Digital Commons Network^™

Dynamic Optimization Algorithms For Baseload Power Plant Cycling Under Variable Renewable Energy, Rebecca Hyen Hae Kim

Graduate Theses, Dissertations, and Problem Reports (ETD)

The growing deployment of variable renewable energy (VRE) sources, such as wind and solar, is mainly due to the decline in the cost of renewable technologies and the increase of societal and cultural pressures. Solar and wind power generation are also known to have zero marginal costs and fuel emissions during dispatch. Thereby, the VRE from these sources should be prioritized when available. However, the rapid deployment of VRE has heightened concerns regarding the challenges in the integration between fossil-fueled and renewable energy systems. The high variability introduced by the VRE as well as the limited alignment between demand and …

Photochemical Motion Control Of Belousov-Zhabotinsky Droplets And Turbulence-Like Patterns In The Aluminum Hydroxide Precipitation System, Syed Jazli Syed Jamaluddin

Graduate Theses, Dissertations, and Problem Reports (ETD)

A Belousov-Zhabotinsky (BZ) droplet that is immersed in an oil-phase can self-propel due to a surface tension gradient that exists on the droplet surface. The surface tension gradient is created as a result of the reactions that occur within and on the surface of the BZ droplet. By affecting the rates of these reactions, the BZ droplet direction can be controlled. In our experiments, we tune the reactions that occur within and on the BZ droplet surface by imposing a light intensity gradient on the droplet. We analyzed the BZ droplet motion and demonstrated that we can control the droplet …

Enabling Technologies For Medicinal Chemistry And Synthesis: I. Cannabinoids; Ii. Illudalic Acid; Iii. Microwave Chemistry, Harvey Fulo

Graduate Theses, Dissertations, and Problem Reports (ETD)

Innovations in synthetic organic chemistry such as methodology improvements, new chemical transformations and technology development significantly impact medicinal chemistry and continue to drive the drug discovery process. Here, new cyclization strategies to the pharmaceutically underexplored 3,3-dimethylcyclopentane-fused aromatic rings are described. One approach highlighted oxidative cycloisomerization, intermolecular [2+2+2] cyclotrimerization and 5-exo-dig cyclization providing indanoylindole cannabinoids that possess high affinity for human CB₂ receptors at nanomolar concentration and good selectivity index. Another featured a [4+2]-type benzannulation reaction which enabled the 5-step synthesis of illudalic acid — compared to the current available sequences (≥16 steps) — and its equipotent and LAR-selective analogs. …

Dynamic Modelling And Control Of Grid-Level Energy Storage Systems, Sai Pushpitha Vudata

Graduate Theses, Dissertations, and Problem Reports (ETD)

The focus of this work is on two energy storage technologies, namely pumped storage hydroelectricity (PHS) and secondary batteries. Under secondary battery technologies, two potential technologies for grid-scale storage, namely high-temperature sodium-sulfur (NaS) battery and vanadium redox flow battery (VRFB), are investigated. PHS is a largescale (>100 MW) technology that stores and generates energy by transporting water between two reservoirs at different elevations. The goal is to develop a detailed dynamic model of PHS and then design the controllers to follow the desired load trajectory accurately with high efficiency. The NaS battery and VRFB are advanced secondary batteries which …

A Systematic Method For Measuring Gentrification Using Building Permits Data: A Washington D.C Case Study, Andey Fomil

Graduate Theses, Dissertations, and Problem Reports (ETD)

Gentrification can significantly alter the socioeconomic, demographic, and commercial aspects of a city. It is a complex process that transforms the characteristics of entire neighborhoods, modifying not only the observable physical aspects, but also the community structure. Traditional quantitative gentrification measurement approaches assess the process through analysis of Census demographic indicators coupled with field visit analysis of the physical built environment. This study proposes a new gentrification measuring approach that combines traditional Census indicators with a new indicator in the form of City Building Permits. Two GIS spatial analysis techniques are utilized to evaluate the effectiveness and accuracy of the …

Examining Changes In Learning And Engagement Of Higher Education Students In A Fully Online Flipped Learning Distance Education Classroom, James David Riel

Graduate Theses, Dissertations, and Problem Reports (ETD)

The challenge of implementing effective online distance education courses for academics and institutions is a centuries-old task. We can look across early developments in the 18^th century with the creation and delivery of correspondence courses; into the 20^th century with teaching and learning across analog methods such as audio and video; and now in the current era of digitized mechanisms that enable the online classroom. This includes advances in internet technologies and computing abilities that are the empowering the backbone processes, bridging connectivity between the student and the instructor. As society has trended toward massive increases in online …

Quantifying The Impact Of Load-Following On Gas-Fired Power Plants, Yifan Wang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Due to rapid penetration of renewables into the grid, natural gas combined cycle (NGCC) power plants are being forced to cycle their loads more frequently and rapidly than for which they were designed. However, the impact of load-following operation on plant efficiency and equipment health are currently poorly understood. The objective of this work is to quantify the impact of load-following on the gas-fired plants by developing high-fidelity multi-scale dynamic models. There are four main tasks in this project. First, dynamic model of an NGCC power plant has been developed. The main components of the NGCC plants are the gas …

Analysis Of Cell Signaling Perturbations In Response To Chronic Localized Infections, Amber Nicole Prince

Graduate Theses, Dissertations, and Problem Reports (ETD)

The tissue-level response to pathogens involves an intricate series of signal transduction events, influenced by immune and healing mediators that alert the host to danger and eliminate the infection. Disruptions to normal signaling events can compromise the host’s ability to respond and lead to the development of chronic infections that cannot be resolved without clinical intervention. Prolonged inflammation due to chronic infection can damage tissues and compromise healing processes, thus, the interactions of immune and healing mediators in signaling cascades are intimately linked to tissue health outcomes. Studying signaling networks relevant to these responses provided a more thorough understanding of …

Single And Multi-Photon Laser Induced Fluorescence For Electric Thruster And Fusion Applications, Thomas E. Steinberger

Graduate Theses, Dissertations, and Problem Reports (ETD)

Single and Multi-photon Laser Induced Fluorescence for Electric Thruster and Fusion Applications

Thomas Edward Steinberger

Laser-based diagnostics are increasingly sought after to investigate a variety of plasmas due to their non-perturbative capabilities. Specifically, laser induced fluorescence (LIF) provides a highly localized and precise spectroscopic technique to measure absolute density, temperature, and bulk flow. In this work, LIF and two-photon absorption laser induced fluorescence (TALIF) are used to investigate electric propulsion and fusion-relevant plasmas, respectively. Ion velocity distribution functions (IVDF) of singly ionized atomic iodine (I II) are measured for the first time and lineshape characteristics are presented for the diagnosis …

Experimental Investigations Of Contact Friction And Transport Properties Of Monolayer And Bilayer Graphene, Prakash Gajurel

Graduate Theses, Dissertations, and Problem Reports (ETD)

Results obtained from experimental investigations of contact friction in monolayer and bilayers graphene and the related effects on their transport properties are presented here along with their discussion and interpretation. For this purpose, chemical vapor deposited (CVD) graphene samples on SiO₂/Si were prepared. The samples were characterized by atomic force microscopy (AFM), Raman and X-ray photoelectron spectroscopy (XPS). Summaries of the results are given below.

Defects-controlled friction in graphene is of technological importance but the underlying mechanism remains a subject of debate. The new results obtained from the analysis of lateral force microscopy images revealed that the contact …

Perceptions And Instructional Practices Used By West Virginian Secondary Agricultural Teachers In Meat Science Education, Kindra D. Carr

Graduate Theses, Dissertations, and Problem Reports (ETD)

A focus on classroom integration of science, technology, engineering, and math (STEM) concepts has resulted in secondary teachers broadening the scope and delivery of STEM principles in their classes. Because agriculture classes allow students to convert abstract ideas into concrete ideas, they provide a useful setting to teach STEM concepts. Using secondary agricultural classes to teach science is effective and has contributed to higher standardized science test scores, as opposed to a science class alone. West Virginia is known for meat processing facilities and meat technology learning activities in its public schools. However, little is known about how the content …

Development Of Collision Resilient Drone For Flying In Cluttered Environment, Al Mahmud

Graduate Theses, Dissertations, and Problem Reports (ETD)

The use of multi-rotor aerial vehicles, also known as drones, has increased significantly in the last decade due to their ease of use and applicability to an extended range of functions. Therefore, the importance of making these vehicles safe, for both themselves and the people around them, has also increased. A clear solution to this problem is the development of algorithms that generate collision-free paths using different sensors. However, even with such onboard computation, avoiding a collision is not always possible. Thus, the use of a protective structure (cage) around the aerial vehicle is a solution to keep it safe …

Application Of 3d Seismic Signal And Geomechanical Attributes For Subsurface Fracture Characterization: A Case Study In Clearfield County, Central Pennsylvania, Iman F. Zulkapeli

Graduate Theses, Dissertations, and Problem Reports (ETD)

Hydrocarbon exploration in unconventional reservoirs is highly risky due to the nature of the reservoirs and the variability in fractures and reservoir geomechanical properties in the subsurface. The reservoir needs to be fully characterized to avoid any complication such as frac hit, wellbore failure, blowout, or even a dry hole. The Clearfield reservoir produces an exceptionally low amount of gas, compared to the neighboring region in the proximity, which has been poorly understood. This raises the question as to what causes the reservoir to have low productivity.

This study focuses on the natural fracture characterization using high-quality 3D seismic signal …

Refining The Sedimentology And Geochemistry Of The Mid-Permian Blaine Formation Of The Rebecca K. Bounds Core From Greeley County, Kansas, Brigitte Petras

Graduate Theses, Dissertations, and Problem Reports (ETD)

Red siliciclastics and evaporites of Permian Nippewalla Group in mid-continental US were deposited in western equatorial Pangea. Previous studies of these rocks record Permian air temperatures as high as 73 °C, saline lake waters with a pH as low as ~1, and sedimentology that shows arid conditions. This current study conducts detailed sedimentological observations and geochemical analyses of the Blaine Formation of the Nippewalla Group. The Rebecca K. Bounds core from west-central Kansas is used to interpret the depositional environments and diagenetic history of the Blaine Formation.

The lithologies of the Blaine Formation, listed in order of most to least …

Pulsar Noise Processes And Emission Physics, Brent Jacob Shapiro-Albert

Graduate Theses, Dissertations, and Problem Reports (ETD)

Precision pulsar timing can be used to study many different astrophysically interesting phenomena, from the emission mechanism of pulsars to the detection of nanohertz gravitational waves. These analyses span topics such as studying the single pulses of pulsars and analyzing years of pulsar timing data from pulsar timing arrays (PTAs). Single-pulse studies allow us to glean information on the emission physics of pulsars on their shortest timescales, while PTA observations of millisecond pulsars (MSPs) allow us to not only study the pulsars themselves, but also probe the interstellar medium (ISM) and constrain the noise in the data for precision pulsar …

Identifying The Technical And Teacher Skills Needed By In-Service Teachers To Effectively Teach An Agricultural Mechanics Course In West Virginia, Coleton Todd Payne

Graduate Theses, Dissertations, and Problem Reports (ETD)

Agricultural mechanics remains one of the largest content sections in school-based agriculture education (SBAE). Therefore, in-service and pre-service teachers need to be effective in teaching agricultural mechanics to their students (Burris et al., 2005; Hainline & Wells, 2019). A number of studies (McKim & Saucier, 2011; Saucier et al., 2014) have identified the importance of safety in agricultural mechanics laboratories, but not the content skills specifically needed to teach the courses. The only areas of content that most new in-service teachers possess are those of basic woodworking and basic metal working. This study bases its theoretical framework off of the …

Multimodel Operability Framework For Design Of Modular And Intensified Energy Systems, Vitor Gazzaneo

Graduate Theses, Dissertations, and Problem Reports (ETD)

In this dissertation, a novel operability framework is introduced for the process design of modular and intensified energy systems that are challenged by complexity and highly constrained environments. Previously developed process operability approaches are reviewed and further developed in terms of theory, application, and software infrastructure. An optimization-based multilayer operability framework is introduced for process design of nonlinear energy systems. In the first layer of this framework, a mixed-integer linear programming (MILP)-based iterative algorithm considers the minimization of footprint and achievement of process intensification targets. Then, in the second layer, an operability analysis is performed to incorporate key features of …

Fundamentals And Applications Of Charge Transfer Dissociation Mass Spectrometry, Zachary Joseph Sasiene

Graduate Theses, Dissertations, and Problem Reports (ETD)

The recent surge in the analysis of biomolecules has driven the need for robust, versatile, sensitive, and accurate techniques such as tandem mass spectrometry for compound structural elucidation. Many fragmentation techniques have been developed over the years, but each has their own limitations, such as the loss of post-translational modifications (PTMs), inability to fragment singly charged precursor ions or cost prohibitiveness. To help fill this gap, a novel fragmentation technique called charge transfer dissociation (CTD) has been developed to fragment stored precursor ions through radical-driven fragmentation processes using kiloelectronvolt reagent cations. CTD has shown success in the analysis of proteins, …

Ecology Of Freshwater Turtles And Other Wetland Wildlife In A North-Central West Virginia Watershed, Darien N. Lozon

Graduate Theses, Dissertations, and Problem Reports (ETD)

The goal of wetland mitigation in the United States is to achieve a no-net-loss of wetlands; however, mitigated wetlands must be monitored to ensure wetland function is comparable to natural wetlands. In this study, relationships between land use practices and freshwater turtle abundance, wetland connectivity, and heavy metal bioaccumulation were investigated. In Chapter 1, a summary of pre-restoration species abundance and diversity is provided for anurans, birds, benthic macroinvertebrates, fishes, small mammals, plants, and turtles in riparian wetlands along Ruby Run, a tributary of Deckers Creek in north-central West Virginia, USA. These data provide a baseline for comparison after mitigation …

Variations In Produced Water Chemistry And Relation To Regional Geology And Production In The Marcellus Shale, Northcentral West Virginia, Jonathan M. Brady

Graduate Theses, Dissertations, and Problem Reports (ETD)

An investigation of 74 Marcellus Shale wells across northcentral West Virginia indicates changes in produced water chemistry and quantity can be related to geologic conditions based on well logs and core data. These changes are determined by reviewing multiple produced water analyses for individual wells for periods up to ten years. Results show variations among the areas in this study. From west to east across central Harrison County to central Taylor County, then north into Monongalia County, gamma-ray logs show increasing intensity, especially in the middle and lower Marcellus. XRD mineralogy from core data shows increasing clay content from west …

Environmental Controls On The Terrestrial Water Cycle In Forested Mountain Ecosystems., Luis Andrés Guillén

Graduate Theses, Dissertations, and Problem Reports (ETD)

Water is a key resource to natural ecosystems and human societies alike, and the water cycle is fundamentally linked to the climate and the characteristics of catchments. However, the challenges posed by environmental change makes it imperative to understand how the water cycle is affected by biotic and abiotic factors, in particular, in areas that are crucial sources of water like forested headwater catchments. Therefore, this doctoral dissertation aims to advance the knowledge on the dynamics between climate, vegetation and landscape that determine the water balance of forested mountain ecosystems. This document presents five chapters, an introductory chapter, three standalone …

Synthesis Of Graphene Using Plasma Etching And Atmospheric Pressure Annealing: Process And Sensor Development, Andrew Robert Graves

Graduate Theses, Dissertations, and Problem Reports (ETD)

Having been theorized in 1947, it was not until 2004 that graphene was first isolated. In the years since its isolation, graphene has been the subject of intense, world-wide study due to its incredibly diverse array of useful properties. Even though many billions of dollars have been spent on its development, graphene has yet to break out of the laboratory and penetrate mainstream industrial applications markets. This is because graphene faces a ‘grand challenge.’ Simply put, there is currently no method of manufacturing high-quality graphene on the industrial scale. This grand challenge looms particularly large for electronic applications where the …

Impacts Of Bike Sharing On Transit Ridership, Moathe Salah Aljeri

Graduate Theses, Dissertations, and Problem Reports (ETD)

Biking is an active, environmentally friendly, and sustainable transportation mode that facilitates short utilitarian and recreational trips. As such, cities around the world have been implementing bicycle sharing/renting programs at stations in a wide network so that a traveler can mount one close to their origins and drop it off at a station nearest to their destinations. In addition, bike sharing programs can solve the first-mile and last-mile connectivity problems of transit modes. Such programs also enable short trips that were previously impossible without using transit modes. This research investigated the relationship between New York City (NYC) subway ridership and …

Development Of New Synthetic Methods For Carbon Nanohoops, Merfat Aljhdli

Graduate Theses, Dissertations, and Problem Reports (ETD)

Carbon nanotubes have received much attention from the material chemists after the synthesis and structure analysis by Iijima in 1991. It was envisioned that cycloparaphenylenes (CPPs), which comprise a sequence of benzene units connected at para position to make a cyclic ring structure, are possible templates for growing carbon nanotubes of a single chirality and single diameter for nanotechnology application. Recently, chemists turned their attention to synthesizing aromatic carbon nanobelts proposed as a general term for carbon molecules composed of fused benzene rings in cylindrical structure shape. Cyclophenacenes (CPAs) as carbon nanobelts are expected to be more suitable candidates for …

Navigation Under Obstacle Motion Uncertainty Using Markov Decision Processes, Jennifer Quyen Nguyen

Graduate Theses, Dissertations, and Problem Reports (ETD)

In terms of navigation, a central problem in the field of autonomous robotics is obstacle avoidance. This research explores how to navigate as well as avoid obstacles by leveraging what is known of the environment to determine decisions with new incoming information during execution. The algorithm presented in this work is divided into two procedures: an offline process that uses prior knowledge to navigate toward the goal; and an online execution strategy that leverages results obtained offline to drive safely towards the target when new information is encountered (e.g., obstacles). To take advantage of what is known offline, the navigation …

Investigation Of Phonon Polaritons In An Hbn Gan Heterostructure, Catherine G. O'Hearn

Graduate Theses, Dissertations, and Problem Reports (ETD)

There have been many great advances in the generation and manipulation of optics in the visible and near infrared (IR) range over the past decade. This is largely due to plasmonic enhancement, which has led to new technology in biosensing and molecule detection, solid-state lighting, and solar energy harvesting. The field of plasmonics uses quanta of plasma oscillations, plasmons, formed from the interaction between electromagnetic radiation and free electrons to enhance optical near field magnitudes. However, there is still a large region of the electromagnetic spectrum, covering the mid-infrared (MIR) and terahertz (THz) regions, ranging from 3 μm to 1 …

Evaluation Of Fitts’ Throughput As A Possible Performance Measure For Manual Assembly Tasks, Pradyumna Bettagere Jagadish

Graduate Theses, Dissertations, and Problem Reports (ETD)

Assembly lines are the backbone of the manufacturing sector. Workers at the assembly lines are expected to perform fast pace hand-arm exertions with precision and accuracy. To protect the workers from injuries, OSHA mandates the use of personal protective equipment (PPE) including gloves. Certain assembly operations require the use of special gloves. Some of these gloves can inhibit hand performance, further increasing the task difficulty. The Index of Difficulty (ID) is a metric measured in ‘bits’ quantifies task difficulty through the quotient of target width and target motion, i.e., distance travelled. The time required to complete the target motion is …

Cerebrovascular Dysfunction And Degeneration In Alzheimer’S Disease Pathophysiology, Dominic Dimitri Quintana

Graduate Theses, Dissertations, and Problem Reports (ETD)

Alzheimer’s disease (AD) is a terminal illness and the most common form of dementia, which disproportionately affects the aged population. The pathophysiology of AD is characterized by neurodegeneration that slowly progresses, affecting regions of the brain that are involved in learning, memory, language, and executive function. In patients with the disease, early symptoms include non-disruptive forgetfulness that evolves into the inability to form new memories and ultimately the loss of autonomy at late stages. Histopathological hallmarks in the brain from patients with AD is the presence of amyloid-β (Aβ)-plaques and neurofibrillary tangles (NFT) deposited in the parenchyma. Since the discovery …

Neuromechanical Tuning For Arm Motor Control, Russell Lee Hardesty Jr

Graduate Theses, Dissertations, and Problem Reports (ETD)

Movement is a fundamental behavior that allows us to interact with the external world. Its importance to human health is most evident when it becomes impaired due to disease or injury. Physical and occupational rehabilitation remains the most common treatment for these types of disorders. Although therapeutic interventions may improve motor function, residual deficits are common for many pathologies, such as stroke. The development of novel therapeutics is dependent upon a better understanding of the underlying mechanisms that govern movement. Movement of the human body adheres to the principles of classic Newtonian mechanics. However, due to the inherent complexity of …

Relating Sonic Velocities, Minimum Horizontal Stress, And Natural Fracture Distribution To Stimulation Efficiency During Completion Of The Marcellus Shale Mip-3h Unconventional Well, West Virginia, Usa, Kaitlin Gayle Evans

Graduate Theses, Dissertations, and Problem Reports (ETD)

Log data from the Marcellus Shale Energy and Environment Laboratory (MSEEL) was acquired along the lateral of the MIP-3H well. This unconventional shale-gas well was completed within the Marcellus Shale just above the Cherry Valley Limestone, a thin limestone member separating organic rich units of the Marcellus. The geomechanical moduli, Poisson’s Ratio (PR) and Young’s Modulus (YME), were generated using compressional and shear sonic logs to indicate zones of increasing brittleness for each of the 28 stages along the 6124 ft. (1867m) horizontal lateral. Brittle reservoir rock is more readily fractured during hydraulic stimulation than more malleable rock. Stages with …