Digital Commons Network^™

Exploring Student Learning In Post-Secondary General Chemistry: Novel Tools For Measuring Linked Concepts And Study Habits, Li Ye

USF Tampa Graduate Theses and Dissertations

This dissertation presents novel tools to help instructors measure students linking of content knowledge and the actions students perform for studying in the context of post-secondary General Chemistry.

The first tool described in this work is Creative Exercises (CEs), an open-ended assessment that has the potential to promote students making connections across the content covered in General Chemistry. Students are given a simple prompt that describes a chemistry situation, and asked to write as many statements as they can that are correct, distinct and relevant to the prompt and the course content. The written responses to CEs from both in-class …

"There Is No Planet B": Frame Disputes Within The Environmental Movement Over Geoengineering, David Russell Zeller Jr.

USF Tampa Graduate Theses and Dissertations

This dissertation examines frame disputes within the environmental movement over geoengineering proposals. Among other core framing tasks, social movement organizations must evaluate solutions and strategies for the social problems they seek to address. These framings are frequently disputed by those within the movement. Recent controversies regarding a set of climate intervention proposals commonly known as geoengineering offer the opportunity to document the ongoing construction of competing visions of environmental sustainability. The nascent quality of these proposals generate dissonant framings—episodes where organizations within the environmental movement exhibit disagreement about one or more core framing tasks—a situation Goffman referred to as a …

The Influence Of Tropical Forests And Climate Change On The Fates Of Select Organic Pollutants In A Jamaican Watershed, Kayon Barrett

USF Tampa Graduate Theses and Dissertations

Many organic compounds, although beneficial, are associated with negative health and ecological impacts. It is therefore imperative to understand the environmental fates of these contaminants. Whereas the fates and health impacts of many persistent organic pollutants have been extensively examined, there is limited research characterizing the fates of these and the less persistent organic compounds in tropical multi-use watersheds. This study therefore aimed to evaluate the roles of forests and climate change on the environmental fates and health impacts of select organic chemicals in the Rio Cobre watershed, a tropical river basin in Jamaica. A total of 16 organic compounds …

Robustness Of The Within- And Between-Series Estimators To Non-Normal Multiple-Baseline Studies: A Monte Carlo Study, Seang-Hwane Joo

USF Tampa Graduate Theses and Dissertations

In single-case research, multiple-baseline (MB) design is the most widely used design in practical settings. It provides the opportunity to estimate the treatment effect based on not only within-series comparisons of treatment phase to baseline phase observations, but also time-specific between-series comparisons of observations from those that have started treatment to those that are still in the baseline. In MB studies, the average treatment effect and the variation of these effects across multiple participants can be estimated using various statistical modeling methods. Recently, two types of statistical modeling methods were proposed for analyzing MB studies: a) within-series model and b) …

Coherent Response Of Two Dimensional Electron Gas Probed By Two Dimensional Fourier Transform Spectroscopy, Jagannath Paul

USF Tampa Graduate Theses and Dissertations

Advent of ultrashort lasers made it possible to probe various scattering phenomena in materials that occur in a time scale on the order of few femtoseconds to several tens of picoseconds. Nonlinear optical spectroscopy techniques, such as pump-probe, transient four wave mixing (TFWM), etc., are very common to study the carrier dynamics in various material systems. In time domain, the transient FWM uses several ultrashort pulses separated by time delays to obtain the information of dephasing and population relaxation times, which are very important parameters that govern the carrier dynamics of materials. A recently developed multidimensional nonlinear optical spectroscopy is …

Germania- And Silica-Based Perfluorinated And Non-Fluorinated Sol-Gel Sorbents For Capillary Microextraction In Chromatographic Analysis, Emre Seyyal

USF Tampa Graduate Theses and Dissertations

Sample preparation is the most time-consuming and error-prone step in chemical analysis. Miniaturization and automation of the sample preparation equipment eliminating or reducing the use of hazardous organic solvents, online hyphenation of sample preparation with analytical instruments in a cost-effective way are important factors that need to be considered to design and implement innovative sample preparation techniques and strategies. Solid-phase microextraction (SPME) is a simple, environmentally benign technique well suited for hyphenation with analytical instruments. However, poor coating stability is a significant drawback of SPME employing conventionally prepared coatings. This shortcoming arises from the lack of chemical bonding between the …

In Vivo Channel Characterization And Energy Efficiency Optimization And Game Theoretical Approaches In Wbans, Yang Liu

USF Tampa Graduate Theses and Dissertations

This dissertation presents several novel accomplishments in the research area of Wireless Body Area Networks (WBANs), including in vivo channel characterization, optimization and game theoretical approaches for energy efficiency in WBANs.

First, we performed the in vivo path loss simulations with HFSS human body model, built a phenomenological model for the distance and frequency dependent path loss, and also investigated angle dependent path loss of the in vivo wireless channel. Simulation data is produced in the range of 0.4−6 GHz for frequency, a wide range of distance and different angles. Based on the measurements, we produce mathematical models for in …

Interference Of Light In Multilayer Metasurfaces: Perfect Absorber And Antireflection Coating, Khagendra Prasad Bhattarai

USF Tampa Graduate Theses and Dissertations

We have studied several metamaterials structures with multiple layers by explaining them theoretically and verifying experimentally. The engineered structures we have designed work either as a perfect absorber or antireflection coating. The multilayer model as we call it Three Layer Model (TLM) has been developed, which gives the total reflection and transmission as a function of reflection and transmission of individual layers. By manipulating the amplitude and phase of the reflection and the transmission of the individual layers, we can get the required functionality of the optoelectronic devices. To get zero reflection in the both perfect absorber and the antireflection …

Controlling And Monitoring Voice Quality In Internet Communication, An Thanh Le

USF Tampa Graduate Theses and Dissertations

The Voice over Internet Protocol (VoIP) is on its way to surpassing toll quality. Although VoIP shares its transmission channel with other communication traffic, today internet has a wider bandwidth than the legacy Digital Loop Carrier and voice could be digitized higher than traditional 8 kbps, to say 16 kbps. Thus, VoIP should not be limited by the toll quality. However, VoIP quality could go down, as a result of unpredictable traffic congestion and network imperfections. These two situations cause delay jitter and packet loss of VoIP. To overcome these challenges, there are ongoing works for service providers including but …

The Sustainability Of Ion Exchange Water Treatment Technology, Adib Amini

USF Tampa Graduate Theses and Dissertations

This research investigated using a life cycle environmental and economic approach to evaluate IX technology for small potable water systems, allowing for the identification and development of process and design improvements that reduce environmental impacts and costs. The main goals were to evaluate conventional IX in terms of life cycle environmental and economic sustainability, develop a method for improving designs of IX systems from a environmental and economic sustainability standpoint, evaluate potential design improvements, and make the research findings accessible to water professionals through user-friendly tools and frameworks that take into account their feedback. This research provides an understanding, from …

The Sustainability Of Career And Technical Education Teacher Preparation Programs In Florida, Lisa Martino

USF Tampa Graduate Theses and Dissertations

There is a historical trend of decline in available Career and Technical Education (CTE) Teacher Preparation programs and an increase in CTE course and program enrollments in Florida’s secondary school system. This contradiction in CTE teacher supply and demand raises an important question. What is going on? More specifically, what sustains the remaining programs in the face of this decline?

The purpose of this qualitative study is to explore sustainability factors from past and present CTE teacher preparation program educators and administrators to gain a better understanding of this issue. The participant selection for this study was identified from four …

On The Conformational Dynamics Of Dna: A Perspective From Molecular Dynamics Simulations, Ning Ma

USF Tampa Graduate Theses and Dissertations

The main focus of my dissertation is on the conformational motion of DNA, studied by applying tools from the computational chemistry field. In addition, studies of relative α- and 310 helical stabilities in peptides/mini-proteins, and a molecular flooding study of the retinoid X-receptor as part of a continuing drug design effort are presented. In molecular biology, it has been well known that sequence determines structure, and structure controls function. For proteins or DNA to work properly, the correct configuration is required. Mutations may alter the structure, which can cause malfunction. Non-mutational effects, such as a change in environment may also …

Strategies For Reducing Preventable Hospital Readmissions On Medicare Patients, Andres Patricio Garcia-Arce

USF Tampa Graduate Theses and Dissertations

The high expenditure of healthcare in the United States (U.S.) does not translate into better quality of care. Indeed, the U.S. healthcare system is recognized by its lack of efficiency and waste (which represents about 20% of the country’s healthcare expenses). Lack of coordination is one of the most referenced causes of waste in the U.S. healthcare system, and preventable hospital readmissions have been acknowledged to be evidence of poor coordination of care. In fiscal year 2013, the Centers for Medicare and Medicaid Services (CMS) established financial penalties for inpatient care reimbursements in hospitals with excessive readmissions. All the same, …

Dynamics Of Multicultural Social Networks, Kristina B. Hilton

USF Tampa Graduate Theses and Dissertations

Historically human endeavors around the globe are in search of bilateral relationships. Knowledge and commerce has played a very significant role in increasing the ability for humans to connect for the betterment of the human species. As the means of communication improve, mutual benefits to the community as a whole also increase. Moreover, the benefits are filtered down to members of the overall community. Recent advancement in electronic communication technologies and in knowledge, in particular, physical, chemical, engineering and medical sciences and philosophies, have facilitated nearly instantaneous multi-cultural interactions. Local problems and solutions have become global. This has generated a …

Mitigation Of Insider Attacks For Data Security In Distributed Computing Environments, Santosh Aditham

USF Tampa Graduate Theses and Dissertations

In big data systems, the infrastructure is such that large amounts of data are hosted away from the users. Information security is a major challenge in such systems. From the customer’s perspective, one of the big risks in adopting big data systems is in trusting the service provider who designs and owns the infrastructure, with data security and privacy. However, big data frameworks typically focus on performance and the opportunity for including enhanced security measures is limited. In this dissertation, the problem of mitigating insider attacks is extensively investigated and several static and dynamic run-time techniques are developed. The proposed …

Optimization And Performance Study Of Select Heating Ventilation And Air Conditioning Technologies For Commercial Buildings, Rajeev Kamal

USF Tampa Graduate Theses and Dissertations

Buildings contribute a significant part to the electricity demand profile and peak demand for the electrical utilities. The addition of renewable energy generation adds additional variability and uncertainty to the power system. Demand side management in the buildings can help improve the demand profile for the utilities by shifting some of the demand from peak to off-peak times.

Heating, ventilation and air-conditioning contribute around 45% to the overall demand of a building. This research studies two strategies for reducing the peak as well as shifting some demand from peak to off-peak periods in commercial buildings:

1. Use of gas heat …

Modeling In Finance And Insurance With Levy-It'o Driven Dynamic Processes Under Semi Markov-Type Switching Regimes And Time Domains, Patrick Armand Assonken Tonfack

USF Tampa Graduate Theses and Dissertations

Mathematical and statistical modeling have been at the forefront of many significant advances in many disciplines in both the academic and industry sectors. From behavioral sciences to hard core quantum mechanics in physics, mathematical modeling has made a compelling argument for its usefulness and its necessity in advancing the current state of knowledge in the 21rst century. In Finance and Insurance in particular, stochastic modeling has proven to be an effective approach in accomplishing a vast array of tasks: risk management, leveraging of investments, prediction, hedging, pricing, insurance, and so on. However, the magnitude of the damage incurred in recent …

The Dynamics Of The L2 Motivational Self System Among Saudi Study Abroad Students, Fahad Alharbi

USF Tampa Graduate Theses and Dissertations

Adult second language acquisition takes time over an extended period of time during which the L2 motivation of learners goes through periods of ups and downs. Dörnyei, MacIntyre and Henry (2015) recognized the inherently dynamic nature of L2 motivation and called for adopting the Complex Dynamic System Theory (CDST) when studying this phenomenon. While using a CDST perspective, this mixed method study drew on Dörnyei’s (2009b) model of the Motivational Self System to examine the L2 motivation of 86 Saudi study-abroad students. Also, the construct of the Anti-ought to Self (Thompson, 2015) and aspects of the Appraisal Theory (Schumann, 2001) …

Exploring Teacher Assessment Literacy Through The Process Of Training Teachers To Write Assessment Items, Heather Peltier Wright

USF Tampa Graduate Theses and Dissertations

The purpose of this study was to examine the process and impact of assessment training content and delivery mode on the quality of assessment items developed by the teachers in a two-year assessment development project. Teacher characteristics were examined as potential moderating factors. Four types of delivery mode were employed in the project: synchronous online, asynchronous online, in-person workshop, and blended (a combination of online and in-person training). The quality of assessment items developed by participating teachers was measured via: 1) item acceptance rate, 2) number of item reviews (as an indicator of how many times accepted items were rejected …

Quantity Trumps Quality: Bayesian Statistical Accumulation Modeling Guides Radiocarbon Measurements To Construct A Chronology In Real-Time, Devon Robert Firesinger

USF Tampa Graduate Theses and Dissertations

The development of an accurate and precise geochronology is imperative to understanding archives containing information about Earth’s past. Unable to date all intervals of an archive, researchers use methods of interpolation to approximate age between dates. Sections of the radiocarbon calibration curve can induce larger chronological uncertainty independent of instrumental precision, meaning even a precise date may carry inflated error in its calibration to a calendar age. Methods of interpolation range from step-wise linear regression to, most recently, Bayesian statistical models. These employ prior knowledge of accumulation rate to provide a more informed interpolation between neighboring dates. This study uses …

Scalable Unsupervised Learning With Game Theory, Alireza Chakeri

USF Tampa Graduate Theses and Dissertations

Recently dominant sets, a generalization of the notion of the maximal clique to edge-weighted graphs, have proven to be an effective tool for unsupervised learning and have found applications in different domains. Although, they were initially established using optimization and graph theory concepts, recent work has shown fascinating connections with evolutionary game theory, that leads to the clustering game framework. However, considering size of today's data sets, existing methods need to be modified in order to handle massive data. Hence, in this research work, first we address the limitations of the clustering game framework for large data sets theoretically. We …

Sustainable Development Through Urban Agriculture, Eric R. R. Weaver

USF Tampa Graduate Theses and Dissertations

This document includes three completed publications to represent Urban Agriculture as a ideal solution to meet the UN Sustainable Development Goals. The first publication (Weaver, 2017a) provided in Chapter Two examines the stormwater Best Management Practices (BMP) modelling parameters for the current EPA Stormwater Management Model (SWMM) as the first step to developing Urban Agriculture BMPs. The second publication (Weaver, 2015) provided in Chapter Three highlights how many high-rated scholars have identified agriculture as a critical driver for the planetary systems impacts we find with community development. The third publication (Weaver, 2017b) provided in Chapter Four breaks down a completely …

Tradeoffs In Protocol Designs For Collaborative Authentication, Jacob Venne

USF Tampa Graduate Theses and Dissertations

Authentication is a crucial tool used in access control mechanisms to verify a user’s identity. Collaborative Authentication (co-authentication) is a newly proposed authentication scheme designed to improve on traditional token authentication. Co-authentication works by using multiple user devices as tokens to collaborate in a challenge and authenticate a user request on single device.

This thesis adds two contributions to the co-authentication project. First, a detailed survey of applications that are suitable for adopting co-authentication is presented. Second, an analysis of tradeoffs between varying protocol designs of co-authentication is performed to determine whether, and how, any designs are superior to other …

Using Remote Sensing To Evaluate Wetland Recovery In The Northern Tampa Bay Area Following Reduction In Groundwater Withdrawals, Amor Elder

USF Tampa Graduate Theses and Dissertations

In the past, the Northern Tampa Bay Area (NTBA) wetlands saw severe declines in hydrologic conditions due to excessive groundwater withdrawal rates. Eventually these rates were reduced to allow the wetlands to recover. To monitor this recovery, the Southwest Florida Water Management district (SWFWMD) set up a fieldwork based scoring methodology, called the Wetlands Assessment Procedure (WAP). WAP has been used in many studies of the area since groundwater withdrawal reductions; with many of those studies finding the recovery to be mixed at best. However, these studies were very limited in the number of wetlands they could assess due to …

Abundance And Habitat Preferences Of Introduced Muscovy Ducks (Cairina Moschata), Jacqueline Marie Perry Cahanin

USF Tampa Graduate Theses and Dissertations

Muscovy ducks are native only to Central and South America, Mexico, and parts of southern Texas and are considered invasive in some areas outside of their native range. Although they have been introduced worldwide, they remain largely unstudied. The primary focus of this study was to relate Muscovy duck abundance to habitat characteristics of wetlands in Tampa, Florida. Muscovy abundance was measured using point count methods at 21 wetland sites that occur within an eight km radius of the University of South Florida’s main campus. Habitat features at these sites were assessed using field methods and Geographic Information Systems (GIS) …

A Novel Approach To The Discovery Of Natural Products From Actinobacteria, Rahmy Tawfik

USF Tampa Graduate Theses and Dissertations

Actinobacteria, primarily the genus Streptomyces, have led to the development of a number of antibiotics, which result from their secondary metabolites or modified derivatives. Secondary metabolite production can result from competition with neighboring microbes in an effort to disrupt growth, aiding in the competition for vital nutrients in impoverished conditions. Such secondary metabolites have the potential to affect a plethora of cellular functions in target cells, including, cell wall development, protein synthesis, protein function and fatty acid synthesis/metabolism. Due to the pandemic spread of antibiotic resistant bacteria, it is imperative to continue the search for new therapeutic agents …

3d Cave And Ice Block Morphology From Integrated Geophysical Methods: A Case Study At Scărişoara Ice Cave, Romania, Jackson Durain Hubbard

USF Tampa Graduate Theses and Dissertations

Scărişoara Ice Cave has been a catalyst of scientific intrigue and effort for over 150 years. These efforts have revealed and described countless natural phenomena – and in the process have made it one of the most studied caves in the world.

Of especial interest is the massive ice block located within its Great Hall and scientific reservations. The ice block, which is the oldest and largest known to exist in a cave, has been the focus of multiple surveying and mapping efforts, typically ones utilizing traditional equipment. In this study, the goals were to reconstruct the ice block/cave floor …

Tunable Combline Filter And Balun: Design, Simulation, And Test, Daniel Alex Ramirez

USF Tampa Graduate Theses and Dissertations

Reconfigurable filters are an attractive solution for many military and commercial applications due to their ability to alter the partitioned frequency band in an RF system without requiring a bank of fixed filters. The onset of this technology has the potential to revolutionize the RF industry by allowing for agile devices which consume less size, weight, and power while providing greater performance. However, at the present state, reconfigurable filters present a reduction in performance when compared to filter banks. This has led to exciting research in the field of RF tunable filters.

For many applications, planar reconfigurable filters have been …

Failure Analysis Of High Nickel Alloy Steel Seal Ring Used In Turbomachinery, Wenbo Wang

USF Tampa Graduate Theses and Dissertations

The system of upper high nickel alloying steel seal ring and lower high nickel alloying steel seal ring, installed in the grooves of turbine, can extend out and fit with the wall of valve cage, resulting in forming a good seal under the pressure. In the project, the failure steel seal ring is considered. This situation had threatened the safety of the whole steam turbine system. The purpose of this study is to identify the failure cause of the steel seal ring used in nuclear steam turbines. New high nickel steel alloy seal ring was compared with the failed seal …

A Study Of Corrosion Monitoring Techniques Used In Urls For Metals, Sirui Li

USF Tampa Graduate Theses and Dissertations

With the increasing use of fission-type nuclear power generation, particularly high-levels radioactive nuclear waste are generated, so the safe use of nuclear energy requires proper disposal of high-level radioactive nuclear waste. The selected treatment method is deep geological disposal. Therefore, underground research laboratory (URL) to prepare for deep geological disposal will also be carried out. Corrosion of metallic materials, which are closely related to the safety of URL, is the focus of this research project. This study selected monitoring techniques for URL and developed a rough monitoring scheme for temperature and resistivity in URL. In this study, corrosion-temperature and corrosion-resistivity …