Digital Commons Network^™

Comparison Of Flow Dynamics And Bifurcation Angles In Tributary And Distributary Channel Networks, Thomas Coffey

Graduate Theses and Dissertations

The dynamics of channel mouth bifurcations on river deltas can be understood using theory developed in tributary channel networks. Bifurcations in groundwater-fed tributary networks have been shown to evolve dependent on diffusive ground water flow patterns

directly adjacent to the channel network, producing a critical angle of 72°. We test the hypothesis that bifurcation angles in distributary channel networks are likewise dictated by a diffusive external flow field, in this case the shallow surface water surrounding the subaqueous portion of distributary channels in a deltaic setting. We measured 25 unique distributary bifurcations in an experimental delta and 197 bifurcations in …

Depositional Dynamics Of The Upper Eagle Ford (Upper Cretaceous): Karnes And Gonzales Counties, South Texas, Josie Brunick

Graduate Theses and Dissertations

The mixed siliciclastic/carbonate late Cretaceous Eagle Ford Formation is commonly divided into the lower Eagle Ford and the upper Eagle Ford. The lower Eagle Ford is arguably the most obvious organic rich interval highlighted with wireline log data; however, the upper Eagle Ford may have just as much potential for hydrocarbon production success as the lower Eagle Ford has had. A better understanding of the upper Eagle Ford will allow a more thorough and educated assessment into its full potential as an unconventional reservoir, and allow its sweet spots for oil or gas to be found and exploited.

This study …

Linear Quadratic Optimal Control For A Cascaded Converters-Based Microgrid, Amlam Niragire

Graduate Theses and Dissertations

There is a constant transformation of the electric grid due to an ongoing interest in the deployment of renewable energy resources and electric microgrid formation. This transformation, though advantageous in many ways, poses great challenges for the energy industry and there must be a constant improvement in modeling, simulation, analysis and control techniques in order to characterize and optimize the system design and operation. In this light, the scope of this thesis is focused on developing a linear model, analyzing the stability and designing an optimal linear quadratic regulator (LQR) for a microgrid system. The microgrid system used is inspired …

Infrared Energy Conversion In Plasmonic Fields At Two-Dimensional Semiconductors, Gregory Thomas Forcherio

Graduate Theses and Dissertations

Conversion of infrared energy within plasmonic fields at two-dimensional, semiconductive transition metal dichalcogenides (TMD) through plasmonic hot electron transport and nonlinear frequency mixing has important implications in next-generation optoelectronics. Drude-Lorentz theory and approximate discrete dipole (DDA) solutions to Maxwell’s equations guided metal nanoantenna design towards strong infrared localized surface plasmon resonance (LSPR). Excitation and damping dynamics of LSPR in heterostructures of noble metal nanoantennas and molybdenum- or tungsten-disulfide (MoS2; WS2) monolayers were examined by parallel synthesis of (i) DDA electrodynamic simulations and (ii) near-field electron energy loss (EELS) and far-field optical transmission UV-vis spectroscopic measurements. Susceptibility to second-order nonlinear frequency …

3-Manifold Perspective On Surface Homeomorphisms For Surfaces With Very Negative Euler Characteristic, Michael Harris

Graduate Theses and Dissertations

The goal of this paper is to show for a compact triangulated 3-manifold M with boundary which fibers over the circle that whenever F is a fiber with sufficiently negative Euler characteristic the monodromymaps an essential simple closed curve or an essential simple arc in F to be disjoint from its image (possibly after isotopy). This is shown by applying the theorem of Ichihara, Kobayashi, and Rieck in [10] to the double of M to get a pair of pants. We then find an equivariant pair of pants and use it to find an essential simple closed curve or an …

An Electrochemical Characterization Of A Vanadium-Based Deoxydehydration Catalyst, Joel Eric Baker

Graduate Theses and Dissertations

Alternative methods for the conversion of polyols into olefins, be it for carbon storage or hydrocarbon fuel production, have become prevalent in today’s chemical industry. One process in particular, deoxydehydration (DODH) has been proven effective in taking sustainable biomass derivatives and converting them through the utilization of various homogenous metal catalysts. While this process may show productive yields and material conversion, it is hindered by the need of a sacrificial reductant. This makes a novel process economically unviable and relatively unused outside of scientific research. That fact begs the question: Can the process be improved? It is proposed here that …

Morphology Controlled Synthesis Of Copper Based Multimetallic Nanostructures And Their Electrocatalytic Properties For Methanol Oxidation Reaction, Leanne Elizabeth Mathurin

Graduate Theses and Dissertations

This research focuses on the development of shape-controlled synthesis of Cu NM, Cu-based bimetallic and trimetallic nanostructures, and their electrocatalytic properties for methanol oxidation reaction (MOR). Copper nanomaterials (Cu NM) with specific surface facets can tailor their catalytic activity. Understanding reagents responsible for Cu NM growth is important for morphology-controlled synthesis of the nanostructures. This research studies the halide influence on Cu NM growth and morphology in an oil-based synthesis. The morphology of the Cu NM varies with the halide type (i.e., Cl-, Br-, I-), and the halide concentration. Additionally, the type of Cu precursor also influenced the morphology of …

Electrochemical Time Of Flight For Rapid And Direct Measurement Of Diffusion Coefficients, Jonathan C. Moldenhauer

Graduate Theses and Dissertations

The determination of diffusion coefficients is of fundamental importance to the understanding of electrochemistry and sensors. Developing a method by which diffusion coefficients of Red/ox active analytes can be determined quickly and elegantly, would be a great advancement over presently accepted methods. This dissertation reports the reviving electrochemical time of flight (ETOF), and developing a method that allows for empirical determination of diffusion coefficients from a single measurement. ETOF is a generate and detect experiment where the time an electrochemically generated species takes to transit a known distance is measured and related to the diffusion coefficient of the species. The …

Evaluation Of The Correlation Between The Oxidation Reduction Potential And Free Chlorine Residual For Different Chlorine Sources Used In Poultry Drinking Water Sanitation, Samantha Renee Cox

Graduate Theses and Dissertations

A critical component in commercial poultry production is to ensure birds are provided clean, quality water. Multiple disinfectants can be utilized to optimize a good water quality program. The goal of these water disinfectants is to greatly reduce or eliminate the presence of all bacteria. In recent years, the oxidation-reduction potential (ORP) meter has been a tool utilized by the poultry industry to monitor chlorine efficacy in drinking water. An ORP reading of 650-750 millivolts (mV) has become the industry standard for assuring an acceptable sanitizing residual of free chlorine is present for controlling microbial contamination regardless of the actual …

On Rings Of Invariants For Cyclic P-Groups, Daniel Juda

Graduate Theses and Dissertations

This thesis studies the ring of invariants R^G of a cyclic p-group G acting on k[x_1,\ldots, x_n] where k is a field of characteristic p >0. We consider when R^G is Cohen-Macaulay and give an explicit computation of the depth of R^G. Using representation theory and a result of Nakajima, we demonstrate that R^G is a unique factorization domain and consequently quasi-Gorenstein. We answer the question of when R^G is F-rational and when R^G is F-regular.

We also study the a-invariant for a graded ring S, that is, the maximal graded degree of the top local cohomology module of S. …

Exploiting Hardware Abstraction For Parallel Programming Framework: Platform And Multitasking, Hongyuan Ding

Graduate Theses and Dissertations

With the help of the parallelism provided by the fine-grained architecture, hardware accelerators on Field Programmable Gate Arrays (FPGAs) can significantly improve the performance of many applications. However, designers are required to have excellent hardware programming skills and unique optimization techniques to explore the potential of FPGA resources fully. Intermediate frameworks above hardware circuits are proposed to improve either performance or productivity by leveraging parallel programming models beyond the multi-core era.

In this work, we propose the PolyPC (Polymorphic Parallel Computing) framework, which targets enhancing productivity without losing performance. It helps designers develop parallelized applications and implement them on FPGAs. …

Plasmon-Mediated Energy Conversion In Metal Nanoparticle-Doped Hybrid Nanomaterials, Jeremy Dunklin

Graduate Theses and Dissertations

Climate change and population growth demand long-term solutions for clean water and energy. Plasmon-active nanomaterials offer a promising route towards improved energetics for efficient chemical separation and light harvesting schemes. Two material platforms featuring highly absorptive plasmonic gold nanoparticles (AuNPs) are advanced herein to maximize photon conversion into thermal or electronic energy. Optical extinction, attributable to diffraction-induced internal reflection, was enhanced up to 1.5-fold in three-dimensional polymer films containing AuNPs at interparticle separations approaching the resonant wavelength. Comprehensive methods developed to characterize heat dissipation following plasmonic absorption was extended beyond conventional optical and heat transfer descriptions, where good agreement was …

Ecological Importance Of Invader Source Population And Disturbance In Aquatic Invasions, Nicole Elizabeth Graham

Graduate Theses and Dissertations

Invasive species are a global problem and their effects on recipient ecosystems may be mediated by disturbance and intraspecific variation. Crayfish can substantially influence stream structure and function, and invasive crayfish often have differential impacts than native crayfish in aquatic ecosystems. Since species traits often vary across a distribution, it is possible that invasive crayfish from different source populations may have distinct impacts on recipient ecosystem structure and function. In the Ozark Highlands of Arkansas and Missouri, USA, invasive O. neglectus (the Ringed Crayfish) may be leading to the displacement of native O. eupunctus (the Coldwater Crayfish). The objective of …

Characteristics And Behaviors Of School Board Members In "Grade A" Arkansas Public School Districts, Bridget Lynn Polk

Graduate Theses and Dissertations

The purpose of this grounded theory study was to describe characteristics and behaviors of school board members in Arkansas school districts where 50% or more of their campuses earned a letter grade of “A” on the 2014 Arkansas School Performance Report (Arkansas Department of Education [ADE], 2015). This purpose was achieved through analysis of artifacts from selected school districts including: achievement patterns; board minutes; and board member professional development records. A web-based survey of school board members was also utilized to gather demographic and background information. Finally, personal interviews were completed with a small group of board members to collect …

Reduction In Recombination Current Density In Boron Doped Silicon Using Atomic Hydrogen, Matthew Garett Young

Graduate Theses and Dissertations

The solar industry has grown immensely in recent years and has reached a point where solar energy has now become inexpensive enough that it is starting to emerge as a mainstream electrical generation source. However, recent economic analysis has suggested that for solar to become a truly wide spread source of electricity, the costs still need to plummet by a factor of 8x. This demands new and innovative concepts to help lower such cost. In pursuit of this goal, this dissertation examines the use of atomic hydrogen to lessen the recombination current density in the boron doped region of n-type …

Controlled Synthesis And Utilization Of Metal And Oxide Hybrid Nanoparticles, Cameron Cowgur Crane

Graduate Theses and Dissertations

This dissertation reports the development of synthetic methods concerning rationally-designed, hybrid, and multifunctional nanomaterials. These methods are based on a wet chemical, solution phase approach that utilizes the knowledge of synthetic organic and inorganic chemistry to generate building blocks in solution for the growth of nanocrystals and hybrid nanostructures. This work builds on the prior knowledge of shape-controlled synthesis of noble metal nanocrystals and expands into the challenging realm of the more reactive first row transition metals. Specifically, a microemulsion sol-gel method was developed to synthesize Au-SiO2 dimers as precursors for the synthesis of segmented heterostructures of noble metals that …

Service Consistency In Vehicle Routing, Kunlei Lian

Graduate Theses and Dissertations

This thesis studies service consistency in the context of multi-period vehicle routing problems (VRP) in which customers require repeatable services over a planning horizon of multiple days. Two types of service consistency are considered, namely, driver consistency and time consistency. Driver consistency refers to using the fewest number of different drivers to perform all of the visits required by a customer over a planning horizon and time consistency refers to visiting a customer at roughly the same time on each day he/she needs service. First, the multi-objective consistent VRP is defined to explore the trade-offs between the objectives of travel …

A Bayesian Variable Selection Method With Applications To Spatial Data, Xiahan Tang

Graduate Theses and Dissertations

This thesis first describes the general idea behind Bayes Inference, various sampling methods based on Bayes theorem and many examples. Then a Bayes approach to model selection, called Stochastic Search Variable Selection (SSVS) is discussed. It was originally proposed by George and McCulloch (1993). In a normal regression model where the number of covariates is large, only a small subset tend to be significant most of the times. This Bayes procedure specifies a mixture prior for each of the unknown regression coefficient, the mixture prior was originally proposed by Geweke (1996). This mixture prior will be updated as data becomes …

An Evaluation Of Arkansas’ Developmental Coursework Policy At Postsecondary Institutions, Evan Thomas Rhinesmith

Graduate Theses and Dissertations

This dissertation is an evaluation of the impacts of assignment to and enrollment in postsecondary remedial coursework in the state of Arkansas. In this study, I evaluate the impacts of the policy on students’ academic achievement and attainment as measured by graduation rates and persistence. I include subgroup analyses of these outcomes to determine whether there are heterogeneous effects for students enrolling at two-year or four-year institutions, institutions with the highest remediation rates, and students of different races, genders, and baseline achievement. Like previous evaluations of remediation in other settings, the results here point to negative impacts of remediation on …

Do You See What I See? Perception And Social Construction Of Academic Success Between Student-Athletes And Support Services, Lauren Kirby

Graduate Theses and Dissertations

The current study explores how academic success is defined and socially constructed between athletic academic support professionals and at-risk student-athletes. There continues to be an increase in academic support services provided to student-athletes, including learning specialists, academic advisors, and academic buildings (Wolverton, 2008). Although a significant relationship between support services and academic output of student-athletes has been found (Hollis, 2002; Ridpath, 2010), the relational and communicative dynamics of these groups have not been fully explored.

Using qualitative methods, one-on-one interviews were conducted with participants, and grounded theory and thematic analysis were employed to identify overarching themes for the research questions. …

Environmental And Climatic Constraints On Large-Scale Camelina Production In Eastern Arkansas, Benjamin Robert Tracy

Graduate Theses and Dissertations

Camelina sativa is a cold weather crop that is typically grown in semi-arid environments in the Western United States, usually as a spring crop, but sometimes during the winter. Research analyzing climate data and soil hydrology is important to better understand the environmental and terrain conditions necessary for Camelina farming wherever it is proposed for large-scale production. This study focused on various conditions and constraints pertaining to the potential for Camelina as a crop biofuel in Eastern Arkansas. Due to interest in the economic potential of crop biofuels in this area, and in particular the low input costs for Camelina, …

Characterization Of The Rnap Binding Sites On A Λ Dna Using A Solid State Nanopore Combined With A Tuning Fork Force Sensing Probe Tip, Harpreet Kaur

Graduate Theses and Dissertations

In this dissertation, the binding positions of RNAP holoenzyme on a λ DNA are characterized using an apparatus that integrates a Solid State Nanopore with a Tuning Fork based Force sensing probe (SSN-TFFSP). The SSN-TFFSP system combines the measurement of ionic current through a solid-state nanopore with a DNA tethered probe tip. The position of the tip is sensed by a tuning fork force sensor and is controlled with a nanopositioning system. With this apparatus, translocation speed of DNA through solid state nanopores has been brought down to 100 μs/base. Such a controlled movement of DNA through a solid state …

The “Apparent” Diffusion Coefficient Of Electrons Through A Nafion Membrane, Marissa Kayle Reynolds

Graduate Theses and Dissertations

The hydrogen/oxygen fuel cell is a greener, more efficient energy solution. However, there are many problems with the fuel cell including storage, infrastructure, cost, the oxygen reduction reaction, and the durability of the proton exchange membrane (PEM). The PEM is not only used as the electrolyte for the cell but also as a physical barrier between the anode and the cathode. The integrity of this membrane is crucial to the functioning of the fuel cell. This thesis will examine using ferricyanide as a probe molecule for diagnostic experiment of Nafion membrane integrity. Using hydrodynamic voltammetry with a rotating disk electrode …

Lost Names In The Paleozoic Lithostratigraphy Of Arkansas, Noah Morris

Graduate Theses and Dissertations

The geology of Arkansas has been studied for nearly 160 years, and our understanding of it is continually evolving. Part of this ever-changing study is the nomenclature of the stratigraphy. From the early reports to today, several lithostratigraphic names have been proposed and abandoned to improve the accuracy and clarity of the understanding of Arkansas’ geology. Over these 160 years of study, 214 names have been proposed for the Paleozoic beds of Arkansas, with nearly 80 of them currently in use today. These names are a testimony and legacy of the history of Arkansas’ natural resource development and Arkansas’ geologists. …

Molecular Dynamics Simulations Of Dna-Functionalized Nanoparticle Building Blocks On Gpus, Tyler Landon Fochtman

Graduate Theses and Dissertations

This thesis discusses massively parallel molecular dynamics simulations of nBLOCKs using graphical processing units. nBLOCKs are nanoscale building blocks composed of gold nanoparticles functionalized with single-stranded DNA molecules. To explore greater simulation time scales we implement our nBLOCK computational model as an extension to the coarse grain molecular simulator oxDNA. oxDNA is parameterized to match the thermodynamics of DNA strand hybridization as well as the mechanics of single stranded DNA and double stranded DNA. In addition to an in-depth review of our implementation details we also provide results of the model validation and performance tests. These validation and performance tests …

Characterization Of Coupled Gold Nanoparticles In A Sparsely Populated Square Lattice, Roy Truett French Iii

Graduate Theses and Dissertations

Metal nanoparticles deposited in regular arrays spaced at optical wavelengths support a resonance due to a coherent coupling between localized surface plasmon mode and lattice diffraction allowing for engineering of tunable devices for use in biological sensors, nanoantennae, and enhanced spectroscopy. Techniques such as electron beam lithography, focused ion beam lithography, nanosphere lithography, and nanoimprint lithography are used for fabrication but are limited by cost, device throughput, and small deposition. Polymer soft lithography and continuous dewetting of particles is a potentially viable alternative showing promise in all of those areas. This thesis developed the fabrication of a refined hydrophilic nanoimprinted …

A Hybrid Partially Reconfigurable Overlay Supporting Just-In-Time Assembly Of Custom Accelerators On Fpgas, Zeyad Tariq Aklah

Graduate Theses and Dissertations

The state of the art in design and development flows for FPGAs are not sufficiently mature to allow programmers to implement their applications through traditional software development flows. The stipulation of synthesis as well as the requirement of background knowledge on the FPGAs' low-level physical hardware structure are major challenges that prevent programmers from using FPGAs. The reconfigurable computing community is seeking solutions to raise the level of design abstraction at which programmers must operate, and move the synthesis process out of the programmers' path through the use of overlays. A recent approach, Just-In-Time Assembly (JITA), was proposed that enables …

Comparing Before-And After-School Neurocognitive Performance In High School Athletes- Implications For Concussion Management, Morgan Anderson

Graduate Theses and Dissertations

There are several factors that influence computerized neurocognitive testing performance however, one factor that has not been examined is the potential deleterious effects of cognitive fatigue from an academic school day combined with time of computerized neurocognitive testing (CNT) administration. The primary purpose of this study was to compare before-and after-school CNT performance and total symptoms in non-concussed high school student athletes. The secondary purpose of this study was to compare before-school and after-school CNT performance and total symptoms and chronotypes in non-concussed student athletes. A crossover design was used to compare before-and after-school CNT performance and total symptoms of …

Applications Of Krylov Subspace And Balanced Truncation Model Order Reduction In Power Systems, Sebastian Emanuel Garrido

Graduate Theses and Dissertations

Dynamic representations of power systems usually result in the order of hundreds or even thousands of buses. Therefore, reduction of these dynamic representations is convenient. Two applications of model order reduction in power systems are discussed in this thesis. First, Krylov subspace-based method is applied to the IEEE-123 Node Test Feeder in the context of distribution-level power systems simulation. Second, a Balanced Truncation-based model reduction is implemented in the 3-Machine 9-Bus system for designing a power system controller in the context of generation- and transmission-level power systems.

First, for the IEEE-123 Node Test Feeder, a two-sided Arnoldi algorithm is proposed …

Dpweka: Achieving Differential Privacy In Weka, Srinidhi Katla

Graduate Theses and Dissertations

Organizations belonging to the government, commercial, and non-profit industries collect and store large amounts of sensitive data, which include medical, financial, and personal information. They use data mining methods to formulate business strategies that yield high long-term and short-term financial benefits. While analyzing such data, the private information of the individuals present in the data must be protected for moral and legal reasons. Current practices such as redacting sensitive attributes, releasing only the aggregate values, and query auditing do not provide sufficient protection against an adversary armed with auxiliary information. In the presence of additional background information, the privacy protection …