Digital Commons Network^™

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …

High-Dimensional Isotope Relationships, Yuyang He

LSU Doctoral Dissertations

High-dimensional isotope relationships describes the relationships of two or more element or position-specific (PS) elements in the same molecule or ion. It provides us more powerful tools to study reaction mechanisms and dynamics. Chapter 1 is about dual or multiple stable isotope relationship on δ-δ (or δ'-δ') space. While temporal data sampled from a closed-system can be treated by a Rayleigh Distillation Model (RDM), spatial data should be treated by a Reaction-Transport Model (RTM). Here we compare the results of a closed-system RDM to a RTM for systems with diffusional mass transfer by simulating the trajectories on nitrate's δ'^{18 …}

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …

Development Of Self-Healing Mechanisms For Asphalt Pavements, Max Abelardo Aguirre Deras

LSU Doctoral Dissertations

Self-healing mechanisms, such as microcapsules or hollow-fibers, filled with an asphalt rejuvenator present an emerging technology that would enhance an asphalt mixture’s resistance to cracking damage caused by vehicular and environmental loading. The objectives of this study were to: (a) Evaluate the effects of asphalt rejuvenators on hot-mix asphalt mixtures in order to test its effects on the fundamental engineering properties of the mixtures at high and intermediate temperatures; (b) Develop a synthesis procedure for production of microcapsules and hollow-fibers containing an asphalt rejuvenator; (c) Evaluate the self-healing efficiency of double-walled microcapsules and hollow-fibers filled with an asphalt rejuvenator, through …

Direct Quantification Of Deubiquitinating Enzyme Activity In Single Intact Cells, Nora Safabakhsh

LSU Doctoral Dissertations

Challenges in drug efficacy occur during the treatment of most types of cancer due to the heterogeneity of the tumor microenvironment. This has led to the development of personalized medicine. Due to the clinical success of the proteasome inhibitors Bortezomib and Carfilzomib in treatment of multiple myeloma, interest has shifted towards molecularly-targeted chemotherapeutics for ubiquitin-proteasome system (UPS). Deubiquitinating enzymes (DUBs) are an essential part of this pathway which have been found to promote Bortezomib resistance in multiple myeloma patients. Unfortunately, there is a lack of specific, high throughput biochemical assays to characterize DUB activity in patient samples before and after …

Ultrafast And Nonlinear Spectroscopy Of Nanomaterials, Rami Anthony Khoury

LSU Doctoral Dissertations

Ultrafast and nonlinear spectroscopies are implemented in the investigation of excited-state dynamics and structural properties of materials and nanomaterials. In the first study, the excited-state dynamics of size-dependent colloidal TiO₂-Au nanocomposites are investigated using ultrafast transient absorption spectroscopy. The dynamics corresponding to the plasmon depletion band are characterized by electron-phonon and phonon-phonon coupling lifetimes that are observed to be independent of the gold nanocluster shell thickness. The excited-state dynamics corresponding to the interband transition of gold is also spectrally overlapped with the interfacial electron transfer lifetime, which is shown to decrease as the nanocluster shell thickness increases. In …

Advanced College Credit Pathways: Six Undergraduates Reflect On Their Journeys As Writers, Candence Malhiet Robillard

LSU Doctoral Dissertations

This study explored the writing habits and behaviors of six undergraduate students who earned advanced college credit from the International Baccalaureate diploma, Advanced Placement exam scores, or through dual enrollment partnerships with accredited colleges. Using narrative and case study methods, the study investigated the relationship between high school advanced credit composition courses and the requirements of undergraduate writing. At the time of the study the participants had already completed a minimum of three semesters of study on a college campus.Participants met a total of three times over the course of one semester. Inreflecting on their experiences and in sharing their …

Re-Forming Educational Reform: An Oral History Of Three Louisiana Teachers, Ashley L. Seatter

LSU Doctoral Dissertations

The purpose of this study is to examine the impact of educational reforms from 1983- 2014 through conducting oral histories with three Louisiana teachers. My research, as a postmodern and cultural feminist, was to interview and create a dialogue with three teachers; to find the intersection between school, reform and the meaning these give to their teaching life. I chose to interview teachers who are currently or close to retirement, who taught in a Louisiana accredited school system.

My focus was to investigate the lives of teachers, including their thoughts on educational reform changes during their tenure of teaching. Much …

Mymathlab Educational Intervention To Enhance Student Performance In Calculus I At Historically Black Colleges And Universities, Sheila Duplechain Derouen

LSU Doctoral Dissertations

According to the Obama Administration, we need a workforce that is going to be STEM ready because this is the only way that the U.S. will be able to compete on a global level with other nations. Louisiana will demand a total of 66,250 STEM jobs by 2018, up from 61,610 in 2008, according to Georgetown University (Carnevale, Smith, & Melton, 2014). By 2020, sixty-five percent of the nation’s jobs will require post-secondary education. According to the National Center for Education Statistics, the attrition rate between first- and second-year college students is 24.5% (2017).

The purpose of this study is …

Nmr Structural Investigation Of Chlamydial Protein Complex And Lysine Glycomimetic For Drug Design, Abigael Chebichiy Songok

LSU Doctoral Dissertations

Research and design of drugs for treatment against microbial infections require the study of pathogenic proteins involved during infection and replication. Drugs can be designed to interfere with the interaction network of these pathogenic proteins and inhibit the infection process. Determination of the structure and ligands of the target proteins in microbes is essential for designing mechanistic-based drugs. Two Chlamydia proteins involved in host cell invasion were investigated in this study. The goal is to identify amino acids involved at the binding interface of Chlamydia chaperon proteins Scc1 and Scc4 by solution NMR spectroscopy. This information will give a lead …

Decentralized Optimal Control With Application In Power System, Boyu Wang

LSU Doctoral Dissertations

An output-feedback decentralized optimal controller is proposed for power systems with renewable energy penetration. Renewable energy source is modeled similar to the classical generator model and is equipped with the unified power flow controller (UPFC). The transient performance of power system is considered and stability of the dynamical states are investigated. An offline decentralized optimal controller is designed that utilizes only the local states. The network comprises conventional synchronous generators as well as renewable sources with inverter equipped with UPFC. Subsequently, the optimal decentralized controller is compared to the initial stabilizing controller used to obtain the optimal controller. An online …

Curve Tracking Control Under State Constraints And Uncertainties, Robert Kelly Sizemore

LSU Doctoral Dissertations

We study a class of steering control problems for free-moving particles tracking a curve in the plane and also in a three-dimensional environment, which are central problems in robotics. In the two-dimensional case, we provide adaptive controllers for curve tracking under unknown curvatures and control uncertainty. The system dynamics include a nonlinear dependence on the curvature, and are coupled with an estimator for the unknown curvature to form the augmented error dynamics. This nonlinear dependence puts our curvature identification objective outside the scope of existing adaptive tracking and parameter identification results that were limited to cases where the unknown parameters …

How Do New Media Environments Influence Consumer Responses To Advertising? A Meta-Analytic Approach To Ad Avoidance, A-Reum Jung

LSU Doctoral Dissertations

This study aims to a) identify a comprehensive list of the antecedents and consequences of ad avoidance, b) examine how strongly they relate to ad avoidance, and c) investigate how those relationships differ across media formats. In order to fulfill these purposes, two studies (a meta-analysis and an online survey) were conducted. The meta-analysis yielded 52 antecedents and 7 consequences. Ad-related perception, ad tactics, personal characteristics, ad exposure conditions, personal experiences, and demographic information were major categories of antecedents. Decreased cognitive abilities to recall and recognize ad messages were primary consequences of advertising avoidance. In addition, the survey found that …

Throughput And Yield Improvement For A Continuous Discrete-Product Manufacturing System, Md Shahriar J. Hossain

LSU Doctoral Dissertations

A seam-welded steel pipe manufacturing process has mainly four distinct major design and/or operational problems dealing with buffer inventory, cutting tools, pipe sizing and inspection-rework facility. The general objective of this research is to optimally solve these four important problems to improve the throughput and yield of the system at a minimum cost.

The first problem of this research finds the optimal buffer capacity of steel strip coils to minimize the maintenance and downtime related costs. The total cost function for this coil feeding system is formulated as a constrained non-linear programming (NLP) problem which is solved with a search …

Non-Local Methods In Fracture Dynamics, Eyad Said

LSU Doctoral Dissertations

We first introduce a regularized model for free fracture propagation based on non-local potentials. We work within the small deformation setting and the model is developed within a state based peridynamic formulation. At each instant of the evolution we identify the softening zone where strains lie above the strength of the material. We show that deformation discontinuities associated with flaws larger than the length scale of non-locality $\delta$ can become unstable and grow. An explicit inequality is found that shows that the volume of the softening zone goes to zero linearly with the length scale of non-local interaction. This scaling …

Broadband Measurement And Reduction Of Quantum Radiation Pressure Noise In The Audio Band, Jonathan Daniel Cripe

LSU Doctoral Dissertations

One hundred years after Albert Einstein predicted the existence of gravitational waves in his general theory of relativity, the Laser Interferometer Gravitational-Wave Observatory (LIGO) made the first direct detection of gravitational waves. Since the first detection of gravitational waves from a binary black hole merger, LIGO has gone on to detect gravitational waves from multiple binary black hole mergers, and more recently from a binary neutron star merger in collaboration with telescopes around the world. The detection of gravitational waves has opened a new window to the universe and has launched the era of gravitational wave astronomy.

With the first …

Heuristics For Client Assignment And Load Balancing Problems In Online Games, Shawn Michael Farlow

LSU Doctoral Dissertations

Massively multiplayer online games (MMOGs) have been very popular over the past decade. The infrastructure necessary to support a large number of players simultaneously playing these games raises interesting problems to solve. Since the computations involved in solving those problems need to be done while the game is being played, they should not be so expensive that they cause any noticeable slowdown, as this would lead to a poor player perception of the game. Many of the problems in MMOGs are NP-Hard or NP-Complete, therefore we must develop heuristics for those problems without negatively affecting the player experience as a …

The Handmaiden Of Gnosis: Music In Esoteric Societies, Justin Andrew Owen

LSU Doctoral Dissertations

Western esotericism, or the practice of trying to understand divinity through secret initiatic means, exists in several philosophical strains, which mystics through the ages have formalized into systems of teaching. One aspect that appears in many of the traditions is music. Music is a direct language of the consciousness within esoteric traditions because it does not rely on language to express higher concepts. Just as these societies teach truths mainly through symbolism, they use music, since it lends itself to interpretations beyond the connotation-laden nature of words. This dissertation focuses on three major strains of western esotericism: Rosicrucians, Theosophists, and …

Invariant Of Noncommutative Algebras And Poisson Geometry, Bach Van Nguyen

LSU Doctoral Dissertations

In this dissertation, we describe the structure of discriminant of noncommutative algebras using the theory of Poisson quantization and ring theoretic properties of Poisson algebra. In particular, under appropriate conditions, we express the discriminant of specialization of K[q^{+-1}]-algebras as product of Poisson prime elements in some Poisson central subalgebra. In addition, we provide methods for computing noncommutative discriminant in various settings using results obtained for specialization of K[q^{+-1}]-algebras. Further, to demonstrate, we explicitly compute the discriminant of algebra of quantum matrices and quantum Schubert cell algebras specializing at roots of unity. This dissertation is part of the collaboration with Trampel …

Backstepping And Sequential Predictors For Control Systems, Jerome Avery Weston

LSU Doctoral Dissertations

We provide new methods in mathematical control theory for two significant classes of control systems with time delays, based on backstepping and sequential prediction. Our bounded backstepping results ensure global asymptotic stability for partially linear systems with an arbitrarily large number of integrators. We also build sequential predictors for time-varying linear systems with time-varying delays in the control, sampling in the control, and time-varying measurement delays. Our bounded backstepping results are novel because of their use of converging-input-converging-state conditions, which make it possible to solve feedback stabilization problems under input delays and under boundedness conditions on the feedback control. Our …

Dimers On Cylinders Over Dynkin Diagrams And Cluster Algebras, Maitreyee Chandramohan Kulkarni

LSU Doctoral Dissertations

This dissertation describes a general setting for dimer models on cylinders over Dynkin diagrams which in type A reduces to the well-studied case of dimer models on a disc. We prove that all Berenstein--Fomin--Zelevinsky quivers for Schubert cells in a symmetric Kac--Moody algebra give rise to dimer models on the cylinder over the corresponding Dynkin diagram. We also give an independent proof of a result of Buan, Iyama, Reiten and Smith that the corresponding superpotentials are rigid using the dimer model structure of the quivers.

Unavoidable Immersions And Intertwines Of Graphs, Matthew Christopher Barnes

LSU Doctoral Dissertations

The topological minor and the minor relations are well-studied binary relations on the class of graphs. A natural weakening of the topological minor relation is an immersion. An immersion of a graph H into a graph G is a map that injects the vertex set of H into the vertex set of G such that edges between vertices of H are represented by pairwise-edge-disjoint paths of G. In this dissertation, we present two results: the first giving a set of unavoidable immersions of large 3-edge-connected graphs and the second on immersion intertwines of infinite graphs. These results, along with …

A Study Of Scalability And Cost-Effectiveness Of Large-Scale Scientific Applications Over Heterogeneous Computing Environment, Arghya K. Das

LSU Doctoral Dissertations

Recent advances in large-scale experimental facilities ushered in an era of data-driven science. These large-scale data increase the opportunity to answer many fundamental questions in basic science. However, these data pose new challenges to the scientific community in terms of their optimal processing and transfer. Consequently, scientists are in dire need of robust high performance computing (HPC) solutions that can scale with terabytes of data.

In this thesis, I address the challenges in three major aspects of scientific big data processing as follows: 1) Developing scalable software and algorithms for data- and compute-intensive scientific applications. 2) Proposing new cluster architectures …

Investigating Early-Career Teacher Propensity For Arts-Based Pedagogy, Jamie Allison Hipp

LSU Doctoral Dissertations

This study investigates the factors which support the use of arts-based pedagogy in elementary settings. To address the lack of a current profile of an early-career teacher (ECT) with a propensity to use the arts – music, theatre, dance, and visual art – this study illuminates ECT attitudes and behaviors related to arts-based pedagogy. The researcher administered Oreck’s (2001) Teaching with the Arts Survey (TWAS) and employed a non-experimental survey design using purposive sampling. The ECT population studied included currently employed elementary (1-5) teachers who completed the compulsory arts-based pedagogy class at a large Louisiana university in the fall of …

New Platinum(Ii) And Rhenium(I) Complexes Of "Linear" Chelate Ligands Terminated With Pyridyl Or Imidazolyl N-Donor Groups, Himali Kokila Ranasinghe Pilana Vithanage

LSU Doctoral Dissertations

The overall goal of this dissertation research is to design, synthesize, and study new Pt(II) and Re(I) complexes relevant to biomedical applications. One of the projects involves the assessment of the interactions of bulky tridentate carrier ligands with a bound guanine nucleobase derivative (G) in platinum complexes, with a goal of developing chemistry potentially relevant to active anti-cancer Pt drugs. In another project, the fac-[Re^I(CO)₃]⁺ core is used to prepare novel Re(I) complexes with the purpose of developing new linking chemistry relevant to ^99mTc and ¹⁸⁷Re radiopharmaceuticals. This research explores …

A Coupled Thermo-Mechanical Theory Of Strain Gradient Plasticity For Small And Finite Deformations, Yooseob Song

LSU Doctoral Dissertations

In this work, a thermodynamically consistent coupled thermo-mechanical gradient enhanced continuum plasticity theory is developed for small and finite deformations. The proposed model is conceptually based on the dislocations interaction mechanisms and thermal activation energy. The thermodynamic conjugate microstresses are decomposed into energetic and dissipative components. This work incorporates the thermal and mechanical responses of microsystems. It addresses phenomena such as size and boundary effects and in particular microscale heat transfer in fast-transient processes. Not only the partial heat dissipation caused by the fast transient time, but also the distribution of temperature caused by the transition from the plastic work …

Spectra Of Quantum Trees And Orthogonal Polynomials, Zhaoxia Wang

LSU Doctoral Dissertations

We investigate the spectrum of regular quantum-graph trees, where the edges are endowed with a Schr\"odinger operator with self-adjoint Robin vertex conditions. It is known that, for large eigenvalues, the Robin spectrum approaches the Neumann spectrum. In this research, we compute the lower Robin spectrum. The spectrum can be obtained from the roots of a sequence of orthogonal polynomials involving two variables. As the length of the quantum tree increases, the spectrum approaches a band-gap structure. We find that the lowest band tends to minus infinity as the Robin parameter increases, whereas the rest of the bands remain positive. Unexpectedly, …

Madden-Julian Oscillation Relationships With Cool Season Cyclogenesis, Daily Precipitation, And Cool Season Severe Weather Frequencies In The Gulf Of Mexico Region, Stephen Paul Caparotta

LSU Doctoral Dissertations

Tropical cyclone variability in the Gulf of Mexico (GoM) has been the focus of a considerable amount of research. Variability on both interannual scales, related to the El Niño-Southern Oscillation (ENSO), and on subseasonal scales, related to the Madden-Julian Oscillation (MJO), is well documented. By contrast, very little research exists on the relationships between the MJO and cool season, non-tropical cyclones in the GoM.

The MJO influence on cool season (October-March) cyclogenesis in the GoM variability is explored here. Additionally, daily precipitation variability and cool season severe weather variability is examined for areas near and just inland of the GoM. …

Free-Radical Polymerization Of Acid-Containing Deep Eutectic Solvents, Kylee Fazende

LSU Doctoral Dissertations

The forefront of this study explored polymerization, specifically thermally-initiated, free-radical frontal polymerization of (meth)acrylic acid monomers while the monomers acted as a hydrogen bond donor of a deep eutectic solvent. These frontal polymerizations were shown to exhibit unusual front velocities and, in some cases, lower front temperatures than the frontal polymerization of the neat monomers or systems containing inert analogs in the place of the hydrogen bond acceptor of these monomer-containing deep eutectic solvents. The frontal polymerization will occur with a range of initiator concentrations including ones that were too low for the pure monomer systems to sustain a front. …

Accelerated Broadband Spectra And Attosecond Charge Migration Simulations Using Real-Time Time-Dependent Density Functional Theory, Adam S. Bruner

LSU Doctoral Dissertations

In this dissertation, the calculations of light-matter interactions offer insight into the structure and dynamical response of electrons in molecular systems. Such information is useful for characterizing molecules, electronic structure, photochemistry, photomaterials, and a host of other applications. In the first part of this work, simulations of broadband absorption spectra are accelerated by the use of Pad´e approximanants of Fourier Transforms and dipole decomposition. Electronic absorption spectra from valence and core levels are obtained using time-dependent methods and compared to results from established perturbative techniques. In addition, core level absorption spectra are calculated for a nickel porphyrin and shown to …