Digital Commons Network^™

New Applications Of Mass Spectrometry For Drug And Lipid Analysis, Elizabeth Lauren Emerson

Graduate Theses and Dissertations

Mass spectrometry is an important tool used in many different disciplines and settings that include forensics, drug discovery, environmental analysis, and proteomics. Gas chromatography - mass spectrometry (GC-MS) and matrix assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI - TOF MS) are two of the most important instruments used for analysis of compounds. Chapters 1 and 2 of this discussion use GC-MS for the investigation of synthetic cannabinoids in `K2' incense products and the detection of metabolites in urine samples from individuals suspected of consuming these mixtures. Analytical standards were synthesized and used for identification and confirmation of structures. Detection of …

Refractive Index Chemical Sensing With Noble Metal Nanoparticles, Phillip Blake

Graduate Theses and Dissertations

Chemical sensing is a key component in modern society, especially in engineering applications. Because of their widespread impact, improvements to chemical sensors are a significant area of research. One class of sensors, plasmonic sensors, is being heavily researched because of their ability to detect low levels of analyte in near real time without destroying the analyte. This work studies a new class of plasmonic sensor that utilizes diffractive coupling to improve sensor performance. Specifically, this work outlines the first study of diffractive coupling sensors with typical nanoparticle shapes. Sensitivity of this new class of sensor is directly compared to typical …

The Lived Experience Of The Parents Of High School Dropouts: A Phenomenological Study, Christine Ann Silano

Graduate Theses and Dissertations

The purpose of this study is to describe the experiences and perceptions of parents whose children did not receive a high school diploma. This subpopulation has been rarely studied. The central question is, "What are the perceptions and experiences of the parents of public high school dropouts as they pertain to schools, their children, and themselves?"

This phenomenological study examined the lived experience of the parents of high school dropouts. Five women and one man participated in the study by sitting for interviews. The collected interview data was transcribed and analyzed using qualitative methodology including open and axial coding as …

Long-Term Effects Of Rice Rotation, Tillage, And Fertility On Near-Surface Soil Carbon And Nitrogen Cycling, Jill Marie Motschenbacher

Graduate Theses and Dissertations

Rice (Oryza sativa L.)-based cropping systems are different from other row crops due to the flood-irrigation scheme used from about one month after planting to a few weeks prior to harvest. The frequent cycling between anaerobic (i.e., flooding during the growing season) and aerobic (i.e., generally, the remainder of the year) conditions can influence the rate of soil organic matter (SOM) decomposition, which can greatly influence carbon (C) and nitrogen (N) storage and sequestration in the soil over time. Therefore, a study was conducted on a silt-loam soil (fine, smectitic, thermic, Typic Albaqualf) at the Rice Research and Extension Center …

Taxonomy And Dna Barcoding In The Genus Manfreda (Salisb.) Asparagaceae, William David Ritchie

Graduate Theses and Dissertations

The genus Manfreda Salisb. of Asparagaceae is a genus of potential horticultural interest and is currently subject to breeding efforts at the University of Arkansas. A lack of taxonomic clarity however undermines the classification of potential inter - and intrageneric hybrids. The study aims to assess existing species delimitation within the genus Manfreda employing morphology while investigating the potential utility of Consortium for the Barcode of Life Plant (CBOL) DNA Barcodes for identification of specific taxa and an External Transcribed Spacer (ETS) - Internal Transcribed Spacer (ITS) DNA barcode for developed hybridized taxa.

Observation of 855 herbarium specimens facilitated phylogenetic …

Design Of A Pretreatment And Enzymatic Saccharification Scheme Of Understory From Managed Pine Forest For A Biochemical-Refinery Platform: The Example Of The Sweetgum Tree, Angele Djioleu

Graduate Theses and Dissertations

The possibility of using sweetgum from southern pine dominated forests as a biobased refinery feedstock was investigated. First, a baseline hydrolysis scheme for sweetgum wood and bark was designed. Sweetgum wood and bark were pretreated with 0.98% (v/v) sulfuric acid at 140°C for 30, 40, 50, 60 or 70 min and at 160°C for 30, 40, 50 or 60 min. The water insoluble solid (WIS) fraction was hydrolyzed with a cellulase enzyme cocktail. Results showed that maximum xylose and glucose yields from the wood were 82 and 86%, respectively. Similarly, the respective maximum yields of xylose and glucose from the …

A Watershed Scale Evaluation Of Selected Second Generation Biofeedstocks On Water Quality, Gurdeep Singh

Graduate Theses and Dissertations

This study compares a novel simulation approach to the conventional Soil and Water Assessment Tool (SWAT) modeler's approach for targeting biofuel crop production on marginal lands. In conventional SWAT modeling approach, non-spatial definition of hydrological response units (HRUs) results in the simulation of biofuel crops on both marginal and non-marginal land. This study provides an alternative approach in which a marginal-land raster was integrated into the land use and land cover (LULC) raster in such a way that the land uses were divided into marginal and non-marginal components. This modified LULC was used for model setup which resulted in marginal …

Evaluation Of The Effects Of Absorption Field Product Architecture Type On Effluent Dispersal And Soil Chemical Properties In A Profile-Limited Soil, Nina J.M. Prater

Graduate Theses and Dissertations

On-site wastewater treatment systems (OWTSs) are commonly used by households in areas of low population density to treat household wastewater and recycle it back to the environment. The traditional absorption field product used in OWTSs is a pipe-and-gravel architecture type, which has been used for decades and is the basis for most design regulations. However, new products of differing architecture types including chambers, polystyrene-aggregate, pipe-and-tire-chip, and gravel-less-pipe systems have recently become available. A three-year field study was conducted in Bethel Heights, AR to assess the performance of several newer products and to compare different architecture types to the traditional pipe-and-gravel …

Plasmonic And Photonic Designs For Light Trapping In Thin Film Solar Cells, Liming Ji

Graduate Theses and Dissertations

Thin film solar cells are promising to realize cheap solar energy. Compared to conventional wafer cells, they can reduce the use of semiconductor material by 90%. The efficiency of thin film solar cells, however, is limited due to insufficient light absorption. Sufficient light absorption at the bandgap of semiconductor requires a light path more than 10x the thickness of the semiconductor. Advanced designs for light trapping are necessary for solar cells to absorb sufficient light within a limited volume of semiconductor. The goal is to convert the incident light into a trapped mode in the semiconductor layer.

In this dissertation, …

Assessing The Impacts Of Surface Water Removal For Use In Natural Gas Extraction On A Watershed Level, Carrie Ann Davis

Graduate Theses and Dissertations

In this study, the Soil and Water Assessment Test (SWAT) was used as a tool to predict whether diffuse water removal from the Cadron Creek watershed for use with natural gas development would have an impact on downstream flow within the watershed. Cadron Creek watershed expands across four counties within Arkansas and is located in the Fayetteville Shale Gas region. This region is experiencing significant growth in natural gas development. Successful development of shale gas depends on the identification of what water supplies are available for production without interfering with community and environmental needs. The SWAT model used to evaluate …

Inquiry-Based Instruction In The Social Studies: Successes And Challenges, Crystal Maree Beshears

Graduate Theses and Dissertations

The purpose of this study was to investigate teachers' perceptions, understanding, and use of inquiry-based instruction in the Social studies, to assess the impact of inquiry-based units on instruction, to detail implementation successes and challenges reported by teachers when implementing inquiry-based instruction, and to provide recommendations for future efforts. Teachers' perceptions of teaching and learning, particularly their beliefs about inquiry-based instruction, changed during the study. Throughout the study, teachers' perceptions and beliefs about teaching Social studies had an impact on how they planned, implemented and reflected on inquiry-based instruction. Many of the teachers changed their perceptions and began regularly teaching …

Topics On Light-Emitting-Diode Driver Research, Jaber Hasan

Graduate Theses and Dissertations

In this dissertation, light-emitting-diode (LED) drivers are investigated for efficiency issues related to driving Red-Green-Blue (RGB) pixels and multiple LED strings in parallel. A high-efficiency digitally controlled RGB LED driver was designed for driving a 3x3 RGB LED display panel. A multiplexer was used to sense the voltage drop across the current controllers. This driver maintained a minimum drive voltage across the RGB LED pixels required to keep it in regulation leading to a reduction of unwanted power losses in the RGB LED pixels by selecting the minimum drop across the current-controllers as the reference voltage of the digital controller. …

Perceptions Of A Middle School Reconfiguration: A Descriptive Case Study, Karen Billingsley Lasker

Graduate Theses and Dissertations

The purpose of this qualitative research study was to follow 1 principal's journey to assist the district in its reconfiguration goals, and help the school change through deep examination of district personnel's and parents' perceptions of the change process. This was done by acknowledging distinctions and differences between junior high schools, the current middle school, and the new middle school, delineated by current middle school-reform research. This study explored issues regarding the policies, personnel, decision-making strategies, timelines, and organizational structures of the new middle school.

The reconfiguration resulted in rezoning attendance zones, reconstructing the new high school, raising the new …

Exploring The Surface Liquid And Lake Regions Of Titan With Laboratory Experimentation And Cassini Spacecraft Data, Felix Casimir Wasiak

Graduate Theses and Dissertations

The surface liquids and lake regions of Titan are studied utilizing three unique techniques, the results of which are reported in this dissertation. The development of a facility to simulate the surface conditions of Titan, and to conduct experiments on samples within that facility, brings an understanding of Titan's surface not possible through observation and modeling alone. The properties of this facility are presented, including conceptual methodology, design, implementation, performance, and experimental results. The facility, the main component of which is a simulation chamber, allows for Titan temperatures of 90 - 94 K and a 1.5 bar N2 atmosphere. The …

Trait Differences In Gender In Technology Use And Study Habits Of Rural Community College Students, Phillip Marc Wilson

Graduate Theses and Dissertations

The purpose for conducting the study was to explore the trait differences by gender of the study habits and technology use patterns of rural community college students. Significant research and data presently exists at the university level specific to study habits and technology use, but little research had been conducted targeting those topics in a rural community college setting.

The following questions guided the research:

1. What were the study habits of rural community college students?

2. How did rural community college students use technology?

3. Were there significant differences, by gender, in the study habits of rural community college …

Penetration Forces For Subsurface Regolith Probes, Ahmed Elshafie

Graduate Theses and Dissertations

Investigating planetary bodies using penetrometers can provide detailed information about its history and evolution. An estimation of subsurface density and porosity can be made from the shape of the penetration curve. Using penetrometers mounted on planetary platforms could be challenging due to the uncertainty of the subsurface composition and since the maximum allowed force for penetration is the weight of the lander or rover on the surface. Estimation of penetration forces can provide a reliable constraint on the maximum reachable depth without endangering the whole mission. Therefore, knowledge of the required penetration force to specific depths can be helpful in …

Predictors Of Academic Success For The National Board Dental Hygiene Examination And The Southern Regional Testing Agency Clinical Exam, Melissa Gail Efurd

Graduate Theses and Dissertations

The purpose for conducting this study was to investigate and describe the relationship between applicant criteria for a dental hygiene program and subsequent outcomes on credentialing exams: the National Board Dental Hygiene Exam and the Southern Regional Testing Agency clinical exam. Because admission criteria play a crucial role in applicant selection, choosing students, that will successfully complete the program as well as the necessary credentialing exams, is a particularly crucial task for admission committees. The study had three elements. First, it investigated the relationship between the variables of age, undergraduate GPA and scores from the Psychological Services Bureau Health Occupations …

Effects Of Felled Shortleaf Pine (Pinus Echinata Mill.) Moisture Loss On Oviposition Preferences And Survival Of Sirex Nigricornis F. (Hymenoptera: Siricidae), Jessica Hartshorn

Graduate Theses and Dissertations

The European woodwasp, Sirex noctilio F. (Hymenoptera: Siricidae) utilizes pine as its host during larval development. Females drill through pine bark to deposit eggs, a symbiotic fungus, Amylostereum, and phytotoxic mucus into the tree. In their native range, these insects are not viewed as primary pests because they attack dead or dying trees. Over the last century, this woodwasp has been accidentally introduced into several countries in the southern hemisphere. Some regions have incurred millions of dollars in damage to large plantations of the widely planted pine species, radiata pine (Pinus radiata D. Don). Sirex noctilio was discovered …

Diagenesis And Reservoir Characterization Of The Pennsylvanian Middle Atoka Formation, Sebastian And Logan Counties, West-Central Arkansas, Elvis Chekwube Bello

Graduate Theses and Dissertations

The Middle Atoka Formation evolved from a stable passive margin during the early Pennsylvanian time to a rapidly subsiding basin, with the sedimentary fill thickening greatly southward during the middle Pennsylvanian time. The basin dips in north-south direction. An east-west anticlines and synclines were observed.

The purpose of this study is to establish the stratigraphic units, reservoir geometry and distribution, and infer the depositional environments and reservoir quality. Well correlation and petrographic studies are used to achieve the goals.

Sandstone Point Count method was used. The Point Counts was divided into five categories. They include the framework grains (quartz, feldspar, …

Modeling, Fabrication And Characterization Of Scalable Electroless Gold Plated Nanostructures For Enhanced Surface Plasmon Resonance, Gyoung Gug Jang

Graduate Theses and Dissertations

The scientific and industrial demand for controllable thin gold (Au) film and Au nanostructures is increasing in many fields including opto-electronics, photovoltaics, MEMS devices, diagnostics, bio-molecular sensors, spectro-/microscopic surfaces and probes. In this study, a novel continuous flow electroless (CF-EL) Au plating method is developed to fabricate uniform Au thin films in ambient condition. The enhanced local mass transfer rate and continuous deposition resulting from CF-EL plating improved physical uniformity of deposited Au films and thermally transformed nanoparticles (NPs). Au films and NPs exhibited improved optical photoluminescence (PL) and surface plasmon resonance (SPR), respectively, relative to batch immersion EL (BI-EL) …

Risk Analysis And Reliability Improvement Of Mechanistic-Empirical Pavement Design, Xingqiang Danny Xiao

Graduate Theses and Dissertations

Reliability used in the Mechanistic Empirical Pavement Design Guide (MEPDG) is a congregated indicator defined as the probability that each of the key distress types and smoothness will be less than a selected critical level over the design period. For such a complex system as the MEPDG which does not have closed-form design equations, classic reliability methods are not applicable. A robust reliability analysis can rely on Monte Carlo Simulation (MCS). The ultimate goal of this study was to improve the reliability model of the MEPDG using surrogate modeling techniques and Monte Carlo simulation.

To achieve this goal, four tasks …

Effects Of Testing Time On Anaerobic Toxicity Assessment, Omolola Atinuke Akintomide

Graduate Theses and Dissertations

Anaerobic digestion has been widely used for wastewater treatment for decades. Several Anaerobic Toxicity tests have been developed to screen wastewater for toxicity and assess the treatability of such toxicants. However, past research and reviews on Biochemical Methane Potential (BMP) test and Anaerobic Toxicity Assay (ATA) were considered in this study.

The experimental tests included ammonium-nitrogen and sodium chloride toxicity tests with varied concentration and solid retention time. These tests were designed to demonstrate the impact of ammonia- nitrogen and sodium chloride on the biological degradation process. The anaerobic test set-up includes bench-scale test reactors and respirometers used for measuring …

Magnitude And Frequency Of Floods For Rural, Unregulated Streams Of Tennessee By L-Moments Method, Hongxiang Yan

Graduate Theses and Dissertations

This study presents a regional frequency analysis of Tennessee using the well-known Bulletin-17B method standardly used in the United States and the relatively new and developing L-Moments methods. Flood frequency characteristics were defined for 416 gaging stations located primarily in rural and lightly developed areas of Tennessee. All the gaging stations have 10 or more years of record through 2006. Using the L-Moments method, the generalized extreme value distribution was identified as the most robust distribution for each of four hydrologic areas. Multiple regression equations were also calculated for estimating the flood frequency of ungaged, unregulated, rural streams in each …

The Development Of A High Performance Concrete To Store Thermal Energy For Concentrating Solar Power Plants, Emerson Esmond John

Graduate Theses and Dissertations

In recent years, due to rising energy costs as well as an increased awareness of the environmental effects of greenhouse gas emissions produced through traditional forms of energy production, there is great interest in developing alternative sources of energy. One of the most viable alternative energy sources is solar energy. In particular, concentrating solar power (CSP) technologies have been identified as an option for meeting utility needs in the U.S. Southwest. These systems are required to produce electricity not only during periods of high solar radiation but also during times of reduced radiation due to cloud cover, and even extend …

Improved Protocols For Automated Wheelpath Crack Detection In Pavements, Daniel Patrick Byram

Graduate Theses and Dissertations

Roadway pavement distress evaluations are vital to understanding the mechanics of pavement stability, determining the distribution of rehabilitation costs, and knowing the appropriate rehabilitation strategies. Advancements in technology over the past two decades have changed the way these surveys have been performed by means of automated data collection and interpretation. More and more state agencies have invested in automated road analyzing vehicles that are able to collect high resolution images of the pavement. Fewer have adopted automated data processing software with the ability to interpret road distresses due to the common discrepancies in distress classification algorithms.

In addition to automated …

Investing In An Agricultural Legacy, Leo Paul Goeringer

Graduate Theses and Dissertations

America's agricultural producers continue to age. According to the U.S. Census of Agriculture, the average age of farm operators increased from 55.3 in 2002 to 57.1 in 2007. During the same period, the Census shows a thirty percent decrease in the number of farmers under age 25. Young and beginning producers (YBPs) entering agriculture face high startup costs and a shortage of land to own or rent.

With these concerns in mind, this manuscript details the impact of an innovative proposed loan program for YBPs in Arkansas, which would offer concessionary interest rates and loan fees by participating banks for …

Locating And Protecting Facilities Subject To Random Disruptions And Attacks, Hugh Medal

Graduate Theses and Dissertations

Recent events such as the 2011 Tohoku earthquake and tsunami in Japan have revealed the vulnerability of networks such as supply chains to disruptive events. In particular, it has become apparent that the failure of a few elements of an infrastructure system can cause a system-wide disruption. Thus, it is important to learn more about which elements of infrastructure systems are most critical and how to protect an infrastructure system from the effects of a disruption. This dissertation seeks to enhance the understanding of how to design and protect networked infrastructure systems from disruptions by developing new mathematical models and …

Optimization Models And Algorithms For Truckload Relay Network Design, Hector Andres Vergara Arteaga

Graduate Theses and Dissertations

Driver turnover is a significant problem for full truckload (TL) carriers that operate using point-to-point (PtP) dispatching. The low quality of life of drivers due to the long periods of time they spend away from home is usually identified as one of the main reasons for the high turnover. In contrast, driver turnover is not as significant for less-than-truckload (LTL) carriers that use hub-and-spoke transportation networks which allow drivers to return home more frequently. Based on the differences between TL and LTL, the use of a relay network (RN) has been proposed as an alternative dispatching method for TL transportation …

What Factors Influence Consumers' Willingness To Purchase And Consume Carbon-Labeled Rice: A Comparative Study Between Arkansas And Belgium, John A. Kelley

Graduate Theses and Dissertations

Climate change is an issue of growing importance around the globe. As global population increases so does attention focused on human contributions to climate change. One major way humans contribute to climate change is through our diets. Agricultural production is a major source of global greenhouse emissions. It has been estimated that food production is responsible for a large majority of the methane and nitrous oxide which is emitted into our atmosphere each year. Carbon footprint labeling has been developed to give consumers a way to lower their footprint and help lower emissions of greenhouse gasses. At least one retailer, …

A Cpfr Readiness Assessment Model, Tanvir Humayun Sattar

Graduate Theses and Dissertations

The retail industry is a pioneer in developing new supply chain practices arising from the fact that the environment is characterized by intense competition and the need to achieve supply chain cost savings. An initiative launched by the Voluntary Interindustry Commerce and Standards Committee (VICS) introduced a concept known as the Collaborative Planning, Forecasting and Replenishment (CPFR). The objective is to integrate business and supply chain processes and provide better visibility and create and effective supply chains. This research develops a CPFR Readiness Assessment Model, which enables organizations to understand their readiness in implementing CPFR. This model can provide an …