Digital Commons Network^™

Dmap As A Catalyst For Carbon Acylation: Elucidation Of Mechanistic Pathway, Including Spectral Characterization Of The Putative Reactive Intermediate, Jagadish K. Boppisetti

Masters Theses

3-Phenylbenzofuranone, when deprotonated with sodium hydride, forms an extended enolate system which, when treated with excess alkyl chloroformates, affords only oxygen-acylated products, as opposed to the usually desired carbon-functionalized derivatives. It was discovered that such molecules, when treated with a catalytic amount of 4- (N, N-dimethylamino)pyridine (DMAP), rearrange quantitatively to the carbon acylated isomers.

These migrations, which are accompanied by a deep blue color, are proposed to involve a reactive intermediate. This intermediate, which is postulated as an ion pair charge transfer (IPCT) complex, has been closely studied in order to gain a better understanding of the …

Impact Of Service Delivery Model, Presenting Problem, And Consultee Characteristics On Teachers’ Preference For Academic And Behavioral Remediation, Kathy Wilson

Masters Theses

This study examined teachers' preferences for academic and behavioral remediation. Specifically, the impact of service delivery model (traditional or flexible), type of presenting problem (academic or behavioral), and selected consultee characteristics (age, years of experience, grade level taught, years at current school, and level of teacher education) on teacher preferences was investigated. Individuals completed a demographic information sheet and an analog study. The survey consisted of two hypothetical scenarios of two different students found within the classroom. The first scenario described a student who only exhibited behavioral/emotional issues. The second scenario described a student who presented with only academic issues. …

The Relationship Between Thigh Muscle Size And 1rm Squat Strength Among Bodybuilders, Powerlifters, And Olympic Weightlifters, James Dinaso

Masters Theses

The purpose of this study was to determine if a significant difference exists in the relationship between measures of muscle size and strength among elite bodybuilders, powerlifters, and Olympic weightlifters. Fifteen male subjects between the ages of 16 and 48 years participated in the study. All three subject groups, Olympic weightlifters (OWL, n=5), powerlifters (PL, n=5), and bodybuilders (BB, n=5), were highly trained and currently involved in competition training. All test subjects were of similar body weight and weighed between 76-96 kilograms. Measures of body weight, body composition (bioelectrical impedence), shoulder width, thigh circumference (proximal, distal, and mid-thigh), and thigh …

A Study Of Role And Function Differences Between School Psychologists Working Within The Flexible Service Delivery System And More Traditional Settings, Jaime L. Hahn

Masters Theses

Practicing school psychologists were surveyed including those working within the Flexible Service Delivery System (FSDS) and traditional settings. The questionnaires were completed by 91 school psychologists from throughout Illinois and Indiana. Participants completed questionnaires examining their specific role and function as a practicing school psychologist. Specific roles that each respondent was asked to rank used a Likert scale consisting of (1) Standardized Testing, (2) Curriculum Based Assessment, (3) Individual Therapy, (4) Group Therapy/Social Skills Training, (5) Consultation with Teachers, (6) Consultation with Parents, (7) Organizational Consultation, (8) Conducting Research, (9) Classroom Intervention, (10) Pre-referral Meetings, (11) Psychological Reports, and (12) …

Factors Influencing Substance Abuse/Dependence And Treatment Outcome Of Adolescents In A Residential Substance Abuse Program: An Exploratory Study, Melissa L. Moody

Masters Theses

Previous research examining the risk factors associated with alcohol and other drug use has primarily focused on the adult population. Few studies have investigated the factors which influence adolescent substance abuse and the respective effects on treatment outcome. This in spite of the considerable decline in the age-of-onset for problematic substance use that could, if gone untreated, escalate into dependence and a variety of other interpersonal problems which extend across the lifespan. Effective interventions targeting the adolescent population would therefore seem to be of utmost importance to both researchers and clinicians. It has been suggested that individualized treatment programs focusing …

Prediction Intervals For The Binomial Distribution With Dependent Trials, Florian Sebastian Rueck

Masters Theses

"A generalization of a prediction interval procedure for the binomial distribution to the case of the binomial distribution with dependent trials is considered. Several different methods have been developed for obtaining prediction intervals for the binomial distribution. An unpublished study by Vlieger and Samaranayake has shown that two of these methods achieve coverage probabilities close to nominal levels. The proposed method is an extension of one of these methods and is based on the maximum likelihood predictive density proposed by Lejeune and Faulkenberry. A simulation study was carried out to investigate the coverage probabilities of the proposed prediction bounds.

This …

Investigation Of The Role Of Self-Efficacy In Postoperative Outcomes In Spinal Fusion Patients, Karen Roberts Burritt

Masters Theses

A descriptive correlational design was utilized to explore the relationship between preoperative self-efficacy and the postoperative outcomes of distance ambulated, brace application, discharge disposition and length of stay in surgical spinal fusion patients. Social cognitive theory and the concept of self-efficacy were used to provide the theoretical framework. A novel self-efficacy questionnaire was developed to measure the independent variable, it was tested for reliability and validity in a 16 patient pilot study. The pilot study was followed by a study of 52 post-operative patients. Preoperative self-efficacy significantly correlated to distance ambulated in the entire sample. Females in this sample demonstrated …

Application Of A Finite Element Model Update Technique To Detect Damage In A Beam Structure, Madhu Kumar Vattipulusu

Masters Theses

"The interest in the ability to monitor a structure and detect damage at the earliest possible stage is pervasive throughout the civil, mechanical and aerospace engineering communities. The thesis focuses on the application of a finite element model updating technique to monitor and detect damage in beams. A Sensitivity Based Element-by- Element (SBEBE) methodology is chosen as the finite element model updating technique. In this method, damage is detected by updating a finite element model with test data obtained from "healthy" and "damaged" structures and observing the relative changes in the updated finite element models. The performance, efficiency and sensitivity …

Numerical Modeling Of Focused Remediation Using A Groundwater Circulation Well, Gretchen R. Miller

Masters Theses

"Groundwater circulation wells (GCWs) allow for the in situ treatment of contaminated water resources. Focused remediation with a GCW could be used to treat groundwater before it enters an existing domestic well already in use. GCWs have been installed at the former Nebraska Ordnance Plant; the model originally developed for these was slightly modified and used to perform a feasibility study of a focused remediation system.

If the focused remediation system works properly, the capture zone of the domestic well should be within the recharge zone of the GCW. Deterministic modeling with capture zone analysis indicated that a GCW installed …

Performance & Project Spirit Of Student Design Competition Teams, Bradley Marcus Davis

Masters Theses

"Student design competition teams present a valuable research possibility in the field of work group research. They are widely available and present greater learning opportunities than do class project groups. This study intended to create an instrument to measure the level of project spirit and team performance in order to establish a link between these two concepts. In the present study, nine student design competition teams from the University of Missouri - Rolla (UMR) campus (n = 186) were surveyed. The results indicate a strong correlation of the project spirit variables (project culture, project commitment, project citizenship, and project satisfaction) …

Hybrid Data Mining Technique For Application In Geo-Chemical Data Analysis, Shipra Dutta

Masters Theses

"Data mining is a very active research area, which has gained a lot of attention over the past few years for its applications in various fields ranging from stock forecasting to detecting damages in the structures like aircrafts. The use of data mining for applications in science and business has evoked a lot of interest in the researchers to explore the area further. In this research, a novel hybrid clustering architecture will be presented as a possible solution to classify the geo-chemical data obtained by conducting various direct and indirect tests on different sites. The fact that no single learning …

Common- And Differential-Mode Signaling And Filtering, Zhe Li

Masters Theses

"Common-mode chokes are widely used as suppression filters against interference of common-mode noise in high-speed differential signaling. This thesis focuses on investigating the characteristics of common-mode chokes. Mixed-mode S-parameters are presented as a useful concept for explaining the modal operation of differential circuits.

Three methods for measuring common-mode and differentia-mode S-parameters of common-mode chokes are demonstrated. The three methods involve (1) ABCD chain matrix, 2) using hybrid couplers and 3) modal decomposition. Each measurement method provides a specific level of accuracy. The modal decomposition method can work up to 10GHz.

SPICE equivalent circuit model of common-mode chokes and the extraction …

The Influence Of Occupational Therapists' Worldview On Clinical Reasoning And Action: A Qualitative Study, Matthew P. Mekkes

Masters Theses

This qualitative study examines the influence of occupational therapists’ worldview on clinical reasoning and action. Recent clinical reasoning research has determined that this complex and multi-faceted process is more than applied theory. Some scholars in occupational therapy have identified intrapersonal factors as influencing clinical reasoning. However, the nature and role of the intrapersonal factors in clinical reasoning remains unclear. To increase understanding of this phenomenon, semi-structured interviews were conducted with expert therapists. Results suggest that a therapist’s worldview, specifically related to beliefs about human nature does affect the way they envision and enact the occupational therapy process. This influence is …

Predicting In-House Survival Post Cardiopulmonary Resuscitation, Catherine Jane Johnson

Masters Theses

No abstract provided.

The Effect Of Esl Instruction On Student Achievement, Amy Jeanne Nelson

Masters Theses

Not all Limited English Proficient (LEP) students receive English as a Second Language (ESL) instruction in public schools across the nation. In the state of Michigan, ESL instruction for LEP students is not mandated. Therefore, districts can choose whether to service these students at all, and/or the degree to which they do so. Some districts provide bilingual education classes; some districts have ESL classes; while yet other districts have neither. Students are serviced by paraprofessionals for a limited amount of time during the school day, or simply not serviced at all and left to “sink or swim”. Research abounds on …

Detection Of Activated Platelets In Normal Pregnancy And Preeclampsia, Judy E. Herbolsheimer

Masters Theses

Normal pregnancy is a hypercoaguable state in and of itself. Evidence has shown that platelets may play a role in the pathogenesis and complications of preeclampsia. The objective of this study is to compare the presence of circulating activated platelets in normal pregnancy and preeclampsia. The subjects’ blood was fixed, washed, incubated with antibodies (which detect platelets and activation of platelets), and evaluated using flow cytometry. Results of this study showed pregnant subjects (normal and preeclamptic) to have an increased percentage of activated platelets over non-pregnant subjects. Increased platelet activation may account for platelet consumption and bleeding complications in preeclamptic …

Factors Influencing Body Image Perception Of Eastern Illinois University Track And Field Athletes, Sandra L. Hussey

Masters Theses

No abstract provided.

Does Knowing Cost Of Enteral Supplements Affect Preference Or Acceptance By Free-Living Older Adults?, Michelle J. Acklie

Masters Theses

No abstract provided.

An Exploration Of Parental Involvement In Head Start Programs, Shaundra Shanese Ceaser

Masters Theses

No abstract provided.

African Americans And Caucasian Americans Perceptions And Experiences Related To Racial Identity And Stereotypes, H. D. Crockett

Masters Theses

No abstract provided.

Kerouac's Instrumental Use Of Jazz, Dawn Nehrkorn

Masters Theses

No abstract provided.

Body Image Perceptions Of Seventh Grade Male And Female Adolescents: A Qualitative Analysis, Laura A. Collins

Masters Theses

No abstract provided.

Factors That Affect Party Institutionalization: Ethnicity, Electoral Systems, And Economics In East Europe, Joe Robbins

Masters Theses

This thesis examines party institutionalization in East Europe. Ethnicity, electoral systems and economics are variables explored in the substantive chapters. Many political science studies examine the number of parties in East Europe, but only a few studies study party institutionalization. Chapter 1 establishes the foundations for this thesis and provides an overview of each chapter.

In the second chapter, I analyze the relationship between institutionalized parties and ethnicity. Kitschelt (1992) argues that in the absence of institutionalized parties, voters look to other factors, such as ethnicity, when voting. The results from this chapter report that ethnicity plays a limited role …

Corporatist Features Of The Security Sector In Democratizing Countries: A Cross-Regional Analysis Of Brazil And Romania, Sebastian Huluban

Masters Theses

The topic of the thesis is to analyse, from a cross-regional comparative perspective, the relationship between the corporatist features and the civil-military relations in two democratising countries, Romania and Brazil. I choose Romania and Brazil because these two countries present peculiar features regarding the civil-military relations within their regions, and, in addition, these countries share a peculiar heritage regarding the corporatist arrangements both in terms of intellectual-cultural legacy and contingent decisions. The paper encompasses a double attempt as an answer to the current appeals within the civil-military relations literature for new analytical perspectives. First, I will show that the corporatist …

Democratic Consolidation In Eastern Europe, Michael Rudy

Masters Theses

This thesis examines democratic consolidation in five Eastern European countries. The Baltic States have consolidated their democratic regimes but Romania and Bulgaria have struggled to do so. I attempt to explain why this has happened. In chapter one, I introduce the topic and provide an overview for the next six chapters.

In the second chapter, I examine the literature that pertains to this topic. The literature focuses on several aspects of democratic consolidation. I examine how economic growth, privatization, foreign direct investment, modes of transition, violence, initial post-communist political contest winner, electoral laws, and the citizenship law all play an …

Political Leadership And The Quest For Unity And Development In Africa, Thierno Thiam

Masters Theses

No abstract provided.

A Trial Of The Effects Of Intercessory Prayer On Student Performance, Christopher Clark

Masters Theses

The purpose of the present study is to test the efficacy of intercessory prayer on academic performance. One hundred and four students enrolled in a college business class and 63 regular church attendees volunteered to participate in the study. Design for the study was a matched groups reversal design. The students were paired according to their GPA's and randomly assigned to one of two groups. The first test of the semester constituted a baseline measure. For the first four-week period of the class and the first test, neither of the groups received prayer. Next, the church goers each received the …

The Effect Of Choice Order On Off Task Behavior In A Child With Autism, Lisa R. Cole

Masters Theses

This research project was designed to examine the effects of child-choice versus clinician-choice over the ordering of activities during speech-language therapy sessions. The dependent variables included disruptive/inappropriate behavior, non-task related verbal behavior, and redirection to the task. The independent variable was the presentation of choice over the ordering of activities within a therapy session.

The subject in this case study was a nine-year-old boy diagnosed with autism. At the beginning of each therapy session either the child or the clinician decided on the ordering of activities. A picture board and picture cards showed the activities that would be completed in …

Regional Dispersal Of Daphnia Lumholtzi In North America Inferred From Issr Genetic Markers, G. Matthew Groves

Masters Theses

The exotic zooplankter Daphnia lumholtzi is believed to have been introduced into Fairfield Lake, TX in 1983. Since introduction, D. lumholtzi has spread throughout the Midwest and Southeast United States. Due to its large head and tail spines, it may be less susceptible than native species to predation and therefore pose a threat to aquatic ecosystems. Development of management practices calls for study of the dispersal and potential impact of D. lumholtzi on invaded ecosystems.

Inter-simple sequence repeat (ISSR) markers were used in an effort to determine dispersal patterns of D. lumholtzi. Previous studies have shown that ISSRs possess …

The Effects Of Social Fields On The Telepathic Reception Of Information, Jamie A. Yarnall

Masters Theses

Field theories are increasingly used as explanations for extrasensory perception, suggesting the existence of some form of collective mind or social field. These theories imply that groups of individuals create fields that can contain and transfer information. The current study explored the telepathic transfer of information regarding randomly selected target locations. Groups of participants "sent" target locations to individuals, observed on close circuit television, who were either members of the group (ingroup) or not members (outgroup). We hypothesized that ingroup members would achieve above chance hit rates while outgroup members would score below chance. Approximately 30 senders sent 16 trials …