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Environmental Applications Of Chromatography-Mass Spectrometry, Wisam Abdulabbas Flayyih Al Isawi

Masters Theses

Gas chromatography-mass spectrometry (GC-MS) and liquid chromatographymass spectrometry (LC-MS) are powerful analytical techniques that combine the separation power in a stationary phase with the detection power of mass spectrometry. GCMS and LC-MS have gained dominant positions in identifying and quantifying different analyte species due to their high selectivity, high sensitivity, and high reproducibility.

My research utilizes the analytical power of LC-MS and GC-MS to address two environmental issues: 1) Identification of biodegradation products of the ionic liquid 1- butyl-3-methylimidazolium chloride (BMIMCl) by an activated sludge microbial community using LC-MS and 2) identification and quantification of polycyclic aromatic hydrocarbons (PAHs) in …

Geochemical And Petrological Characterizations Of Peridotite And Related Rocks In Marquette County, Michigan, Andrew Lloyd Sasso

Masters Theses

This study characterizes the following rock units in Marquette County, Michigan in terms of geochemistry and petrology: (1) Presque Isle Peridotite, (2) Deer Lake Peridotite, (3) Yellowdog Peridotite, and (4) Black Rock Point Gabbro. Analyses were conducted to determine if any petrological or geochemical relationships exist between these units, and to assess the potential of these units to host magmatic sulfide deposits.

The generated data and chosen geotectonic proxies indicate that Black Rock Point Gabbro and Deer Lake Peridotite crystallized from unrelated magmas, probably during the formation of the Great Lakes Tectonic Zone (2.7-1.85 Ga). No evidence was found which …

Extent Of Capillary Rise In Sands And Silts, Rachel Lynn Salim

Masters Theses

The values reported in literature for the height of capillary rise in fine sands, silts, and clays are contradictory. Most of the values were based on mathematical models, which used estimated rather than measured input data. This work measured capillary rise values in laboratory experiments in fine-grained sands and silts.

Two uniform sands with grains 0.35--0.7 mm in diameter and 0.3-0.6 mm in diameter, silt with an average grain size below 40 microns, and 0.35--0.7 mm sand coated with a water-repellant spray were carefully packed into two-inch diameter glass columns. These columns were placed into clear plastic tanks with water …

A Geographic Distribution Analysis And Examination Of Social-Psychological Factors And Their Lmpact On Death Penalty Support In The United States, Katy Moharter

Masters Theses

Since the reinstatement of the death penalty in the United States in 1977, research has focused on shifting attitudes and waning public support for this institution. Support for the death penalty varies between different temporal, geographic, and demographic boundaries. Research also suggests that social-psychological factors such as attributional style and moral disengagement play a significant role in rationalization of death penalty support, as well as the intensity of the support. Aspects of moral disengagement serve as reliable predictors for death penalty support for a limited sample of participants, which this research intends to evaluate at a greater scale. This research …

Lnfluence Of Persulfate On Solidification/Stabilization Characteristics Of Iss Treatment, Jeffrey M. Hudson

Masters Theses

Two environmental remediation technologies that lend themselves well to being combined in a single application are In Situ Chemical Oxidation (ISCO) using activated persulfate (PS), and In Situ Stabilization (ISS). Persulfate can be activated by increasing the pH to 10.5 and/or increasing temperatures to 30ºC. Many common ISS amendments increase temperature to 30°C and/or pH to 10.5 when in contact with soil water. Laboratory experiments were conducted with various soils to determine the ability of eight ISS amendments to activate persulfate. All eight ISS amendments activated persulfate. This work also showed that the relative contribution of heat vs. alkaline activation …

Geochemical And Petrological Studies On The Origin Of Nickel-Copper Sulfide Mineralization At The Eagle Lntrusion In Marquette County, Michigan, Benjamin Davis Hinks

Masters Theses

The Eagle magmatic intrusion is located in the Upper Peninsula of Michigan in Marquette County. It hosts a high grade magmatic nickel-copper sulfide ore deposit. Country rocks surrounding the Eagle intrusion are metamorphosed slate and greywacke of the Proterozoic Michigamme Formation and Archean granite-gneiss. The aim of this thesis is to characterize the magmatic sulfide mineral deposit at Eagle and to establish its relationship to the surrounding host rocks of the Baraga Basin area.

The Eagle East intrusion is located 600 meters east of the Eagle intrusion. These two intrusions are similar in composition and sulfide mineralization. Sulfide textural domains …

Model Based Vehicle Simulation For Electrically Actuated Transmission Test Cells, Kenneth L. Gruel

Masters Theses

The Eaton Vehicle Group is responsible for the development of a large family of automotive products, including manual and automated manual transmissions for light, medium, and heavy duty vehicles. To further expand the transmission testing capabilities at Vehicle Group headquarters, the Vehicle Simulator system was developed and integrated into an existing motor-based test cell. System development time and cost were reduced by leveraging readily available vehicle models and real-time hardware. The Vehicle Simulator system allows a user to control the speed and torque settings of the test cell motors in manual mode, or switch the motors to vehicle emulation mode. …

A Parameterized Implementation Of A Hybrid Fuzzy Boolean Finite State Machine Using An Fpga, Sean T. Fuller

Masters Theses

A fuzzy system based on the extended Hybrid Fuzzy Boolean Finite State Machine (HFBFSM) model is designed and implemented in a Xilinx Zynq® all programmable System on Chip (SoC). The system allows for a single dominant crisp state and multiple non-dominant states to be activated simultaneously. A method is proposed to calculate the degree of membership of non-dominant states, β, by the distance of defuzzified fuzzy inputs to state transition trigger mechanisms.

The HFB-FSM is was realized by the author using custom logic written in VHDL (Very High Speed Integrated Circuit (VHSIC) Hardware Description Language) in the Programmable Logic (PL) …

Differentiating Saginaw From Huron-Erie Lce Lobe Meltwater Deposits In South Central Michigan Using Longitudinal Profiles, Grain Size Analysis, And Lithology, Nathan R. Erber

Masters Theses

The Saginaw and Huron-Erie lobes of the Laurentide Ice Sheet had a significant impact on the landscape of south-central Michigan after the Late Glacial Maximum. During the advances and retreats of these lobes, a complicated network of meltwater channels developed. Two goals of this study are: 1) to use sand-grain lithology, grain-size analysis, and longitudinal profiles to determine if a difference exists between Saginaw lobe and Huron-Erie lobe meltwater deposits; and 2) to determine if a large meltwater sluiceway containing the modern St. Joseph River had a source of meltwater and outwash from the Huron-Erie lobe. Two cores from drumlinized …

The Value Of The Arts In Education, Thorin Teague

Masters Theses

Art is a subject that has no substitute, as the learning and production of art satisfies a uniquely human need to communicate and connect with other human beings. The marriage of art and society can (and should) be thought of as culture. This author intends to assert that the arts have a critical place in education and indeed human society itself, bringing ancillary benefits to bear on the subject without relying on them as the primary justification for the retention and even expansion of arts programs; education (which could in turn be thought of the dissemination of cultural knowledge) of …

Structures And Nuclear Quadrupole Coupling Tensors Of 1,2-Dichloroethane, 1-Chloro-2-Fluoroethane And 2,3-Dichloropropene Studied Using Microwave Spectroscopy And Computational Chemistry, Asela Sampath Dikkumbura

Masters Theses

The Fourier-transform microwave (FTMW) spectra of 1,2-dichloroethane (12DCE), 1-chloro-2-fluoroethane (1C2FE) and 2,3-dichloropropene (23DCP) have been studied in the 6 to 18 GHz range to determine experimental rotational constants, nuclear quadrupole coupling constants (NQCC) and quartic centrifugal distortions constants. These three molecules have different spatial arrangements (anti and gauche) resulting from different relative orientations of chlorine and/or fluorine atoms about the C-C single bond. The lowest energy anti conformer of 12DCE is non-polar and it is not detectable by microwave spectroscopy, but rotational spectra of gauche-12DCE with three isotopologues, gauche-1C2FE with three isotopologues, and both anti- …

White-Rot Fungi As Pretreatment Agents For Wood Destined For Biofuel Applications, Ryan M. Kalinoski

Masters Theses

Efficient and economical conversion of lignocellulosic biomass to biofuels is often hampered by the chemical recalcitrance of the material. Inexpensive and environmentally-friendly pretreatment processes are therefore desirable in order to lower the cost of biofuel production and minimize negative environmental impacts. To that end, we have explored the use of a naturally occurring white-rot fungus, Trametes versicolor, as a direct pretreatment agent for hardwood destined for biofuel applications. Specifically, we examined the pretreatment effects on the hardwood mixture after treatment with the wild-type strain of T. versicolor (52J) compared with those from a cellobiose dehydrogenase (CDH)-deficient strain (m4D) , …

Theoretical Investigations Of Difluorobenzene Interacting With Ne And Infrared Analysis Of 1,1-Dichloroethylene From Synchrotron Data, Seri P. Kamari

Masters Theses

The intermolecular interactions between two molecules are of great importance in proteins, polypeptides, DNA binding, and drug binding interactions. Dimers of chemical rings such as difluorobenzene with hydrogen containing molecules such as acetylene (HCCH) and atoms such as neon are classic systems for investigating weak interactions; however, the microwave spectrum of 1,2-difluorobenzene...Ne does not behave as expected. Possible explanation of this phenomenon is that there is some large amplitude motion perturbing the spectrum.

A computational study was performed to analyze the potential energy surface (PES) of Ne or Ar with ortho, meta, and para difluorobenzene, and reveal the …

Understanding The Management Of Sustainability On One Public Midwestern College Campus, Eric Swinehart

Masters Theses

Environmental sustainability is a substantial issue within our world today that is on the forefront of policy makers' minds. Implementation of sustainability initiatives on a college campus comes in many forms and different scales, which falls upon the question of who manages all the moving pieces to make these initiatives successful. This study was designed to gain an understanding of how administrators are defining and implementing environmental sustainability initiatives on their campus, to understand their role in managing these tasks. Using a qualitative approach, the researcher interviewed a purposeful sample of four higher education administrators from one public Midwestern university. …

Is The Demand For Health Care Income Elastic? The Case Of 40 Sub-Saharan African Countries, Meron Masresha Nadew

Masters Theses

This paper uses panel data (1995 to 2011) from 40 Sub-Sahara African countries to analyze the income elasticity of health care expenditure along with some of the other theoretical determinants. The empirical results of the instrumental variable approach indicate that per capita income is a core and statistically significant determining factor of health expenditure. The value of the elasticity is about 0.48, suggesting that health expenditure as a commodity is a necessity for this region. In simple words, the goal of the system in this region is curative rather than caring. The percentage of population age 65 or older and …

Synthesis And Characterization Of Dicopper(Ii) Complexes With Biological Relevance, Ashley E. Hall

Masters Theses

The research discussed in this study focused on the design, synthesis, and characterization of new model complexes that mimic the type-3 enzyme, catechol oxidase, which oxidizes catechols to their corresponding quinones. Our approach focused on the design and synthesis new model complexes that contain a dicopper(II) center that can be fine-tuned in a variety of ways, such as sterics and exogeneous bridging molecules. This method allows a multitude of complexes to be created and compared to determine how the overall structure affects the catecholase activity of the complexes.

Two ligands were synthesized; they contain a phenolate body, two amide groups, …

Correlation Between Sleep And Lifespan In Drosophila Melanogaster, Courtney H. Fiebelman

Masters Theses

”Sleep has previously been associated with lifespan. Monitoring sleep in any given fly over their lifetime facilitates the ability to predict the lifespan of that given fly. Using this estimate, lifespan can potentially correlate with biological age to identify when health parameters have declined.

To confirm that the prediction algorithm could identify short and long-lived flies, glutathione levels in heads and bodies were compared between two groups. The results showed this to be consistent in the bodies of wild-type Canton S male flies, and showed that glutathione was decreased in the predicted biologically older flies. These data show that glutathione …

Exhumation Of The Nacimiento Block: A Thermochronologic Analysis, Lisa Marie Arnold Lori

Masters Theses

"Through the analysis of both U-Pb and (U-Th)/He ages from detrital zircon grains we can constrain thermal histories by establishing ages which correspond to crystallization and exhumation events, respectively. This combined geo-/thermochronologic approach is used here to constrain the history of the polyphase Nacimiento fault. This fault traverses central and southern California and has accumulated at least 150 km of slip since Late Cretaceous time. Major displacements along the structure occurred between 75 and 56 Ma, with Neogene to Holocene strike-slip remobilization linked to the San Andreas fault system. Detrital zircon U-Pb geochronology from Franciscan subduction assemblages west of the …

Bridging The Gap Between Supply Chain And Consumer Experience, Cui Zou

Masters Theses

Many researchers agree that supply chain management is at the root of addressing customer values and increasing customer satisfaction. However, in reality the route to accomplishing these goals is not so clearly defined. The studies herein attempt to shed some insight on a special perspective to bridge the gap between supply chain and customer experience. The ideas behind these studies explore the notion that customer experience can be impacted by a vast spectrum of factors from suppliers to even the specific mobile commerce (m-commerce) tools they use.

To gain insight into the supplier dimension of the supply chain, a survey …

Analysis Of Va Sacramento Medical Center Capacity Using Discrete Event Simulation, Tatiana Alejandra Cardona

Masters Theses

"The development of simulation models continues to provide effective solutions to a wide range of problems in healthcare systems. In the research presented within this thesis is the development of a representative and validated discrete event simulation model for the purpose of evaluating additional capacity. The study consists of a detailed exploratory analysis, verification and validation tests of the simulation results, and a thorough design of experiments. The exploratory analysis consisted of developing simulation models that provide similar characteristics found in the data. The design of experiments consisted of generating scenarios of various bed additions in the hospital units of …

Using Adaptive Thresholding And Skewness Correction To Detect Gray Areas In Melanoma In Situ Images, Jason R. Hagerty

Masters Theses

"The incidence of melanoma in situ (MIS) is growing significantly. Detection at the MIS stage provides the highest cure rate for melanoma, but reliable detection of MIS with dermoscopy alone is not yet possible. Adjunct dermoscopic instrumentation using digital image analysis may allow more accurate detection of MIS. Gray areas are a critical component of MIS diagnosis, but automatic detection of these areas remains difficult because similar gray areas are also found in benign lesions. This paper proposes a novel adaptive thresholding technique for automatically detecting gray areas specific to MIS. The proposed model uses only MIS dermoscopic images to …

A Study On Non-Metallic Inclusions In Foundry Steel Process, Marc Leonard Harris

Masters Theses

"The effects of sample area and automated SEM/EDS feature analysis parameters (step size, magnification and threshold) on nonmetallic inclusion characterization results has been investigated and optimized. A post-processing program was developed to automatically determine average inclusion chemistry, total element concentrations within inclusions, and for generating joint ternary diagrams with size visualization for representing nonmetallic inclusion populations. Using these tools the evolution of nonmetallic inclusions was examined for 4320 steel at a participating industrial steel foundry. The steel was sampled throughout electric arc furnace melting through ladle refining to the final casting where an in-mold sampling procedure was developed to procure …

A Statistical Analysis Of A 4.5 Mw Solar Energy Center, Archit Patnaik

Masters Theses

"This project helps a regional utility evaluate the performance of their 4.5 MW photovoltaic plant. The performance evaluation consists of characterizing the peak and average power and energy output of the plant over varying time periods. A characterization of the output power drops, or dips, is done by performing a statistical analysis of the photovoltaic plant output data. Dips are characterized by dip frequency, depth of dip, energy loss by dip, and dip duration. The results of this study will help the utility to select appropriate voltage regulating equipment on the basis of dip characteristics, and thus, optimize the performance …

Understanding Mentoring Relationships: The Black Male Graduate Student Perspective, Kwame R. Patterson Jr.

Masters Theses

Black males face many obstacles in higher education. They are disproportionately represented among students who are forced to withdraw, underperform academically, and report negative experiences. Despite the negative experiences Black males may encounter, many still have a strong interest in education, and mentoring plays a role in that interest. The purpose of this study was to explore the mentoring relationships and influence on the Black male graduate students experience. A qualitative study was conducted with Black males who received their master's degrees from a regional Midwestern institution. Research revealed that mentoring played a major role in Black male's graduate experience …

Initial Student Impressions And Affinity Towards The Institution, Andrew Doto

Masters Theses

This study attempted to explore the relationship between the university affinity and initial impressions of undergraduate students at a mid-size, Midwestern university. A quantitative study was employed after acquiring data using Berquam's (2013) Relationship Quality Student Affinity instrument, which measured a student's commitment and pride, as well as their initial impressions towards the university. Results from the Chi Square test for independence showed evidence that initial impressions were related to university affinity, aligning with prior research. Other results from the study indicated that initial impressions and university affinity were also related to university choice rank. Recommendations were made for the …

Universal Design: A Student Affairs Perspective, Becca Lynn

Masters Theses

College is one of the most exciting times in an individual's life and could also be one of the most challenging. Students are coming in to college needing amenities and different accommodations for a variety of different reasons; very commonly, learning and physical disabilities. Utilizing qualitative methodology, this study aimed to explore five different student affairs areas on campus to see if they provide a universally designed environment for college students with both learning and physical disabilities. Each professional shared their knowledge of universal design, universal strategies that they currently use, areas professionals believe are the most accommodating on campus …

Functionalized Bodipy Dyes For Dye-Sensitized Solar Cells, Mahmoud A. Elkhalifa

Masters Theses

It is predicted that more than 20 terawatts of carbon-free energy will be demanded by 2050 to maintain a sufficient energy supply for the increasing global population, and photovoltaics are predicted to contribute significantly to the global energy needs. Dye-sensitized solar cells (DSCs) are an emerging class of photovoltaics (PV) that has produced promising power conversion efficiencies at low costs. Currently, electron recombination, dye aggregation, weak adsorption, and inefficient absorbance are among of the largest contributors to low DSC efficiencies.

BODIPY dyes are one of the most promising classes of dyes emerging for DSC application. These low molecular weight fluorophores …

Holography In The Secondary Physics Curriculum, Stephen P. Hogan

Masters Theses

This paper presents a unit plan for effective implementation of a holography learning activity in the secondary science physics classroom. The study of holography has traditionally been limited to collegiate optics courses due to financial and physical constraints. Recent developments in the technology of holographic film has eliminated these two limiting factors. Recent secondary educators who have introduced holography with their secondary science classes have completed the activities, without much discussion or explanation regarding the scientific principles that allow the phenomenon to occur. In this paper we develop a foundational unit plan that finishes with holography as the pinnacle activity, …

An Exposition Of The Eisenstein Integers, Sarada Bandara

Masters Theses

In this thesis, we will give a brief introduction to number theory and prime numbers. We also provide the necessary background to understand how the imaginary ring of quadratic integers behaves.

An example of said ring are complex numbers of the form ℤ[ω] = {a+bω ∣ a, b ∈ ℤ} where ω² + ω + 1 = 0. These are known as the Eisenstein integers, which form a triangular lattice in the complex plane, in contrast with the Gaussian integers, ℤ[i] = {a + bi ∣ a, b ∈ …

Design Of An Intrusion Detection System (Ids) And An Intrusion Prevention System (Ips) For The Eiu Cybersecurity Laboratory, Adekunle Adeyemo

Masters Theses

Cyber Security will always be a subject of discussion for a long time to come. Research has shown that there is massive growth of cyber-crime and the currently available number of Cyber Security experts to counter this is limited. Although there are multiple resources discussing Cyber Security, but access to training in practical applications is limited. As an institution, Eastern Illinois University (EIU) is set to start Masters of Science in Cyber Security in Fall 2017. Then the challenge is how EIU will expose students to the practical reality of Cyber Security where they can learn different detection, prevention and …