Digital Commons Network^™

Solid State Nmr Analysis Of Insect Wing Membranes, Samuel Eddy

Graduate Theses, Dissertations, and Problem Reports (ETD)

Solid State NMR is a powerful tool for analyzing the chemical composition of insects. Previous studies have used Solid State NMR to investigate the chemical composition and investigate the sclerotization (tanning) process of insect exoskeletons. Acquiring sufficient exoskeleton sample for analysis has been relatively simple. This is however not the case for other components of an insect’s physiology, particularly the wing membrane material. The wings of an insect only compose a small percentage of their overall body mass, and many hundreds to thousands of insects must be processed in order to achieve a few milligrams of wing membrane sample. The …

Footwear Image Quality Classification: Using Subjective Assessments And Objective Image Metrics To Predict Impression Quality, En-Tni Lin

Graduate Theses, Dissertations, and Problem Reports (ETD)

Shoeprints deposited during the commission of a crime vary in quality as a function of numerous factors, such as substrates, media, and the specific physical activities carried out by perpetrators. This variability in impression quality impacts the amount of information available from questioned crime scene impressions, and therefore an examiner's confidence in providing opinions of source attribution. In response, this research attempted to characterize footwear impression quality based on image sharpness, contrast, entropy, homogeneity, noise, quantity of information, and complexity, and to integrate these hand-engineered feature descriptions with subjective opinions of impression quality.

The methodology followed a five-pronged approach. First, …

Probabilistic Short Term Solar Driver Forecasting With Neural Network Ensembles, Joshua Daniell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Commonly utilized space weather indices and proxies drive predictive models for thermosphere density, directly impacting objects in low-Earth orbit (LEO) by influencing atmospheric drag forces. A set of solar proxies and indices (drivers), F_10.7, S_10.7, M_10.7, and Y_10.7, are created from a mixture of ground based radio observations and satellite instrument data. These solar drivers represent heating in various levels of the thermosphere and are used as inputs by the JB2008 empirical thermosphere density model. The United States Air Force (USAF) operational High Accuracy Satellite Drag Model (HASDM) relies on JB2008, and …

Love, Life, And Controversial Topics: A Content Analysis Of The Top Liked Abortion Tiktok Videos Before And After The Overturning Of Roe V. Wade, Jill E. Sturges

Graduate Theses, Dissertations, and Problem Reports (ETD)

TikTok is a trendy social media platform that has attracted billions of monthly users. Anyone can post a short video about their interests, beauty, relationships, travel, and controversial topics if they are 13 or older. Many young adults turn to social media platforms, such as TikTok, to help them make decisions regarding their everyday lives and to discuss controversial topics, such as abortion. The concern with social media content is the misinformation and disinformation that can spread rapidly across the globe with a click of a button. Numerous studies have begun to examine social media platforms for the accuracy of …

Deadly Divisions: Class And Stigma As Fundamental Social Causes Of Spatial Health Inequalities, Misty Lee Harris

Graduate Theses, Dissertations, and Problem Reports (ETD)

The objective of this dissertation is to investigate how class and stigma influence spatial inequalities in health across the US, from the structural to the individual level. Class, stigma, and subsequent access to capital resources are not equally distributed across the US. Women, poor, and minority populations continue to have unequal access to capital resources across the country, though this is spatially determined. Similarly, while there are health inequalities along the same social cleavages at the national level, they differ significantly across localities. Research has not paid enough attention to the fundamental social causes of inequities, resulting in the inability …

Longitudinal Oxygen Imaging In 3d (Bio)Printed Models, Ryan Curtis O'Connell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Electron paramagnetic resonance (EPR), and its molecular imaging modality, is a powerful tool to noninvasively map various biological and chemical markers within objects of interest. Reliable data acquisition is a major impeding factor for longitudinal hands-off measurements. Measurements are especially challenging in biomedical applications, as live objects are not static. Frequent changes occur that require constant fine recalibration of the EPR detection system, called the resonator. To enable longitudinal imaging, a technology permitting automatic digital control of resonator coupling, tuning, and EPR data acquisition was developed. Automation was achieved through the utilization of a microcontroller and digital peripheral components such …

Biologically – Plausible Load Feedback From Dynamically Scaled Robotic Model Insect Legs, William Zyhowski

Graduate Theses, Dissertations, and Problem Reports (ETD)

Researchers have been studying the mechanisms underlying animal motor control for many years using computational models and biomimetic robots. Since testing some theories in animals can be challenging, this approach can enable unique contributions to the field. An example of a system that benefits from this modeling and robotics approach is the campaniform sensillum (CS), a kind of sensory organ used to detect the loads exerted on an insect's legs. The CS on the leg are found in groups on high-stress areas of the exoskeleton and have a major influence on the adaptation of walking behavior. The challenge for studying …

Development Of Novel Mass Spectrometry Method For The Analysis Of Complex Compounds, Jing Wang

Graduate Theses, Dissertations, and Problem Reports (ETD)

As mass spectrometry methods continue to advance, there is a growing need for innovative interfaces that can seamlessly integrate sample pretreatment, separation, and ionization, allowing for direct mass analysis while maintaining a simple and flexible system. The evolution of ambient ionization techniques has made it feasible to nebulize analyte compounds at ambient pressure. Moreover, single-cell proteomics using mass spectrometry is gaining increasing attention, necessitating the development of precise sample preparation techniques to enhance sensitivity. In this dissertation, I demonstrate the novel mass spectrometry system to couple the sample pretreatment with the direct mass spectrometry detection for the analysis of diverse …

Object Detection And Classification In The Visible And Infrared Spectrums, Domenick D. Poster

Graduate Theses, Dissertations, and Problem Reports (ETD)

The over-arching theme of this dissertation is the development of automated detection and/or classification systems for challenging infrared scenarios. The six works presented herein can be categorized into four problem scenarios. In the first scenario, long-distance detection and classification of vehicles in thermal imagery, a custom convolutional network architecture is proposed for small thermal target detection. For the second scenario, thermal face landmark detection and thermal cross-spectral face verification, a publicly-available visible and thermal face dataset is introduced, along with benchmark results for several landmark detection and face verification algorithms. Furthermore, a novel visible-to-thermal transfer learning algorithm for face landmark …

The Effect Of Different Fracturing Fluids On The Productivity Of Multi-Staged Fractured Marcellus Shale Horizontal Wells, Vida Gyaubea Matey-Korley

Graduate Theses, Dissertations, and Problem Reports (ETD)

While hydraulic fracturing has undeniably improved the production from oil and gas reservoirs, this technology is not without limitations. The primary hurdles lie in the areas of proppant transport, fluid rheology, and stress management. Despite the extensive research conducted in this domain, there remains a considerable amount of work to be done for comprehensive solutions that account for the complex interactions among fracturing fluid, proppant distribution, and geomechanical conditions. Achieving this will then make room for a holistic and efficient hydraulic fracturing strategy.

This study addresses the above-mentioned problem by examining the impact of fluid type on proppant transport and …

Investigation Of Regulator Of G Protein Signaling-12 (Rgs12) As A Modulator Of Monoamine Transporters And Behavioral Responses To Cocaine, Allison Noel White

Graduate Theses, Dissertations, and Problem Reports (ETD)

Stimulant use disorder is a psychiatric illness that is characterized by repeated use of stimulant drugs despite harm to the user. There are currently no Federal Drug Administration (FDA)- approved medications for stimulant use disorder, and the number of stimulant use-associated deaths have increased over the past decade. Given the prevalence of and lack of treatments for stimulant use disorder, there is an urgent need to identify new drug targets and treatments for this illness. Our group is investigating Regulator of G protein Signaling-12 (RGS12) as one such potential drug target for stimulant use disorder. Mice lacking RGS12 are insensitive …

Outdoor Recreation Participation: Negotiation Strategies For Overcoming Constraints Related To Race, Ethnicity And Gender In Florida Keys National Marine Sanctuary, Larissa Martins

Graduate Theses, Dissertations, and Problem Reports (ETD)

By understanding the demographics of those participating in outdoor recreation, and identifying who is using these resources, managers can effectively create opportunities for underrepresented communities. Previous research had underscored the innumerous benefits related to coastal outdoor recreation activities, from human well-being to local socio-economic benefits. This study is divided into two papers that both took place in Florida Keys National Marine Sanctuary. The purpose of the first paper was to investigate the constraints that minority groups related to gender, race and ethnicity groups face prior participation in coastal activities, along with negotiation strategies that are employed in order to overcome …

Design And Manufacture Of An Aerodynamic Body That Meets Scaling Law Requirements And Survives Severe G-Load Environment For Free-Flight Testing, Anthony R. Gonzalez

Graduate Theses, Dissertations, and Problem Reports (ETD)

Design and Manufacture of an Aerodynamic Body that Meets Scaling Law Requirements and Survives Severe G-load Environment for Free-Flight Testing

Anthony Gonzalez

Developing scale models to test functionality and ascertain aerodynamic properties is critical before manufacturing full-size products. Through dimensional analysis and similitude, engineers create scale models to test any parameter of interest. This research aims to design a scale model of an aerodynamic body for repeated free-flight testing. The Froude number is the dominant scale model law used to determine the geometric, mass, and inertia scaling laws. A critical requirement for this research is that the model should be …

Synthetic Well Log Generation Software, Daniel E. Keller

Graduate Theses, Dissertations, and Problem Reports (ETD)

In this study, we developed a novel approach to generate synthetic well logs using backpropagation neural networks through the use of an open source software development tool. Our method predicts essential well logs such as neutron porosity, sonic, photoelectric, and resistivity, which are crucial in various stages of oil and gas exploration and development, as they help determine reservoir characteristics. Our approach involves sequentially predicting well logs, using the outputs of one prediction model as inputs for subsequent models to generate comprehensive and coherent sets of well logs. We trained and tested our models using 16 wells from a single …

Development Of A Hydrometallurgical Process For The Extraction Of Cobalt, Manganese, And Nickel From Acid Mine Drainage Treatment Byproduct, Alejandro Agudelo Mira

Graduate Theses, Dissertations, and Problem Reports (ETD)

Critical minerals (CMs) are defined as crucial elements for the country's economy due to the development of new cutting-edge applications and the risk of an eventual disruption in their supply chain. The unique chemical and physical properties of the CMs have made these elements decisive in the growth of industries such as telecommunications, army, medicine, Aerospace, etc. In 2022, the US Geological Survey established a list of 50 CMs, including manganese, cobalt, nickel, aluminum, magnesium, and others. Of the total of CMs, 26 are 100% imported from outside the United States (Venditti, 2022).

Driven by the ever-increasing demand for critical …

Leveraging Artificial Intelligence And Geomechanical Data For Accurate Shear Stress Prediction In Co2 Sequestration Within Saline Aquifers (Smart Proxy Modeling), Munirah Alawadh

Graduate Theses, Dissertations, and Problem Reports (ETD)

This research builds upon the success of a previous project that used a Smart Proxy Model (SPM) to predict pressure and saturation in Carbon Capture and Storage (CCS) operations into saline aquifers. The Smart Proxy Model is a data-driven machine learning model that can replicate the output of a sophisticated numerical simulation model for each time step in a short amount of time, using Artificial Intelligence (AI) and large volumes of subsurface data. This study aims to develop the Smart Proxy Model further by incorporating geomechanical datadriven techniques to predict shear stress by using a neural network, specifically through supervised …

Integrated Immunity-Based Methodology For Uav Monitoring And Control, Ryan G. Mclaughlin

Graduate Theses, Dissertations, and Problem Reports (ETD)

A general integrated and comprehensive health management framework based on the artificial immune system (AIS) paradigm is formulated and an automated system is developed and tested through simulation for the detection, identification, evaluation, and accommodation (DIEA) of abnormal conditions (ACs) on an unmanned aerial vehicle (UAV). The proposed methodology involves the establishment of a body of data to represent the function of the vehicle under nominal conditions, called the self, and differentiating this operation from that of the vehicle under an abnormal condition, referred to as the non-self. Data collected from simulations of the selected UAV autonomously flying a set …

Methods For Analyzing Physics Student Retention And Physics Curricula, John Darrell Hansen

Graduate Theses, Dissertations, and Problem Reports (ETD)

Retention of students in college has been a concern of academic institutions for many years. In the last two decades, the focus on student retention in STEM fields has intensified. The current graduation rate of students in science, technology, engineering and mathematics (STEM) fields is well below that required to fill the projected need of STEM professionals. The work presented in this dissertation investigates the problem of student retention in physics programs. Four studies were performed. The first identifies the relationships between student retention and pre-college and early-college academic factors at an eastern U.S. university using logistic regression and Bayesian …

Manganese-Based A-Site High-Entropy Perovskite Oxides For Solar Thermochemical Hydrogen Production, Cijie Liu

Graduate Theses, Dissertations, and Problem Reports (ETD)

Non-stoichiometric perovskite oxides have been studied as a new family of redox oxides for solar thermochemical hydrogen (STCH) production owing to their favourable thermodynamic properties. However, conventional perovskite oxides suffer from limited phase stability and kinetic properties, and poor cyclability. Here, we report a strategy of introducing A-site multi-principal-component mixing to develop a high-entropy perovskite oxide, (La_1/6Pr_1/6Nd_1/6Gd_1/6Sr_1/6Ba_1/6)MnO₃ (LPNGSB_Mn), which shows desirable thermodynamic and kinetics properties as well as excellent phase stability and cycling durability. LPNGSB_Mn exhibits enhanced hydrogen production (~77.5 mmol moloxide^–1) compared to (La …

Parent And Adolescent Report Of Helicopter Parenting: Examining Reporter Discrepancies And Associations With Adolescent Depression And Anxiety, Avneet Batra

Graduate Theses, Dissertations, and Problem Reports (ETD)

Research is replete with studies on Helicopter Parenting (HP) and its association with depression and anxiety (Cui et al., 2019; Schiffrin et al., 2014; 2019). However, most of the studies have focused on college students’ reports on helicopter parenting and there is relative dearth of studies with adolescents or with parents’ reports of HP (Pistella et al., 2020; Schiffrin et al., 2019). The current study aims to fill the gap in the literature by including both parent and adolescents’ perspectives on helicopter parenting, assess its unique association (parent and teens HP reports) with teen depression and anxiety both concurrently and …

Health Behaviors As Mediators Of Caregiver Physical Health, Michaela Clark

Graduate Theses, Dissertations, and Problem Reports (ETD)

Informal caregivers provide the bulk of care to older adults in the United States (Ali et al., 2021). Informal caregivers include family, friends, and neighbors, many of whom do not have any formal training for this role. There are costs associated with taking on a caregiving responsibility, such as scheduling appointments, helping with medications, household tasks, and even financial support (Rha et al., 2015). Many of these informal caregivers lack the coping skills necessary to manage the challenges associated with caregiving (Xu et al., 2021). Many also take on this role despite the personal costs on one’s own health, time, …

Quantifying Variation In High-Quality Footwear Replicate Impressions, Samantha K. Brady

Graduate Theses, Dissertations, and Problem Reports (ETD)

A footwear impression collected at a crime scene can provide information about the shoe that created it, yielding investigative leads, excluding persons-of-interest, and linking evidence between cases. The analysis of footwear evidence often requires the preparation of test impressions from known exemplar shoes created under controlled laboratory conditions for comparison to questioned impressions. The goal of these comparisons is to evaluate the degree of similarities and differences between the questioned impression and potential sources.

Given that this comparison leads to an assessment of the nature and degree of agreement between questioned and known impressions, it is important to characterize the …

Exploring Prenatal Care In A Rural Appalachian State: A Project Watch Study Of Barriers And Facilitators In All Births From May 2018 To March 2022, Madelin Gardner

Graduate Theses, Dissertations, and Problem Reports (ETD)

Introduction: PNC is essential in protecting the health of birthing person and infant. Teenage and advanced maternal age (AMA) birthing persons are known risk factors for poor birth outcomes. However, less is known about whether these age groups are associated with inadequate PNC. Births to teenagers continue to be of concern in rural areas however, little is known about the association between inadequate PNC and poor infant outcomes in teenage populations. Previous studies have determined that greater risk of inadequate PNC has been linked to more rural areas compared to more urban areas. WV is the third most rural state …

Adverse Childhood Experiences And Intimate Partner Violence In Gender Minority Populations, Claire Mason Mccown

Graduate Theses, Dissertations, and Problem Reports (ETD)

Childhood adversity has been linked to numerous health and mental health concerns in adulthood (Felitti et al., 1998). Among the many outcomes associated with adverse childhood experiences (ACEs), victimization and perpetration of intimate partner violence (IPV) remains a public health crisis. Research has found that those identifying as gender minority individuals are disproportionately impacted by IPV (Messinger, 2017; Peitzmeier et al., 2020). Further, gender minority individuals experience equivalent, if not higher, rates of ACEs when compared to their cisgender counterparts (Baams, 2018; Juárez-Chávez et al., 2018; Schnarrs et al., 2019; Tobin & Delaney, 2019). While many factors contribute to the …

Sex Differences In Endothelial Function, Metabolism, And Sleep: Responses To Disrupted Circadian Rhythms, Olga Hecmarie Meléndez-Fernández

Graduate Theses, Dissertations, and Problem Reports (ETD)

Circadian rhythms are endogenous cycles that recur approximately every 24 h, and manifest in virtually every physiological and behavioral process among the vast majority of organisms. These rhythms, sustained by the central circadian clock, the suprachiasmatic nucleus (SCN) of the hypothalamus, allow for optimal timing of biological processes that ensure organisms’ homeostasis, and are entrained to precisely 24 h by daily exposure to light. Disruption of the molecular mechanisms that drive these rhythms have negative consequences on physiology and behavior that may impair survival. The molecular mechanisms that underlie these effects are widely studied and linked to multiple diseases and …

Sexism In The Digital World: A Thematic Content Analysis Of The Cyberbullying Of Lil Miquela, Shyanne Elizabeth Schmithorst

Graduate Theses, Dissertations, and Problem Reports (ETD)

As artificial intelligence (AI) evolves, social issues associated with this technology are also perpetuated. This is especially pertinent to online violence against women. In April 2016, fictional character “Lil Miquela,” an AI robot who would quickly rise to fame as a social media influencer, was created using Computer-Generated Imagery (CGI). Significant backlash has persisted against Lil Miquela throughout its existence, which has typically taken the form of demeaning comments made by other users on Lil Miquela’s social media pages. As the robot looks deceptively like a human female, the robot receives online treatment that mimics that of human women. Utilizing …

Internalized Heterosexism, Shame Proneness, And Disclosure In Clinical Supervision Among Sexual Minority Supervisees, Christian Joseph Carey

Graduate Theses, Dissertations, and Problem Reports (ETD)

Sexual minority supervisees face unique struggles including prejudice, discrimination, and heterosexism, which may impact their psychological well-being and development within the supervisory experience through shame proneness and reduced disclosure. This study aims to explore the challenges facing sexual minority trainees and contribute to the empirical knowledge of multicultural supervision. Thus, this study proposes two mediation models for the hypothesized relationships among internalized heterosexism, shame-related withdrawal, shame-related negative self-evaluation, and disclosure in supervision. A total of 170 supervisees identifying as sexual minorities completed an online survey. The primary analysis included a three-step linear regression and confirmatory analysis for mediation. The results …

Exploring Early Childhood Educators’ Attitudes About Addiction And Their Association With Student-Teacher Relationships, Megan E. Mikesell

Graduate Theses, Dissertations, and Problem Reports (ETD)

This project aimed to address significant gaps in literature around addiction-related attitudes by identifying early childhood educators’ addiction-related attitudes and how these attitudes associate with their relationships with students who come from homes with addiction. A sample of 501 ECEs completed an online survey which included the Public Attitudes About Addiction Survey (PAAS; a 54-item measure used to identify a person’s beliefs about addiction across five models), the Student-Teacher Relationship Scale (STRS; a 15-item scale used to measure the level of closeness and conflict), and various demographic and community questions. Path analysis revealed that both moral and nature aligned attitudes …

Social Comparison Theory: The Effects Athletic Influencers Have On An Appalachian Generation Z Men Audience, Aaron David Dickens

Graduate Theses, Dissertations, and Problem Reports (ETD)

Many studies have highlighted how social comparison can influence self-efficacy for exercise, body dissatisfaction, and motivation to exercise, especially on social media; in addition, several studies have supported how attitude toward exercise and confidence toward exercise correlate with one another. However, these dependent variables have not been examined in the context of Generation Z men in Appalachia. Despite the lack of literature on this demographic, it is important to study Generation Z Appalachian men because of the frequent health problems this demographic faces, such as obesity. Therefore, this pretest-posttest between-subjects lab experiment investigated how an athletic influencer on social media …

Bedrock Channel Geometry: Meter To Micron Scale Controls On Fluvial Incision, Nicholas J. Colaianne

Graduate Theses, Dissertations, and Problem Reports (ETD)

The relative resistance of various rock types to incisional processes vary widely and the properties governing bedrock erodibility are poorly understood. Lithologic properties influencing erodibility are the culmination of a rock’s depositional, diagenetic, and exhumation processes. Difficulty identifying a convenient physical proxy for erodibility suggests examining evidence of these processes holistically may offer insight into the role of each in setting a rock’s resistance to incisional forces. In this study we use measured channel geometries along a short stretch of the Dry Fork, WV hosting three distinct lithologic settings to infer relative erodibility against measured and observed fluvial, lithologic, and …