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No Honor Among Snails: Conspecific Competition Leads To Incomplete Drill Holes In The Naticid Gastropod Neverita Delessertiana (R Cluz), Jack A. Hutchings

USF Tampa Graduate Theses and Dissertations

The fossil record of drilling predation has been widely used to study predator-prey interactions and their relative importance on long-term evolutionary processes. Incomplete drill holes have been interpreted as indicators of failed attacks due to well-defended prey. However, this interpretation is based on pair-wise interactions between one predator and one prey, a condition commonly compromised in nature. The hypothesis that interference among drilling predators leads to an increase in the relative frequency of incomplete drill holes was tested in the laboratory using the naticid Neverita delessertiana (R cluz) and a common prey, the bivalve Chione elevata (Say). The experiment consisted …

Perceptions Of A Learning Organization And Factors Within The Work Environment That Influence Transfer Of Training In Law Enforcement, Yvonne Olive Hunter-Johnson

USF Tampa Graduate Theses and Dissertations

Abstract

The purpose of this study was to determine law enforcement officers' perception of factors within the workplace that influence transfer of training and their perception of the organization being a learning organization. The study actually had three parts. First, it intended to investigate the perception of law enforcement officers regarding factors within their work environment that influence or impede the transfer of training process (specifically, organizational support and transfer climate/culture). Second, it intended to determine the perception of law enforcement officers concerning the promotion of their organization's learning practices, learning culture, and the continuous learning environment at an individual, …

Community As Metaphor: Dialectical Tensions Of A Racially Diverse Organization, Joseph Jacob Jenkins

USF Tampa Graduate Theses and Dissertations

In recent years, a sense of community has declined throughout the United States. Common Point Community Church has responded to this trend by prioritizing "community" as an organizational metaphor. The present study explores how this metaphor is co-constructed through the communication practices of current organizational leaders and members. I begin this process, first, by positioning the study within existing literature on institutional theory, institutional legitimacy, community, community of practice, social construction of race, sensemaking, organizational metaphor, tension-centered approach, and dialectic theory. Building upon more than three years of ethnographic field work, I then outline the study's context and methodology. Next, …

Chiral Binol Metal Phosphate/Phosphoric Acid Catalyzed Enantioselective Addition Of Phosphorus And Sulfur Nucleophiles To Imines And Epoxides, Gajendrasingh Ingle

USF Tampa Graduate Theses and Dissertations

The research presented in this dissertation focuses on chiral BINOL metal phosphatephosphoric acid catalyzed enantioselective additions of phosphorus and sulfur nucleophiles to imines and epoxides. In chapter 2, we reported a new method to synthesize chiral amino phosphine oxides. The reaction combines N-substituted imines and diphenylphosphine oxide catalyzed by chiral magnesium 9-antryl phosphate. A wide variety of aliphatic and aromatic aldimines substituted by electron neutral benzhydryl or dibenzocycloheptene groups were excellent substrates for the addition reaction. The imines protected with dibenzocycloheptene protecting group provided better enantioselectivity than those protected with benzhydryl group, while both imines gave comparable yields. Also, …

Development And Optimization Of Kinetic Target-Guided Synthesis Approaches Targeting Protein-Protein Interactions Of The Bcl-2 Family, Sameer Shamrao Kulkarni

USF Tampa Graduate Theses and Dissertations

Kinetic target-guided synthesis (TGS) and in situ click chemistry are among unconventional discovery strategies having the potential to streamline the development of protein-protein interaction modulators (PPIMs). In kinetic TGS and in situ click chemistry, the target is directly involved in the assembly of its own potent, bidentate ligand from a pool of reactive fragments. Herein, we report the use and validation of kinetic TGS based on the sulfo-click reaction between thio acids and sulfonyl azides as a screening and synthesis platform for the identification of high-quality PPIMs. Starting from a randomly designed library consisting of nine thio acids and nine …

Archaeological Survey And Testing On St. Vincent Island, Northwest Florida, Elicia Victoria Kimble

USF Tampa Graduate Theses and Dissertations

St. Vincent Island is one of the barrier islands in the Florida panhandle between Apalachicola Bay and the Gulf of Mexico. The St. Vincent National Wildlife Refuge encompasses all 5000 hectares of the island. Archaeological fieldwork in the summer of 2009 included a survey of the entire island and a test unit at one of the island's richest sites. In spring of 2010 a second test unit was excavated at another archaeologically rich site. A total of 16 known sites were investigated and two newly discovered sites recorded. This research combines all these data with information obtained from existing artifact …

Precipitation Of Phosphate Minerals From Effluent Of Anaerobically Digested Swine Manure, Alex Y. Lin

USF Tampa Graduate Theses and Dissertations

Swine production represents approximately 40% of the world's meat production, and its wastes contain high concentrations of organic carbon, nitrogen (N), and phosphorus (P). Anaerobic digestion is an increasingly popular technology for treating animal wastes while simultaneously generating energy. Its propagation and ability to solubilize organic N and P make adding a struvite recovery process attractive. Recovering struvite (MgNH4PO4) from anaerobically digested swine waste can address global P shortages, meet P discharge guidelines, and produce slow-release fertilizer, which can be sold for revenue.

Anaerobic digesters were operated with at organic loading rates of 3.4-3.9 g volatile solids per liter per …

Lenalidomide Targets The T-Cell Co-Stimulatory Pathway To Mediate Immune Modulation, Jessica Marie Mcdaniel

USF Tampa Graduate Theses and Dissertations

T-cells are lymphocytes that make up part of the adaptive arm of the immune system, and are essential for efficient protection from and eradication of viruses and pathogens. T-cells not only play an important role in protection from external agents, but also regulate and prevent activation towards self-peptides and detect and remove erratically growing cells. Alterations in T-cell activation and suppression contribute to auto-immunity, immunocompromised disorders, and cancer progression.

The immune system, and T-cells in particular, provides daily surveillance, recognition and destruction of aberrant cells. Although the immune system is proficient at suppressing malignant progression, tumor cells acquire various methods …

Precarious Manhood And Men's Attributional Biases In Partner Conflict, Joshua Guy Lenes

USF Tampa Graduate Theses and Dissertations

A study investigated men and women's attributions of criticism, rejection, and threats to gender status in a fictitious partner conflict scenario in which the victim was either a man or a woman. The results indicated that in the context of a partner conflict scenario that ends in violence, greater perceived threats to gender status are attributed to a female victim who criticizes a man's manhood more than a male victim who criticizes a woman's womanhood. The results also revealed that women attribute greater amounts of criticism/rejection and gender status threat in a victim's statements toward an abuser than men do, …

Masculinity, Sexuality, And Soccer: An Exploration Of Three Grassroots Sport-For-Social-Change Organizations In South Africa, Sarah Theresa Mcghee

USF Tampa Graduate Theses and Dissertations

Programs that utilize soccer as a tool for social change are steadily emerging throughout townships and rural areas in South Africa, the most economically disadvantaged areas of the country. In South Africa, grassroots sport-for-social-change organizations are compensating for failed government policies and programs that seek to help at-risk youth. As a result, program staff are often members of the community who are not versed in academic critiques of the use of sport in development initiatives. Additionally, much of the existing literature on sport-for-social-change champions the advancement of specific projects without asking critical research questions, which should include the appropriateness of …

Design Of Colloidal Composite Catalysts For Co2 Photoreduction And For Co Oxidation, Bijith D. Mankidy

USF Tampa Graduate Theses and Dissertations

In this doctoral dissertation, novel colloidal routes were used to synthesize nanomaterials with unique features. We have studied the impact of nanoparticle size of catalyst, role of high surface area of a photocatalyst, and the effect of varying elemental composition of co-catalytic nanoparticles in combination with core-shell plasmonic nanoparticles. We have demonstrated how physical and chemical characteristics of nanomaterials with these unique features play a role in catalytic reactions, specifically the oxidation of CO and the photoreduction of CO2. The first objective of this doctoral dissertation involved the preparation of CoO nanoparticles with discrete nanoparticles sizes (1-14 nm) using a …

Parental Leave: Policy And Practice, Amanda Parr

USF Tampa Graduate Theses and Dissertations

Parental leave is a broad term that encompasses maternity and/or paternity leave to care for an infant. Parental leave provides job protection for workers and may be paid or unpaid, with provisions varying throughout the world. Every industrialized nation offers some form of paid parental leave, with the exception of the United States, whose only federal policy regarding parental leave is the Family and Medical Leave Act (FMLA), a law that allows eligible workers to take up to twelve weeks of unpaid, job protected leave for the birth or adoption of a child.

This research project explored how parents understand …

A Preliminary Investigation Of Family Engagement Practices In Schools Implementing Problem-Solving/Response To Intervention (Ps/Rti)., Devon Minch

USF Tampa Graduate Theses and Dissertations

The current study investigated the relationships among level of Problem-Solving/Response to Intervention (PS/RtI) implementation, school factors, educator factors, family factors, and a) educator reports of individual and school-wide practices to engage families, and b) family perceptions of educators' family engagement practices in schools implementing PS/RtI. Survey instruments measuring family engagement in PS/RtI were developed for the current study. Survey data measuring the beliefs about family engagement, perceptions of knowledge and skills for family engagement, and perceptions of family engagement practices were collected from 396 families and 933 educators from 40 schools in a local school district. Findings suggest that PS/RtI …

Enantioselective Brønsted And Lewis Acid-Catalyzed Reaction Methodology: Aziridines As Building Blocks For Catalytic Asymmetric Induction, Shawn E. Larson

USF Tampa Graduate Theses and Dissertations

Chiral molecules as with biological activity are plentiful in nature and the chemical literature; however they represent a smaller portion of the pharmaceutical drug market. As asymmetric methodologies grow more powerful, the tools are becoming available to synthesize chiral molecules in an enantioselective and efficient manner.

Recent breakthroughs in our understanding of phosphoric acid now allow for Lewis acid catalysis via pairing with alkaline earth metals. Using alkaline earth metals with chiral phosphates is an emerging approach to asymmetric methodology, but already has an influential record.

The development of new conditions for the phosphoric acid-catalyzed highly enantioselective ring-opening of meso-aziridines …

Socioscientific Issues: A Path Towards Advanced Scientificliteracy And Improved Conceptual Understanding Of Socially Controversial Scientific Theories, Dean William Pinzino

USF Tampa Graduate Theses and Dissertations

Abstract

This thesis investigates the use of socioscientific issues (SSI) in the high school science classroom as an introduction to argumentation and socioscientific reasoning, with the goal of improving students' scientific literacy (SL). Current research is reviewed that supports the likelihood of students developing a greater conceptual understanding of scientific theories as well as a deeper understanding of the nature of science (NOS), through participation in informal and formal forms of argumentation in the context of SSI. Significant gains in such understanding may improve a student's ability to recognize the rigor, legitimacy, and veracity of scientific claims and better discern …

Water's Dependence On Energy: Analysis Of Embodied Energy In Water And Wastewater Systems, Weiwei Mo

USF Tampa Graduate Theses and Dissertations

Water and wastewater treatment is a critical service provided for protecting human health and the environment. Over the past decade, increasing attention has been placed on energy consumption in water and wastewater systems for the following reasons: (1) Water and energy are two interrelated resources. The nexus between water and energy can intensify the crises of fresh water and fossil fuel shortages; (2) The demand of water/wastewater treatment services is expected to continue to increase with increasing population, economic development and land use change in the foreseeable future; and (3) There is a great potential to mitigate energy use in …

Graphene Casimir Interactions And Some Possible Applications, Anh Duc Phan

USF Tampa Graduate Theses and Dissertations

Scientific development requires profound understandings of micromechanical and nanomechanical systems (MEMS/NEMS) due to their applications not only in the technological world, but also for scientific understanding. At the micro- or nano-scale, when two objects are brought close together, the existence of stiction or adhesion is inevitable and plays an important role in the behavior operation of these systems. Such effects are due to surface dispersion forces, such as the van der Waals or Casimir interactions. The scientific understanding of these forces is particularly important for low-dimensional materials. In addition, the discovery of materials, such as graphitic systems has provided opportunities …

Spatial And Temporal Variability Of Remotely Sensed Ocean Color Parameters In Coral Reef Regions, Daniel Brooks Otis

USF Tampa Graduate Theses and Dissertations

The variability of water-column absorption due to colored dissolved organic matter (CDOM) and phytoplankton in coral reef regions is the focus of this study. Hydrographic and CDOM absorption measurements made on the Bahamas Banks and in Exuma Sound during the spring of 1999 and 2000 showed that values of salinity and CDOM absorption at 440nm were higher on the banks (37.18 psu, 0.06 m^-1), compared to Exuma Sound (37.04 psu, 0.03 m^-1). Spatial patterns of CDOM absorption in Exuma Sound revealed that plumes of CDOM-rich water flow into Exuma Sound from the surrounding banks. To examine absorption variability in reef …

Multi-Time Scales Stochastic Dynamic Processes: Modeling, Methods, Algorithms, Analysis, And Applications, Jean-Claude Pedjeu

USF Tampa Graduate Theses and Dissertations

By introducing a concept of dynamic process operating under multi-time scales in sciences and engineering, a mathematical model is formulated and it leads to a system of multi-time scale stochastic differential equations. The classical Picard-Lindel\"{o}f successive approximations scheme is expended to the model validation problem, namely, existence and uniqueness of solution process. Naturally, this generates to a problem of finding closed form solutions of both linear and nonlinear multi-time scale stochastic differential equations. To illustrate the scope of ideas and presented results, multi-time scale stochastic models for ecological and epidemiological processes in population dynamic are exhibited. Without loss in generality, …

Responses To Chemical Exposure By Foraminifera: Distinguishing Dormancy From Mortality, Benjamin James Ross

USF Tampa Graduate Theses and Dissertations

The Deepwater Horizon blowout in 2010 released an estimated 4.9 million barrels of crude oil into the Gulf of Mexico in the 83 days between the initial explosion and the capping of the well. Response included extensive use of Corexit© oil dispersant. Although South Florida was spared exposure by currents, this event highlights the need for effective bioassay organisms for coral reefs. Amphistegina spp. are benthic foraminifers that host diatom symbionts in a relationship similar to that of coral and their zooxanthellae. Amphistegina spp. occur abundantly in reef communities nearly worldwide, are easily collected and maintained in culture, and are …

Development Of A Bio-Molecular Fluorescent Probe Used In Kinetic Target-Guided Synthesis For The Identification Of Inhibitors Of Enzymatic And Protein-Protein Interaction Targets, Katya Pavlova Nacheva

USF Tampa Graduate Theses and Dissertations

Abstract

Fluorescent molecules used as detection probes and sensors provide vital information about the chemical events in living cells. Despite the large variety of available fluorescent dyes, new improved fluorogenic systems are of continued interest. The Diaryl-substituted Maleimides (DMs) exhibit excellent photophysical properties but have remained unexplored in bioscience applications. Herein we present the identification and full spectroscopic characterization of 3,4-bis(2,4-difluorophenyl)-maleimide and its first reported use as a donor component in Forster resonance energy transfer (FRET) systems. The FRET technique is often used to visualize proteins and to investigate protein-protein interactions in vitro as well as in vivo. The analysis …

Perceived Barriers For Implementing Primary Sexually Transmitted Infection Prevention, Rachel Monique Stewart-Campbell

USF Tampa Graduate Theses and Dissertations

Adolescents continue to be at increased risk for contracting sexually transmitted infections (STI's). This research study describes the perception of barriers that providers in the Tampa Bay area encounter when implementing primary STI prevention programs for adolescents within the community context. This study used semi structured interviews to explore perceived barriers for implementing primary such programs for adolescents in the Tampa Bay area programs. Participants reported faith based institutions/churches and schools as common sectors for presenting a variety of barriers for implementing their program. Perceptions of barriers were described as, the need to tailor program messages and presentations based on …

Dolphin Sound Production And Distribution On The West Florida Shelf, Peter Simard

USF Tampa Graduate Theses and Dissertations

This dissertation is an investigation of dolphin sound production and distribution off west central Florida. Although a wealth of information exists on the production of common sounds (whistles, echolocation) made by captive, trained dolphins, far less is known about free-ranging dolphin sound production and of unusual sounds. In addition, while inshore dolphin populations or communities are the subjects of research projects in many locations, dolphins in offshore waters are less commonly studied. The objectives of this dissertation were to contribute information on free-ranging dolphin sounds and continental shelf dolphin distribution.

While echolocation has been rigorously studied in captive, trained dolphins, …

Improvisational Music Performance: On-Stage Communication Of Power Relationships, David A. Steinweg

USF Tampa Graduate Theses and Dissertations

This project explores how musical improvisational processes come into being through interacting discursive power relationships that are embodied and enacted through performance. By utilizing the concepts of framing and performativity I am able to show how discursive power constitutes the performance of improvisational music. To exemplify this theory, the project presents a case study examining a Grateful Dead cover band named Uncle John's Band that performs at Skipper's Smokehouse in Tampa, FL. Using an ethnographic methodology, the project articulates the dominant discursive power relationships that constitute Uncle John's Band's improvisational performances. The dominant discursive power relationships revolve around the lived …

Optical Detection And Classification Of Phytoplankton Taxa Through Spectral Analysis, Daniel Tyler Sensi

USF Tampa Graduate Theses and Dissertations

Phytoplankton serve as the bottom of the marine food web and therefore play an essential role in marine ecosystems. On the other hand, coastal phytoplankton communities can adversely affect the marine ecosystem and humans. A variety of techniques have been developed to measure and study phytoplankton, including in situ methods (e.g., flow cytometry) and laboratory methods (e.g., microscopic taxonomy). These provide accurate measurements of phytoplankton taxa and concentrations, yet they are limited in space and time, and synoptic information is difficult to obtain with these techniques.

Optical remote sensing may provide complementary information for its synoptic nature, as demonstrated by …

Environmental Change And Place-Based Identities: Sponge Fishing In Tarpon Springs, Florida, Michael Suver

USF Tampa Graduate Theses and Dissertations

Abstract

As the environmental consequences of urbanization and climate change become apparent in coastal communities, it has become important to understand how residents of these communities experience and approach their changing environments. This becomes especially significant in places where nature-based livelihoods constitute a major part of the economy. This thesis focuses on the city of Tarpon Springs, located along the Gulf of Mexico in Florida, where sea sponge fishing is an important contributor to the local economy while also being central to place-based tourist and ethnic identities. It seeks to understand how environmental changes in the sea sponge economy will …

Design Of Novel Inhibitors For Infectious Diseases Using Structure-Based Drug Design: Virtual Screening, Homology Modeling And Molecular Dynamics, Divya Ramamoorthy

USF Tampa Graduate Theses and Dissertations

The main aim of the study in this thesis was to use structure-based protocols to design new drugs for enzymes, DXS and DXR in the non mevalonate pathway. Another aim of this study was to identify the dimer interface in E.coli FabH as an allosteric binding site for designing new class of anti-infective drugs. We have attempted to identify potential inhibitors for DXS by docking the NCI Diversity set compounds, compound libraries available from GSK-MMV and St. Jude's Children's research center. FabH dimer interface has been identified as a potential target using SiteMap, Alanine mutagenesis and docking studies.

The first …

Assessing The Reuse Potential Of Wastewater For Irrigation: The Removal Of Helminth Eggs From A Uasb Reactor And Stabilization Ponds In Bolivia, Matthew Eric Verbyla

USF Tampa Graduate Theses and Dissertations

Extreme hunger, malnutrition, and the lack of access to sanitation are among the most pressing development challenges, but the world is not on track to meet the targets that have been established by the Millennium Development Goals. The integration of wastewater treatment and food production systems allows for the recovery of resources from wastewater, and can provide an important solution to meet the sanitation needs of growing urban populations and provide periurban farmers with a consistent supply of water and nutrients. Stabilization ponds have been long considered to be an appropriate technology for wastewater reuse systems in developing countries, but …

Remote Sensing Of Whitings In The Bahamas, Ryan Allen Lloyd

USF Tampa Graduate Theses and Dissertations

Whitings on both the Great Bahama Bank (GBB) and Little Bahama Bank (LBB) were evaluated using data collected from 2000-2010 by the Moderate Resolution Imaging Spectroradiometer (MODIS) instruments onboard the Terra and Aqua satellites. A semi-objective method was developed to classify whiting patches from other look-alike features using the recently developed Floating Algae Index (FAI) algorithm, an empirical cloud masking algorithm, and a gradient analysis from the 250-m resolution MODIS data. A total of 1,500 images with minimal cloud cover was used to calculate long-term and seasonal trends as well as an average daily coverage for both banks. Annual and …

Ontogeny And Littoral Structure Of Lakes Created On Phosphate Mined Lands Of Central Florida, Chrysoula Mitraki

USF Tampa Graduate Theses and Dissertations

Created lakes are an end product of phosphate mining in Florida. Beginning in 1975, Florida reclamation rules set criteria for phosphate created lakes aiming to approximate the structure of natural lakes, and emphasizing extensive littoral zones with both emergent and submersed vegetation.

Lake development relative to lake age and design were examined for 22 phosphate lakes representing a 40-year age trajectory, utilizing water quality and benthic invertebrate communities from littoral and deep-water locations (Chapter 1). The relative importance of morphometry and lake age in the development of littoral plant communities was examined using multiple vegetation surveys throughout the year, in …