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Thermodynamic Model And The Controlling Variables Of Phosphate Lattice Loss, Mohammad Abutayeh

USF Tampa Graduate Theses and Dissertations

A thermodynamic model was developed based upon five equilibrium reactions to predict the limits of distribution of phosphates between the liquid and the solid phases in a reactor used to extract phosphoric acid from phosphate rock. A computer code was generated to carry out different simulations of the model using several inputs of temperatures and liquid phase sulfuric acid contents. Ideal Solution, Debye-Hückel, and Robinson-Guggenheim-Bates electrolyte activity coefficient models were employed alternately in each simulation to complete the thermodynamic model and the outputs were compared to one another.

Experimental data of equilibrium constants were regressed to adjust the values of …

Genetic Variation In Chrysopsis Floridana Small, The Endangered Florida Golden Aster, As Revealed By Random Amplification For Polymorphism Detection (Rapd), Laurie Lysle Walker Markham

USF Tampa Graduate Theses and Dissertations

Chrysopsis fioridana Small (Asteraceae) is a federally endangered plant endemic to the Tampa Bay area of west central Florida. It is confined to the sand pine scrub community, growing in open, sunny, and sandy areas or in disturbed areas at the edges of scrub. As a means ofassessing the genetic variability ofthis species, eight populations in Hillsborough County were compared with a seed stock collection housed at Bok Tower Gardens in Lake Wales using random amplification for polymorphism detection (RAPD). The objectives of this study were to (I) describe the overall genetic variation among and within populations and subpopulations of …

Florida Red Tides From A Scientific And Public Information Perspective, Kristen M. Kusek

USF Tampa Graduate Theses and Dissertations

This thesis consists of a comprehensive historical review and evaluation of Florida red tide research and a multifaceted analysis of red tide coverage by the St. Petersburg Times from 1953 to 1997. Red tides caused by Gymnodinium breve along the Florida Gulf coast are riddled with complexity; scientists have been asking many of the same questions for nearly 50 years. Red tides also attract considerable media publicity. This thesis addressed the following: 1. What have scientists learned about Florida red tides since G. breve was identified in 1948?, and 2. How well was the issue covered by the newspaper media? …

The Influence Of Habitat Variation On Demography Of Blue Jays (Cyanociita Cristata) In South-Central Florida, Keith Allen Tarvin

USF Tampa Graduate Theses and Dissertations

Vertebrate populations rarely are homogeneous. Instead they exist as arrays of demographically variable subpopulations that are linked through dispersal. Variation in habitat quality is a major cause of demographic variability among subpopulations, but few studies have examined habitat-specific demography empirically. Here I present a detailed field study o f habitat-specific demography in Blue Jays (Cyanocitta cristata) that occupied a habitat mosaic landscape in south-central Florida. By measuring habitat-specific demographic parameters, including density, reproductive output, survival, and dispersal, I tested for the existence of population sources and sinks associated with different habitats, and the applicability ofa series ofhabitat selection models …

Habitat Disturbance Within An Urban Forest Fragment, Tampa, Florida, John Forest Turbiville Jr.

USF Tampa Graduate Theses and Dissertations

The purpose of this study is to determine the effects of forest fragmentation on a forest fragment in south Tampa, Florida. To determine these effects, several research objectives are defined, which include: (1) an historical analysis of the development and fragmentation of the study area; (2) documentation of the effects of fragmentation on the site; and (3) development of a management policy relating to site-specific fragmentation effects.

Forest fragmentation and its attendant human impacts have altered many of the natural physical and biological processes associated with the three ecosystem types present within this forest fragment. These ecosystems include pine flatwoods, …

Homing Behavior And Orientation In The Gopher Tortoise, Gopherus Polyphemus, Kevin Michael Connor

USF Tampa Graduate Theses and Dissertations

Gopher tortoises are found in xeric habitats in the southeastern United States. In these xeric habitats, gopher tortoises excavate and reside in burrows which provide shelter and protection. Gopher tortoises are active throughout the year, often making several journeys a day away from their burrows. Although they may move substantial distances, they return to their burrows, suggesting that they posses a well-developed orientation and homing ability. This study investigated the ability of gopher tortoises to home from short distance (40 meters, just outside of or on the perimeter of their home ranges) and intermediate distances (200 meters, approximately 2 home …

Chemical Fate Of Bunker C Fuel Oil In A Subtropical Marine Environment Following A Spill In Tampa Bay, Florida, Dana Lynn Wetzel

USF Tampa Graduate Theses and Dissertations

A hydrocarbon chemistry study was performed on sediments, oil masses and mangrove prop roots of a mangrove island in Boca Ciega Bay, Florida following a spill of Bunker C fuel oil in Tampa Bay. Normal alkane (n-alkane) and polycylic aromatic hydrocarbon (PAH) profiles were monitored for effects of degradation and weathering in these mediums for a period of one year. Initial findings indicated a loss of lower molecular weight n-alkanes and PAH's in sediments and prop roots. There was little or no loss of these low molecular weight components in the oil mass samples. Hydrocarbon profiles at the end of …

Analysis Of Lead In Soils Adjacent To Interstate 275 In Tampa, Florida, Mark R. Hafen

USF Tampa Graduate Theses and Dissertations

Analysis of two hundred and twenty-four soil samples collected at logarithmic intervals on perpendicular transects adjacent to Interstate Highway 275 in Tampa, Florida revealed that thirty-five percent of the samples contained health-threatening levels of lead (greater than 500 ppm), although the pattern of contamination was not predictable. Twenty-two of the thirty-two transect locations extended toward residential areas and, of these, twenty contained soil lead values dangerous to humans. This analysis also revealed that soil lead does not decrease logarithmically with distance from the highway, as shown in other studies. Soil lead at 3, 9, 27, 81, 243, 729, and 2187 …

Abundance And Distribution Of Herbaceous Angiosperms In Grass-Sedge Marshes Of West-Central Florida: The Effect Of Seasonal Water-Level Fluctuation, Pamela S. Botts

USF Tampa Graduate Theses and Dissertations

Grass-sedge marshes in west-central Florida were studied to determine the abundances and distributions of herbaceous angiosperms. Cluster analysis, reciprocal averaging, and a biotic boundaries technique were used to analyze the relationship between community composition and depth within the marsh. Shallow areas were dominated by Rhynchospora filifolia, Dichanthelium sabulorum, and Rhynchospora cephalantha. Abundances of the species fluctuated seasonally and varied between marshes. Deep areas of individual marshes differed markedly from shallow areas and from each other. A deep, well-drained marsh supported a monospecific stand of Juncus repens, while a less deep, but poorly drained marsh had a …

The Geometry Of James Joyce's Ulysses: From Pythagoras To Poincaré: Joyce's Use Of Geometry For Structure, Metaphor, And Theme, Susan Sutliff Brown

USF Tampa Graduate Theses and Dissertations

The extensive, previously unrecognized, use James Joyce made of contemporaneous geometric concepts for structure, metaphor, and theme in Ulysses provides new keys to how Joyce, following the model of his predecessors and contemporaries in Cubism, responded to the revolutions in aesthetics and physics which marked his intellectual milieu. As an examination of pre-publication materials reveals, during the six months before February 2, 1922, Joyce manipulated the pagination of the Ulysses placards and page proofs to impose geometric aesthetic proportions on the overall text and within individual episodes. Most significantly, Joyce aesthetically proportioned the pagination of the disparate eleven "initial style" …

The Diet Of The Gopher Tortoise, Gopherus Polyphemus, In A Sandhill Habitat In Central Florida, Laurie Ann Macdonald

USF Tampa Graduate Theses and Dissertations

Scat analysis and foraging observations were used to determine the diet of a gopher tortoise, Gopherus polyphemus, population in a sandhill community in west central Florida. Live vegetation was assessed to determine plant availability. The bulk of the gopher tortoise diet was composed of the dominant plant species in the habitat while the tortoises were selective with respect to most plant genera. Tortoises ingested many plant taxa with Poaceae, Asteraceae, Fabaceae, Pinaceae and Fagaceae being the most frequent components of the diet. Sixty-eight genera from 26 families were identified in the tortoise diet. In the scat the most common …

Stable Hydrogen And Carbon Isotopic Compositions Of Biogenic Methanes, Roger Allen Burke Jr.

USF Tampa Graduate Theses and Dissertations

Stable hydrogen and carbon isotopic compositions of biogenic methanes collected from the sediments of several deep-sea, nearshore marine-estuarine, and freshwater environments were determined. The isotopic compositions of methane samples from eight different DSDP Sites (mean σD-CH₄ = -185⁰>/∞, std. dev. = 7⁰>/∞, n = 75; mean σ¹³C-CH₄ = -71.3⁰/∞, std. dev. = 6.3⁰/∞, n = 44) are generally typical of methane formed via C0₂ reduction in deep-sea sediments.

Methane collected from several freshwater environments was D-depleted (mean σD-CH₄ = -300⁰>/∞ , std. dev. = …

Uptake Of Zn65 And Mn54 Into Body Tissues And Renal Granules By The Southern Quahog, Mercenaria Campechiensis, William Lynn Miller Jr.

USF Tampa Graduate Theses and Dissertations

A study was conducted to examine the influence of elevated inorganic phosphate and trace metal concentrations on the uptake and distribution of Zn⁶⁵ and Mn⁵⁴ into the body tissue and phosphoritic renal concretions of a subtropical estuarine bivalve, Mercenaria campechiensis. Chronological sampling of gills, mantle, adductor muscle, viscera, kidneys, and renal granules using gamma ray spectrometry allowed examination of both tissue distribution and accumulation patterns over time. The kidney was the principal site of Mn⁵⁴ accumulation whereas Zn⁶⁵ was concentrated in both the gill and the kidney. The gill initially accumulated zn65 three times faster …

Behavior, Habitat Use, Food, And Foraging Efficiency Of Three Species Of Sympatric Merons (Egretta), Donald M. Kent

USF Tampa Graduate Theses and Dissertations

The foraging ecology and behavior of Little Bule Herons (Egretta caerulea), Snowy Egrets (E. thula), and Tricolored Herons (E. tricolor) was studied from October 1981 to August 1982 in Old Tampa Bay and Safety Harbor, Hills borough and Pinellas Counties, Florida. Little Blue Herons foraged exclusively by walk-slow and employed head sways or tilted during 75% of the observations. Snowy Egrets used stand, walk-slow, disturb-and-chase, and foot-stirring. Tricolored Herons used stand, walk-slow, disturb-and-chase, ana stand-and-chase. Tricolored Herons using stand-and-chase stood near shore facing open water and when prey was spotted they ran or hopped in the direction of the prey …

Demography, Movements, Activity, Habitat Utilization And Marking Behavior Of A Bobcat (Lynx Rufus) Population In South-Central Florida, Douglas A. Wassmer

USF Tampa Graduate Theses and Dissertations

Eighteen (6 male and 7 female adults, 5 juveniles) radio-collared bobcats (Lynx rufus) were monitored on the Archbold Biofogical Station and vicinity during 1979-1982. Mean density was 0.06 males, 0.11 females, and 0.19 juveniles per 100 ha. Mean sex and age ratios were 0.6 adult males per adult female and 1.22 juveniles per adult. Breeding occurred from September to March. Mean size of 13 mobile litters was 2.5 (range 1-4). Nine (50%) of 18 collared cats died. Nine additional individuals were found dead or reported killed. Known causes of 16 deaths were: road-killed 8, feline panleukopenia or notoedric …

Reproductive Variability In Lytechinus Variegatus (Echinodermata: Echinoidea) From Different Habitats In A Florida West Coast Estuary, Robert G. Ernest

USF Tampa Graduate Theses and Dissertations

Lytechinus variegatus (Lamarck, 1916) is a sea urchin inhabiting shallow sub-littoral environments from Beaufort, North Carolina to southern Brazil. Although it has been collected extensively for embryological material in the southeastern United States (Harvey, 1956; Brookbank, 1968). there have been relatively few studies of its reproduction. Gonad indices were used to follow its annual reproductive cycle at Bermuda and Miami (Moore et al., 1963; Moore and Lopez, 1972), while elsewhere, only observations of spawn- ing have been reported (Boolootian, 1966).

In the Anclote estuary near Tarpon Springs, Florida, Lytechinus is the most conspicuous of the macroepibenthic invertebrates, and where requisite …

A Population Study Of The Burrowing Owl Near Tampa, Florida, William D. Courser

USF Tampa Graduate Theses and Dissertations

No abstract provided.

The Growth And Toxicity Of The Florida Red Tide Organism, Gymnodinium Breve, Marion Tilton Doig Iii

USF Tampa Graduate Theses and Dissertations

Mass mortalities of marine organisms in the Gulf of Mexico have been associated with blooms of the unarmored dinoflagellate, Gymnodinium breve. This investigation concerns the factors affecting the growth of G. breve and the properties of a toxin produced by the organism.

A modification of the Flask Test of the Provisional Algal Assay Procedure of the Joint Industry/Government Task Force on Eutrophication was used to determine the response of G. breve to various natural waters and enrichments. The growth-promoting potential of natural waters obtained from areas where outbreaks of G. breve frequently occur was greater than that of waters …