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The Solubility Of Inorganic Salts In Carbon Disulfide: The Case Of Aluminum Bromide, Herman Henry Kaveler

Masters Theses

"Since about 1890, the interest in solubility has turned to a large extent to the investigation of the solubility of compounds in organic solvents. This has resulted in a great deal of work being done on the solubility of inorganic salts in non-aqueous solvents. As this mass of data steadily accumulated, the theoretical considerations of solubility and the ideal solution made rapid advances, as Hildebrand has pointed out. We express as much wonder over these theoretical advances as chemists did over the discover "that salts do dissolve in organic compounds". To add some useful data to that already accumulated on …

Concentration Of Fluorspar Ores In The Illinois-Kentucky District, Omar Watson Greeman

Masters Theses

"The object of this investigation is to study the means of beneficiating fluorspar ores in order that a marketable product may be made"--Preface, page v.

The Origin And Development Of The Arthurian Story In English Literature To The Nineteenth Century, Nadine Matlock Sease

Masters Theses

"It is the purpose of this paper to trace the story of the Arthurian romance from its origin to the nineteenth century with especial reference to the literature of the English language"--pages 1-2.

Effect Of The Use Of Old Retorts As Grog And Of Zinc Oxide Upon The Properties Of Bodies For The Manufacture Of Retorts, Elmer Gammeter

Masters Theses

"In the fall of 1924 the Mississippi Valley Experiment Station of the United States Bureau of Mines, Department of Commerce, in cooperation with the Missouri School of Mines and Metallurgy began an investigation of the properties of raw materials used in the manufacture of retorts for the zinc industry. The investigation proceeded cooperatively until December, 1926, when the Bureau of Mines withdrew from ceramic research. The School then took over and is completing the problem as outlined. The first phase of the investigation had for its object the determination of the properties of the fireclays and body mixtures now in …

The Catalytic Action Of Neutral Salts : The Effect Of Normal Alkali Sulphates On Alkali Acid Sulphates In The Ketonic Splitting Of Ethyl Acetoacetate, Elbridge Alvah Goodhue

Masters Theses

"The catalytic effect of neutral salts has been investigated for numerous reactions and various theories propounded to account for their action. In this work the action of normal potassium and sodium sulphates on solutions of the corresponding acid salt has been investigated for two concentrations of the latter at three different temperatures. An attempt has been made to account for the observed actions"--Introduction, page 1.

A Study Of The Iodine Content Of Representative Missouri Waters, Edmond Carl Hunze

Masters Theses

"Investigations have shown that the iodine content of natural waters bears a direct relationship to the goiter incidence of a given region. A number of the states have analysed [sic] their water for this constituent in the development of this hypothesis. A search of the literature revealed the fact that with the exception of two instances the iodine content of Missouri water had not been determined. Since in certain regions of Missouri there is quite a prevalence of goiter, it was deemed important to determine the iodine content of Missouri waters. It was believed that such information would be a …

The System: Calcium Oxalate - Sulphuric Acid, Joseph Maple Wilson

Masters Theses

"The manufacture of oxalic acid includes as one of the steps in the process, the conversion of calcium oxalate to the desired oxalic acid by treatment with sulphuric acid, and the subsequent crystalization [sic] of the oxalic acid from the solution of it thus made. This investigation has dealt with this conversion step, with regard to the various factors affecting it. The effect of time, acid concentration, temperature, volume of solution, solubility of reaction products, and possible compound formation have all been considered, and from the information thus gained the conclusion has been drawn"--Introduction, page 1.

The Solubility Of Solid Paraffin In The Lower Molecular Weight Hydrocarbons, Paul Weber

Masters Theses

"In the process of oil refining, a certain fraction of distillate from the crude oil composes the so-called wax distillate fraction from which is obtained the various lubricating oils. But the presence of the waxes and solid paraffins in these oils is very undesirable as they possess no lubricating qualities. Consequently, they must be removed from this wax distillate before the oil can be marketed"--Introduction, page 1.

A Study Of Electrometric Methods For Determining Selenium And Tellurium, Bertie Lee Browning

Masters Theses

"The quantitative oxidation of tellurious acid to telluric acid by potassium dichromate has been shown by Lenher and Wakefield to be applicable to the volumetric determination of tellurium. The purpose of this investigation was to study the applicability of the electrometric method to this titration"--Introduction, page [1].

Electrothermic Dry Distillation Of Zinc, Ira Nathan Goff

Masters Theses

"Although the work described in this thesis cannot be considered as complete, until certain mechanical changes have been made and the furnace operated continuously over a considerable period of time, this electrothermic dry distillation process for the extraction of zinc from ores offers excellent commercial possibilities. The literature has been reviewed, the process that was used at East St. Louis described, and the results of work at the Mississippi Valley Experiment Station of the United States Bureau of Mines, Department of Commerce, Rolla, Missouri along the line of electrothermic metallurgy of zinc considered"--Summary, page 58.

A Study Of The Reduction Of Zinc Oxide By Hydrogen And Methane, Frederick Adam Weirich

Masters Theses

"The purpose of the investigation was to make a study of the reduction of zinc oxide by hydrogen and methane and to study the conditions for the most efficient condensation of the zinc vapor"--Investigations, page 4.

A Specific Gravity Study Of Some Of The Southeast Missouri Lead Ores And Tailings, Robert Gibson O'Meara

Masters Theses

"The object of this investigation was to study some of the Southeast Missouri lead ores and tailings to trace the freeing of galena through all of the screen sizes. It was also desired to determine the efficiency of recovery with the present treatment and, whether or not a change to finer crushing would be advisable. In order to isolate parts of different specific gravity in the ores and tailings, heavy liquids were used"--Object of Investigation, page 2.

Comparative Value Of Various Grog Materials For The Manufacture Of Zinc Retorts, Wei-Tung T. Hu

Masters Theses

"As before stated, this present investigation, of which this thesis covers only a part, undertakes to study the comparative values of various grog materials for the manufacture of zinc retorts, having as its object to find better grog materials for the purpose than those commonly in use at the present time, and to determine the best proportions of bond clay to use with each kind of grog"--Scope of Investigation, page 4.

The Properties Of Refractories In Zinc Metallurgy. Part Iii. Comparison Of Various Clays, Richard Elkanah Sears

Masters Theses

"This thesis...contains a description of a part of a general investigation on the subject of the refractories used in the distillation of zinc. This investigation has been in progress for the past eighteen months at the Mississippi Valley Experiment Station of the United States Bureau of Mines, Department of Commerce, in cooperation with the School of Mines and Metallurgy of the University of Missouri. The first phase of this investigation had for its theme the determination of the properties of the fire clays and body mixtures now used in the manufacture of zinc retorts. The second phase deals with the …

A Granular Briquette Resistance Furnace For The Electrothermic Dry Distillation Of Zinc Ores, Milton E. Countryman

Masters Theses

[This thesis] "describes experiments carried on at the Mississippi Valley Experiment Station of the United States Bureau of Mines, Department of the Interior, cooperating with the School of Mines and Metallurgy of the University of Missouri, which had for their purpose the development of a 'granular briquet [sic] resistance furnace' for the electrothermic dry distillation of zinc ores"--page v.

The Properties Of The Fire Clays Used For The Manufacture Of Zinc Retorts, Adolph Harmon Kuechler

Masters Theses

"The ultimate object of this refractories investigation is to develop a body for zinc retorts, or changes in the method of their manufacture, that will result in better retorts than the ones now in use. In doing this, the question of permissible cost must, at all times, be kept in mind. The immediate object of the present phase of this investigation, of which this thesis covers only a part, is to determine the physical and chemical properties of the refractories (fire clays, grogs, bodies, etc.) now used for the manufacture of zinc retorts. This will be a basis for later …

Effect Of The Size Of Particles Of Zinc Ore And Carbon Upon The Rate Of Reduction Of Zinc Ore By Carbon, Keith Oxley Alexander

Masters Theses

"In the retort smelting of zinc ores one of the chief metallurgical problems is to obtain as complete a reduction of the zinc as is consistent with economical operation. Among the factors influencing the completeness of reduction are the temperature and time of distillation, the form in which the zinc exists in the ore, the form of carbon used as reducer, and the size of the particles or ore and reducer"--Introduction, page 1.

Effect Of Various Factors On The Rate Of Reduction Of Zinc Ferrite, Calamine, And Willemite By Carbon, Foster Cary Nix

Masters Theses

"Zinc ores containing large amounts of ferric oxide, calamine and willemite have been known for a long time among practical zinc metallurgists to be more difficult to reduce than ores of the same type but free from the above named compounds. This has been thought to be due to the high temperatures necessary for the reduction of the zinc ferrite and the zinc silicates by carbon. The ferrite is formed both during the roasting of sulphide ores and during distillation in the retorts, while calamine and willemite are introduced as such in the ores. The amount of ferrite formed during …

Hydro-Electric Treatment Of Joplin-Miami Zinc Concentrate, David Francis Walsh

Masters Theses

"The Electrolytic Process is a process capable of almost unlimited mechanicalization. For obvious reasons it is more economic to treat high grade concentrates; yet, the extremely high grade concentrates are not essential. The Electrolytic Process can treat economically concentrates as low as 30.% zinc under certain conditions. It is significant that as the grade of concentrates offered for treatment is lowered, the treatment cost per ton of concentrates decreases for the Electrolytic Process; whereas, it will increase, as previously stated, for the Retort Process. It is seen then that the position of the Electrolytic Process is strengthened where lower grade …

Lactose Fermenting Bacteria In The Water Supplies Of The Rolla Quadrangle, Joe Beaty Butler

Masters Theses

"I. Preliminary investigations. This includes the securing of 139 water samples from water sources in the Rolla Quadrangle, and inoculating 1cc samples from these into Dunham's Lactose tubes and thereby getting lactose gas production checks on the field samples. II. Confirmatory tests. This consisted in the isolation of lactose fermenters on Eosin-Methylene Blue Agar and checking of the cultures back through the lactose and then through dulcitel and saccharose so as to complete Jackson's Classification. 106 cultures were classified in this manner. III. Running through a complete set of tests of pure cultures, so as to completely (as possible) identify …

The Solubilities Of Certain Inorganic Salts In Anhydrous Normal Alcohols, William Orval Keeling

Masters Theses

"An examination of the literature shows that extensive studies have been made of the solubilities of inorganic salts in aqueous, normal alcohols, but that little has been done in determining the solubilities in anhydrous alcohols. Northing was found of a systematic study of the solubilities of NaCl, KCl, NaN0₃ and KNO₃ in the lower alcohols over a fairly wide range of temperature. The author has made a study of the solubilities of the above mentioned salts in lower anhydrous normal alcohols at the temperatures 20°C, 25°C, 30°C and 40°C"--Introduction, page 1.

Conductivity And Ionization Of Certain Salts In Absolute Alcohol, Armin Brene Jewell

Masters Theses

"One of the most striking observations one makes in connection with the study of the conductivities of alcoholic solutions is their great similiarity [sic] to those of aqueous solutions with the exception that the values of the concentrations are very much smaller. The differences are rather of degree than of kind. It will be noted that as the temperature is increased the molecular conductivity increases and the fraction of salt decreases which is what would be expected by analogy"--Discussion, page 43.

The Reduction Of Zinc Oxide By Carbon, George August Zeller

Masters Theses

"In spite of the fact that the reduction of zinc oxide by carbon is the fundamental reaction upon which the pyrometallurgy of zinc is based, there is a decided lack of accurate knowledge concerning the mechanism of the reaction, the temperature at which it begins, and the effect of various factors upon the rate at which it takes place"--Introduction, page 1.

On Plain Carbon Steel, Walter Edward Remmers

Masters Theses

"In 1921, an investigation was carried on by Messrs. Howe, Foley and Winlock, under the auspices of the National Research Council, the results of which were published under the title of - "Influence of Temperature, Time and Rate of Cooling on Physical Properties of Carbon Steel," by the American Institute of Mining and Metallurgical Engineers, February, 1923. These results showed that all physical properties of a 0.34 C. percent steel are improved by increasing the rate of cooling from temperatures above the critical range up to a certain rapidity beyond which, there is a gain in strength at the expense …

The Disintegration Of Refractory Brick By Carbon Monoxide, Wilbur J. Darby

Masters Theses

"In experimental work carried on at East St. Louis, Illinois in 1916 and 1917, with a furnace of commercial size for the electrothermic dry distillation of zinc ores, a difficulty that developed was the destruction of the firebrick lining in certain parts of the large condenser. The condenser was satisfactory in other ways, yielding a large proportion of the zinc as liquid metal, with no blue powder; but in order to obtain a proper length of service from the condenser it became necessary to find and overcome the cause of the disintegration of the lining ... it will be evident …

On The Breakage Of Rock Drill Steel, Muir Luken Frey

Masters Theses

"Prior to 1920 there was little attention paid to the general problem of breakage of rock drill steel. Each locality had its problem and the matter was treated as a purely local one, independent upon conditions in that particular section. But in the above-mentioned year, there arose an interest of wider scope, from what causes it is impossible to determine accurately, and the matter is now the subject of a broad investigation in which the users of rock drill steel, the United States Bureau of Mines, and the United States Bureau of Standards are cooperating...There is, to date, no satisfactory …

Effect Of Time And Temperature On Distillation Of Zinc-Lead-Silver Complex Sulphide Concentrates, Ernest Sterling Wheeler

Masters Theses

"Accurate information is lacking as to the effect of temperature and time of distillation on the relative proportions of zinc, lead and silver volatilized from complex ores, and while it is evident that the possibility of the commercial treatment of these complex ores has engaged the attention of metallurgists for years, it is one that will still bear investigation even on a small scale"--Statement of Problem, page 5.

Design And Construction Of The Experimental Mine, Robert Knox Stroup

Masters Theses

"The mining laboratory and experimental mine at the Missouri School of Mines was opened in 1913. At a suitable location, on the site of an old dolomite quarry, one and one half miles southwest of town a tunnel was started into the hillside and the necessary plant erected. This plant consisted of a fifty horse-power Erie Iron Works boiler of the modified locomotive type, and an Ingersoll Rand type 10 single stage duplex air compressor of a capacity of one hundred cubic feet of free air per minute. This plant was in operation during the fall months of each year …

The Middle Ordovician Section In East Central Missouri, Morris James Ingerson, Josiah Bridge

Masters Theses

"One of the most serious difficulties confronting anyone working on stratigraphic problems in the Ozark area is the lack of detailed faunal lists of the various formations. A great deal of general work has been done, but very few detailed faunal studies have ever been published, and correlation of the Missouri section with sections in adjoining states is often difficult.

In a recent paper, Dake has discussed the origin and correlation of the St. Peter sandstone. In this study he found considerable difficulty in correlating the various formations above the St. Peter, and at his suggestion, the present study was …

The Equilibrium Of The Reaction Zn + Co₂ = Zno + Co, Clarence Ware Burkhart

Masters Theses

"Many attempts have been made in the last twenty years to smelt zinc ores in the electric furnace. The disadvantages of the present retort process have been discussed so often that they need not be dwelt upon here. The principle ones are, the low thermal efficiency of the retort furnace, low metal recoveries, small smelting units necessary, short life of the retorts and the difficulty of treating impure and low grade ores. Electric smelting offers remedies for most of these difficulties"--Introduction, page 1.