Digital Commons Network^™

Exploring Thermoresponsive Affinity Agents To Enhance Microdialysis Sampling Efficiency Of Proteins, Thaddeus Vasicek

Graduate Theses and Dissertations

Affinity agents increase microdialysis protein relative recovery, yet they have not seen widespread use within the microdialysis community due to their additional instrumentation requirements and prohibitive cost. This dissertation describes new affinity agents for microdialysis that require no additional instrumentation to use, have nearly 100% particle recovery, are 7 times more cost efficient than alternatives, and have low specificity enabling their use for a wide variety of proteins. Initially gold nanoparticles were chosen as an affinity ligand support due to their high surface area/volume ratio and colloidal stability. Poly (N-isopropylacrylamide) was immobilized to the gold nanoparticles, which served to sterically …

Use Of The Silver-Level Arkansas Career Readiness Certificate As A Pre-Hire Screening Tool, Bentley E. Wallace

Graduate Theses and Dissertations

At a statewide level in Arkansas, the Arkansas Career Readiness Certificate (ACRC) is marketed as a means for assessing and exhibiting individual worker skill levels and as an additional aggregate credential to be presented alongside high school and college degree attainment levels. Employers from multiple sectors use the ACRC as a pre-hire screening tool and to determine incumbent worker eligibility for advancement.

Despite having been in place in the state for nearly a decade with over 65,000 Arkansans earning an ACRC, prior to this study no research had been conducted to determine the effectiveness of the ACRC as a pre-hire …

Using Cross-Sets For Paleodischarge Estimation And Paleocurrent Vectors In The Parthenon Sandstone, Northwest Arkansas, Sean Robert Parry

Graduate Theses and Dissertations

In this thesis, set thicknesses are used to estimate the paleohydraulics (paleodischarge and give magnitudes for paleocurrent directions) of the ancient river system which deposited the Parthenon Sandstone in northwest Arkansas. Set thickness is the vertical thickness of a group of strata conformable series (Mckee and Weir, 1953); set thickness represents truncated dunes. The goal of this thesis is to: 1) obtain paleodischarge estimates of the Parthenon sandstone via cross-sets and compare the results with previously calculated discharge estimates which use basin area to discharge collation techniques and 2) use paleodischarge estimates calculated within this thesis to give magnitude to …

Soil Moduli Obtained From A Back Pressure Constant Rate Of Strain Bender Element Consolidation Apparatus, Yi Zhao

Graduate Theses and Dissertations

A back-pressure saturated, constant-rate-of-strain consolidation device was modified to incorporate bender elements (BP-CRS-BE) and thus allowed for shear wave measurements during consolidation tests. This newly fabricated system has many advantages over other previous or current devices: 1) it can be utilized not only for laboratory prepared soil samples but also for field sampled soils such as Shelby tube samples, and 2) continuous compression curves, and continuous values of vertical hydraulic conductivity and coefficient of consolidation can be acquired with a significant reduction in testing time. Soil modulus values such as shear modulus and constrained modulus are also able to be …

Willingness To Pay For Irrigation Water Under Scarcity Conditions, Tyler Robert Knapp

Graduate Theses and Dissertations

Reliance of Arkansas agricultural producers on groundwater for irrigation has led to depletion of the Mississippi River Valley alluvial aquifer. Without intervention, consequences include insufficient groundwater to meet irrigation demand as well as drawdown of the deeper Sparta Aquifer, upon which communities in eastern Arkansas rely for non-agricultural use. Among proposed solutions to combat groundwater decline is the construction of off-farm surface water infrastructure to meet the irrigation needs of producers. Despite the importance of irrigated agriculture to Arkansas, there is little know about the economic value of irrigation water to producers. Thus, we implement a double-bounded dichotomous choice contingent …

Grouping Techniques To Manage Large-Scale Multi-Item Multi-Echelon Inventory Systems, Anvar Abaydulla

Graduate Theses and Dissertations

Large retail companies operate large-scale systems which may consist of thousands of stores. These retail stores and their suppliers, such as warehouses and manufacturers, form a large-scale multi-item multi-echelon inventory supply network. Operations of this kind of inventory system require a large number of human resources, computing capacity, etc.

In this research, three kinds of grouping techniques are investigated to make the large-scale inventory system “easier” to manage. The first grouping technique is a network based ABC classification method. A new classification criterion is developed so that the inventory network characteristics are included in the classification process, and this criterion …

Development Of A Pluto Chamber For Surface Simulations, Zachary Michael Mcmahon

Graduate Theses and Dissertations

In light of the exciting new discoveries being made by the New Horizons team, more data on Pluto is available than ever before. However, with the increase in recovered data, there is now a need for laboratory data to interpret it. Laboratory simulation of these conditions and subsequent testing of materials and samples therein is now possible and necessary to understand what has been observed. To do these simulations, a vessel that can achieve low temperatures and high vacuum is required. The scope of this work presented here was to design, build, and test a chamber that could perform these …

Stratigraphy And Depositional Environment Of The Middle Atoka Formation, Central Arkoma Basin, Western Arkansas, Yueyang Wang

Graduate Theses and Dissertations

Wire line logs are widely used in analysis of the subsurface stratigraphy of the middle Atoka Formation, Central Arkoma Basin, Western Arkansas. SP log, Gamma ray log, resistivity log and conductivity log provide valuable information to construct cross sections.

The middle Atoka formation is composed of a succession of shale and sandstone alternations with thickness reaching approximately 3000 feet in the study area. It contains several sandstone units which include Morris, Tackett, Areci, Bynum, Casey and Dunn”A” separated by shale intervals. The purpose of this study is to identify these units and predict sequence stratigraphy and depositional environment by constructing …

Temporal Co2 Variations And The Influence Of Bat Colonies In Speleogenesis: Continuous Co2 Monitoring In War Eagle Cavern, Arkansas, Ginny Sue Holcomb

Graduate Theses and Dissertations

Dissolved concentrations of CO2 in a karst aquifer are a major control on calcite dissolutional processes, as CO2 combines chemically with water to form carbonic acid. As increasing amounts of CO2 are added to the system, greater resultant water aggressivity generates greater rates of dissolution. Spatial and temporal variations in carbon flux through the system may occur over a range of time scales, and high-resolution data collection is needed to truly understand and characterize such variability. Continuous CO2 monitoring in War Eagle Cavern, Arkansas, will suggest a number of influential parameters with varying degrees of importance throughout an annual cycle. …

Role Of The Inner Shell Architecture On The Various Blinking States And Decay Dynamics Of Core-Shell And Core-Multishell Quantum Dots, Pooja Bajwa

Graduate Theses and Dissertations

Colloidal semiconductor nanocrystals (quantum dots, QDs) have received much attention in recent years due to their uniquely size-tunable properties leading to a number of promising applications. Some of their most popular applications include their use as fluorescent probes in biology, as electro-optical components and in photovoltaic devices. CdSe-based QDs are particularly important because of their ease of synthesis, high photoluminescence quantum yields (PL QYs) across the whole visible spectrum and their photostabilty. Shelling of core QDs is usually carried out to improve their optical properties, minimize outer environmental effects on their properties, and avoid toxic element exposure to the environment. …

An Analysis Of Secondary Integrated Stem Lesson Plans: Common Characteristics, Learning Expectations And The Impact From The Teacher's Definition Of I-Stem, Jacob Hayward

Graduate Theses and Dissertations

This qualitative study investigated teachers’ understanding of their definition of I-STEM (Integrated STEM education), how those understandings manifested into lessons and associated lesson artifacts, how they assessed students in such lessons, and what factors or rationales supported their ability to conduct or not conduct I-STEM lessons. A survey was sent to the members of four professional organizations representing I-STEM disciplines to solicit their participation in this project. Ten teachers ranging from grades 9-12 participated in this study. Of those who responded, six teachers identified with National Science Teachers Association (NSTA), three teachers selected International Technology and Engineering Education Association (ITEEA), …

Fabrication Of Infrared Photodetectors Utilizing Lead Selenide Nanocrystals, Justin Anthony Hill

Graduate Theses and Dissertations

Colloidal lead selenide and lead selenide / lead sulfide core/shell nanocrystals were grown using a wet chemical synthesis procedure. Absorbance and photoluminescence measurements were made to verify the quality of the produced nanocrystals. Absorbance spectra were measured at room temperature, while photoluminescence spectra were measured at 77 K. Organic ligands were exchanged for shorter ligands in order to increase the conductivity of the nanocrystals. Absorption and PL spectra for both core and core/shell nanocrystals were compared. Interdigital photodetector devices with varying channel widths were fabricated by depositing gold onto a glass substrate. Lead selenide nanocrystals were deposited onto these metallic …

Discord And Global Discord In Systems Of Coupled Quantum Dots In Driven Cavities With Dissipation, And A Method For The Calculation Of Global Discord, Willa Danielle Rawlinson

Graduate Theses and Dissertations

In the field of quantum information, which is subdivided into quantum computing and quantum cryptography, quantum correlations are essential for a performance or security boost not achievable with classical means. Various quantum correlation measures exist for evaluating a state’s potential to be a qubit (quantum bit). Entanglement, or nonseparability of quantum states, is the older, better known class of measures. However, for a mixed state, quantum entanglement is an incomplete measure of quantumness. Quantum discord, and its multibody extension global discord, encompass all quantum correlations. We study systems of coupled quantum dots using these measures.

We study the discord of …

"That's Empowering!": The Influence Of Community Activism Curriculum On Gifted Adolescents' Self-Concepts, Ashley D. Beason-Manes

Graduate Theses and Dissertations

The first of the following manuscripts addresses the experiences of a group of gifted middle school students as they engaged in community action projects that provided them opportunity to become activists in their school, neighborhood, and larger community. This study pays special attention to participants’ self-concepts as measured by the Harter Self-Perception Profile for Children (2012) and through participant interviews. The study finds evidence of students’ co-cognitive components of giftedness when themes of courage, sensitivity to human concerns, and sense of destiny are applied. Main themes from Harter’s scale are also applied, and participant interviews reveal evidence of academic and …

A Gis Approach To Modeling Groundwater Levels In The Mississippi River Valley Alluvial Aquifer, Josef Orion Lilly

Graduate Theses and Dissertations

Groundwater depletion, a subject of growing concern for a significant portion of Arkansas, may lead to future economic challenges for the Arkansas Delta region. The Mississippi River Valley Alluvial Aquifer is the uppermost aquifer and features the largest groundwater capacity in the Mississippi Embayment Aquifer System. The Mississippi River Valley Alluvial Aquifer, commonly referred to as the “alluvial aquifer”, spans 53,000〖 km〗^2 underlying portions of Arkansas, Kentucky, Louisiana, Mississippi, Missouri, Illinois, and Tennessee. As the alluvial aquifer trends southward for approximately 250 miles alongside the Mississippi River, its geographical extent ranges from 50 to 125 miles wide. There is a …

Investigation Of The Optical Properties Of Pbse/Pbx Nanocrystals For Photodetector Applications, Haley Ann Morris

Graduate Theses and Dissertations

Lead selenide and lead selenide/lead sulfide core/shell nanocrystals were investigated for use in near infrared photodetectors. A colloidal synthesis method was used for both the core and core/shell configurations. The lead sulfide shell was examined in order to mitigate oxidation of the nanoparticle surface. Absorbance and photoluminescence spectra were measured at room temperature and 77 K, respectively. Transmission electron microscopy images were also obtained to confirm crystallography and size. Bulk lead selenide was simulated in WIEN2k utilizing the linear-augmented plane wave method of solving density functional theory to better understand the electronic structure of PbSe. The crystal structure, electron density, …

How Select Groups Of Preservice Science Teachers With Inquiry Orientations View Teaching And Learning Science Through Inquiry, Peggy Diana Ward

Graduate Theses and Dissertations

Although hailed as a powerful form of instruction, in most teaching and learning contexts, inquiry-based instruction is fraught with ambiguous and conflicting definitions and descriptions. Yet little has been written about the experiences preservice science teacher have regarding their learning to teach science through inquiry. This project sought to understand how select preservice secondary science teachers enrolled in three UTeach programs in Arkansas conceptualize inquiry instruction and how they rationalize its value in a teaching and learning context. The three teacher education programs investigated in this study are adoption sites aligned with the UTeach Program in Austin, TX that distinguishes …

Bioorthogonal Reactions: Synthesis And Evaluation Of Different Ligands In Copper Catalyzed Azide-Alkyne1,3-Dipolar Cycloaddition (Cuaac), Zainab Abdullah Almansaf

Graduate Theses and Dissertations

The Copper CatalyzedAzide-Alkyne1,3-Dipolar Cycloaddition (CuAAC) reaction has unique features that qualify it to be one of the best click reactions. Its applications have been shown in different aspects and for multiple purposes. The oxidative degradation of biological systems (labile proteins and live cells) is, however, generally recognized as the major problem when using this reaction in living systems. Reactive oxidation species can be easily produced in the presence of copper(II), ascorbate and air, and this is the main cause of toxicity. However, the uses of ligands have shown a major impact on reducing copper toxicity, protecting Cu(I) from the redox …

Liming Characteristics Of A High-Calcium, Dry Flue Gas Desulfurization By-Product And Its Effects On Runoff Water Quality, Jason Richard Burgess-Conforti

Graduate Theses and Dissertations

In 2013, only 37% of the 32 million Mg of flue gas desulfurization (FGD) by-products generated in the United States were reused beneficially. If FGD by-products could be used as a beneficial soil amendment, millions of megagrams may be diverted away from surface impoundments and landfills. The purpose of this research was to identify the liming characteristics of a high-Ca dry FGD (DFGD) by-product in comparison to a Class-C fly ash (FA) and reagent-grade CaCO3, and to evaluate the effects of land application to a managed grassland on runoff, plant, and soil quality. Liming characteristics were determined by measuring the …

Direct Attachment Of 4-Hydroxybenzoic Acid Polymers And Capture Agents To Flat Sheet And Microdialysis Membranes For Improved Mass Transport, Sarah Jane Phillips

Graduate Theses and Dissertations

Microdialysis (MD) sampling is a diffusion-based separation method which has the ability to sample any analyte that can diffuse across the semi-permeable membrane. However one challenge for MD is that for soluble proteins greater than 10 kDa, the relative recovery (RR) using a 100 kDa MD probe is between 1-5%.1 There are two major barriers that lead to these low recovery values - nonspecific adsorption (NSA) and poor solute mass transport. To overcome these two barriers, the modification of PES-based MD membranes has been initiated by laccase. Previous researchers have used laccase to modify PES flat sheet and hollow fiber …

Synthesis, Characterization, And Fabrication Of All Inorganic Quantum Dot Leds, Haider Baqer Salman

Graduate Theses and Dissertations

Quantum Dot LEDs with all inorganic materials are investigated in this thesis. The research was motivated by the potential disruptive technology of core shell quantum dots in lighting and display applications. These devices consisted of three main layers: hole transport layer (HTL), electron transport layer (ETL), and emissive layer where the emission of photons occurs. The latter part was formed of CdSe / ZnS core-shell quantum dots, which were synthesized following hot injection method. The ETL and the HTL were formed of zinc oxide nanocrystals and nickel oxide, respectively. Motivated by the low cost synthesis and deposition, NiO and ZnO …

Interactive Physics And Characteristics Of Photons And Photoelectrons In Hyperbranched Zinc Oxide Nanostructures, Garrett Edward Torix

Graduate Theses and Dissertations

As is commonly known, the world is full of technological wonders, where a multitude of electronic devices and instruments continuously help push the boundaries of scientific knowledge and discovery. These new devices and instruments of science must be utilized at peak efficiency in order to benefit humanity with the most advanced scientific knowledge. In order to attain this level of efficiency, the materials which make up these electronics, or possibly more important, the fundamental characteristics of these materials, must be fully understood. The following research attempted to uncover the properties and characteristics of a selected family of materials. Herein, zinc …

Cover Crop Establishment And Potential Benefits To Arkansas Farmers, Ashley Elizabeth Humphreys

Graduate Theses and Dissertations

Soybean farmers in Arkansas need best management practices (BMPs) that maximize the benefits of using cover crops including planting date and fertilization recommendations. An evaluation of cover crop species, planting dates, seeding rates, fertilizer rates, and N accumulation aids in providing these BMPs. The first objective of this research is to assess the effect of planting date on biomass production, as well as looking at the interaction of seeding rate or fertilizer rate for legumes or non-legumes, respectively, using Austrian winter pea (Pisum sativum), cereal rye (Secale cereale), black oats (Avena strigosa), wheat (Triticum aestivum), and tillage radish (Raphanus sativus). …

Optimal Sensing And Transmission In Energy Harvesting Sensor Networks, Xianwen Wu

Graduate Theses and Dissertations

Sensor networks equipped with energy harvesting (EH) devices have attracted great attentions recently. Compared with conventional sensor networks powered by batteries, the energy harvesting abilities of the sensor nodes make sustainable and environment-friendly sensor networks possible. However, the random, scarce and non-uniform energy supply features also necessitate a completely different approach to energy management.

A typical EH wireless sensor node consists of an EH module that converts ambient energy to electrical energy, which is stored in a rechargeable battery, and will be used to power the sensing and transmission operations of the sensor. Therefore, both sensing and transmission are subject …

Gastrointestinal Health As A Stimulus For Native American Attraction To Medicinal Asteraceae And Further Implications For Human Evolution, Christopher David Stiegler

Graduate Theses and Dissertations

The Asteraceae, or the daisy family, is the largest family of flowering plants in the world, and its ethnobotanical, medical, and economic value is readily apparent cross-culturally. The aim of this thesis is to examine why constituent genera of the Aster family have remained such an integral part of human medicinal plant knowledge, and thereby to reveal any potential physiological, biological, or evolutionary mechanisms underlining human patterns of use regarding the Asteraceae. The present study focuses specifically on Native American plant knowledge made available by the expansive database in the works Daniel Moerman (Moerman 2003). Frequencies of plant use and …

Analysis Of Break-Points In Financial Time Series, Jean Remy Habimana

Graduate Theses and Dissertations

A time series is a set of random values collected at equal time intervals; this randomness makes these types of series not easy to predict because the structure of the series may change at any time. As discussed in previous research, the structure of time series may change at any time due to the change in mean and/or variance of the series. Consequently, based on this structure, it is wise not to assume that these series are stationary. This paper, discusses, a method of analyzing time series by considering the entire series non-stationary, assuming there is random change in unconditional …

Twice Heard, Paradoxically (Un)Seen: Walking The Tightrope Of Invisibility In Palestinian Translated Fiction, Mona Nabeel Malkawi

Graduate Theses and Dissertations

This study examines the translators’ invisibility in postcolonial translated Palestinian fiction. On one hand, this analysis revolves around the ethical stance of translators towards authors in a postcolonial theoretical framework. On the other, it brings postcolonial translation scholars’ approaches into practice and examination. Therefore, this study provides a critical analysis of reading novels in translation as both a channel of decolonization from Oriental and imperial discourses and an aesthetic catalyst for freedom in exile, specifically translated by Trevor LeGassick, Elizabeth Fernea, Salma Jayyusi, Adnan Haydar, and Roger Allen. The intriguing paradox of the translator’s invisibility is inherent in the contradiction …

Safety Performance Prediction Of Large-Truck Drivers In The Transportation Industry, Emily Moneka Francis Xavier

Graduate Theses and Dissertations

The trucking industry and truck drivers play a key role in the United States commercial transportation sector. Accidents involving large trucks is one such big event that can cause huge problems to the driver, company, customer and other road users causing property damage and loss of life. The objective of this research is to concentrate on an individual transportation company and use their historical data to build models based on statistical and machine learning methods to predict accidents. The focus is to build models that has high accuracy and correctly predicts an accident. Logistic regression and penalized logistic regression models …

Monte Carlo Methods In Bayesian Inference: Theory, Methods And Applications, Huarui Zhang

Graduate Theses and Dissertations

Monte Carlo methods are becoming more and more popular in statistics due to the fast development of efficient computing technologies. One of the major beneficiaries of this advent is the field of Bayesian inference. The aim of this thesis is two-fold: (i) to explain the theory justifying the validity of the simulation-based schemes in a Bayesian setting (why they should work) and (ii) to apply them in several different types of data analysis that a statistician has to routinely encounter. In Chapter 1, I introduce key concepts in Bayesian statistics. Then we discuss Monte Carlo Simulation methods in detail. Our …

Examining Denitrification In Agricultural Ditch Sediments Vegetated With Rice Cutgrass (Leersia Oryzoides): Modeling Seasonal Variation Across Increasing Levels Of Nitrate Loading And Model Application To Pre-Existing Datasets, Shannon Lee Speir

Graduate Theses and Dissertations

Nitrogen (N) derived from fertilizer application in agricultural systems may contribute to significant environmental impacts, including eutrophication of fresh and coastal waters. Rice cutgrass (Leersia oryzoides) can significantly enhance denitrification potential in agricultural ditch sediments, but relationships with known drivers are not well understood. To address this, I examined effects of nitrate (NO3-) availability on dinitrogen gas (N2) and NO3- fluxes seasonally in Chapter 2. Denitrification rates were measured as N2 flux from intact vegetated sediment cores using Membrane Inlet Mass Spectrometry (MIMS). Michaelis-Menten models were developed from observations to mathematically describe N2 fluxes across the spring, summer, and fall …