Digital Commons Network^™

Recovery Of Phthalic Acid, George Thomas Roberts

Theses

Crude phthalic acid from the fusion processing of alkyd resins was found to be recoverable by solvent extraction, neutralization-acidification, sublimation, distillation, esterificatton with monohydric alcohols, ion exchange or alkyd resin preparation.

The author proposes that alkyd resin preparation, based on analysis of the crude phthalic acid, is the most practical way for the alkyd resin manufacturer to recover the crude phthalic acid. No purification of the crude phthalic acid is necessary for this utilization and the resulting alkyd resin is saleable at a profit.

Hydrolysis Of Sodium Silicofluoride, Frank Arthur Graf

Theses

The kinetics of an apparent solubility decrease of commercial sodium fluoride encountered in a piece of equipment designed to produce saturated sodium fluoride solution was Investigated, in order to understand why a consistently saturated solution was not possible to achieve with plain tap water as solvent.

The main impurity, about 1 percent sodium silicofluoride, coats the sodium fluoride crystals, resulting in an equilibrium shift during dissolution of the salt in water; and under certain conditions results in the formation of a protective gel. Therefore, in order to produce a constant strength sodium fluoride solution, this coated impurity must be decomposed …

The Preparation Of 3,4-Diaminopyridine, Emil John Fencl

Theses

The preparation of 3,4-diamincpyridine from pyridine was investigated, but found to be of little synthetic value because of the low yield obtained on the rearrangement of 4-nitraminopyridine to 3-nitro 4-aminopyridine. In attempt to nitrate nicotinamide-N-oxide resulted in the isolation of nicotinic acid-N-oxide. Attempts to nitrate nicotinic acid-N-oxide were unsuccessful. Attempts to oxidize 3-methylpyridine-N-oxide and 4-nitro-3-methylpyridine were unsuccessful. The nitration of 3-methylpyridine-N-oxide led to the isolation of 2-nitro-5-methylpyridine, which has not previously been reported as a by-product of that reaction.

Ammonia Catalized Phenol Formaldehyde Resins, Murlin Charles Ehrgott

Theses

The literature on ammonia-catalyzed phenol-formaldehyde resins is reviewed and critical comparisons are made of the manner in which the ammonia-catalyzed resins differ from both the alkali- and acid-catalyzed resins.

Intermediate products formea during the initial stapes of the ammonia-catalyzed phenol-formaldehyde reactions, as reported in the literature, are tabulated and % N contents are calculated.

Experimental determinations of N content of resins with molar ratios of 1:1.25 phenol to formaldehyde with ammonia at 0.2, 0.5, and 1.0 moles per mole of phenol, show that at the 0.2 molar ratio of ammonia, all the N enters into the resin and remains during …

Electrodeposition Of Cellulose And Carboxy-Methylcellulose, Charles Edward Driesens Jr.

Theses

The previous work done by Frank Cozzarelli on the eleotrodeposition of cellulose from a sodium zincate-urea-cellulose system has been verified, except that zinc was found to deposit on the cathode at all voltages and current densities within the range of the optimum conditions for deposition. The optimum conditions are: voltage - 1.10 to 1.28 volts; current density 0.13 to 1.10 amperes/square foot; electrode material - copper. Current efficiencies range from 0.80 to 5.53%.

A chelate-like complex formed from the sodium zincate and urea which couples with the cellulose has been proposed as a possible explaination of the mechanism governing the …

Viscosity Of Non-Newtonian Suspensions, David Edward Gullett, Edward Curtis

Theses

The object of this project ras to obtain a reasonable correlation of the effect of velocity, concentration and particle size on apparent viscosity of non-Newtonian slurries.

Through the use of dimensional and graphical analysis an equation, μ/μ_w=1.02(Ak/GC)^.105, was developed which filled these conditions. The average deviation of the apparent viscosity calculated from this equation compared to the experimental value was 14.4%.

The authors believe that this correlation should be tested under a greater variety of conditions of particle size and particle thermal conductivity and for suspending mediums other than water.

The Recovery Of Elemental Phosphorous From Phosphorous-Bearing Sludges, Rajendra Nath Bery

Theses

The theory dealing with the propagation of phosphorus sludges in elemental phosphorus production is generally well known, but it has long been felt that an investigation should be made in order to devise a suitable process whereby it may become possible to effect a separation of phosphorus. It is perhaps unfortunate that while the development of the electric furnace process continued, it sometimes overshadowed the importance of recovering additional amounts of phosphorus by relatively simple and inexpensive means since this is considered vital to the economics of elemental phosphorus production. At the present time, there is no economically feasible process …

The Development Of Executives, Joseph Ralph Messineo

Theses

The ever-increasing trend toward improved industrial efficiency creates the problem of supplying capable executives. The supply of executive manpower in business corporations ever needs replenishing. Expansion of operations, retirements, and other circumstances cause executive demands and vacancies which must be filled. Therefore, the purpose of this thesis is to analyze and report on what industry is actually doing today to develop executives to meet present and future requirements. Also, it is the author's intent to formulate a comprehensive executive development program that can be adopted with some limitations by industry for the building of an executive reserve.

In order to …

Correlation Of The Number Of Theoretical Plates Vs. Reflux Ratio, George Ignatius Parisi

Theses

A correlation is presented from which the number of theoretical plates for a given separation by distillation can be estimated as a function of the reflux ratio. The effects of relative volatility and feed composition upon such a correlation are also studied. Smoker's (1) equation was used in calculating the data. The results were obtained by varying the several parameters which have to be given for any separa tion desired. These include feed compositions of 0.25, 0.50, and 0.75; relative volatilities of 1.1, 1.2, 1.5, and 2.0; and various reflux ratios. The overhead product and bottoms product compositions were kept …

Ultrafiltration In The Pigment Field : A Critical Literature Survey, Charles Walter Manger

Theses

The objective in this work has been to determine, through a critical literature survey, the possible application of ultrafiltration, and other related techniques, towards the solution of certain problems encountered in the research and testing of various pigments.

Among these problems may be mentioned the following:

1. The determination of water-soluble salts in pigments, which when dispersed in water to leach out the salts, tend to peptize, thus being unfilterable through the usual filter paper. Among these pigments are the following: iron blue, certain chrome yellows, pigment green B, copper maroon, and several others. It may be added that these pigments …

The Synthesis Of 2-Amino-4-Chlorophenol-6 Sulfonic Acid, Herman Albert Bronner

Theses

The work described in this thesis was undertaken with the view of exploring a reaction sequence suggested by early French investigators to synthesize 2-amino-4-chlorophenol-6-sulfonic acid especially in reference to the German claim that a low yield of product would result following this preparation, In particular, a successful application of this procedure would afford a relatively direct and inexpensive route to the sulfonic acid which is used as an azo dyestuff intermediate and could possibly find application in medicinal chemistry.

It was found that sulfonation and nitration of p-dichlorobenzene gave a high yield of the sodium-2-nitro-1,4-3 dichloro-benzene-6-sulfonate (91%) when using the …

Tetranitromethane And Related Compounds, Thomas James Tully

Theses

No abstract provided.

Waterfront Construction In New York Harbor, Carman William Garrison

Theses

The following chapters are devoted to the various phases of that branch of construction which is followed from the offshore side of the waterfront. This branch, in the parlance of the building trades, is known as dockbuilding. Years ago all waterfront structures in New York Harbor were constructed almost entirely of timber and experience taught that the most economical approach for building docks and wharves was made by utilizing floating piledrivers and derricks. Thus it happened that dockbuilders became skilled both in the use of wood framing tools and in handling marine equipment. Modern dockbuilders must have, in addition to …

Organic Ion-Exchange Materials, Harry Burrell

Theses

This thesis is offered as partial fulfilment for the degree of Chemical Engineer at the Newark College of Engineering. It covers a very new subject - one which has been rather intensively developed by several investigators during the past three years. The writer has had the fortunate opportunity of working on organic ion-exchange materials at the Ellis-Foster Co., which kindly gave permission through Mr. Carleton Ellis for the publication of experimental results. Many thanks are due to Dr. Frank B. Root, the laboratory director, whose gracious, constructive criticisms aided the writer in all phases of the work.

An attempt has …

The Rahway Valley Trunk Sewer And Its Relations To, And Effect Upon The City Of Rahway, Fred A. Hedeman

Theses

This treatise is divided into three separate parts, each portraying a particular phase of the Rahway Valley improvement. Although not directly connected with the Joint Meeting, the fact that I served as Assistant City Engineer in Rahway during 1931 and 1932 naturally presented to me the opportunity of attending meetings and studying the project especially as it pertained to the City of Rahway.

Part one is a general review of the activities of the Rahway Valley Joint Meeting, both prior to and after the completion of the trunk sewer. The second portion reveals some of the intricate problems evolving in …

Problems Encountered In The Development Of An Airport, A. H. Armstrong

Theses

The progress of a nation and. its transportation facilities have always advanced hand in hand.

Just as it has always beerthe Civil Engineer's problem to develop facilities for other means of transportation, such as roads, harbors, and. railroad terminals, so is it his problem today to build airports.

In presenting the problems encountered in the development of an airport, the writer has considered the airport's place in city and regional planning, as well as the part it plays in air transportation.

An expression of thanks is given to Mr. Wm. S. La Londe, Jr., professor in Civil Engineering at the …

Piles And Pile Driving, Robert W. Van Houten

Theses

This thesis on the subject of "Piles and Pile Driving" has been written to fulfill one of the requirements for the granting of the degree of Civil Engineer by the Newark College of Engineering. The material contained in this thesis has been gleaned from many books, catalogs, magazines and from the author's own experience. Much still needs to be accomplished in the field of research but this can be done only through the cooperation of the companies who are engaged in this work and have the equipment necessary for making many tests under actual field conditions.

The author wishes to …