Digital Commons Network^™

Effects Of Co2 On The Strength Of Lime Treated Clay Soil, Tuncer Karakurt

Masters Theses

“A large number of the difficulties encountered in highway work are due to the variable nature of soils. In addition to its variable nature, soil is a difficult material to deal with because of the complexity of its physical and chemical properties. From prehistoric times the construction of a satisfactory foundation has been one of the greatest problems facing the engineer and builder. Even though the needs of scientific methods were necessary far earlier, the study of soils as a construction material was scientifically given attention to only during the last three decades. Soil science being so young there are …

The Separation And Microdetermination Of Cobalt In High Purity Nickel, John Richard Knapp Jr.

Masters Theses

"It has been found that many substances in an extremely pure form or containing certain trace impurities exhibit many unique physical and chemical properties. Investigators studying these properties have encountered many difficulties, especially in preparing the extremely pure substance and/or in accurately determining the quantity of impurities present. These problems arise chiefly from the very similar chemical properties of the constituents being separated and the possibility of contamination during the necessary processing of the substance for purification or analysis.

Trace analysis, therefore, has become very important in recent years. Where previously analyses based upon parts per hundred were adequate, now …

A Thermodynamic Study Of Germanium Sulfides, Sham Lal Malhotra

Masters Theses

"The vapour pressure of germanium monosulfide (liquid) was determined by a boiling point method. An expression for the vapour pressure as a function of temperature was obtained and the heat of vapourization calculated. Using the heat of sublimation data obtained by other investigators, the heat of fusion was calculated.

The thermodynamic properties, change of standard free energy (Δ F°) heat content (Δ H°) and entropy (Δ S°); of germanium disulfide were determined by using an indirect method. The equilibrium H₂S/H₂O ratios are determined for the reaction:

GeS₂ (s) + 2H₂O(g) = GeO_{2 …}

The Lattice Constants Of Chromium And Vanadium Containing Dissolved Gases, Paluri Bhimeswara Rao

Masters Theses

"The physical properties of chromium and vanadium are so important that a study of their lattice constants and their coefficients of thermal expansion, requires special consideration.

A number of research workers, over a period of about forty years, have done considerable work in determining the above constants. Some of the previous investigators found an anomaly in the thermal expansion, electrical resistivity and other physical properties of chromium. They observed that at about 37°C, chromium showed a discontinuity in the above physical properties. However it is not known what causes the discontinuity in the expansivity curve of chromium. The discontinuity may …

The Redesign And Construction Of A Rotating Disc Contactor, Richard Henry Okenfuss

Masters Theses

"Liquid-liquid extraction has played a major role in the processing of nuclear fuels. The Department of Chemical Engineering of the Missouri School of Mines and Metallurgy realizing this, petitioned the Atomic Energy Commission for funds to design and construct an instructional facility representing the chemical processing of nuclear fuels. With this unit and its solvent recovery equipment, in which stress is placed on extraction and distillation, not only are the principles of nuclear fuels processing demonstrated, but the more basic concepts of mass and energy transfer are also illustrated. Extraction depends upon solubility differences to achieve a transfer of a …

An Experimental Investigation Of Receiver System Sensitivity, James Henry Johnson

Masters Theses

"A method of determining the minimum detectable power density incident at the receiving antenna of a UHF receiver is proposed. The minimum detectable power density is the power density required to produce a signal-to-noise ratio of unity in the output of the receiver. The proposed method includes the receiving antenna impedance, the necessary connecting transmission lines, and the receiver impedance.

It is shown that an error in the antenna directivity will produce a significant error in the overall sensitivity of a receiving system. Since the directivity is the most difficult system variable to determine experimentally, it is probably the limiting …

Some Dynamic Creep Characteristics Of Gypsum, Ikram-Ul-Haq Dar

Masters Theses

"A review of literature concerned with time-dependent deformation of geologic and non-geologic materials is presented. A static loading machine and a four unit dynamic loading unit was designed and assembled to evaluate static and dynamic creep properties of gypsum. The tests were run for various levels of static loads, and superimposed dynamic loads. Investigations were carried out to determine the relationships, if any, between impact energy, impact velocity and momentum, and dynamic strains. Viscoelastic coefficients were determined for the investigations. The conclusion was presented that time-dependent strain in the dynamic creep tests of the particular gypsum rock tested is a …

Coal Dust Explosions And Their Prevention, Surya Narayan Roychowdhury

Masters Theses

"The purpose of this study is to review the various causes of coal dust explosions and to summarize the preventive measures through which it may be possible to minimize the hazards of coal dust explosions. The properties of coal dust which have an important influence on its explosibility are: fineness, purity, percentage of volatile matter, dryness, age and degree of oxidation, lifting velocities and dispersability, and its static electrification.

Explosibility of coal dust has been studied in laboratories, in explosion galleries and in an experimental coal mine. The data and results obtained from the tests showed that finely pulverized coal …

The Status Of Gas-Lubricated Bearings, Bhaskar Dattatraya Shiwalkar

Masters Theses

"The idea of gas-lubricated bearings was suggested as far back as 1854 by Hirn, but it is only very recently that they have aroused a great amount of interest. The interest is centered on the advantages of gas-bearings for the following major applications:

1. High temperature lubrication where ordinary liquid or grease lubrication fails.
2. Bearings operating in radio-active atmospheres where conventional lubrication may break down.
3. Applications sensitive to contamination where fouling from lubricating oil becomes serious.
4. Low-friction devices--an especially important advantage because of the trend to high speed machinery.
5. Applications where positional accuracies down to micro-inches are required.

As a result …

Design Of An Intermediate Frequency Amplifier And Variable Frequency Oscillator, Robert Charles Mcintyre

Masters Theses

"Since the advent of the transistor in 1948 many technological barriers have been overcome in the field of semiconductors. Unfortunately, however, there is a considerable period of time between the discovery of a scientific phenomena and its widespread use and understanding by practicing engineers. The motivating factor which prompted this investigation was primarily the lack of knowledge which the author possessed concerning transistors. The selection of the amplifier and oscillator design confined the study primarily to the transistor. Considerable time, however, had to be spent in the study of basic transistor theory before any phase of the design could be …

Automatic Tuning Of A.C. Compensating Networks, Giles C. Sinkewiz

Masters Theses

"The purpose of this thesis is to illustrate the practicality of using an auxiliary servo system to shift parameters in damping networks of the main servo system.

Since amplification is most easily achieved with A.C. amplifiers and since A.C. servo motors are superior in operation to D.C. servo motors, because no brushes or commutators are needed, the A.C. servo system is widely used. However, one major problem is confronted when designing an A.C. servo system. This is the problem of designing damping circuits and compensating circuits which are insensitive to carrier frequency fluctuations. Notch filters provide the desired transfer functions, …

The Evaluation Of The Influence Of Large Aggregate On The Permeability Of Single-Grained Soils, Edward Clayton Grubbs

Masters Theses

"Each year many earth fill structures are designed and built with the primary purpose of impounding water. As these structures are only relatively impervious, engineers must consider the control of seepage in design. In order to predict seepage, the engineer must have knowledge of the potential flow or water through the earthen structure. He is, therefore, faced with the problem of determining a coefficient of permeability for use in design calculations.

The coefficient of permeability is easily enough determined for fine-grained materials. However, in construction it is very rare to find proper fill material which does not include quite a …

Properties Of Air-Entrained Concrete At Early Ages, Ugur Ozoguz

Masters Theses

"This study, entitled "Properties of Air-Entrained Concrete at Early Ages" concerns a group of tests designed to provide quantitative information regarding the effect of entrained air on the strength and durability of concrete before it reaches its 28 day strength.

Experiences in the field and laboratories have demonstrated that the addition of a moderate amount of air to any concrete mix will bring a marked increase in resistance to the disintegrating effects of freezing and thawing.

There have been extensive studies made on the subject of durability of air entrained concrete. Most of these studies were based on the effect …

Critical Load For A Rectangular Plate Simply Supported On Three Edges, Built In On The Fourth Edge, And Compressed On Two Opposite Simply Supported Edges By A Load In The Plane Of The Plate, Bert Louis Smith

Masters Theses

"There are many engineering structures in which thin plates are used extensively, some examples of which can be found in ship and airplane structures, bridges, etc. The problem contained in this thesis is the analysis of a thin rectangular plate simply supported on three edges, built in on the fourth edge, and compressed on two opposite simply supported edges by a load in the plane or the plate. This problem becomes one of stability, and the object of the solution is to find the smallest load that will cause the plate to buckle"--Introduction, page vi.

A Method For The Prediction Of Detection Ranges For Pulsed Doppler Radar, Phillip Orlan Brown

Masters Theses

"Modern radar systems must provide greater detection ranges both against high and low altitude targets because of the significant advances in weapon speed and range. Extended range indicates that the power transmitted by the radar must be increased. It follows, that ground return becomes a problem even at high altitudes.

There are at present three basic types of radars which are (1) pulsed, (2) continuous wave, and (3) pulsed doppler radar. The conventional pulsed radar now closely approaches the theoretical optimum performance; however, it does not have the inherent ability to distinguish between ground return and moving targets. The continuous …

A Dissolution Rate Study In Hydrofluoric Acid Of Titanium And The Alpha Solid Solutions Of Oxygen In Titanium, John L. Ratliff

Masters Theses

"The dissolution mechanism of titanium in hydrofluoric acid was studied by collecting the hydrogen evolved during the dissolution reaction. A concentration range of 0.05 N to 0.50 N and a temperature range of 15°C to 45°C were employed for the determination. Values of the reaction order and energy of activation were determined for both pure titanium and the alpha solid solutions of oxygen in titanium and found to be the same within experimental limits. This indicated that the reaction giving rise to hydrogen evolution on the surfaces of both pure titanium and the TiO_x alloys was the same. The …

A Method Of Design For Spiral Reinforced, Eccentrically Loaded, Concrete Columns, Lloyd O. Senter

Masters Theses

"This thesis presents a method of designing spiral reinforced, eccentrically loaded, concrete columns on the basis of the 1957 American Association of State Highway Officials specifications.

Equations from AASHO, in conjunction with equations derived in this thesis, are programmed for and solved by the IBM 650 digital computer. The data obtained from the computer is plotted such that, given the normal load and moment on a column, the minimum required area or reinforcing steel may be read directly from the graph.

The derivation or equations, the computer program, and the graphs are included in the thesis"--Introduction, page 1.

Heat Transfer In A Vortex Flow Metal To Air, Elisha Rachovitsky

Masters Theses

"In this study heat transfer in a vortex flow has been investigated experimentally and analyzed qualitatively.

Air was forced through a Ranque tube in order to get a swirling turbulent flow in its "hot" section. The test section, having a diameter of .355 inches and a length of 27.5 inches, was heated by an induction coil.

Three types of flow were under investigation: a linear turbulent flow, a vortex uniflow and a mixed vortex-linear turbulent flow.

The experiments covered a range of tube-wall temperature from 570 to 900 Deg. R and inlet pressure to the vortex generator ranged from 25 …

Comparative Petrographic, Petrochemical And Spectrographic Analyses Of The Precambrian Granitic Rocks Of Southeastern Missouri, Eva B. Kisvarsanyi

Masters Theses

"Petrographic, petrochemical and spectrographic studies were completed on selected Precambrian granitic rock samples from Southeastern Missouri. This investigation contributes to a more detailed knowledge of the Precambrian granitic rocks of this part of the state.

Petrographic analysis of forty-four thin sections of granitic rocks from the St. Francois Mountains area revealed six different granite types. These have been named the Fredericktown, Knoblick, Doerun, Graniteville, Klondike and Silvermine granites. These rocks form a large part of a composite batholith. More than one period of granitic intrusion is represented, but differentiation also contributed to the formation of this diversity of the rocks. …

Methods For Calculating The Minimum Amortization Tonnage And Maximum Present Value For An Ore Body, Garrett M. Sainsbury

Masters Theses

"The discussion is divided into three parts. Part I describes a procedure for determining the mining rate that gives the minimum amortization tonnage required of an ore body, and the amount of that tonnage. The basic idea is that amortization tonnage is equivalent to the estimated capital costs, including interest, divided by the estimated operating profit per ton. Both capital costs and operating profit per ton can be expressed as functions of mining rate by making use of empirical equations. Therefore, amortization tonnage can be expressed as a function of mining rate. The amortization tonnage is calculated for a series …

High Temperature Oxidation Of Nickel, Virgil R. Friebel

Masters Theses

"Using a sensitive volumetric technique, a study was made of the kinetics of oxidation of nickel at 1200° C. and 1300° C. Three purities of nickel were used for the investigation which was limited to the initial three hours of reaction.

The rate of oxidation of nickel followed the parabolic rate law after an initial period of deviation which lasted up to 40 minutes. No direct correlation was found between the oxide thickness and the end of the period of deviation from the parabolic rate law.

The purity of the nickel was found to have a marked effect on the …

The Dielectric Strength Of Some Anti-Corrosive Paints, John Harvey Gustafson

Masters Theses

"Metals undergo chemical reaction with nonmetallic elements of their surroundings to produce compounds which are either oxides or salts. These corrosion products, as they are called, may accelerate, impede, or have no influence on the course of further corrosion. It is unfortunate that iron, the metal of greatest use to man, receives very little protection from its corrosion products. There are no easy or inexpensive means of prevention of this corrosion and at best the reactions can only be controlled. One method of control is the use of anti-corrosive paints. Their protection is produced by placing an inert, continuous, and …

The Effect Of The Rare Earth Elements On The Hot Workability Of Ingot Iron, L. A. Neumeier

Masters Theses

"The effect of mischmetal and rare earth oxides on the hot workability of ingot iron in the hot-short region was studied. Thirteen heats were melted in air in a basic-lined induction furnace. All heats were thoroughly deoxidized with aluminum prior to the rare earth additions. Mischmetal was added in amounts of 0.1, 0.3 and 0.5 per cent. Rare earth oxides were added in amounts of 0.1 and 0.2 per cent. Temperatures were maintained at approximately 2900°F and holding intervals between mischmetal additions and pouring at two minutes. Bars were hot rolled and swaged for hot twisting in the hot-short region. …

Determination Of Vapor-Liquid Equilibrium Data By Continuous Distillation, David William Bunch

Masters Theses

"The procuring of experimental vapor-liquid equilibrium data has been a problem of considerable importance to chemical engineers for a number of years. Modern distillation theory and practice have made accurate vapor-liquid equilibrium data practically a necessity.

Using conventional methods for determining vapor-liquid equilibrium data, an experimenter can obtain only a single vapor-liquid equilibrium composition per trial. Ramalho working with Tiller has developed a new method which makes possible the determination of all values of the vapor and liquid concentrations in a single experiment.

The work done by Ramalho indicated that the necessity for very precise temperature measurements presented a serious …

A Study Of The Inlet Characteristics And Entrance Losses Of Pipe Culvert With A Flush Mounted, Sharp Edged Inlet, Luke Lea Callaway Jr.

Masters Theses

"Of all hydraulic structures, culverts are by far the most numerous. Lack of understanding of the functioning of culverts has resulted in many of them being implaced improperly and as a result, they function with less efficiency and at reduced capacity. Much has been written regarding the flow of water in open channels, culverts included, but little has been done regarding inlet conditions. It is necessary in the design of culverts, as with any other structure, that conditions which govern the operation of the structure be established. This paper is a study of the inlet conditions of a circular cross …

Water Resources Development -- An Analysis Of Economic Justification Practices Of The Corps Of Engineers, Kerwood W. Barrand

Masters Theses

"Presented herein is a brief analysis of the economic justification practices of the Corps of Engineers as commonly implemented in proposals concerning water resources projects. Where applicable, recommended methods are compared to similar methods advocated for, and accepted by, private engineering firms in similar situations.

The major problem exists in the lack of a profit motive in programs undertaken with the use of public funds. However, a profit can be said to have been realized in public works programs if the total benefits of the programs to all the people exceed the costs of these programs and, further, if the …

The Separation Of Selected Radioactive Fission Products By Electrodialysis, Jerry David Vie

Masters Theses

"The recent advent of nuclear energy has opened an era of almost unlimited power and countless problems. A problem of extreme importance is the recovery of unburned nuclear fuel and the claiming of transmutation products, such as Pu²³⁹ and U²³³, from the irradiated fuel elements. The chemical processing must also separate the fission products from the fissionable material if the fuel is to be used again.

At present, the irradiated fuel elements are stored for 90 to 120 days to allow the intense short half-life activity to decay. After "cooling down", the nuclear fuels are separated from …

Physical Property Tests Of Rock, Centrifugal Tests And The Design Of Underground Mine Openings, Samuel Shu Mou Chan

Masters Theses

"Proper design of stable underground mine openings is important to the mining industry today. Various methods have been utilized by investigators to approach this goal.

A review of previous investigations of each of the phases of underground mine opening stress analysis is presented.

An approximate method of designing underground mine structures based on estimation of the initial stress field, rock physical property tests, and model tests, together with preliminary field data, is presented, and a specific example given"--Forward, page i.

Construction Of A Pulsed Perforated-Plate Extraction Unit, Clarence James Vetter Jr.

Masters Theses

"Liquid-liquid extraction is an important operation in the production and reprocessing of nuclear fuels. In the purification of uranium by liquid-liquid extraction, uranyl nitrate is separated from impurities by extraction into an organic solvent, followed by re-extraction into an aqueous phase. Further processing of the aqueous uranyl nitrate solution is tailored to yield uranium metal or any desired uranium compound.

In order that students in nuclear and chemical engineering may have an understanding of the practical as well as theoretical aspects of liquid-liquid extraction, a model of a uranium purification plant was designed and built in the Unit Operations Laboratory …

Mississippian Bioherms Of Southwestern Missouri And Northwestern Arkansas, Arthur R. Troell Jr.

Masters Theses

"Lenticular bodies of massive limestone, flanked by thin crinoidal beds, crop out in southwestern Missouri and northwestern Arkansas. They are within the St. Joe limestone of the Lower Mississippian.

Strata underlying these bodies typically are down-warped, those on the flanks lapping against, finally passing completely over the limestone core. Dips away from the “reef” are commonly around 5 degrees, but reach as much as 30 degrees. Conglomeratic detritus, originating from the core, occurs in flanking beds at their contact with it.

Thin sections of these masses show no more than 15 per cent of the limestone to consist of fossil …