Rankin Stroke Outcome Scale (RS) and the Barthel Index (BI). The Rankin Scale, which was designed for applications to stroke, is based on assessing directly the global conditions of a patient. The Barthel Index, which was designed for general applications, is based on a series of questions about the patient’s ability to carry out 10 basis activities of daily living. As both scales are commonly used, but few studies use both, translating between scales is important in gaining an overall understanding of the efficacy of …

The Comment, August 29, 2003, Bridgewater State College

The Comment

No abstract provided.

Structural Requirements For Expression Of Factor Va Activity, Michael Kalafatis, Daniel O. Beck, Kenneth G. Mann

Chemistry Faculty Publications

Thrombin activated factor Va (factor VIIa, residues 1-709 and 1546-2196) has an apparent dissociation constant (Kd,app) for factor Xa within prothrombinase of approximately 0.5 nM. A protease (NN) purified from the venom of the snake Naja nigricollis nigricollis, cleaves human factor V at Asp697, Asp1509, and Asp1514 to produce a molecule (factor VNN) that is composed of a Mr 100,000 heavy chain (amino acid residues 1-696) and a Mr 80,000 light chain (amino acid residues 1509/1514-2196). Factor VNN, has a Kd,app for factor Xa of 4 nm and reduced clotting activity. Cleavage of factor VIIa by NN at Asp697 results …

Daily Eastern News: August 29, 2003, Eastern Illinois University

August

No abstract provided.

Volume 41, Number 1: August 29, 2003, University Of North Dakota

University Letter Archive

No abstract provided.

Real Options In Law: (Possibly, Frivolous) Litigation And Other Applications, Peter H. Huang

ExpressO

This Article advances the thesis that real options are not only ubiquitous in law, but also provide novel insights about legal decision making, doctrines and rules. An introduction provides a brief a primer about financial options, real options, and real options in law. Part I of this Article develops implications of the fact that every lawsuit contains a sequence of real options for the plaintiff to unilaterally abandon that lawsuit. Part II of this Article appraises the limitations of game-theoretic analysis of the abandonment options embedded in litigation and some responses to such limitations. Part III of this Article illustrates …

Eastern Progress - 28 Aug 2003, Eastern Kentucky University

Eastern Progress 2003-2004

No abstract provided.

August 28, 2003, James Madison University

The Breeze, 2000-2009

The Breeze is the student newspaper of James Madison University in Harrisonburg, Virginia.