Digital Commons Network^™

Five Plays, William Roth Ortwein

Theses

None provided.

Correlation Of Drain Breakdown With Excess Noise And Other Surface-Related Phenomena In Enhancement Mosfets, Jerry J. Rij

Theses

An investigation of semiconductor surface-related phenomena has been undertaken to correlate 1/F noise with drain breakdown in P-channel enhancement MOSFET's. Increases in the intensity of drain current fluctuations at 10Hz and at 1KHz, particularly at the higher frequency, was observed following accelerated life-testing for threshold voltage drift. It was also concluded that mobile ions near the oxide-semiconductor interface produce a sharp increase in fast trapping centers. It was also found that 1/F noise intensity consistently peaked at the threshold of drain breakdown and that it steadily decreased with further increases in drain current. Of all the transistors tested, those with …

Rubbery Acrylic Polymer Adhesives, Steven Walter

Theses

This study shows how rubbery acrylic polymer adhesives can be used to adhere rubber substrates to each other. Two substrate rubber compounds were used. A styrene-butadiene copolymer and a styrene-acrylonitrile copolymer. The adhesives were homopolymers based on polybutyl acrylate and poly2-ethyl hexyl acrylate.

Two reference standards were used. The first was commercial rubber based, solvent cements. The second was commercial acrylic solution polymers. All experimental work was compared to these standards. An attempt was made to optimize the adhesive components, as well as the adhesive application procedures and curing conditions.

A primer coating consisting of polymer, monomer, and catalyst was …

Biocatalytic Oxidation Of Nitrilotriacetate, Saul Hammerman

Theses

The specific scope of this work is to study the biological and chemical effects of a single genetic strain of bacteria, Bacillus subtilis #9524, on the specific destruction to innocuous products of sodium nitrilotriacetate (NTA) and sodium tripolyphosphate (STPP). Insofar as the same strain of bacteria was used each time, under limited variability and sterile conditions, the side effects of multiple bacterial strains and their inter-relationships among themselves and the organic substrates are eliminated. This has allowed for excellent replication of results.

This is a generalized technique for the evaluation of the biodegradability of a compound. Whereas tests with activated …

The Design And Analysis Of A Rapid Transit Speed Regulator, Frank Svet

Theses

A rapid transit speed regulator is examined utilizing classical control theory and digital computer simulation. The transient response to velocity step input commands are examined under constraints placed on percent overshoot, steady state error, acceleration and jerk limiting. The effect of each constraint is examined for various weight trains. A means of loop compensation that will meet the desired design objectives concerning the transient response is then analyzed and simulated. A detailed discussion of both vehicle and motor dynamics is also presented.

The Quantitative Characterization Of Middle Distillate Fuels For Reduced Smoke Emission And Improved Low Temperature Operability, R. S. Feamster

Theses

Forty-eight inference equations are presented to approximate the hydrocarbon composition of middle distillate fuels and of the solids separating from these fuels at temperatures below their cloud points by consideration of fuel physical inspections. The physical inspections consist of API gravity, aniline point, cloud point, and distillation curves for ten fuels from major United States and European refineries. To determine the percentage of solids separating from cooled fuels, each fuel is filtered over a temperature range from the cloud point to -40 F in 10 F increments. Aromatic, naphthenic, and paraffinic hydrocarbon contents and the r-paraffin carbon number distributions of …

Stress-Relaxation Of Cross-Linked Polyethylene At Elevated Temperature, Ravio Luik

Theses

Polyethylene because of its excellent chemical, physical, mechanical and electrical properties, as well as its easy adaptability to extrusion, molding and other processes and its low cost has become a very widely used material for hundreds of applications. But, because it is a thermoplastic, it also deforms and flows when temperatures approach or exceed the crystalline melting point. This handicap, however, can be reduced by crosslinking the polymer chains and thereby converting the thermoplastic to a thermoset material. To further expand the possible uses of this popular material and to further improve the properties, fillers and antioxidants may be compounded …

The Photolysis Of P-Xylene In An Aqueous Environment, Joseph Daniel Lintott

Theses

The photolysis of p-xylene in several aqueous solutions was studied as a model for removing refractory organic pollutants from water, and to demonstrate that photochemical reaction of these compounds may be an important factor in their degradation in the environment.

Solutions of p-xylene in deaerated water, water saturated with oxygen, 0.05M sodium phosphate tribasic, 0.1M sodium nitrate and 3.28X10^-4M ferric sulfate were exposed to ultraviolet and visible radiation. p-Xylene in 3.28X10^-4M ferric sulfate was also exposed to sunlight. The reaction rate was determined by measuring the disappearance of the p-xylene.

In all of the photolyses, except …

The Photolysis Of Chlorobenzene In An Aqueous Environment, Louis John Del Tufo

Theses

Chlorobenzene was chosen as a model system for the study of photochemically induced reactions in an aqueous environment. It was the goal of this research to achieve a reaction system which best approximates conditions existing in the environment. To do this, a basic model system was established, and then the effect on the rate by various parameters was studied. These parameters, which included the presence of oxygen and such inorganic compounds as might be present in receiving waters, (e.g. nitrate, sulfate, and phosphate), were chosen so as to meet the goal of this research.

Kinetic data was obtained for seven …

A Theoretical Study Of Continuous Parametric Pumping At Constant Temperature, Philip Weingartner

Theses

A continuous parametric pump, operating at constant temperature with pressure as the driving force, is analyized by means of an equilibrium theory. A thorough explanation of the process and the resulting mathematical model reveal how the parameters effect pump performance. The experimental data cited agree well with the analytical results in the CO₂-He on silica gel system. Complete removal of the solute from one of the product streams can be achieved through the proper selection of penetration distances and pressure levels.

Distillation Design Techniques, Ronald Michael Carlucci

Theses

A design method for binary distillation systems is presented that minimizes the required rigorous calculations. A computer program is developed that finds the number of theoretical stages, and feed stage for a specified separation and reboiler vapor rate. Results for three binary systems are presented.

The design method and computer program are extended to the multicomponent case at the condition of total reflux. Results for one ternary system are presented. The possibility of using the method at other than total reflux is discussed. Usage of the method to search for multicomponent azeotropes and results are also presented.

Analytic equations are …

Antoine Type Equation For Liquid Viscosity Correlations, Edward Goletz Jr.

Theses

A modified Andrade⁴ equation, similar to the Antoine equation for vapor pressure-temperature correlations, was developed for liquid viscosity-temperature correlations. Included in the investigation were the following compounds: n-alkanes (C₂-C₂₀), n-alkenes (C₂-C₂₀), n-alkyl benzenes (C₆-C₁₀), n-alkyl cyclohexanes (C₆-C₂₂), and fifteen polar compounds. Except for propene, errors of less than 5% were obtained. Normal heptadecane was used to compare correlations developed by Andrade⁴, Walther²⁰, and Doolittle⁹, with the modified Andrade equation. The latter was found to give the best …

A Computer Solution For Absorbers And Strippers Using The Newton-Raphson Iterative Method, Robert J. Lukach

Theses

The solution of absorber or stripper calculations by traditional methods can be a tedious, time consuming, if not a completely fruitless procedure. Hence a computer solution of these calculations is both desirable and, as the complexity of chemical process plants increases, necessary.

The component oriented Newton-Raphson procedure was programed to perform this calculation, and makes full use of the material and enthalpy balance equations to perform the iterative equilibrium stage calculations. A Newton-Raphson stage oriented method was also developed as a verification program to check the solutions obtained from the Newton-Raphson component oriented procedure.

Computer Simulation Of A Split Feed Claus Sulfur Recovery Plant, Thomas R. Woolley

Theses

A computer program which calculates a complete heat and material balance around a "split feed" Claus sulfur recovery plant was written in Fortran IV for the RCA Spectra 70 computer. The program provides for up to three catalytic reactors, the hot gas bypass method of reheating, and a feed gas containing hydrogen sulfide, water vapor, hydrogen, and nitrogen. The program user specifies as input data the feed stream composition and temperature, the number of reactors, the combustion air temperature, the conversion in each reactor, the outlet temperature in each condenser, and the fraction of burner exit gas used for reheating …

Effect Of Errors In Spectrophotometry Due To Fluorescence On The Ability To Calculate Colors By The Neugebauer Equations, Junichi Iwao

Theses

Spectrophotometers were originally designed without taking into account the fluorescent effect of papers and inks on spectrophotometric measurements. Monochromatic illumination is used in most of the available spectrophotometers, but the spectrophotometric curve measured by using monochromatic light does not approximate the same effect that is seen by the eye if fluorescence is present. White light illumination must be used to obtain a valid spectrophotometric curve of fluorescent materials. The Neugebauer equations are often used to calculate the tristimulus values of halftone prints. As long as the Neugebauer primaries do not fluoresce, measurements of primaries made by monochromatic illumination are valid. …

A Dead Time Process Controller, Frank Hermance

Theses

The control of systems containing pure dead time elements has plagued the control engineer for many years. This thesis discusses a new controller developed by this writer which offers improved performance in first order processes dominated by a dead time element.

Resolving Power Determination By Direct Observation Of Unprocessed Film By Reflected Light, James Belisle, Emery Prather

Theses

Measurement of resolving power of an emulsion is usually determined by an extensive exposure and development series. Resolving power is reported at the optimum value and exposure and density are reported also. Such a procedure is wasteful and time consuming. This paper explores the determination of resolving power by the observation of a reflected image of a resolution target on unprocessed. The reflection from the gelatin support was higher than that of the silver halide grains and thereby masked the reflected image from the grains. This phenomenon was observed over the entire range tested. The maximum obtained was 746 lines …

The Objective Evaluation Of Image Quality Produced With Physical Development, Bruce C. Smith, Keith M. Snyder

Theses

This experiment was an analysis of the difference in objective measures of image quality between chemical and physical development methods, including prefixation and postfixation processes. Of particular interest was the process outlined by Matejec1 for postfixation physical development. An investigation of resolving power and MTF for two fine grain films was carried out for four different development processes all possessing approximately the same speed capability. Both the effect of combined chemical and optical spread functions and the chemical spread alone were investigated through edge analysis using Fourier methods. A significant increase in image quality was found with the finest grain …

The Use Of Thin Layer Chromatography (Tlc) In Qualitative And Quantitative Determinations Of Photographic Developing Agents (In Developer Solution) Using A Scanning Densitometer, Michael Gilbert

Theses

TLC was used, for qualitative and quantitative analysis of photographic developing agents hydroquinone, metol, phenidone, para phenylenediamine, para aminophenol, ascorbic acid and the oxidized species. Experimental conditions and procedures for reporting Rf values of the aqueous solutions of the developing agent were standardized. Quantitative TLC was done for hydroquinone. The density maxima obtained from the scanning densitometric trace of the eluted and visualized chromatogram was correlated to the concentration of the hydroquinone. Aqueous solutions of hydroquinone were prepared at four levels of concentration, three levels of pH and two levels of sodium sulfite concentration for quantitative analysis using TLC.

Diffusion Studies With Novel Plastics, Marion Toohey Conway

Theses

The rates of diffusion through two fluorinated groups and two non-fluorinated groups of laboratory prepared membranes were compared with each other and with commercially available cellulose membranes. The membranes.were evaluated, in particular, for possible use with the artificial kidney. Diffusion experiments were conducted with sodium chloride, urea and uric acid. Experimental results were compared to diffusion coefficients calculated in the literature for cellulose membranes. The results show that the rates of diffusion of all of the solutes tested for the laboratory prepared membranes are comparable to that of the cellulose membranes. The fluorinated group had a slightly higher diffusion coefficient …

Minimum Reflux In Fractionating Columns : A New And Improved Short-Cut Method, Elizabeth Garcia

Theses

A short-cut method is presented for calculating the minimum, reflux rate for multicomponent systems. This new method is best suited for use on the computer and gives a very accurate estimate of this important factor in the design of fractionating columns. It does so without going to the tedious and time-consuming calculations of the rigorous methods.

The calculation approach is based on a simplification of the Thiele and Geddes method for fractionating columns under minimum reflux conditions.

The program is written in Fortran IV language and was used on an IBM 370 computer. Input specifications include the split of the …

An Analysis Of The Geneva Mechanism As A Timing Device, Hubert W. Meyer

Theses

A mathematical analysis of the Geneva mechanism was conducted to determine the potential of this device as a tinting mechanism, and the feasibility of replacing the widely used pallet and starwheel escapement with a Geneva mechanism.

The primary objective of the study was to determine if the Geneva mechanism will attain a terminal velocity, and if so, how much time is required to reach this velocity.

To accomplish this objective, the differential equation of motion for the system was derived using Lagrangian dynatos. The equation was programmed and solved on a digital computer.

The study indicated that the Geneva mechanism …

Aboveground Fuel Oil Storage Tanks, Lawrence George Palmer

Theses

A review of the American Petroleum Institute Standard 650 and Appendixes points out the advantages of using high strength steel and the variable point design method (Appendix K) to obtain reasonably uniform shell stresses. Design limitations imposed by notch toughness and residual stresses are pointed out.

Design considerations for the installation of an internal floating roof in a standard cone roof tank are discussed. Methods of calculating evaporation losses and an economic justification for a floating roof are included. Budget estimate figures have been compiled as a function of tank capacity for tanks, site preparation and tank ringwall or piled …

A Study Into The Feasibility Of Constructing A Pedestrian Mall In Newark Downtown, Stephen Wesley Warren

Theses

Newark's central business district has been suffering steady economic decline for at least a decade. In an attempt to halt this trend, and perhaps even reverse it, a feasibility study has been conducted toward the goal of implementing a pedestrian mall in the area.

This study was accomplished by conducting both field examinations of Halsey Street, the area under consideration, and investigating data from other existing United States pedestrian malls.

The results of this study show that it is feasible to construct a permanent pedestrian mall on Halsey Street and that the benefits of doing so far outweigh the costs …

Sidestream Tower Fractionation : A Short-Cut Calculation Method, Richard David Prickett

Theses

A short-cut procedure has been developed for making calculations on a complex fractionation tower. A Simplification of the Thiele-Geddes plate-to-plate procedure provided the basis for the short-cut procedure. The application discussed in this paper is for a tower with a liquid sidestream drawoff in the rectifying section.

The tower was broken at the feed point and sidestream drawoff locations into three calculation sections. The fractionation in each tower section can then be represented by a rigorous series solution expressed in terms of absorption or stripping factors. These rigorous equations can then be simplified by the use of average absorption or …

Separation Of Glucose - Fructose - Water Systems Via Thermal Parametric Pumping, Zikri Mostafa Ahmed

Theses

Series of experiments were carried out to determine the effect of different factors on adsorption from aqueous solutions of sugar using fuller's earth ( LW 16-30 Mesh ) as an adsorbent. The equilibrium data were fitted to the Langmuir's equation., and an explanation for the deviation of some of these data has been given.

Systems of glucose-fructose and water mixtures were subjected to semi-continuous and continuous parametric pumping operations using activated carbon (400 Filterasorb) as an adsorbent. The results obtained confirm the equilibrium theory of the parametric pump and essentially fulfill the requirements established by Chen and Hill (6) to …

Kinetic Modeling Study Of Catalytic Hydrogenation Of Codimer, William Mounce

Theses

A kinetic modeling study was made on a gas phase catalytic reaction. The data used was that on the hydrogenation of codimer, collected by Tschernitz, et al, The objective was to determine if non-linear least squares regression offers an advantage over linear least squares regression in discriminating between Langmuir. Hinshelwood kinetic equations.

For the experimental data in question, it was found that neither linear nor non-linear regression could distinguish between the two plausible mechanisms. With the particular mechanistic equations and range of data used in this study, the more laborious non-linear analysis offered no advantage over linear regression in discriminating …

An Accounting System For The Artist, Designer, And Craftsman, Toby Thompson

Theses

None provided.

Plastics Combined With Metals In The Production Of Desk Objects, Sharon Church

Theses

None provided.

Fast Fourier Transform With Computer Program, James Chapin

Theses

Many computer programs have been developed to calculate the Fast Fourier Transform (FFT). It is the intention of this thesis to develop the tree graph idea, presented by E. 0. Brigham and R. E. Morrow in the article "The fast Fourier transform," into another computer program that will calculate both the forward and inverse Fourier transforms using nonsymmetrical periodic functions. Most of the information obtained was from periodicals with relatively little available in text books. General matrix equations and calculations presented in proofs were developed by this thesis. The tree graph idea was also expanded to a general form. First …