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Equilibrium And Non-Equilibrium Ultrafast Carrier Transport And Dynamics In Chalcopyrite Semiconductors, Rishmali Thanuja Sooriyagoda

Graduate Theses, Dissertations, and Problem Reports (ETD)

Chalcopyrite crystals in the II-IV-V₂ family have received significant interest due to their high nonlinearity, composition-tunable bandgaps, wide transparency windows, and high damage threshold. These semiconductors have been explored for electromagnetic (EM) screening, spintronic and photovoltaic applications, making them good optical and optoelectronic materials. This thesis uses terahertz spectroscopy to understand optical, electronic, and vibrational dynamical processes in CdGeP₂, ZnGeP₂ and CdSiP₂ chalcopyrite semiconductors.

We have employed Terahertz time-domain spectroscopy to investigate temperature-dependent ground-state properties of bulk chalcopyrite crystals that can be related to electronic transport and electron-lattice interactions. The complex spectra provide refraction and …

Examining West Virginia's Economic Development: Natural Resources, Development Agencies, And Labor Force Development, Gaillynn Marie Bowman

Graduate Theses, Dissertations, and Problem Reports (ETD)

Examining West Virginia's Economic Development: Natural Resources, Development Agencies, and Labor Force Development Gaillynn Bowman Economic development is well-recognized as being fundamental to facilitating an overall improved quality of life for communities and their residents. Throughout West Virginia’s history, the state has experienced economic hardships caused by boom and bust cycles associated with resource extraction. This dissertation consists of three essays that explore the impacts of economic development activities, including conservation programs, economic development agency initiatives, and workforce development agencies. The first essay explores the relationship nonresident landowners have with the conservation programs within West Virginia, specifically the Natural Resources …

The Memorization, Preparation, And Performance Of Piano Music: Cognitive Foundations And Current Neuro-Music Research, Amy M. Simpson

Graduate Theses, Dissertations, and Problem Reports (ETD)

Memorization of piano music for performance has often been shrouded in mystery. A body of neuro-music research has emerged, mostly in the last twenty years, that addresses how musicians perceive, learn, and memorize music, and how these processes operate in music performance. This paper is a compendium of current research on music perception, learning, memorization, and performance, specifically focused on piano music and piano performance. It is intended to benefit both pianists (performers, teachers, students), and neuro-music researchers.

This research explains the operation of human memory systems and, from this platform, addresses aspects of music memorization such as multi-modal approaches …

Magnetic Properties Of Lsmo/Sto Thin Films: Magnetocaloric, Spin Dynamics And Magnetic Viscosity Investigations, Navid Mottaghi

Graduate Theses, Dissertations, and Problem Reports (ETD)

While other films are discussed, this dissertation will focus on detailed studies of the dc and ac bulk magnetometry in a characteristic 7.6 nm thin film of La_0.7Sr_0.3MnO₃ grown on SrTiO₃ (001). The dc bulk magnetometry measurements show that the sample is magnetically inhomogeneous. Temperature variation of magnetization (M vs. T) was measured in zero-field-cooled and field-cooled protocols to determine the blocking temperature T_B in different applied magnetic fields. The field variation of T_B is interpreted as the presence of embedded spin clusters of 1.4 nm. Moreover, the M vs. …

Characterization Of Modern Ammunition And Background Profiles: A Novel Approach And Probabilistic Interpretation Of Inorganic Gunshot Residue, Korina Layli Menking-Hoggatt

Graduate Theses, Dissertations, and Problem Reports (ETD)

Gunshot residue (GSR) can provide essential clues in gun-related investigations. The standard practice for GSR analysis uses SEM-EDS, with the capability for single particle elemental and morphological analysis. However, the method is time-consuming and based on categorical classification models without considering case circumstances. Therefore, complementary and more encompassing methods are needed to improve evidence interpretation of modern ammunition. This research aims to fill these demands by developing standard materials and alternative methods to characterize and interpret IGSR.

This study developed primer GSR (pGSR) standards from sixty discharged primers that were fully characterized by three techniques. The number of GSR particles, …

Feeling Depleted? If English Is Not Your First Language, You Might Be Experiencing Stereotype Threat, Mingang K. Geiger

Graduate Theses, Dissertations, and Problem Reports (ETD)

An estimated 67.3 million people are nonnative English speakers in the U.S. Research has shown that nonnative English speakers are often perceived to be less competent in communication, less intelligent, and less reliable in English-speaking environments, regardless of their actual capability. Given that English is a common tool for business communication, the nonnative English speaker stigma is likely to be particularly salient in the workplace. For example, empirical research evidence has shown that nonnative English speakers are less likely to be hired or promoted to managerial positions and are more likely to fail to receive funding for their business due …

Prioritization Framework For Advanced Systems Of Urban Roads In The Context Of Smart Cities, Jinwoong Lee

Graduate Theses, Dissertations, and Problem Reports (ETD)

The concept of a smart city has emerged as a solution to resolve various urban challenges by applying advanced systems for the functions of the city (e.g., environment, economy, infrastructure, governance, and people). Urban infrastructure with the use of modern technologies, such as Information Communication Technology and the Internet of Things, plays an essential role in enhancing the capability of the city to resolve the challenges. Particularly, urban roads supported by advanced systems with modern technologies serve as a principal bedrock to establish a smart city. Witnessing the benefits from intelligent urban roads has promoted city stakeholders to make investment …

Identification Of Crash Contributing Factors In Av Involved Crashes, Md Tanvir Ashraf

Graduate Theses, Dissertations, and Problem Reports (ETD)

Autonomous Vehicles (AVs) can dramatically reduce the number of traffic crashes and associated fatalities by eliminating the avoidable human-errors related crash contributing factors. Many companies have been conducting pilot tests on public roads in several states in the United States and other countries to accelerate AV mass deployment. AV pilot operations on California public roads saw 251 AV-involved crashes (as of February 2020). These AV-involved crashes provide a unique opportunity to investigate AV crash risks in a mixed traffic environment. This study collected the AV crash reports from the California Department of Motor Vehicles and applied the Decision Tree (DT), …

Effects Of Different Liquid Smoke Treatments On Osmotic Dehydration Of Apple Cubes, Rohit Singh

Graduate Theses, Dissertations, and Problem Reports (ETD)

Refined Liquid Smoke (RLS) (1%) was incorporated during osmotic dehydration of apple cubes (10 mm each side) to observe its effect on solid gain, water loss, yield, water activity, product quality, and consumer preference. Three different treatments, POD (pure osmotic dehydration, no RLS), LSISS (RLS inside sugar solution) and PTLS (pre-treatment with RLS), were compared in this study. Osmotic dehydration was carried out using 42 °Brix sugar solution, and the fruit to solution ratio was kept at 1:4. The osmotically dehydrated apples were evaluated for soluble solid content (SSC), water loss, and solid gained. After osmotic dehydration, apple cubes were …

Biocompatible And Multifunctional Trityl Spin Probes For Electron Paramagnetic Resonance Spectroscopy, Teresa D. Gluth

Graduate Theses, Dissertations, and Problem Reports (ETD)

The primary objective of my thesis was to develop and utilize a biocompatible multifunctional trityl spin probe for concurrent measurement of pO₂, pH_e, and [P_i] in vivo by electron paramagnetic resonance (EPR) spectroscopy (Chapter 2). My first goal was to synthesize the proposed probe we are terming HOPE71. Secondly, HOPE71 was characterized by X-band and L-band EPR spectroscopy. Next, the biocompatibility of HOPE71 was assessed through an albumin binding test, cytotoxicity assays, and in vivo intravenous tolerance. Then, the use of HOPE71 to measure the target parameters was demonstrated in a breast cancer …

Identifying Self-Determined Learning Practices Within Social Media For Teacher Professional Development, Leah Mcjilton

Graduate Theses, Dissertations, and Problem Reports (ETD)

The collective increase of learner-centered teaching and substantial technology use in the classroom has given instructors potential opportunities to support students in developing lifelong learning skills. The ability to manage one’s own learning is an essential skill for lifelong learners in today’s workforce. Heutagogy, or self-determined learning, suggests that individuals have agency with respect to how, what, and when they learn. Heutagogy provides a framework for making the most of these developments, drawing on established learner-centered education theories. The key principles of heutagogy provide a foundation for designing and developing learning environments using social media. In order for teachers to …

A Deep Learning Approach To Lncrna Subcellular Localization Using Inexact Q-Mer, Weijun Yi

Graduate Theses, Dissertations, and Problem Reports (ETD)

Long non coding Ribonucleic Acids (lncRNAs) can be localized to different cellular components, such as the nucleus, exosome, cytoplasm, ribosome, etc. Their biological functions can be influenced by the region of the cell they are located. Many of these lncRNAs are associated with different challenging diseases. Thus, it is crucial to study their subcellular localization. However, compared to the vast number of lncRNAs, only relatively few have annotations in terms of their subcellular localization. Conventional computational methods use q-mer profiles from lncRNA sequences and then train machine learning models, such as support vector machines and logistic regression with the profiles. …

Design And Synthesis Of Targeted Immunotherapeutic Agents, Md Shohel Rana

Graduate Theses, Dissertations, and Problem Reports (ETD)

The therapeutic monoclonal antibodies are very important tools to fight against the diseases especially in the field of cancer immunotherapy. Many immunotherapeutic antibodies are being used to treat cancer that target multiple different components of the cancer microenvironment. Cells with extracellular juxtacrine ligands [JL-cells] and extracellular juxtacrine receptors [JR-cells] form JL-cell-JR-cell interfaces that produce juxtacrine signals inside JR-cells. [76] Juxtacrine signaling unlike endocrine or paracrine signaling requires no release or cellular uptake of ligands. [76] Immune checkpoint inhibitors are soluble IgG antibodies that block juxtacrine ligand engagements with juxtacrine receptors on tumor or other immune cells. [77] Rapid Nobel Prize …

Unique Biological Applications Of Charge Transfer Dissociation Mass Spectrometry, Halle M. Edwards

Graduate Theses, Dissertations, and Problem Reports (ETD)

The ever-changing landscape of mass spectrometry is driven by gaps in knowledge, and one of the biggest driving forces is the desire to understand the structure and dynamics of biomolecules in living organisms. New and better methods of tandem mass spectrometry are often at the heart of technological developments. Some fragmentation methods are limited to expensive FTICR instruments, some techniques are limited multiply charged precursors, and others are limited to breaking only the weakest bonds in precursor ions; all of which support the pursuit of new activation methods. Charge transfer dissociation (CTD) addresses some of these concerns by providing structurally …

Can Stable Isotopes From Tree Rings Improve Our Understanding Of Past Variability In The Southern Annular Mode?, Zachary Grzywacz

Graduate Theses, Dissertations, and Problem Reports (ETD)

Few annually dated stable isotope records exist across Oceania. In mid- to high-latitude locations in South America, tree-ring stable isotopes provide information about past climate dynamics such as the Southern Annular Mode (SAM). The SAM drives latitudinal shifts in Southern Hemisphere westerly winds, influencing temperature and moisture delivery across the mid- to high-latitudes, including Tasmania. Combinations of paleoclimate proxies from across the Southern Ocean might provide insight into dynamic processes like the SAM that are difficult to measure with a single proxy. Measuring stable carbon and oxygen isotope ratios from tree rings in Tasmania could provide complementary data to contribute …

Identification Of Moving Bottlenecks In Production Systems, Funmilayo Mofoluwasola Adeyinka

Graduate Theses, Dissertations, and Problem Reports (ETD)

Manufacturing sector have been plagued by bottlenecks from time immemorial, leading to loss of productivity and profitability, various research effort has been expended towards identifying and mitigating the effects of bottlenecks on production lines. However, traditional approaches often fail in identifying moving bottlenecks. The current data boom and giant strides made in the machine learning field proffers an alternative means of using the large volume of data generated by machines in identifying bottlenecks. In this study, a hierarchical agglomerative clustering algorithm is used in identifying potential groups of bottlenecks within a serial production line.

A serial production line with five …

Validation Of Shoulder Strain Index, Fabiha Islam

Graduate Theses, Dissertations, and Problem Reports (ETD)

Musculoskeletal disorders (MSDs) of shoulder are one of the most frequent and major causes of morbidity and pain among full-time workers in the USA. In 2018, shoulder disorders were the most severe type of MSDs in terms of lost workdays. Recent epidemiological studies have identified several biomechanical, organizational, and psychological factors that increase the risk of shoulder MSDs. Though multiple biomechanical studies have evaluated physical causal factors of shoulder MSDs with a goal of risk mitigation, literature lacks a standardized risk assessment tool. The main objective of this study was to validate a previously developed shoulder strain index. The strain …

Single And Differential Morph Attack Detection, Baaria Chaudhary

Graduate Theses, Dissertations, and Problem Reports (ETD)

Face recognition systems operate on the assumption that a person's face serves as the unique link to their identity. In this thesis, we explore the problem of morph attacks, which have become a viable threat to face verification scenarios precisely because of their inherent ability to break this unique link. A morph attack occurs when two people who share similar facial features morph their faces together such that the resulting face image is recognized as either of two contributing individuals. Morphs inherit enough visual features from both individuals that both humans and automatic algorithms confuse them. The contributions of this …

Soil Response Of Helicopter Liming In The Monongahela National Forest, Jarrett Douglas Fowler

Graduate Theses, Dissertations, and Problem Reports (ETD)

Soils in the Monongahela National Forest (MNF) are acidic due to sandstone parent material, acid deposition, uptake of base cations by vegetation, and release of organic acids by organic matter (OM) decomposition. Increases in soil acidity have caused declines in forest health and changed species composition and nutrient status. Liming can neutralize soil acidity, but no large-scale liming projects have been done on acid forest soils in the USA. In anticipation of acquiring funding for a proposed liming project in the MNF, in 2007 and 2009 10 sites were selected to sample and analyze soils before lime was applied. In …

Effects Of Acute And Chronic Nicotine Administration On Choice Of Probabilistic Outcomes, Katya A. Nolder

Graduate Theses, Dissertations, and Problem Reports (ETD)

Risky choice can be operationally defined as the choice for a larger, uncertain reinforcer over a smaller, certain reinforcer. Research suggests smokers engage in more risky or maladaptive decisions when compared to nonsmokers. The relation between nicotine and risky choice could benefit from further investigation, since nicotine is the active substance of tobacco products that maintains tobacco addiction. Acute nicotine administration has shown to alter risky choice; however, since the everyday smoker uses nicotine repeatedly, more research on chronic administration is warranted and would allow for assessment of tolerance or sensitization of these effects. The present study investigated effects of …

Well Performance Analysis Of Mseel1 And Mseel2 Wellpads, Mohammad Faiq Adenan

Graduate Theses, Dissertations, and Problem Reports (ETD)

MSEEL1 and MSEEL2 are wellpads that were developed as a means of conducting research into how a gas well being developed in the Marcellus shale can be optimized from the reservoir identification stage to the completions and operational stage. This thesis provides a report of the workflow performed to use the generated data from different sources and analyze them for optimization.

MIP-3H and Boggess 17H were designated as science wells, for which the majority of the well logging and coring experiments were conducted on. The data obtained from the experiments were used as a basis for petrophysical analysis, the results …

Independent, Semi-Automated Classification Of Petrographic Features In Volcanic Rocks Using Fiji And Weka, Holly Danielle Pettus

Graduate Theses, Dissertations, and Problem Reports (ETD)

Traditional methods of collecting quantitative petrographic data from thin sections (modal mineralogy, size distribution, shapes, etc.) are time- and labor-intensive, and rarely have sample sizes adequate to statistically describe complex rocks (i.e. volcanic rocks). Although manual counting and measurements are now routinely supplemented by digital image analysis, the majority of quantitative petrographic studies still go through a manual digitization stage where object classes are traced before further analyses. This is a major rate-limiting step that reproduces the same problems of small n-values resulting from significant effort. We have valuated the potential and limitations of using the Trainable Weka Segmentation (TWS) …

Financial Literacy, Experience, And Age Differences In Monetary Sequence Preferences, Jenna M. Wilson

Graduate Theses, Dissertations, and Problem Reports (ETD)

The emerging research on age differences in monetary sequence preferences suggests that older adults make decisions that are normatively correct from the standpoint of economic theory when choosing to receive larger versus smaller amounts of money sooner than later, but make non-optimal decisions about paying money. In an adult life-span sample (N = 594, aged 20-88, M_age = 46.48, SD= 15.16) recruited through MTurk, the present study examined age differences in monetary sequence preferences. Participants received eight hypothetical scenarios that described monetary events, and completed measures of financial literacy and financial experience. Older age was associated with …

Powertrain Fuel Consumption Modeling And Benchmark Analysis Of A Parallel P4 Hybrid Electric Vehicle Using Dynamic Programming, Aaron Robert Mull

Graduate Theses, Dissertations, and Problem Reports (ETD)

As regulations on the emission of greenhouse gasses continue to tighten on the automotive industry, the production of hybrid electric vehicles has gained significant popularity in recent years. With the increase in production, there has been a parallel demand in the advancement of both mechanical hardware and control system implementation used in these vehicles. A critical factor in the efficient operation of a hybrid electric vehicle is the energy management strategy where the goal is to maximize the efficient use of fuel energy to propel the vehicle. Designing a fuel-efficient control system is a complex challenge due to the degrees …

Investigation Of Ions Accelerated Through Electrostatic Menisci In An Inductively Coupled Plasma, David D. Caron

Graduate Theses, Dissertations, and Problem Reports (ETD)

Plasmas are used in semiconductor fabrication as they allow for very precise control over processes such as etching and doping. This is achieved by extracting a beam of ions from the plasma to interact with and modify the surface of a silicon wafer. However, conventional fabrication methods are reaching spatial limitations as semiconductor features reach the atomic scale. Therefore, in order to better control the fabrication processes and facilitate the transition to three-dimensional architecture, a greater understanding of ion beam formation is needed. Ion beams are extracted at the boundary between the Debye sheath and an externally applied potential, which …

Improving Microbial Safety Of Food Products By Thermal And Non-Thermal Technology And Evaluate The Knowledge Of Antibiotic Resistant Issue Among Local Produce Growers, Wentao Jiang

Graduate Theses, Dissertations, and Problem Reports (ETD)

Microbial contamination of food products is one of the main transmission routes of disease in the world today, which is responsible for about two-thirds of all food-borne disease outbreaks although the hygiene process was improved recently. Improving microbial safety and implementing a good food management system are important elements to reduce microbial contamination and improve food safety and security. To improve microbial safety, I conducted inactivation studies on food pathogens and further explored antibiotic resistant risks. Initial research evaluated the efficacy of commercial antimicrobials distribution by comparing electrostatic sprayer with conventional sanitization process. The antibiotics applied by electrostatic spraying achieved …

Development Of Vibrating Sharp-Edge Spray Ionization (Vssi) Methods For Mass Spectrometry Analysis And Imaging, Nandhini Ranganathan

Graduate Theses, Dissertations, and Problem Reports (ETD)

Mass Spectrometry (MS) is one of the widely used tools for chemical detection down to attomole concentrations for certain proteins. Ionization sources are a critical component for MS analysis. One of the major ionization methods is electrospray ionization (ESI), which remains a gold standard for proteins and peptides. ESI uses voltages up to ~4 kV to produce ions from solubilized molecules. Recently, a novel ionization method termed vibrating sharp-edge spray ionization (VSSI) that nebulizes liquids efficiently at the edge of a vibrating glass slide has been reported. The work in this thesis leverages the capabilities of VSSI for continuous flow-based …

Petrographic And Core Analysis Of The Jurassic Norphlet Formation: A Case Study In The Lithofacies Control Of Diagenesis And Porosity In The Flomaton Field, Al, Jarrett Thomas Smith

Graduate Theses, Dissertations, and Problem Reports (ETD)

This study includes a sedimentologic and petrographic study of cores and thin-sections from the Jurassic Norphlet Formation in the Flomaton Field in southern Alabama to define a specific paragenetic history of each facies encountered and to identify key controls on reservoir quality. Eolian dune, nearshore, sand flat, and wadi facies were likely encountered in Norphlet core and thin-section samples that displayed a high degree of heterogeneity between them in terms of porosity, grain contacts, cement abundance/type, intergranular volume, and overall diagenetic processes. These distinct petrographic differences suggest that the paragenesis in the Flomaton Field is primarily facies controlled. The eolian …

The Impacts Of An Entrepreneurial Course On Secondary Students' Entrepreneurial Self-Efficacy And Entrepreneurial Intentions, Toi E. Hershman

Graduate Theses, Dissertations, and Problem Reports (ETD)

There is considerable agreement that promoting entrepreneurship stimulates economic development and job creation, which helps maintain a country’s economic competitiveness. Entrepreneurship education is a key to increasing the likelihood of potential entrepreneurs. While substantial research has documented strategies for enhancing students' entrepreneurial mindset and building entrepreneurial skills in higher education, entrepreneurship is rarely incorporated into or studied in secondary education. This mixed-method study examined the impact of an online ten-lesson entrepreneurship course on secondary students' entrepreneurial self-efficacy and entrepreneurial intentions. Students took a pre-survey that measured their entrepreneurial self-efficacy and intentions before the course and a post-survey upon completing the …

On The Lagrangian Description And Uniqueness For The One-Dimensional Pressureless Euler System, Mark David Suder

Graduate Theses, Dissertations, and Problem Reports (ETD)

In this work we show that the one-dimensional pressureless Euler system admits a Lagragian characterization under fairly general initial conditions, extending recent results by Hynd [7]. Moreover, we show that if the initial velocity is right-continuous and bounded, then we have uniqueness of this Lagrangian solution (called Sticky Particles Flow, or SPF solution), which coincides with the Scalar Conservation Laws (or SCL) solution. An important tool we employed in order to prove existence is a result by Gangbo et al. [5], which establishes a canonical (i.e. the flow is given by the optimal maps pushing the Lebesgue measure restricted to …