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Speech Mode Classification Using The Fusion Of Cnns And Lstm Networks, Pratyusha Chowdary Vakkantula

Graduate Theses, Dissertations, and Problem Reports (ETD)

Speech mode classification is an area that has not been as widely explored in the field of sound classification as others such as environmental sounds, music genre, and speaker identification. But what is speech mode? While mode is defined as the way or the manner in which something occurs or is expressed or done, speech mode is defined as the style in which the speech is delivered by a person.

There are some reports on speech mode classification using conventional methods, such as whispering and talking using a normal phonetic sound. However, to the best of our knowledge, deep learning-based …

Development And Implementation Of A Novel Voltage-Free Interface For Capillary Electrophoresis-Mass Spectrometry Separations Of Proteins, Courtney J. Kristoff

Graduate Theses, Dissertations, and Problem Reports (ETD)

Capillary electrophoresis-mass spectrometry is a powerful technique for high-throughput and high efficiency separations combined with structural identification. Electrospray ionization is the primary interface used to couple capillary electrophoresis to mass analyzers; however, improved designs continue to be reported. A new interfacing method based on vibrating sharp-edge spray ionization is presented in this work to overcome the challenges of decoupling applied voltages and to enhance the compatibility with separations performed at near-neutral pH. The versatility and ease of use of this ionization source is demonstrated using β-blockers, peptides, and proteins. The cationic β-blocker pindolol was injected electrokinetically and detected at concentrations …

Understanding Academic Relevancy: Linking Practice To Classroom Through Adventure Stem Education, Alice Morgan

Graduate Theses, Dissertations, and Problem Reports (ETD)

The purpose of this research paper was to examine the relationship between vocational relevancy and adventure STEM education in the context of a four-day adventure STEM camp. Middle school students participated in a variety of adventure activities designed to teach STEM concepts. Using a concurrent triangulation mixed methods design, 246 students completed pre- and post-surveys that assessed changes in attitudes related to STEM interest, career interest, STEM career knowledge, STEM identity, STEM self-efficacy, and STEM value. Fourteen students and eight teachers participated in semi-structured interviews to further examine the role of vocational relevancy in curricula. Overall, results indicate some support …

A Machine Learning Approach To Estimate The Annihilation Photon Interactions Inside The Scintillator Of A Pet Scanner, Sai Akhil Bharthavarapu

Graduate Theses, Dissertations, and Problem Reports (ETD)

Biochemical processes are chemical processes that occur in living organisms. They can be studied with nuclear medicine through the help of radioactive tracers. Based on the radioisotope used, the photons that are emitted from the body tissue are either detected by single-photon emission computed tomography (SPECT) or by positron emission tomography (PET) scanners. SPECT uses gamma rays as tracer but gives a weaker contrast and spatial resolution compared to a PET scanner which uses positrons as tracer. PET scans show the metabolic changes occurring at the cellular level in an organ or a tissue. This detection is important because diseases …

Energy Forensics Analysis, Rupa Das

Graduate Theses, Dissertations, and Problem Reports (ETD)

The energy consumed by a building can reveal information about the occupants and their activities inside the building. This could be utilized by industries and law enforcement agencies for commercial or legal purposes. Utility data from Smart Meter (SM) readings can reveal detailed information that could be mapped to foretell resident occupancy and type of appliance usage over desired time intervals. However, obtaining SM data in the United States is laborious and subjected to legal and procedural constraints. This research develops a user-driven simulation tool with realistic data options and assumptions of potential human behavior to determine energy usage patterns …

Design, Modeling And Optimization Of Reciprocating Tubular Permanent Magnet Linear Generators For Free Piston Engine Applications, Jayaram Subramanian

Graduate Theses, Dissertations, and Problem Reports (ETD)

Permanent Magnet Linear Generators (PMLG) are electric generators which convert the linear motion into electricity. One of the applications of the PMLG system is with free piston engines. Here, the piston is moved by the expander using an internal combustion engine or a Stirling engine. Other applications of the PMLG are wave energy conversion, micro energy harvesters, and supercritical CO₂ expander systems. The most common technology of the electric generators is a rotary electric generator. The current technology of the engine-generators (GENSET) is of a rotary type which uses a crankshaft to convert the linear motion to rotary motion …

Application Of Flowing Material Balance In Unconventional Reservoirs, Salem Alharbi

Graduate Theses, Dissertations, and Problem Reports (ETD)

The application of the horizontal drilling and hydraulic fracturing to unconventional reservoirs, such as Marcellus Shale, has resulted in a significant increase in gas production in the United States. The estimation of the original hydrocarbons in place is an essential element for evaluating the economic success of any reservoir. There are a number of techniques available for estimating the original hydrocarbon in place such as decline curve analysis, volumetric method, and the material balance equation. Flowing Material Balance (FMB) is a more advanced techniques which has become popular in recent years because it does not require static (shut-in) pressure data …

Genetic And Biochemical Characterization Of Ergot Alkaloid Synthesizing Fungi And Their Symbionts, Matthew Duane Maust

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ergot alkaloids are fungal tryptophan derived toxins which affect mammalian circulation and neurotransmission. These compounds are biosynthesized by a conserved genetic pathway, known as the ergot alkaloid synthesis (EAS) pathway by fungi belonging to the ascomycete families Trichocomaceae and Clavicipitaceae. Several Ipomoea species and related plants in the morning glory family harbor vertically transmitted symbiotic fungi in the genus Periglandula, also members of Clavicipitaceae, that produce ergot alkaloids. Metabolomic analysis of seeds identified a previously uncharacterized glycoside form of the pharmaceutically important ergot alkaloid, ergonovine. Several species belonging to the fungal genus Metarhizium have recently been shown to have the …

Effect Of Particle Concentration, Sealing Condition And Breathing Rate On Total Inward Leakage For N95 Filtering Facepiece Respirators, Taoreed T. Lawal

Graduate Theses, Dissertations, and Problem Reports (ETD)

Several researchers have considered the relationship between total inward leakage (TIL) and other parameters such as sealing condition, particle concentration, type of particulate material breathing parameters, etc., however, there is dearth of information on the effects of varying particle concentration on the penetration efficiency of filtering facepiece respirators (FFRs), hence, this study aims to study the effect of varying NaCl particle concentration, sealing condition and breathing rate on the TIL as a result of the filtering efficiency of the filters.

To achieve this, we followed the sampling procedure used by He et al., 2014. Four different sealing conditions (SCs) namely; …

Microbial Responses To Unconventional Oil And Gas Development May Alter Ecosystem Function In Headwater Streams, Rachel Michaels

Graduate Theses, Dissertations, and Problem Reports (ETD)

The demand for natural gas, and the need for efficient extraction, has led to the development of unconventional oil and natural gas (UOG) techniques. Due to the novelty of UOG, the potential impacts to freshwater ecosystems are not fully understood. We used a dual pronged approach to study the effects of UOG development on microbial biodiversity and function via a laboratory microcosm experiment and a survey study of streams with and without UOG development within their watersheds. The laboratory microcosm study simulated stream contamination with produced water, a byproduct of UOG operation, using sediment collected from one high water-quality stream …

Investigation Of Phonon Polaritons In An Hbn Gan Heterostructure, Catherine G. O'Hearn

Graduate Theses, Dissertations, and Problem Reports (ETD)

There have been many great advances in the generation and manipulation of optics in the visible and near infrared (IR) range over the past decade. This is largely due to plasmonic enhancement, which has led to new technology in biosensing and molecule detection, solid-state lighting, and solar energy harvesting. The field of plasmonics uses quanta of plasma oscillations, plasmons, formed from the interaction between electromagnetic radiation and free electrons to enhance optical near field magnitudes. However, there is still a large region of the electromagnetic spectrum, covering the mid-infrared (MIR) and terahertz (THz) regions, ranging from 3 μm to 1 …

Paleoecological Successions From Shallow-Marine Depositional Environments In Upper Silurian Carbonate Rocks Of Blair County, Pennsylvania, Shadya El-Ashkar

Graduate Theses, Dissertations, and Problem Reports (ETD)

Studies of paleoenvironment and paleoecology are important for investigating relationships between the different environmental and biological variables that influenced biodiversification patterns during the Silurian Period. The mixed carbonate and siliciclastic rocks of the Bloomsburg and Mifflintown Formations in central Pennsylvania represent transitions between carbonate ramp and deltaic settings. The goal of this study was to assess changes in depositional environment and paleoecology of an undescribed Bloomsburg/Mifflintown locality in Bellwood, Pennsylvania. In central Pennsylvania, the interfingered relationship of mixed carbonate and siliciclastic mudstones of the Mifflintown Formation with red fine-grained sandstones and shales of the Bloomsburg Formation presented challenges for deciphering …

Experimental And Computational Exploration Of The Dilute Magnetic Delafossite Cual1-Xfexo2 Alloys, Mina Aziziha

Graduate Theses, Dissertations, and Problem Reports (ETD)

CuAlO₂ is among several ternary delafossites, which is a rare p-type semiconductor with potential applications as a transparent conductive oxide, photocatalyst, and spintronics when doped with transition metal ions. Reported in this thesis are results from our investigations of CuAl_1-xFe_xO₂ (x = 0 to1) with a focus on the x-dependence of structural, magnetic, vibrational, optical properties, and the role of defects and impurities. Samples are prepared by solid-state reactions.

We performed a complete study of magnetic properties to investigate the possibility of room temperature ferromagnetic alloys, which are used in …

Silver-Mediated Decarboxylation Reactions: Expanding Reaction Scope Through Kinetic Analysis, Robert Anthony Crovak

Graduate Theses, Dissertations, and Problem Reports (ETD)

Transition metal-catalyzed decarboxylative coupling reactions have received considerable attention in recent years as a method to obtain biaryl compounds. However, the oxidative version of this reaction class is still in its infancy, limited to specific substitution patterns on the benzoic acids – ortho-substitution - used in these transformations. This thesis describes our attempts to understand the key decarboxylation step of this important class of reactions. The first chapter of this thesis discusses an introduction into cross-coupling reactions, decarboxylative cross-coupling reactions, and outlines relevant physical organic parameters. The following chapter details the synthesis of a series of (1,10-phenanthroline)silver(benzoate) complexes. This chapter …

Mechanistic Analysis Of Reductive Boracarboxylation Using Low Valent Copper And Co2, Notashia Nicole Baughman

Graduate Theses, Dissertations, and Problem Reports (ETD)

The synthesis of organoboron compounds is of contemporary importance in the chemistry community given their utility in subsequent functionalization reactions as well as their growing therapeutic potential in the treatment of human disease. This, coupled with the ubiquity of carboxylic acid functional groups in pharmaceuticals and fine chemicals, has led to interest in one-pot difunctionalization reactions using CO₂ and a boron source. An (ICy)copper(I)-catalyzed boracarboxylation reaction was recently developed wherein CO₂ and a pinacolboryl group is added across the double bond of vinyl arenes was recently developed, providing access to α-aryl-β-boryl propionic acid derivatives. A subsequent publication detailed …

Cerebrovascular Dysfunction And Degeneration In Alzheimer’S Disease Pathophysiology, Dominic Dimitri Quintana

Graduate Theses, Dissertations, and Problem Reports (ETD)

Alzheimer’s disease (AD) is a terminal illness and the most common form of dementia, which disproportionately affects the aged population. The pathophysiology of AD is characterized by neurodegeneration that slowly progresses, affecting regions of the brain that are involved in learning, memory, language, and executive function. In patients with the disease, early symptoms include non-disruptive forgetfulness that evolves into the inability to form new memories and ultimately the loss of autonomy at late stages. Histopathological hallmarks in the brain from patients with AD is the presence of amyloid-β (Aβ)-plaques and neurofibrillary tangles (NFT) deposited in the parenchyma. Since the discovery …

Solutions To Some Mine Subsidence Research Challenges, Jian Yang

Graduate Theses, Dissertations, and Problem Reports (ETD)

The objective of this work is to address three challenging topics, (1) effects of overburden key strata on subsurface subsidence; (2) effects of longwall subsidence on interstate highways and highway bridges; and (3) effects of dewatering mine water on surface subsidence over inactive room-and-pillar mines, in mine subsidence and to continue improvement of mine safety and health by reducing mine-subsidence related hazards.

Surface and subsurface subsidence events induced by underground mining activities are often capable of causing significant disturbances not only to surface structures, but also to subsurface structures. In this work, models and techniques to study three challenging topics …

Effect Of Western Diet And Caloric Substitution With Apple Pomace On Fatty Acid Composition And Gene Expression In The Hypothalamus Of Growing Female Sprague-Dawley Rats, Ayad Abdulhamid Alawadi

Graduate Theses, Dissertations, and Problem Reports (ETD)

The hypothalamus plays a major role in regulating food-intake and energy-expenditure. Hypothalamic dysfunction implicated in neurodegenerative diseases is characterized by diet-induced neuroinflammation and energy dysregulation. Apple pomace, a waste byproduct of processing, is rich in polyphenols and soluble fibers, has the potential to ameliorate diet-inducing inflammation. The objective of this study was to determine the effects of Western diet and caloric substitution of Western diet with 10% apple pomace on brain fatty acid composition and gene expression related to hypothalamic function and health in growing female rats. Growing female Sprague-Dawley rats (age 22-29 days) were randomly assigned (n=8 rats/group) to …

Protein/Peptide Characterization Using Mass Spectrometry And Molecular Dynamics Simulations, Ahmad Kiani Karanji

Graduate Theses, Dissertations, and Problem Reports (ETD)

Mass spectrometry (MS) based-techniques and molecular dynamics (MD) simulations have been used to characterize protein/peptide structure as well as their interactions with lipid vesicles and detergents. Chapter 1 introduces an introduction to the concepts and tools that were used in this work. In Chapter 2, the dominant gas-phase conformer of [M+3H]3+ ions of the model peptide Acetyl-PSSSSKSSSSKSSSSKSSSSK are examined with ion mobility spectrometry (IMS), gas-phase hydrogen deuterium exchange (HDX), and mass spectrometry (MS) techniques. This section furthers the development of a protein structural prediction tool by providing information about gas-phase ion conformers of two model peptides having different solution conformational …

Palmprint Gender Classification Using Deep Learning Methods, Minou Khayami

Graduate Theses, Dissertations, and Problem Reports (ETD)

Gender identification is an important technique that can improve the performance of authentication systems by reducing searching space and speeding up the matching process. Several biometric traits have been used to ascertain human gender. Among them, the human palmprint possesses several discriminating features such as principal-lines, wrinkles, ridges, and minutiae features and that offer cues for gender identification. The goal of this work is to develop novel deep-learning techniques to determine gender from palmprint images. PolyU and CASIA palmprint databases with 90,000 and 5502 images respectively were used for training and testing purposes in this research. After ROI extraction and …

Development Of New Synthetic Methods For Carbon Nanohoops, Merfat Aljhdli

Graduate Theses, Dissertations, and Problem Reports (ETD)

Carbon nanotubes have received much attention from the material chemists after the synthesis and structure analysis by Iijima in 1991. It was envisioned that cycloparaphenylenes (CPPs), which comprise a sequence of benzene units connected at para position to make a cyclic ring structure, are possible templates for growing carbon nanotubes of a single chirality and single diameter for nanotechnology application. Recently, chemists turned their attention to synthesizing aromatic carbon nanobelts proposed as a general term for carbon molecules composed of fused benzene rings in cylindrical structure shape. Cyclophenacenes (CPAs) as carbon nanobelts are expected to be more suitable candidates for …

Global Existence And Asymptotic Behavior Of The Solutions To Models For Chemotaxis Systems With Chemo Attractants And Repellents, Aesha Lagha

Graduate Theses, Dissertations, and Problem Reports (ETD)

We study global existence and asymptotic behavior of the solutions to models for chemotaxis systems with chemo attractants and repellents in three dimensions. Chemo attractants and repellents may be called chemo agents. For Part I, we use the logistic model for the mass. The interactions between chemo agents and the mass are taken into account. For Part II, we consider the case when mass is conserved and we use the Lotka-Volterra type model for chemo agents. To accomplish this, we use the Fourier transform and energy method. We show the existence of global solutions by the energy method. Also, we …

Behavior Coaching In Pennsylvania Schools Implementing School-Wide Positive Behavior Interventions And Supports At The Universal Tier One Level, Lisa Anderson

Graduate Theses, Dissertations, and Problem Reports (ETD)

School-Wide Positive Behavior Interventions and Supports (SWPBIS) is a multi-tiered system of student support that emphasizes the use of positive behavior strategies for a school’s students. Schools are adopting SWPBIS because it gives staff the opportunity to teach desired behaviors to students and emphasizes the enhancement of instructional time by minimizing disruptions. SWPBIS uses a support framework that includes a building-level behavior coach and a core team made up of an administrator, parent(s), and professional school staff. Staff and student training is bridged with implementation efforts to sustain a positive school climate and prevent student behavior problems. The SWPBIS coach …

Evaluation Of Object Attributes To Study Speed-Accuracy Trade-Off Of Gloves Using Iso 9241-411 Standard, Isha Gaut

Graduate Theses, Dissertations, and Problem Reports (ETD)

Selection of appropriate gloves plays an important role in the overall comfort and productivity of workers. Currently, there are no standards and/or guidelines available to systematically evaluate the glove performance based on speed-accuracy trade-off. The ISO 9241-411 standard which is based on Fitts’ Law has been extensively used in the literature to measure speed-accuracy trade-off in terms of throughput in the virtual environments. This study was aimed at developing guidelines for implementing ISO 9241-411 standard in the physical environment so that it can be used to estimate (and compare) throughputs of safety gloves. Specifically, the various physical attributes of objects …

The Effects Of Membrane Physicochemical Properties On Huntingtin Membrane Association And Downstream Aggregation, Maryssa Beasley

Graduate Theses, Dissertations, and Problem Reports (ETD)

Huntington’s Disease (HD) is a fatal neurodegenerative disorder caused by an expanded glutamine repeat region (polyQ) within the huntingtin protein (htt). As a result of the expanded polyQ domain, htt associates into a variety of toxic aggregate species. The polyQ domain of htt is flanked at the N-terminal end by 17 amino acids (Nt17) that adopt an amphipathic α-helical structure in the presence of binding partners such as lipid membranes. In addition to comprising a lipid binding domain, the Nt17 amphipathic α -helix has been directly implicated in htt aggregation initiation via self-association with other Nt17 α -helices. Due to …

Modeling Of Rotary Packed Beds For Reactive And Non-Reactive Systems, Chinyere Evangeline Ezeobinwune

Graduate Theses, Dissertations, and Problem Reports (ETD)

Rotary packed beds (RPBs) are used in a wide range of reactive and non-reactive applications. In this research, a 2-d, first-principles, dynamic model of a non-reactive RPB that is used for heat exchange between the outgoing flue gas from a power plant and the incoming air to the boiler/pulverizer of the power plant is developed. A 2-d, first-principles model of a reactive RPB is developed where a functionalized metal-organic framework (MOF) is used for CO₂ capture.

For the non-reactive system, a Ljungstrom-type air preheater (APH) is considered. Existing models for these rotating heat exchangers are typically 1-d. There are …

Using The Enrichment Triad Model To Explore Place And Support Curriculum In One Rural Gifted Program, Myriah Mae Miller

Graduate Theses, Dissertations, and Problem Reports (ETD)

Using narrative inquiry, this case study explored how one teacher, who had deep connections to place, learned and utilized the place-based Enrichment Triad in her rural Appalachian elementary gifted program. Data collected included teacher, student, and parent interviews and classroom observations. Data were analyzed using a socio-cultural narrative analysis and narrative thematic analysis. Results from analysis created thick descriptions of the teacher’s journey to teaching, her existing practices, her experiences learning and implementing the framework, and her future curricular intentions. Developments in the teacher’s practice included establishment of scope and sequence, a sharing of power, and embracing students’ identities through …

Depth Dependent Atomic Valence Determination In La0.7sr0.3mno3 Thin Films Using Synchrotron Techniques, Robbyn B. Trappen

Graduate Theses, Dissertations, and Problem Reports (ETD)

The valence of atoms often has a strong effect on the properties of materials, such as magnetism, conductivity, and superconductivity. The atomic valence is often perturbed at the surface and/or interface and this deviation may play a strong role in many physical phenomena such as interfacial coupling and dead layers, both magnetic and electric. In this dissertation, I present a non-destructive approach of combining two X-ray absorption detection modes, electron yield and fluorescence, with very different probing depths in conjunction with theory to map out the layer-by-layer valence of a thin film.

The weighted average Mn atomic valence as measured …

A Deep Dive Into The Land Development Dynamics Of A Complex Landscape, Pariya Pourmohammadi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Land development is a complex and dynamic process simultaneously interacting with numerous environmental, cultural and economic procedures. In this research we studied past, present and future of land transformation in Appalachia. This dissertation is organized in three-essay format and each essay is focused on one aspect of land development processes in a sub-region in the Appalachian region. In the first essay, deep learning techniques are used to build predictive models for the land development. This study presets deconvolutional neural networks models in predicting land development. On the second essay, spatial data analysis and remote sensing are used to investigate the …

Three Essays On Water Economics, Fahad Alzahrani

Graduate Theses, Dissertations, and Problem Reports (ETD)

This dissertation consists of three essays that explore the impacts of changes in public water quality, reliability, and raw water source. The first essay explores the relationship between episodes of contaminated drinking water and health care expenditures in the United States. Using panel data from 48 contiguous states from 2000 to 2011 and spatial econometrics modeling methods, the results indicate that there is positive and statistically significant impact on per capita health care expenditures from the percentage of a state’s population exposed to contamination episodes. The second essay examines the problem of water supply reliability due to aging infrastructure of …