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Masters Theses

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Analysis Charts For Single And Multi-Span Gabled Frames, John (Chung-Su) Ma Jan 1966

Analysis Charts For Single And Multi-Span Gabled Frames, John (Chung-Su) Ma

Masters Theses

"A method for analyzing single and multi-span gabled frames using analysis charts is presented. This method requires considerably fewer computations than methods previously used (such as the moment distribution and slope-deflection methods). Analysis charts are presented for single gabled frames having fixed or pinned ends at ground level, and charts are also presented which can be used to efficiently analyze multi-gabled frames.

The data for the analysis charts were obtained using matrix techniques in conjunction with the digital computer. These techniques are described"--Abstract, page ii.


A Study Of Modified Plug Designs For A Globe Valve, Robert W. Wagner Jan 1966

A Study Of Modified Plug Designs For A Globe Valve, Robert W. Wagner

Masters Theses

"This thesis presents an empirical study of the characteristics of a cylindrical skirted disk valve used as a flow regulating device. Holes were drilled in two separate removable cylinders, which, when respectively attached to the valve plug adapter, provided control of the flow rate. These cylinders could be moved to permit exposure of more or less flow area by means of the valve stem and crank mechanism. At the closed position of the valve no holes were available for flow within the differential pressure zone of the valve, while at the full-open position all the drilled holes were within the …


Approximate Solution Of The Momentum And Energy Equations For Partially Ionized Argon, Sir-Hoi Chen Jan 1966

Approximate Solution Of The Momentum And Energy Equations For Partially Ionized Argon, Sir-Hoi Chen

Masters Theses

"Based on available experimental data, the transport properties of partially ionized argon gas have been determined by solving the integral equations of momentum and energy conservation by an approximate method. The momentum and the energy conservation integral equations are solved simultaneously by an iteration method by assuming both parabolic and cubic velocity and temperature profiles separately. The results are compared with the case of linear velocity and temperature profiles"--Abstract, page iii.


Stable Predictor-Corrector Methods For First Order Ordinary Differential Equations, Terrell Lester Carlson Jan 1966

Stable Predictor-Corrector Methods For First Order Ordinary Differential Equations, Terrell Lester Carlson

Masters Theses

"Because of the wide variety of differential equations, there seems to be no numerical method which will affect the solution best for all problems. Predictor-corrector methods have been developed which utilize more ordinates in the predictor and corrector equations in the search for a better method.

These methods are compared for stability and convergence with the well known methods of Milne, Adams, and Hamming"--Abstract, page ii.


The Development Of A Modified Soil Shear Vane, Vernelle Truman Smith Jan 1966

The Development Of A Modified Soil Shear Vane, Vernelle Truman Smith

Masters Theses

"The purpose of this investigation was to determine how the soil shear graph could be modified to measure more accurately values of shear strength of fine-grained, cohesive soils. Several modifications were tried, however, the one that gave the most satisfactory results consisted of a vane and base plate mechanism.


A red clay of high plasticity obtained from a local cave was tested in both the natural or undisturbed state and in the remolded state. The only variable was the moisture content. Compaction effort was the same for all remolded specimens. Tests were conducted on undisturbed samples taken with thin walled …


The Mössbauer Effect In Bismuth Ferrate, Bruce A. Banks Jan 1966

The Mössbauer Effect In Bismuth Ferrate, Bruce A. Banks

Masters Theses

"The magnetic hyperfine structure of the Fe⁵⁷ nuclei in bismuth ferrate was investigated using the Mössbauer effect. A Mössbauer effect spectrometer was built with consideration given to the elimination of vibration and the optimizing of the source, absorber, and detector geometries to produce the largest fractional Mössbauer effect per fractional standard deviation. The internal magnetic field at the Fe nuclei in BiFeO₃ was determined to (482 ± 9) kilooersteds at room temperature"--Abstract, page ii.


Ecology And Distribution Of Foraminifers Of A Traverse In The Northwestern Gulf Of Mexico, Faiz Nassir Thomas Jan 1966

Ecology And Distribution Of Foraminifers Of A Traverse In The Northwestern Gulf Of Mexico, Faiz Nassir Thomas

Masters Theses

"Foraminiferal populations have been analyzed from five bottom samples along a traverse in the northwestern Gulf of Mexico, approximately 27⁰20' to 97⁰15' north latitude and 97⁰20' to 97⁰05' west longitude. Eighty-eight species and twenty-nine genera, belonging to eighteen families, were recorded. Species were identified and described.

Statistical studies indicate that probably five benthonic foraminiferal depth facies could be recognized in the area at the following approximate depths: 4 fathoms, 4-8 fathoms, 8-12 fathoms, 12-16 fathoms, and 16-20 fathoms. Determination of facies is based largely on the range of species. The frequency distribution of species of foraminifers was plotted against change …


Kinetics And Mechanisms Of Base-Catalysed Reactions, Rohit Panalal Sheth Jan 1966

Kinetics And Mechanisms Of Base-Catalysed Reactions, Rohit Panalal Sheth

Masters Theses

"Base-catalysed reactions normally involve complex series of transformations. their kinetics is usually governed by a variety of equilibria, participating in the overall and concurrent processes as well as by competitive side-reactions that interfere with the normal course of such reactions. Mechanisms which have been proposed, by and large, are primarily based on product, by-product and intermediate analyses together with some scattered kinetic and isotopic evidence. In the cases where kinetic studies have been attempted, highly complex mechanisms have usually been proposed due to the frequent necessity of using heterogeneous media or employing involved mathematical treatments to describe the kinetics of …


Electrodialysis Of Tomato Juice, Raghunath R. Khetan Jan 1966

Electrodialysis Of Tomato Juice, Raghunath R. Khetan

Masters Theses

"Thermal decarboxylation of carboxylic acids has been helpful in illustrating some fundamentals of reaction kinetics in solution. It has been important in formulation of the theory of unimolecular reactions. It is also used frequently in the synthetical methods of organic chemistry.

In a recent study of the anodic oxidation of malonic acid in sulfuric acid at 80⁰C using a platinum anode, the interpretation of some results was impossible due to the spontaneous decomposition of the malonic acid. As no information is available in the literature about decomposition rates of malonic acid in sulfuric acid at the concentrations used, it was …


Mass Transfer In Droplets With Turbulent Internal Circulation - Mathematical Description, Jayantilal Mohanbhai Patel Jan 1966

Mass Transfer In Droplets With Turbulent Internal Circulation - Mathematical Description, Jayantilal Mohanbhai Patel

Masters Theses

"This investigation was carried out to check the accuracy of the eigenvalues, λn, calculated by Wellek and Skelland, using some method other than the Rayleigh-Ritz technique and also, to determine the coefficients, Bn in series solution, which were not calculated before.
The eigenvalues were obtained by trial and error procedure using the standard Runge-Kutta method. The coefficients Bn were obtained by using eigenvalues. By using this information the fractional extraction was calculated as a function of droplet contact time.


The Wellek-Skelland modification was also solved by finite difference technique to compute fraction extracted as a function …


Analysis Of Time-Varying Linear Multipole Filters With Sampled Nonstationary Random Inputs, Ming-Chwan Chow Jan 1966

Analysis Of Time-Varying Linear Multipole Filters With Sampled Nonstationary Random Inputs, Ming-Chwan Chow

Masters Theses

"In this thesis an analytical method is developed to determine an optimum time-varying linear filter in order to satisfy the following specifications. The filters are of sampled data multipole form with n inputs and m outputs. The signal of each input is a member of a nonstationary random process, and the signal is corrupted by stationary noise.


The statistical optimization theory developed by Wiener is extended to a linear time- varying filter with nonstationary input. Correlation functions are defined for nonstationary ensembles. The mean- square error is calculated in terms of these correlation functions. By minimization of the mean-square error, …


The Effect Of Structure On The Consolidation Characteristics Of A Clay Soil, Dale E. Sukow Jan 1966

The Effect Of Structure On The Consolidation Characteristics Of A Clay Soil, Dale E. Sukow

Masters Theses

"This paper reports the results of an investigation conducted to establish the effect of structure on the consolidation characteristics of a clay soil. Soil structure was caused to form in the soil by the addition of electrolytes to flocculate and disperse the clay fraction of the soil.


Consolidation tests were performed on specimens of the treated soil prepared at moisture contents well above the liquid limit of the soil. The consolidation data from these tests are evaluated and comparisons are made to relate the influence of structure to the consolidation characteristics of the treated soil.


The influence of structure on …


An Application Of The Variable Gradient Method Of Generating Liapunov Functions To Discrete Systems, Henry N. Peterson Jan 1966

An Application Of The Variable Gradient Method Of Generating Liapunov Functions To Discrete Systems, Henry N. Peterson

Masters Theses

"The variable gradient method of generating Liapunov functions has been used only for continuous systems. This thesis presents an application of the variable gradient method to non-linear sampled data control systems.
Certain modifications to the variable gradient method are developed and several examples are presented which demonstrate the application. An attempt was made to synthesize the control system parameters, but due to the complexity of the ΔV functions, the synthesis in general cannot easily be obtained . To circumvent the problem of determining if the ΔV functions are negative definite, a set of computer programs were written to determine a …


A Mathematical Study Of Voigt Viscoelastic Love Wave Propagation, David Nuse Peacock Jan 1966

A Mathematical Study Of Voigt Viscoelastic Love Wave Propagation, David Nuse Peacock

Masters Theses

"This research is a mathematical investigation of the propagation of a Love wave in a Voigt viscoelastic medium. A solution to the partial differential equation of motion is assumed and is shown to satisfy the three necessary boundary conditions. Velocity restrictions on the wave and the media are developed and are shown to be of the same form as those governing the elastic Love wave"--Abstract, page ii.


Geology Of The Acari Iron Mining District Arequipa, Peru, Raul Alejandro Zevallos Jan 1966

Geology Of The Acari Iron Mining District Arequipa, Peru, Raul Alejandro Zevallos

Masters Theses

"The Acari Iron Mining District, part of a tilted uplifted fault block, comprises an area about 300 square kilometers, in the southern part of the coastal belt of Peru. It is in the foothills of the western range of the Andes and it is dominantly formed by granodioritic and granitic intrusive rocks which belong to the Andean batholith of Cretaceous-Tertiary age. The intrusive rocks are overlain by a central, elongated, northwest trending band, of metasedimentary and volcanic rocks

The magnetite deposits of Acari district are long, dike-shaped bodies, which fill two systems of fractures in the granodiorite intrusive, located in …


The Preparation Of 5-Arylazopyrimidines, Frederic Edwin Dutton Dec 1965

The Preparation Of 5-Arylazopyrimidines, Frederic Edwin Dutton

Masters Theses

Introduction

The synthesis of 5-arylazopyrimidines was undertaken in search of potential anticancer agents.

While many azo compounds have carcinogenic activity, it has been shown by several workers in this area that some 5-arylazopyrimidines have anticancer properties. S. Hibino(1) has shown that p-(2,4,6-triamino-5-pyrimidinylazo) benzene-sulfonic acid shows promise as an effective anticancer agent when used in conjunction with 6-mercaptopurine and adrenal steroidal hormones. When tested clinically, total remission of the leukemic process was achieved in 85.7% of the cases treated. In comparison, total remission was achieved in only 57.5% of the cases treated with a mixture of 6-MP and the hormone which …


The Effect Of Instructions On Problem Solving Efficiency, Douglas Allen Webb Dec 1965

The Effect Of Instructions On Problem Solving Efficiency, Douglas Allen Webb

Masters Theses

No abstract provided.


Phase Shift Analysis Of Protons Elastically Scattered By 016 Near EP = 8.3 Mev, Glenn D. Westin Dec 1965

Phase Shift Analysis Of Protons Elastically Scattered By 016 Near EP = 8.3 Mev, Glenn D. Westin

Masters Theses

Chapter I

Introduction

The study of the resonances in the scattering cross section of the p + O16 reaction can reveal information regarding the energy levels of the compound nucleus F17. The analysis is simplified because of the zero spin of the O16 nucleus. Also, the low binding energy of the proton added to O16 allows examination of the low-lying energy levels in F17.1 The reaction has been intensively investigated at the University of Wisconsin in a series of experiments using an electrostatic accelerator as a source of protons.


The Calculation Of The Cross-Section Of The Interaction Between Two Yang-Mills Fields, Richard A. Starr Dec 1965

The Calculation Of The Cross-Section Of The Interaction Between Two Yang-Mills Fields, Richard A. Starr

Masters Theses

The Problem and Its Background

This thesis presents a study of the interaction between two arbitrary fields, named Yang-Mills fields1 for their originators. The basic equations for the calculations of the Yang-Mills interaction are due to modern quantum field theory and its specific application to quantum electrodynamics.2

Much useful information can be obtained from the formulation of the dynamical equations for a classical system: for example, the classical description of the electromagnetic field, based on Maxwell's equations, leads to wave concepts. Then using this formalism as a starting point, one can proceed to the quantum theory of free …


Plant-Derived Pigments And Dyes Used By Artists, Samuel C. Rizzetta Dec 1965

Plant-Derived Pigments And Dyes Used By Artists, Samuel C. Rizzetta

Masters Theses

History

Uses of Biologically-derived Products in Painting

Throughout history man has relied heavily on plant-derived materials in the production of paintings. Plant products have been used to fulfill each of the material requirements of painting. The ground or surface upon which an artist applies paint -is usually of plant origin, such as woven fabrics and paper. The ancient Egyptians painted on canvas (from Linum usitatissimum L.), papyrus, (from Cyperus papyrus L.), and wood (Lucas, 1934:149-150, 201-203; Laurie, 1910:17, 31-32).

At the time of Theophilus leather parchment, preferably of horsehide, was popular for painting (Bazzi, 1960:13). After parchment, walls and wooden …


The Reaction Of Metal Hydrides With Azoacetates, Thomas H. Althuis Oct 1965

The Reaction Of Metal Hydrides With Azoacetates, Thomas H. Althuis

Masters Theses

Introduction

The term aliphatic azo compound refers to those azo compounds in which at least one of the two nitrogen atoms is linked to a tetrahedral, that is, sp3 -hybridized carbon atom. Di-imides, RN=NH, however, are not being considered. Mixed aliphatic-aromatic azo compounds are those in which one nitrogen atom is linked to an sp3 -hybridized carbon atom and the other to an aromatic sp2 -hybridized carbon atom. If present, a symmetry element (point or plane) is determined by the mid-point between the two nitrogen atoms.


Study Of The Stereochemistry Of A Carbanion Generated From An Azoacetate, Nguyen Thanh Buu Sep 1965

Study Of The Stereochemistry Of A Carbanion Generated From An Azoacetate, Nguyen Thanh Buu

Masters Theses

Introduction

The reaction of lead tetraacetate with ketohydrazones to form azoacetates has been reported recently by Iffland, Salisbury and Schafer (13) and may be represented by the following equation:

R2C=N-NH-R' + Pb(0Ac)4 → R2C-N=N-R' + Pb(OAc)2 + HOAc OAc

Of principal interest has been the base-catalyzed decomposition of an azoacetate in a protonic solvent to give a ketone, a hydrocarbon, nitrogen and an acetate salt. The following sequence of steps has been proposed to account for these products (11).


Aminomethylation And Hydroxymethylation Of 6-Mercaptopurine And 6-Alkylthiopurines, Charles P. Bryant Sep 1965

Aminomethylation And Hydroxymethylation Of 6-Mercaptopurine And 6-Alkylthiopurines, Charles P. Bryant

Masters Theses

Introduction

The Mannich reaction and hydroxymethylation were used to prepare analogs of 6-mercaptopurine as possible antimetabolites. Physical and chemical methods were used to elucidate the structures of the compounds prepared.


Interests, Attitudes And Personality Patterns Of Undergraduate Students In Speech Pathology And Audiology, Sandra Mary Henderson Jul 1965

Interests, Attitudes And Personality Patterns Of Undergraduate Students In Speech Pathology And Audiology, Sandra Mary Henderson

Masters Theses

Chapter I

The Problem and Its Background

Introduction

Over the past several decades there has been increasing interest in the occupational choices of men and women, and the interests and attitudes associated with various professional groups. Since occupations are becoming increasingly more specialized, employers and educators have found that those people who perform best in the position of their choice are those who exhibit certain interests and attitudes with regard to their occupation. Colleges emphasize the necessity of counseling in order to enable students to effectively choose general areas of concentration. The fields of study chosen by students are a …


Nuclear Magnetic Relaxation And Diffusion In Paraffin Oil, David E. Parker Jul 1965

Nuclear Magnetic Relaxation And Diffusion In Paraffin Oil, David E. Parker

Masters Theses

Introduction

Since the introduction of the spin echoes technique by E. L. Hahn1 many studies have been made in the determination of the spin relaxation T2, spin-lattice relaxation T1, and the diffusion rates in gases, liquids2-5, and solids6-10. Hahn's methods were later improved by Carr and Purcell11. The Carr-Purcell method serves as the basic technique for this study.

Several studies have been published on the relaxation and diffusion rates in hydrocarbons12. These studies have shown:

1. The spin relaxation time T2, is independent of the …


The Polarizing Effects Of Inhibitors Upon The Reaction Of Iron With Hydrochloric Acid, Duane L. Mickelson Jul 1965

The Polarizing Effects Of Inhibitors Upon The Reaction Of Iron With Hydrochloric Acid, Duane L. Mickelson

Masters Theses

Introduction

Corrosion inhibitors have been widely studied. Electrical methods of study have been utilized (7) (10) (24) and polarization curves (2) (6) (18) (26) have been plotted by many observers in studying different aspects of corrosion. In this research the measured polarizing currents a.re used strictly in an effort to find out how the corrosion inhibitors affect the anodic and the cathodic reactions.


Reaction Of Dihydropyran With Substituted Benzenesulfonyl Azides, Douglas L. Rector Jun 1965

Reaction Of Dihydropyran With Substituted Benzenesulfonyl Azides, Douglas L. Rector

Masters Theses

Introduction

The intent of this investigation was to study the addition of arylsulfonyl azides to vinyl ethers, specifically 2,3-dihydro-4H-pyran, and to establish by chemical and physical methods the structure of the adduct.


A Study Of The Relationship Of The Verb-Adjective Ratio In Linguistic Construction To Induced Stress, Bruce A. Schurman Jun 1965

A Study Of The Relationship Of The Verb-Adjective Ratio In Linguistic Construction To Induced Stress, Bruce A. Schurman

Masters Theses

No abstract provided.


Helianthus Annuus - The Separation And Identification Of A New Fatty Acid, Donald C. Gruber Jun 1965

Helianthus Annuus - The Separation And Identification Of A New Fatty Acid, Donald C. Gruber

Masters Theses

Introduction

The term "fatty acids" was first applied principally to saturated, monobasic carboxylic acids and especially to long chain acids derived from animal and vegetable oils. As time passed and the knowledge of natural fats increased, polyunsaturated, hydroxy, keto and branched chain acids were also found as constituents of these fats and oils and these also came under the heading of fatty acids. Even acids containing alicyclic substituents were found.

More recently the term 11 fatty acid" has been applied to include saturated and unsaturated monobasic carboxylic acids and several other series of substituted acids having carbon skeletons similar to …


Synthesis Of Potential Anti-Tumor Agents Related To Ethanolamine. I. Phenoxyacetic Acid Derivatives, Kenneth Wayne Rodarmer Jun 1965

Synthesis Of Potential Anti-Tumor Agents Related To Ethanolamine. I. Phenoxyacetic Acid Derivatives, Kenneth Wayne Rodarmer

Masters Theses

Introduction

Derivatives of phenoxyacetic acid (PAA), because of their activity as synthetic auxins, have long been of interest in the botanical sciences. PAA itself was noted (29) to have some auxin activity. However, real interest in PAA derivatives awaited the establishment of 2,4-dichlorophenoxyacetic acid (2,4-D) as a powerful, selective herbicide (12). An enormous number of PAA analogs and homologs have been investigated for their potential in the herbicide industry, and the statistical evidence from these investigations has been used as the basis for several interesting and sometimes conflicting theories of auxin mechanisms (17, 26, 23, 27).

Physiological effects of PAA …