Digital Commons Network^™

Dynamic Study Of Mo/Zsm-5 Catalyst For Ch4 Dehydroadomation, Hadi Yahya Almusawa

Graduate Theses, Dissertations, and Problem Reports (ETD)

Methane dehydroaromatization (CH₄-MDA) is a highly promising venture for natural gas utilization/exploitation, i.e., direct conversion of methane (CH₄) to liquid aromatics (benzene) and hydrogen. This process is a catalytic reaction and therefore, is subject to all the advantages and constraints of catalysis. This study discussed the structure and reactivity of Mo/ZSM-5 zeolite catalysts and their effect on the active conversion of methane to valuable aromatic products such as benzene: 1) The preparation and characterization of Mo/ZSM-5, which are crucial steps in any catalytic reaction process since a better performing catalyst consequently leads to better outcomes; 2) …

Synthesis Of Graphene Using Plasma Etching And Atmospheric Pressure Annealing: Process And Sensor Development, Andrew Robert Graves

Graduate Theses, Dissertations, and Problem Reports (ETD)

Having been theorized in 1947, it was not until 2004 that graphene was first isolated. In the years since its isolation, graphene has been the subject of intense, world-wide study due to its incredibly diverse array of useful properties. Even though many billions of dollars have been spent on its development, graphene has yet to break out of the laboratory and penetrate mainstream industrial applications markets. This is because graphene faces a ‘grand challenge.’ Simply put, there is currently no method of manufacturing high-quality graphene on the industrial scale. This grand challenge looms particularly large for electronic applications where the …

Innovative Approaches To 3d Gis Modeling For Volumetric And Geoprocessing Applications In Subsurface Infrastructures In A Virtual Immersive Environment, Pragya Srivastava

Graduate Theses, Dissertations, and Problem Reports (ETD)

As subsurface features remain largely ‘out of sight, out of mind’, this has led to challenges when dealing with underground space and infrastructures and especially so for those working in GIS. Since subsurface infrastructure plays a major role in supporting the needs of modern society, groups such as city planners and utility companies and decision makers are looking for an ‘holistic’ approach where the sustainable use of underground space is as important as above ground space. For such planning and management, it is crucial to examine subsurface data in a form that is amenable to 3D mapping and that can …

Rational Drilling Control Parameters To Reduce Respirable Dust During Roof Bolting Operations, Hua Jiang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Roof bolting has been the primary means to improve mine safety in the aspect of preventing different types of roof falls in underground mines. However, based on the published researches, underground roof bolting operators exhibit a continued risk for overexposure to high levels of respirable coal and crystalline silica dust from the roof drilling operation. Inhaling these dust can cause coal workers’ pneumoconiosis (CWP), also known as black lung. Another job-related lung disease silicosis, a disabling and even fatal and irreversible illness, could be developed through overexposure to quartz-laden dust. A recent NIOSH research shows that the quartz content in …

Paper-Based Point-Of-Care Tools For Blood Testing, Xuefei Gao

Graduate Theses, Dissertations, and Problem Reports (ETD)

Early detection of malignant disease is crucial for timely diagnosis and effective medical intervention, which significantly increases survival rates and reduce financial burden on patients. Biomarkers are becoming increasingly important in detection of malignant diseases, because they can be employed for indicating diseases, predicting risks and monitoring the progression of diseases. In addition, biomarkers show up at early stages of diseases in human tissues and fluids (e.g., blood, urine and saliva), which shows great promise for early disease detection. In this dissertation, paper-based lateral flow strips (PLFSs) have been developed for the detection of disease biomarkers, including protein biomarkers and …

Elucidating The Properties And Mechanism For Cellulose Dissolution In Tetrabutylphosphonium-Based Ionic Liquids Using High Concentrations Of Water, Brad Crawford

Graduate Theses, Dissertations, and Problem Reports (ETD)

The structural, transport, and thermodynamic properties related to cellulose dissolution by tetrabutylphosphonium chloride (TBPCl) and tetrabutylphosphonium hydroxide (TBPH)-water mixtures have been calculated via molecular dynamics simulations. For both ionic liquid (IL)-water solutions, water veins begin to form between the TBPs interlocking arms at 80 mol % water, opening a pathway for the diffusion of the anions, cations, and water. The water veins allow for a diffusion regime shift in the concentration region from 80 to 92.5 mol % water, providing a higher probability of solvent interaction with the dissolving cellulose strand. The hydrogen bonding was compared between small and large …

Automated And Standardized Tools For Realistic, Generic Musculoskeletal Model Development, Trevor Rees Moon

Graduate Theses, Dissertations, and Problem Reports (ETD)

Human movement is an instinctive yet challenging task that involves complex interactions between the neuromusculoskeletal system and its interaction with the surrounding environment. One key obstacle in the understanding of human locomotion is the availability and validity of experimental data or computational models. Corresponding measurements describing the relationships of the nervous and musculoskeletal systems and their dynamics are highly variable. Likewise, computational models and musculoskeletal models in particular are vitally dependent on these measurements to define model behavior and mechanics. These measurements are often sparse and disparate due to unsystematic data collection containing variable methodologies and reporting conventions. To date, …

Enabling And Threatening Factors Affecting Persistence. A Qualitative And Quantitative Study On Rural First-Generation Stem Students’ And Stem Faculty's Perspectives., Travis A. Miller

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study focuses on the factors that enable and threaten rural first-generation STEM students’ persistence. Limited empirical studies are available that focus on rural first-generation STEM majors’ persistence. Quantitative analysis was conducted using Kruskal Wallis H and Mann-Whitney U tests to determine any significant differences with the survey results. Content and thematic analysis was conducted on the student and faculty interviews to determine themes of enabling and threatening factors affecting persistence.

Enabling factors affecting persistence were found to be: Drive or Motivation, Experiences and skills, and Support. These were both faculty and student interview themes whereas a …

Production Allocation Of Reservoir Layers Using Data-Driven Reservoir Modeling, Semaa Alessa

Graduate Theses, Dissertations, and Problem Reports (ETD)

The pros of having a commingled layer scheme would be considered high with successful reservoir management. If not, the cons will impact the production drastically as unfortunate consequences may result in reservoir fluids communication, well integrity issues, and production termination. Although the plane requires optimizing production with minimal capital investments and operating expenses, it is an enormous challenge considering commingled layers frequent surveillance and workover requirements.

As the value of information is a decision tool for the surveillance frequency, the oil industry often uses static assumptions as an economical replacement of dynamic measurements such as KH static modeling. However, the …

Confirmation Of Tdm Capabilities In Modeling Compartmentalized Wag Eor, Anthony William Morrow

Graduate Theses, Dissertations, and Problem Reports (ETD)

Data-Driven Reservoir Modeling (DDRM), commonly referred to as Top-Down Modeling (TDM), is a relatively new and cutting-edge approach to the traditional numerical reservoir modeling and simulation techniques. DDRM uses artificial intelligence and machine learning in tandem to construct full-field models using measured data instead of calculations that refer to equations derived from averaged values and type curves. TDM allows all of the measured data from a field to be combined and used towards generating predictions of the production on a well by well basis for a specific field. Due to TDM not using the traditional physics-based approach, it is subjected …

Modeling Of Rotary Packed Beds For Reactive And Non-Reactive Systems, Chinyere Evangeline Ezeobinwune

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rotary packed beds (RPBs) are used in a wide range of reactive and non-reactive applications. In this research, a 2-d, first-principles, dynamic model of a non-reactive RPB that is used for heat exchange between the outgoing flue gas from a power plant and the incoming air to the boiler/pulverizer of the power plant is developed. A 2-d, first-principles model of a reactive RPB is developed where a functionalized metal-organic framework (MOF) is used for CO₂ capture.

For the non-reactive system, a Ljungstrom-type air preheater (APH) is considered. Existing models for these rotating heat exchangers are typically 1-d. There are …

Navigation Under Obstacle Motion Uncertainty Using Markov Decision Processes, Jennifer Quyen Nguyen

Graduate Theses, Dissertations, and Problem Reports (ETD)

In terms of navigation, a central problem in the field of autonomous robotics is obstacle avoidance. This research explores how to navigate as well as avoid obstacles by leveraging what is known of the environment to determine decisions with new incoming information during execution. The algorithm presented in this work is divided into two procedures: an offline process that uses prior knowledge to navigate toward the goal; and an online execution strategy that leverages results obtained offline to drive safely towards the target when new information is encountered (e.g., obstacles). To take advantage of what is known offline, the navigation …

Characterizing Premixed Syngas Combustion In Micro-Channels, Sunita Pokharel

Graduate Theses, Dissertations, and Problem Reports (ETD)

Increasing demands in the next-generation portable power-generation devices such as unmanned aerial vehicles (UAV), microsatellite thrusters, micro-chemical reactors and sensors calls for fuels with high specific energy and low emissions to meet the current demand of green energy. Fuel-lean synthesis gas (syngas) meets both these requirements exhibiting a promising route to a clean and green environment. Thus, it is of critical importance to characterize syngas combustion and understand its properties in the micro-combustion industry. In addition to complicated flame dynamics in microscale systems, varying the syngas-fuel mixture composition as well as the boundary conditions and geometry of a combustor significantly …

Experimental And Field Evaluation Of Frp Pedestrian Bridge Decks, Kalrav Singh Tomer

Graduate Theses, Dissertations, and Problem Reports (ETD)

Traditional materials such as steel, timber, and concrete have continued to dominate their usage in civil infrastructure. They offer great advantages like strength and stiffness but at the same time they pose major issues in terms of durability and maintenance. Fiber reinforced polymer (FRP) exhibits outstanding properties like lightness, excellent corrosion and wear resistance along with superior thermo-mechanical properties. Glass FRPs (GFRPs) have emerged as one of the best alternatives in the field of civil infrastructure. It has been more than four decades since fiber reinforced polymer (FRP) composites have gained notable applications in civil infrastructure industry. However, FRPs have …

Fast Decision-Making Under Time And Resource Constraints, Kyle Gabriel Lassak

Graduate Theses, Dissertations, and Problem Reports (ETD)

Practical decision makers are inherently limited by computational and memory resources as well as the time available in which to make decisions. To cope with these limitations, humans actively seek methods which limit their resource demands by exploiting structure within the environment and exploiting a coupling between their sensing and actuation to form heuristics for fast decision-making. To date, such behavior has not been replicated in artificial agents. This research explores how heuristics may be incorporated into the decision-making process to quickly make high-quality decisions through the analysis of a prominent case study: the outfielder problem. In the outfielder problem, …

Fully Compressible Hydrodynamic Simulation Of Non-Equidiffusive Premixed Flames Propagation In Channels, Olatunde A. Abidakun

Graduate Theses, Dissertations, and Problem Reports (ETD)

Premixed combustion remains of fundamental interest in energy generation and propulsion systems as well as in implementation of safety measures for residential and industrial accidental fire explosions. While the fast pace and complex nature of the combustion process has previously necessitated the analytical and computational studies to employ the simplifying assumption of equidiffusivity, when the Lewis number defined as the thermal-to-mass diffusivities ratio is unity , the ongoing advancements in technology and the requirements for efficiently operating combustors over a wide range of conditions make the combustion process more non-equdiffusive ( ) than ever. The impact of non-equidiffusivity on the …

Oxygen Transport Kinetics Of Surface Modified Mixed Conductor (La0.60sr0.40)0.95co0.20fe0.80o3-X As Solid Oxide Fuel Cell Cathode, Manuel Serrano Laguna

Graduate Theses, Dissertations, and Problem Reports (ETD)

The oxygen transport kinetics of the electrodes of Solid Oxide Fuel Cells (SOFC) are critical properties to achieve higher efficiencies in the cell. (La0.60Sr0.40)0.95Co0.20Fe0.80O3-x (LSCF) is a mixed ion-electron conductor material that is expected to be optimized and utilized as the cathode of the SOFC’s. The reason for LSCF to be considered as the next cathode material for SOFC is due to its high ionic and electronic conductivities, and high oxygen transport kinetics. Additionally, to the excellent properties that this material offers, it has been seen that the kinetic properties of the material can be further optimized by adding a …

Seasons Past: Wildcat Strikes And The Smith-Connally Act During World War Ii, Andrew Robert Mccloskey

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis explores the phenomenon of wildcat strikes during World War II in the United States, the raging public opinion about these wartime strikes, and the passage of the War Labor Disputes Act (popularly known as the Smith-Connally Act) of 1943. Broadly, this thesis examines the wellsprings of working-class anger and frustration which underscored the spontaneous wildcat strikes, the No-Strike Pledge, and the various factions within the public’s perception of these strikes. This thesis furthermore analyzes the congressional debate surrounding the SmithConnally Act and the American public’s reaction to the passage of this restrictive legislation. Finally, this thesis posits that …

Aeroelasticity Of Composite Plate Wings Using Hsdt And Higher-Order Fem, Justin A. Haught

Graduate Theses, Dissertations, and Problem Reports (ETD)

The aeroelasticity of composite wings is becoming an increasingly researched topic in aircraft design, as designers continue to replace aluminum alloy components with those made of composite materials because of their favorable strength-to-weight ratio, fatigue characteristics, and corrosion resistance. Additionally, the bending-torsion coupling exhibited by composite laminates readily allow for the aeroelastic optimization of an aerodynamic structure through the process of aeroelastic tailoring. Wings made of composites materials, however, are more vulnerable to shear deformation.

The objective of the present research is to study the divergence and flutter characteristics of composite plate wings using a higher-order shear deformation theory (HSDT) …

The Costume Design Process For The Phantom Tollbooth, Chloe Elizabeth Cappuccilli

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis will give an account of the costume design process for The Phantom Tollbooth at West Virginia University. Specifically, the responsibilities of the role of Costume Designer, from initial meetings to final production. This document will include research about child psychology that inspired the primary design process, specifically the influence of children’s dreams, and their relationship to toys. This information was utilized to create designs explicitly for children’s theatre audiences. I will present and evaluate the costume designs, including the design evolution until the final production. Detailing the process of costume construction while working with a costume shop. Visual …

Dreams Of Industrial Utopias: Leading Manufacturers Of The Deep South And Their Mill Towns During The Civil War Era, Francis Michael Curran

Graduate Theses, Dissertations, and Problem Reports (ETD)

Broadly speaking, this dissertation explores the intersection of industrialization and social reform in the nineteenth-century American South. It focuses on leading manufacturers of the Deep South and their mill towns during the Civil War era. More precisely, it investigates the relationship between these industrialists, their mill towns, and social reform efforts of the period. In the 1830s, 1840s, and 1850s, William Gregg, Daniel Pratt, and Barrington King created and managed some of the largest and most financially successful manufacturing establishments in the entire South. These men, however, were more than simply industrialists. They were also idealistic and steadfast social reformers …

Leaf Angle And Leaf Stomata Responses To Experimental Drought In Quercus Velutina And Acer Saccharum, Brittany Nichole Casey

Graduate Theses, Dissertations, and Problem Reports (ETD)

The possibility of increased severity and frequency of drought conditions, as a result of global climate variability, greatly complicates our ability to forecast future forest functions such as productivity and carbon sequestration. Assessing how tree species vary in their response to drought can aid in predicting the impact on forest ecosystems as a whole. Throughfall exclusion (TfE) experiments are potentially useful tools to simulate realistic drought conditions within intact forest ecosystems. We employed a TfE experiment during the 2018 growing season within the WV Land Trust’s Elizabeth’s Woods Nature Preserve, near Morgantown, WV, to assess the leaf angle and leaf …

On-Site Measurement Of The Water-Cementitious Ratio And Heat Of Hydration Of Delivered Concrete, Seyednavid Mardmomen

Graduate Theses, Dissertations, and Problem Reports (ETD)

In this study, AASHTO T318-15 was adopted to estimate the water content of fresh concrete mixes and then revised to have better precision. The additional step required sieving out the coarse aggregate after drying the sample in a microwave oven, and it was then used in the calculation of the absorbed water and cementitious material content. Several laboratory batches, as well as on-site water-cementitious (w/cm) ratio tests, were performed on concrete mixes containing ordinary Portland cement, ground granulated blast furnace slag, and Class F fly ash. The results of the experiments indicated that the accuracy of the revised method was …

Field Evaluation Of A Modular Press-Brake-Formed Steel Tub Girder In An Application That Includes Skew And Superelevation, Adam D. Roh

Graduate Theses, Dissertations, and Problem Reports (ETD)

The Short Span Steel Bridge Alliance (SSSBA) is a group of bridge and culvert industry leaders (including steel manufacturers, fabricators, service centers, coaters, researchers, and representatives of related associations and government organizations) who have joined together to provide educational information on the design and construction of short span steel bridges in installations up to 140’-0” in length. A technical working group from within the SSSBA developed the notion for the modular shallow press-brake-formed steel tub girder as a solution for the short span steel bridge market.

After extensive testing at West Virginia University and multiple successful field demonstrations, members of …

An Examination Of The Impacts Of The Wvu Research Apprenticeship Program (Rap), Mostafa Hashemi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Finding solutions to the problem of high attrition rates among students has been widely discussed by policymakers. Many intervention programs have been introduced to address this issue. The current study uses the tripartite integration model of social influence (TIMSI), (Kelman 1958, 1961; Estrada et al., 2011) to investigate and evaluate the effects of the research apprenticeship program (RAP), an intervention program aimed at supporting student performance and persistence through research and mentorship implemented at West Virginia University. The mediation analysis revealed research identity as a significant mediator in the relationship between RAP status and STEM persistence. Furthermore, RAP participants were …

Relating Sonic Velocities, Minimum Horizontal Stress, And Natural Fracture Distribution To Stimulation Efficiency During Completion Of The Marcellus Shale Mip-3h Unconventional Well, West Virginia, Usa, Kaitlin Gayle Evans

Graduate Theses, Dissertations, and Problem Reports (ETD)

Log data from the Marcellus Shale Energy and Environment Laboratory (MSEEL) was acquired along the lateral of the MIP-3H well. This unconventional shale-gas well was completed within the Marcellus Shale just above the Cherry Valley Limestone, a thin limestone member separating organic rich units of the Marcellus. The geomechanical moduli, Poisson’s Ratio (PR) and Young’s Modulus (YME), were generated using compressional and shear sonic logs to indicate zones of increasing brittleness for each of the 28 stages along the 6124 ft. (1867m) horizontal lateral. Brittle reservoir rock is more readily fractured during hydraulic stimulation than more malleable rock. Stages with …

Blind Image Denoising Using Supervised And Unsupervised Learning, Surekha Pachipulusu

Graduate Theses, Dissertations, and Problem Reports (ETD)

Image denoising is an important problem in image processing and computer vision. In real-world applications, denoising is often a pre-processing step (so-called low-level vision task) before image segmentation, object detection, and recognition at higher levels. Traditional image denoising algorithms often make idealistic assumptions with the noise (e.g., additive white Gaussian or Poisson). However, the noise in the real-world images such as high-ISO photos and microscopic fluorescence images are more complex. Accordingly, the performance of those traditional approaches degrades rapidly on real-world data. Such blind image denoising has remained an open problem in the literature.

In this project, we report two …

Reservoir Characterization And Static Earth Modeling For Potential Co2 Storage In Upper Pennsylvanian Cyclothems Of Midcontinent, Usa, Valerie Lynn Smith

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation details the estimation of CO₂ storage volume using reservoir characterization and the building of static earth models in two papers: 1) for Sleepy Hollow Field in Red Willow County, Nebraska and, 2) for Huffstutter Field, Phillips County, Kansas. These models are used to obtain estimates of CO₂ storage capacity in stacked carbonate intervals of the Pennsylvanian Lansing and Kansas City groups (LKC). The LKC constitutes a regional succession of interbedded carbonates and shales. Located over the Cambridge Arch of Nebraska, these interbedded units were evaluated for carbon storage potential. Understanding the occurrence of carbonate porosity among …

Modeling And Tuning Of Cvt Systems For Sae® Baja Vehicles, Sean Sebastian Skinner

Graduate Theses, Dissertations, and Problem Reports (ETD)

Continuously variable transmission (CVT) describes a family of transmission styles. These systems serve the same purpose as their traditional counterparts; transmitting power while offering a variable gearing ratio. The difference lies in the CVT’s ability to change ratio continuously between a minimum and maximum without halting power transfer. They offer many benefits of an automatic transmission while being significantly lighter. For this reason, CVTs are often used on Baja SAE^® vehicles to control gearing ratio.

WVU’s Baja team has used mechanical CVTs for many decades. These systems are simpler in the sense that they don’t require power to operate. …

Genetic Algorithms Used For Search And Rescue Of Vulnerable People In An Urban Setting, Shuhad Aljandeel

Graduate Theses, Dissertations, and Problem Reports (ETD)

The main goal of this research is to design and develop a genetic algorithm (GA) for path planning of an Unmanned Aerial Vehicle (UAV) outfitted with a camera to efficiently search for a lost person in an area of interest. The research focuses on scenarios where the lost person is from a vulnerable population, such as someone suffering from Alzheimer or a small child who has wondered off. To solve this problem, a GA for path planning was designed and implemented in Matlab. The area of interest is considered to be a circle that encompasses the distance the person could …