Digital Commons Network^™

Use Of Assessments In College Chemistry Courses: Examining Students' Prior Conceptual Knowledge, Chemistry Self-Efficacy, And Attitude, Sachel M. Villafañe-García

USF Tampa Graduate Theses and Dissertations

Students' retention in STEM-related careers is of great concern for educators and researchers, especially the retention of underrepresented groups such as females, Hispanics, and Blacks in these careers. Therefore it is important to study factors that could potentially influence students' decision to stay in STEM. The work described in this dissertation involved three research studies where assessments have been used in college chemistry courses to assess students' prior content knowledge, chemistry-self-efficacy, and attitude toward science. These three factors have been suggested to have an influence on students' performance in a course and could eventually be a retention factor.

The first …

Investigation Of Bioactive Metabolites From The Antarctic Sponge Dendrilla Membranosa And Marine Microorganisms, Chris G. Witowski

USF Tampa Graduate Theses and Dissertations

Natural products continue to be a valuable source of compounds in research involving chemical ecology and drug discovery. Secondary metabolites are biosynthesized to benefit the host organism in its environment (feeding deterrence from predators, antibiotic properties to avoid infection, etc.) but these compounds also serve as useful scaffolds in drug discovery applications. The research herein describes both aspects of these two branches of natural products chemistry. The Antarctic sponge Dendrilla membranosa produces diterpenes, of which membranolide A, deters feeding of the predatory amphipod Gondogenia antarctica. A metabolomic study of several sponges was undertaken to determine environmental factors that govern …

Mid-Holocene Speleothem Climate Proxy Records From Florida And Belize, Anna L. Pollock

USF Tampa Graduate Theses and Dissertations

As global temperatures rise due to anthropogenic climate change, water resources, thus economies, are threatened. A geologically recent period of increased temperatures is the mid-Holocene and an investigation of its climate may allow for a better understanding of future precipitation and changes to regional water resources. The regions of interest are tropical Northern Central America and subtropical North America with Belize and Florida representing each climate zone. By reconstructing mid-Holocene climate in Florida and Belize, I hope to provide a better understanding of how increased temperatures and a reduced latitudinal temperature gradient impacts both precipitation patterns and variability. Today, drivers …

Relationships Between The Algebraic Performance Of Students In Subject-Specific And Integrated Course Pathways, Derrick Saddler

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to compare the algebraic performance gains of high school students who enroll in an integrated mathematics course pathway (i.e., Integrated Mathematics I-II-III) to the algebraic performance gains of high school students who enroll in a subject-specific course pathway (i.e., Algebra I-Geometry-Algebra II). Several studies have been performed in which researchers examined relationships between mathematics outcomes and the course-taking patterns of high school students enrolled in subject-specific course pathways. However, there is little extant research in which researchers have investigated effects of content organization on students' learning and achievement. Therefore, this study addresses calls for …

Assessing Viscoelastic Properties Of Polydimethylsiloxane (Pdms) Using Loading And Unloading Of The Macroscopic Compression Test, Mustafa Fincan

USF Tampa Graduate Theses and Dissertations

Polydimethylsiloxane (PDMS) mechanical properties were measured using custom-built compression test device. PDMS elastic modulus can be varied with the elastomer base to the curing agent ratio, i.e. by changing the cross-linking density. PDMS samples with different crosslink density in terms of their elastic modulus were measured. In this project the PDMS samples with the base/curing agent ratio ranging from 5:1 to 20:1 were tested. The elastic modulus varied with the amount of the crosslinker, and ranged from 0.8 MPa to 4.44 MPa. The compression device was modified by adding digital displacement gauges to measure the lateral strain of the sample, …

Effect Of Interactive Digital Homework With An Ibook On Sixth Grade Students' Mathematics Achievement And Attitudes When Learning Fractions, Decimals, And Percents, Jennifer Zakrzewski

USF Tampa Graduate Theses and Dissertations

Over the past decade, technology has become a prominent feature in our lives. Technology has not only been integrated into our lives, but into the classroom as well. Teachers have been provided with a tremendous amount of technology related tools to educate their students. However, many of these technologically enhanced tools have little to no research supporting their claims to enhance learning.

This study focuses on one aspect of technology, the iBook, to complete homework relating to fractions, decimals, and percents in a sixth grade classroom. An iBook is a digital textbook that allows the user to interact with the …

Large-Eddy Simulation Of The Inner Continental Shelf Under The Combined Effects Of Surface Temperature Fluxes, Tidal Currents And Langmuir Circulation, Rachel Walker

USF Tampa Graduate Theses and Dissertations

In a shallow shelf region, turbulent motion can have a major effect on coastal processes including ecosystem functioning, surface gas exchange and sediment resuspension. Many factors contribute to such turbulence; wind and wave forcing, buoyancy induced by surface heat fluxes and tidal forcing all play a key role in generating vertical mixing in this shallow region. Alongside these independent sources of turbulence, combinations thereof can lead to full-depth turbulent structures acting secondary to the mean flow and leading to enhanced vertical mixing throughout the entire water column.

Field and laboratory experiments can often prove to be costly and time consuming, …

"Now You Know What You're Reaching For...On The Up And Up": An Interpretative Phenomenological Analysis Of Scholar Identity Development Among Black Male Achievers, Coretta Andréa Irby

USF Tampa Graduate Theses and Dissertations

Common discourse concerning the educational trajectories of African American males consists of dismal future outcomes due to defective schooling experiences in kindergarten through twelfth grades. There has been a disregard of counter narratives of high academic achievement and overall school success coupled with a highlighting of failure through deficit-based research practices. Consequently, African American males are positioned as delayed or troubled, which serves to perpetuate educational inequity. This study attempts to increase the scarcity of literature by giving voice to the experiences of high achievement among African American adolescent males attending a school designed to support the achievement of impoverished …

Quest Toward The Design And Synthesis Of Functional Metal-Organic Materials (Moms): A Supermolecular Building Layer Approach (Sbl), Hasnaa Mouttaki

USF Tampa Graduate Theses and Dissertations

Metal-Organic Materials (MOMs) represent an important division of coordination chemistry. They are self-assembled through the linking of metals with organic ligands. They gained their spotlight among scientists for their aptitude for design and facile synthesis via their multi-component coordination, and their readiness to functionalization. MOMs have been targeted for specific industrial and environmental applications such as gas storage, catalysis and CO₂ sequestration.

Throughout the past decade, studies have been conducted to develop systematic approaches toward the design and synthesis of functional MOMs. Their synthesis from targeted building units has facilitated their rational design and functionalization. The Molecular Building Block …

Active Tile Self-Assembly And Simulations Of Computational Systems, Daria Karpenko

USF Tampa Graduate Theses and Dissertations

Algorithmic self-assembly has been an active area of research at the intersection of computer science, chemistry, and mathematics for almost two decades now, motivated by the natural self-assembly mechanism found in DNA and driven by the desire for precise control of nanoscale material manufacture and for the development of nanocomputing and nanorobotics. At the theoretical core of this research is the Abstract Tile Assembly Model (aTAM), the original abstract model of DNA tile self-assembly. Recent advancements in DNA nanotechnology have been made in developing strand displacement mechanisms that could allow DNA tiles to modify themselves during the assembly process by …

Precalculus Students' Achievement When Learning Functions: Influences Of Opportunity To Learn And Technology From A University Of Chicago School Mathematics Project Study, Laura A. Hauser

USF Tampa Graduate Theses and Dissertations

The concept of function is one of the essential topics in the teaching and learning of secondary mathematics because of the central and unifying role it plays within secondary and college level mathematics. Organizations, such as the National Council of Teachers of Mathematics, suggest students should be able to make connections across multiple representations of mathematical functions by the time they complete high school. Despite the prominent role functions play in secondary mathematics curriculum, students continue to struggle with the complex notion of functions and especially have difficulty using the different representations that are inherent to functions (algebraic, graphical and …

A Conceptual Analysis Of Perspective Taking In Support Of Socioscientific Reasoning, Sami Kahn

USF Tampa Graduate Theses and Dissertations

Scientific literacy is concerned with the informed citizens' ability to negotiate scientifically-related societal issues. The suite of skills necessary to negotiate these complex issues is referred to as Socioscientific Reasoning (SSR). SSR requires, among other things, perspective-taking abilities in order to consider the multi-faceted nature of these open-ended, debatable socioscientific issues (SSI). Developing interventions and instruments to foster and measure perspective taking in support of SSR is therefore critical to the promotion of functional scientific literacy through both research and practice. Although widely studied in many disciplines, perspective taking is a particularly tangled construct that has been used to describe …

Mainstreaming Green Infrastructure: The Nexus Of Infrastructure And Education Using The Green Space Based Learning (Gsbl) Approach For Bioretention Plant Selection, Ryan Charles Robert Locicero

USF Tampa Graduate Theses and Dissertations

The Green Space Based Learning (GSBL) approach builds on a long-term partnership between a Research I university, surrounding community, and local school district, transforming underutilized community green space into an interactive educational tool to addresses national infrastructure and educational challenges. The GSBL approach is an educational platform for engaging K-12 and the local community in engineering design and construction of sustainable Green Infrastructure (GI) projects. GSBL was piloted as a part of a federally funded Research Experience for Teachers (RET) program in which teachers participated in two intensive 6-week summer research experiences and two consecutive academic year components. The summer …

The Evaluation And Study Of Modern Radiation Dosimetry Methods As Applied To Advanced Radiation Therapy Treatments Using Intensity Modulated Megavoltage Photon Beams, Cassandra Stambaugh

USF Tampa Graduate Theses and Dissertations

The purpose of this work is to evaluate quasi-3D arrays for use with intensity modulated radiation therapy (IMRT) and volumetric modulated arc therapy (VMAT) and to determine their clinical relevance. This is achieved using a Delta4 from Scandidos and ArcCheck from Sun Nuclear and the associated software. While certain aspects of these devices and software have been previously evaluated, the main goal of this work is to evaluate the new aspects, such as reconstructing dose on a patient CT set, and extending the capabilities. This includes the capability to reconstruct the dose based on a helical delivery as well as …

"I Want To Be The Sun": Tableau As An Embodied Representation Of Main Ideas In Science Information Texts, Margaret Branscombe

USF Tampa Graduate Theses and Dissertations

In this study I investigated the process drama convention of tableau to mediate for the representation of main ideas in science information texts. My pedagogical goal was to focus on the body as a tool for engaging with information texts and my rationale for this goal was the belief that the body is neglected in classroom learning. The task of creating caused the students to be active and to think of their own and other bodies as signifiers of meaning.

The methodology was based on a formative experiment that allowed for changes and modifications to be made in response to …

Facilitating Motivation In A Virtual World Within A Second Language Acquisition Classroom, Andrew Warren Gump

USF Tampa Graduate Theses and Dissertations

No abstract provided.

Aldehydic C-H Amination Reactions Via Co(Ii)-Based Metalloradical Catalysis And Construction Of Novel Chiral Meso-Amidoporphyrin Ligands, Christopher Lee Lizardi

USF Tampa Graduate Theses and Dissertations

Medium-sized organic ring synthesis poses a seemingly insurmountable challenge, and because of this it is a field under immense investigation. Heterocyclic containing medium-sized rings are common structural motifs in nature, which has caused researchers to investigate their potential biological activity and properties as materials. This research focused on the grand challenge of medium-sized heterocyclic ring synthesis, providing the synthesis community with new tools to generate these highly evasive products, while elucidating energetic and geometric properties of one of Nature's least understood organic ring systems.

Cobalt(II)-Amidoporphyrins, [Co(D₂-Por)], are an emerging class of metalloradical catalysts (MRC) which can facilitate …

Morphodynamics Of Mullet Key, West-Central Florida, Emeli Sandoval

USF Tampa Graduate Theses and Dissertations

Mullet Key is a right angle barrier island located at the mouth of Tampa Bay, west-central Florida. Based on historical shoreline data from 1873, the Gulf (west)-facing section of the beach has been dynamic illustrating large beach advances and retreats of up to 500 m on a decadal scale, while the south (channel)-facing section of the beach has shown to maintain a stable shoreline. This study focuses on the morphodynamics of the Gulf-facing beach. Since the 1920s, most of the Gulf-facing beach has been accreting except at the southern end near the Tampa Bay main channel. However, over the past …

An Experimental Study On Passive Dynamic Walking, Philip Andrew Hatzitheodorou

USF Tampa Graduate Theses and Dissertations

In this study, a previously designed passive dynamic walker (PDW) is built out of aluminum and plastic. The aim of the study was to produce an asymmetrical PDW and to compare the results to a computer simulation to validate the mathematical model. It also aimed at identifying the limitations of using additive manufacturing to create components for a PDW as well as gain insights on asymmetric systems.

Beginning with a five mass kneed model, parameters were varied to produce up to a nine mass kneed model solution. The nine mass model allows more variability in added mass locations and separates …

Adhesion Of Germanium Electrode On Nickel Substrate For Lithium Ion Battery Applications, Aadithya Jeyaranjan

USF Tampa Graduate Theses and Dissertations

Lithium ion batteries (LIBs) have gained increasing popularity due to their high potential, low self-discharge, zero priming and minimal memory effect. However, the emergence of electrical vehicles and hybrid electrical vehicles in the automobile industry, where LIBs are predominantly in use, instilled a need to improve LIB batteries by experimenting with new materials. Graphite, the commonly used anode material for LIBs suffers from low theoretical capacity (372 mA h g-1) and torpid rate performance. Germanium (Ge) seems to be a promising substitute of carbon due to its high theoretical capacity, high Li+ diffusivity and electrical conductivity. However, Ge undergoes large …

The Speleogenesis Of Vallgornera Cave (Mallorca, Spain): A Mineralogical And Morphological Study, Jacqueline Amelia Diehl

USF Tampa Graduate Theses and Dissertations

Cova des Pas de Vallgornera (CPV) is morphologically and scientifically, the most prominent karst feature of Mallorca Island (Spain). It consists of over 74 km of passages developed within two carbonate lithologies (reef front and back reef facies) of Upper Miocene age. Two distinct cave patterns are recognized, both tightly controlled by the type of facies; spongework mazes and collapse chambers are characteristic for the reef front unit, whereas linear, fracture-guided galleries develop in the back reef carbonates. CPV is abundantly decorated with a variety of speleothems.

The overarching goal of this study is to provide evidence towards the cave's …

A Natural Case For Realism: Processes, Structures, And Laws, Andrew Michael Winters

USF Tampa Graduate Theses and Dissertations

Recent literature concerning laws of nature highlight the close relationship between general metaphysics and philosophy of science. In particular, a person's theoretical commitments in either have direct implications for her stance on laws. In this dissertation, I argue that an ontic structural realist should be a realist about laws, but only within a non-Whiteheadean process framework. Without the adoption of a process framework, any account of laws the ontic structural realist offers will require metaphysical commitments that are at odds with ontic structural realism. In arguing towards this aim, I adopt an attenuated methodological naturalistic stance to show that traditional …

Integrated Multi-Criteria Signal Timing Design For Sustainable Traffic Operations, Rui Guo

USF Tampa Graduate Theses and Dissertations

Traffic signal systems serve as one of the most powerful control tools in improving the efficiency of surface transportation travel. Traffic operations on arterial roads are particularly complex because of traffic interruptions caused by signalized intersections along the corridor. This dissertation research presents a systematic framework of integrated traffic control in an attempt to break down the complexities into several simpler sub-problems such as pattern recognition, environment-mobility relationships and multi-objective optimization for multi-criterial signal timing design.

The overall goal of this dissertation is to develop signal timing plans, including a day plan schedule, cycle length parameters, splits and offsets, which …

Origins Of Music Programs In Liberal Arts Institutions: The Story Of Three Florida Catholic Universities, Cynthia S. Selph

USF Tampa Graduate Theses and Dissertations

This study examines the music programs in liberal arts colleges through the historical lens of three Catholic Universities in the state of Florida. Although there are numerous historical dissertations and theses written about individual music schools and departments, and a few that compare music programs in similar types of institutions, none have compared music programs in Catholic universities within the same state. After teaching at Saint Leo University and experiencing the process of rebuilding a music program after it was almost completely lost in the mid-1990s, I wanted to study the histories of Saint Leo and other Florida Catholic institutions …

Dcms: A Data Analytics And Management System For Molecular Simulation, Meryem Berrada

USF Tampa Graduate Theses and Dissertations

Despite the fact that Molecular Simulation systems represent a major research tool in multiple scientific and engineering fields, there is still a lack of systems for effective data management and fast data retrieval and processing. This is mainly due to the nature of MS which generate a very large amount of data - a system usually encompass millions of data information, and one query usually runs for tens of thousands of time frames. For this purpose, we designed and developed a new application, DCMS (A data Analytics and Management System for molecular Simulation), that intends to speed up the process …

The Detection And Quantitative Analysis Of Endocannabinoids And Endogenous Fatty Acid Amides In Apis Mellifera And Tribolium Castaneum, Perry Robert Mitchell Jr.

USF Tampa Graduate Theses and Dissertations

Endocannabinoids, and the fatty acid amides from which they are a member, have garnered greater scientific interest in the last two decades due to the cannabimimetic properties of these endogenous molecules. The most well-known of these is Anandamide, which has thus far been discovered in several species of animal ranging from C. elegans, fruit flies, to bovine and humans. Because of the importance and increasing impact of these compounds a brief overview is first presented herein, with a major focus on the N-acyldopamines due to the direct impact they potentially pose to human physiology.

Secondly, the detection and …

Constrained Motion Particle Swarm Optimization For Non-Linear Time Series Prediction, Nicholas Sapankevych

USF Tampa Graduate Theses and Dissertations

Time series prediction techniques have been used in many real-world applications such as financial market prediction, electric utility load forecasting, weather and environmental state prediction, and reliability forecasting. The underlying system models and time series data generating processes are generally complex for these applications and the models for these systems are usually not known a priori. Accurate and unbiased estimation of time series data produced by these systems cannot always be achieved using well known linear techniques, and thus the estimation process requires more advanced time series prediction algorithms.

One type of time series interpolation and prediction algorithm that has …

Secondary Band Participation And Executive Function, Dakeyan Cha' Dre' Graham

USF Tampa Graduate Theses and Dissertations

Data on standardized tests is often used to advocate for the inclusion of music programs in secondary education curriculum. There have been studies that claim to identify a relationship between music participation and higher earned test scores; however, correlation does not necessarily equate to causation. The argument between whether music instruction improves student testing ability or if higher achieving students are attracted to music courses is still prevalent within the music education domain. Executive function represents the processes within the brain that encompass a number of cognitive ability processes used in the transfer of knowledge. These processes are essential to …

The Development Of An Adaptive Driving Simulator, Sarah Marie Tudor

USF Tampa Graduate Theses and Dissertations

The ability to drive a car is an important skill for individuals with a spinal cord injury to maintain a high quality of life, particularly their freedom and independence. However, driving with a physical disability often requires the installation of an adaptive driving system to control steering, gas, and braking. The two main types of adaptive driving controls are mechanical and electrical, also known as drive by wire (DBW). DBW controls work by converting electric signals to mechanical actuators. Driving simulators are useful tools for adaptive driving systems because they allow users to test different control devices, to practice driving …

Parent-Child Interaction Therapy As A Treatment For Adhd In Early Childhood: A Multiple Baseline Single-Case Design, Kendall Jeffries Deloatche

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to examine the effectiveness of PCIT as an alternative to medication in managing symptoms and behavior problems of preschool-aged children with ADHD. Using a multiple baseline single-case design, the study measured the impact of PCIT on four preschool-aged children's problem behaviors and ADHD symptoms, parenting practices, and mothers' attitudes towards therapy. Outcome measures included the Child Behavior Checklist, Eyberg Child Behavior Inventory, Behavior Assessment System for Children, ADHD Symptom Observation form, Dyadic Parent-Child Interaction Coding System, Parenting Practices Interview, and Therapy Attitude Inventory. Results from visual analyses, a visual permutation test, and hierarchical linear …