Digital Commons Network^™

Rad Rivers In Rad Places: Characterizing The Historical And Future Whitewater Resources In Select Regions Of The United States, Melissa D. Shafer

Graduate Theses, Dissertations, and Problem Reports (ETD)

Outdoor recreation is a highly profitable industry in the United States. In 2021, outdoor recreation accounted for $454.0 billion, or 1.9% of the current-dollar gross domestic product for the nation. Many states have benefited financially from focusing on promoting their outdoor recreation and natural resources. Whitewater (WW) paddling has been a recreational activity since the 1950s. In 2007 there were an estimated 1.2 million participants in whitewater kayaking. As of 2020, that number increased to 2.6 million, doubling the number of participants. WW resources can be leveraged to reshape local and regional economies. The framework developed in this study provides …

An Empirical Analysis Of Algorithms For Simple Stochastic Games, Cody William Klingler

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis presents the findings of a computational study on algorithms for Simple Stochastic Games (SSG). Simple Stochastic Games are a restriction of the Shapley stochastic model motivated by their applications in AI planning, logic synthesis, and theoretical computer science. This thesis seeks to empirically assess the performance of these algorithms to compensate for their lack of strong complexity results. Where applicable, we include both variations of algorithms where stable strategies are computed by a linear-programming and naive approach. These algorithms are evaluated on random inputs, in addition to specific difficult cases that were identified experimentally. We are interested in …

Nonlinear Dynamic Analysis And Control Of Chemical Processes Using Dynamic Operability, San Quan Dinh

Graduate Theses, Dissertations, and Problem Reports (ETD)

Nonlinear dynamic analysis serves an increasingly important role in process systems engineering research. Understanding the nonlinear dynamics from the mathematical model of a process helps to find the boundaries of all achievable process conditions and identify the system instabilities. The information on such boundaries is beneficial for optimizing the design and formulating a control structure. However, a systematic approach to analyzing nonlinear dynamics of chemical processes considering such boundaries in a quantifiable and adaptable way is yet to exist in the literature. The primary aim of this work is to formulate theoretical concepts for dynamic operability, as well as develop …

Dynamic Modeling, Data Reconciliation, Parameter Estimation, And Health Monitoring Of A Supercritical Power Plant, Katherine Grace Hedrick

Graduate Theses, Dissertations, and Problem Reports (ETD)

With the introduction of a larger portion of renewable sources of power coming onto the U.S. power grid in recent decades, the operational strategy of coal-fired power plants has changed significantly to focus more on flexibility in response to the changing energy market. This has naturally led to different operational challenges. Many of these challenges are focused on the boilers within these plants, as they are producing more emissions and experiencing increased damage during load-following, which in turn leads to increased costs from penalties for not achieving emission standards or maintenance costs as boilers accumulate damage from the cycling behavior. …

Physics Infused Lstm Network For Track Association Based On Marine Vessel Automatic Identification System Data, Tasmiah Haque

Graduate Theses, Dissertations, and Problem Reports (ETD)

In marine surveillance, a crucial task is distinguishing between normal and abnormal vessel movements to timely identify potential threats. Subsequently, the vessels need to be monitored and tracked until necessary action can be taken. To achieve this, a track association problem is formulated where multiple vessels' unlabeled geographic and motion parameters are associated with their true labels. These parameters are typically obtained from the Automatic Identification System (AIS) database, which enables real-time tracking of marine vessels equipped with AIS. The parameters are time-stamped and collected over a long period, and therefore, modeling the inherent temporal patterns in the data is …

Synthesis And Pharmacology Of Illudalic Acid And Analogous Chemical Structures, Robert Gaston Jr

Graduate Theses, Dissertations, and Problem Reports (ETD)

Natural products are the foundation of modern medicine and an inspiration for chemical innovation. Developing new synthetic strategies to complex natural products drives synthetic innovation and promotes pharmacological exploration. As bioactive secondary metabolites of fungi, illudalic acid and associated analogs have unrealized medicinal potential due to synthetic limitations. Illudalic acid is notably the first selective covalent inhibitor of the LAR-PTPs, a class of enzymes linked to many human illnesses, including stimulant addiction. The chemistry herein focuses on optimizing synthetic routes to illudalic acid and associated analogs toward exploring their pharmaceutical potential. We report a second-generation synthesis of illudinine (55% overall …

On The Role Of Task Preference And Work Removal For Identifying Escape Functions, Brian Patrick Long

Graduate Theses, Dissertations, and Problem Reports (ETD)

Abstract

On the Role of Task Preference and Work Removal for Identifying Escape Functions

Brian P. Long

Students within the public school system may exhibit severe challenging behavior to escape from academic demands. Procedures to identify the reinforcers that maintain challenging behavior, such as functional analysis, may improve the probability of treatment success. Functional analysis involves manipulating contingencies to determine if positive (e.g., attention following challenging behavior) or negative (e.g., escape from aversive events such as task demands) reinforcers may maintain challenging behavior (Iwata et al., 1982). The absence of evocative tasks could produce inaccurate results when testing for effects …

Laboratory Experimentation And Numerical Modeling To Enhance Drainage In Geotextile Tubes, Jonah G. Tyson

Graduate Theses, Dissertations, and Problem Reports (ETD)

ABSTRACT

Laboratory Experimentation and Numerical Modeling to Enhance Drainage in Geotextile Tubes

Jonah G. Tyson

Geotextile fabrics are commonly used in the dewatering and filtration of high-water content geomaterials. Acid Mine Drainage (AMD) sludge is a geomaterial and has increasing production volumes in West Virginia. The WVDEP has large sludge storage sites for dewatering and long-term disposal. Currently the AMD is treated then transferred by pumping the material into geobags for long-term disposal in tubular shape geotextile bags that dewater the sludge. The current design of the geobags limit the pathways for the water to filter out due to the …

Spin Recovery Analysis On A Simulation Model Of The Nasa F-18 High Alpha Research Vehicle (Harv) Using Thrust Vectoring, Brock M. Dolly

Graduate Theses, Dissertations, and Problem Reports (ETD)

In the early years of aviation, spins were poorly understood and frequently fatal. With just over a century of research and experiments dedicated to spins, today’s aviation world has a very firm grasp on spin aerodynamics. Most fighter aircraft have airframes and control surfaces specifically designed to ensure the ability of departure from the possible spin modes the aircraft can enter. An alternative and/or additional approach is given by thrust vectoring. Implementing thrust vectoring into spin recovery can potentially save an aircraft and/or the life of the pilot in situation where control-surface-only spin recovery is not able to recover the …

Evaluation Of Renewal During Differential Reinforcement With Asymmetrical Choices And A Context Fading Mitigation Technique, Kacey R. Finch

Graduate Theses, Dissertations, and Problem Reports (ETD)

Successful clinical behavior analytic treatment often results in decreases in challenging behavior and increases in appropriate behavior. These reductions in challenging behavior are often achieved by implementing differential reinforcement of alternative behavior (DRA; Petscher et al., 2009). One variation of DRA to decrease challenging behavior is differential reinforcement with asymmetrical choices, which are two or more concurrently available response options associated with differential outcomes (Fisher & Mazur, 1997; Kestner et al., 2023). However, responding that was previously reduced sometimes reemerges. Specifically, renewal is the reemergence of a previously reduced response following a context change. The first two experiments evaluated renewal …

Ambient Ammonia Synthesis Via Microwave-Catalytic Materials And Plasma Chemistry, Siobhan Brown

Graduate Theses, Dissertations, and Problem Reports (ETD)

Ammonia is critical to supporting human life on earth because of its use as fertilizer. The Haber-Bosch process to produce ammonia has been practiced for over 100 years. This process operates at high pressure and temperature to overcome the thermodynamic and kinetic limitations of the ammonia synthesis reaction thus researchers have tried to overcome it for decades. At present this process represents 1% of global energy usage and 2.5% of global CO₂ emissions. The proposed chemical looping ammonia synthesis approach seeks to reduce the environmental impact of this critical process and to elucidate microwave-catalytic principles.

This research aims to …

Optimal Design And Operation Of Integrated Hydrogen Generation And Utilization Plants, Ijiwole Solomon Ijiyinka

Graduate Theses, Dissertations, and Problem Reports (ETD)

There are considerable efforts worldwide for reducing the use of fossil fuel for energy production. While renewable energy sources are being increasingly used, fossil fuel still contribute about 80% of the energy used worldwide. As a result, the level of CO₂ is still increasing fast in the atmosphere currently exceeding about 410 parts per million (ppm). For reducing CO₂ build up in the atmosphere, various approaches are being investigated. For the electric power generation sector, two key approaches are post-combustion CO₂ capture and use of hydrogen as a fuel for power generation. These two solutions can also …

Investigation Of Early Complex Formation Of Huntingtin Protein With And Without Lipids, Alyssa R. Stonebraker

Graduate Theses, Dissertations, and Problem Reports (ETD)

Huntington’s disease (HD) is a fatal neurodegenerative disease caused by the expansion of the polyglutamine (polyQ) domain of the huntingtin protein (htt). The expansion of the polyQ domain beyond a threshold of approximately 35 repeats triggers complex toxic aggregation mechanisms and results in altered interactions between htt and lipid membranes. Many factors modulate these processes. One such modulator includes sequences flanking the polyQ domain, most notably the first 17 amino acids at the N-terminus of the protein (Nt17), and environmental factors including the presence of membranous structures. Nt17 has the propensity to form an amphipathic a-helix in the presence of …

Reservoir Simulation Of The Volve Oil Field Using Ai-Based Top-Down Modeling Approach, Amir Ansari

Graduate Theses, Dissertations, and Problem Reports (ETD)

With the rise of high-performance computers, numerical reservoir simulators became popular among engineers to evaluate reservoirs and develop the fields. However, this technology is still unable to fully model the reservoirs with commingled production and highly complex geology, especially when it comes to uncertainty qualification and sensitivity analysis where hundreds of runs are required. This dissertation aims to provide a successful case study of the history matching of a complex reservoir in the North Sea (Volve field).

The proposed model relies only on the measured field variables such as well, formation, completion characteristics, production rates, and operational conditions while it …

On Eulerian Subgraphs And Hamiltonian Line Graphs, Yikang Xie

Graduate Theses, Dissertations, and Problem Reports (ETD)

A graph {\color{black}$G$} is Hamilton-connected if for any pair of distinct vertices {\color{black}$u, v \in V(G)$}, {\color{black}$G$} has a spanning $(u,v)$-path; {\color{black}$G$} is 1-hamiltonian if for any vertex subset $S \subseteq {\color{black}V(G)}$ with $|S| \le 1$, $G - S$ has a spanning cycle. Let $\delta(G)$, $\alpha'(G)$ and $L(G)$ denote the minimum degree, the matching number and the line graph of a graph $G$, respectively. The following result is obtained. {\color{black} Let $G$ be a simple graph} with $|E(G)| \ge 3$. If $\delta(G) \geq \alpha'(G)$, then each of the following holds. \\ (i) $L(G)$ is Hamilton-connected if and only if $\kappa(L(G))\ge …

Copper-Catalyzed Dehydrogenative Decarboxylation Reactions Of Carboxylic Acids To Alkenes, Michael P. Stanton

Graduate Theses, Dissertations, and Problem Reports (ETD)

Linear alpha olefins (LAOs) are important building blocks in the production of linear low-density polyethylene, a plastic used in products such as shrink wraps, plastic bags, tubing, plasticizers, among others. Commercial methods for generating LAOs utilize ethylene oligomerization, but this method is reliant on fossil fuels and leads to unselective product formation. Synthesis of LAOs from renewable resources, namely carboxylic acids, by decarbonylative dehydration strategies has been well studied, however, this method has inherent drawbacks rooted in the formation of internal olefin side-products through isomerization pathways. With the goal of avoiding internal isomerization, this thesis explores a dehydrogenative decarboxylation strategy …

Nature Based Interventions For Human Health And Wellbeing, Samantha I. Moyers

Graduate Theses, Dissertations, and Problem Reports (ETD)

Background. Nature exposure is beneficial to human health and wellbeing, but the evidence base for nature-based interventions (NBI) is still developing. Heterogeneous naming conventions, study designs, and intervention contexts create difficulty in accessing and assessing the evidence for such programming. While NBI have been utilized in a wide array of human populations, no interventions have been reported among clinical health professions students. Aims. The objectives of this dissertation project were to review the existing body of NBI literature exploring health and wellbeing outcomes, and to conduct a feasibility trial of forest bathing, a type of NBI, among clinical students. Specifically, …

Natural Fracture Evolution: Investigations Into The Middle Devonian Marcellus Shale, Appalachian Basin, Usa, Natalie Abigail Mitchell

Graduate Theses, Dissertations, and Problem Reports (ETD)

Optimizing recovery from unconventional shale reservoirs has generated considerable research into optimal recovery methods through hydraulic fracturing design and shale reservoir characterization in the development of long-term hydrocarbon producers. Permeability at multiple scales from nanometer-scale pore sizes and nano-darcy permeability to completion-induced fractures defining a 100’s of meter stimulated reservoir volume plays a significant role in hydrocarbon flow during production in shale reservoirs. Preexisting cemented fractures in unconventional shale reservoirs are abundant and preferentially reactivate during induced hydraulic fracturing treatment to create necessary large-scale permeability. While previous investigations have significantly improved our knowledge of shale reservoirs, it has also highlighted …

The Role Of Nedd9 In Her2-Driven Breast Cancer., Marc Louis Purazo

Graduate Theses, Dissertations, and Problem Reports (ETD)

Tumor initiation is often driven by unrestricted proliferation. One such driver of proliferation is Human epidermal growth factor receptor 2 (HER2). HER2 is a receptor tyrosine kinase that is part of the epidermal growth factor receptor family (EFGR) that is commonly overexpressed in breast cancer. HER2 positive (+) breast cancers often respond to anti- HER2 therapy, yet many patients eventually develop resistance. Multiple mechanisms contribute to resistance, including activation of HSP90, PI3K/Akt or Src that rely on adaptor molecules (GRB2, p130cas, NEDD9). Neural precursor cell expressed, developmentally downregulated protein 9 (NEDD9) is an adaptor protein that promotes integrin signaling. We …

Addition Of Apple Pomace To Feeding Substrate On Growth, Development, And Survival Rates Of Yellow Mealworms (Tenebrio Molitor) And Characterization Of Their Proteins Extracted By A Ph-Shift Process, Michelle Duvall

Graduate Theses, Dissertations, and Problem Reports (ETD)

The weight changes, survival/mortality rates, and proximate compositions of Tenebrio molitor (yellow mealworm) larvae whose diets were supplemented with apple pomace were analyzed after a 4-week feeding study to examine the nutritional quality of the insects for use as a future potential food source. Going forward, the terms “mealworm(s)”, "yellow mealworm(s)”, “T. molitor” will be used interchangeably and will always refer to the same species. The mealworm larvae were randomly divided into two groups: in addition to standard worm chow, one group was given 15 g/week of non-nutritive water-storing polymer crystals and the other was given apple pomace …

Effects Of Climate Change And Landscape-Scale Forest Management On Avian Communities, Abundance, And Nest Success In The Appalachian Mountains, Hannah L. Clipp

Graduate Theses, Dissertations, and Problem Reports (ETD)

Birds are integral components of ecosystems and account for billions of dollars in tangible benefits to humans. As such, recent continental declines of bird species have ecological and economic consequences, providing the impetus for my dissertation research. I identified knowledge gaps and proposed novel questions about how birds in the Appalachian Mountains are influenced by changing environmental conditions due to climate change and forest management. The Appalachian Mountains encompass an important biogeographical region with high conservation value due to its myriad habitats and corresponding bird species diversity. Thus, there is a critical need to evaluate the effects of shifting climate …

Exploration Of Metal-Carbonyl Complexes For Decarbonylation Reactions, Rebekah C. Krupa

Graduate Theses, Dissertations, and Problem Reports (ETD)

In recent years, transition metal-mediated decarbonylation reactions have emerged as an alternative to conventional cross-coupling methods due to the advantages associated with the use of carbonyl-containing functionalities as coupling electrophiles instead of organohalides found in traditional cross-coupling reactions. This, coupled with the ubiquity of carbonyl-containing compounds in pharmaceuticals and non-biodegradable chemicals, has led to the interest in developing efficient systems for transition metal-catalyzed decarbonylation. However, these reactions are commonly limited to stoichiometric amounts of metal reagents due to the strong metal-carbonyl bond formed during transition metal-mediated decarbonylation. With the goal of gaining a better mechanistic understanding of CO dissociation in …

A Comparison Of Fish Health Indices Applied To Freshwater Species Of The Chesapeake Bay Watershed, Josiah B. Jensen

Graduate Theses, Dissertations, and Problem Reports (ETD)

Fish kills, increased disease prevalence, and endocrine disruption have been observed in multiple freshwater fish populations of the Chesapeake Bay watershed (CBW). Some of these health issues occur in conjunction with declining abundance. A combination of multiple stressors is believed to be weakening sensitive fish species in non-tidal regions of the CBW. Fish health indices such as Deformity, Erosion, Lesion, and Tumor counts (DELTs), and the Health Assessment Index (HAI) are simple tools designed to evaluate the general health of fish populations. Both indices could be widely applied in the watershed because they require limited training and equipment. However, their …

Machine Learning Assisted Framework For Advanced Subsurface Fracture Mapping And Well Interference Quantification, Mohammad Faiq Adenan

Graduate Theses, Dissertations, and Problem Reports (ETD)

The oil and gas industry has historically spent significant amount of capital to acquire large volumes of analog and digital data often left unused due to lack of digital awareness. It has instead relied on individual expertise and numerical modelling for reservoir development, characterization, and simulation, which is extremely time consuming and expensive and inevitably invites significant human bias and error into the equation. One of the major questions that has significant impact in unconventional reservoir development (e.g., completion design, production, and well spacing optimization), CO2 sequestration in geological formations (e.g., well and reservoir integrity), and engineered geothermal systems (e.g., …

Development Of A Mass Transfer Correction Factor In A Thermodynamic Model To Explain The Weathering Patterns Of Ignitable Liquids On Household Substrates At Elevated Temperatures, Max T. Denn

Graduate Theses, Dissertations, and Problem Reports (ETD)

To determine whether a questioned fire is the result of arson or not, forensic chemists will often attempt to extract and identify any ignitable liquid residues present in the fire debris. Forensic chemists use gas chromatography-mass spectrometry (GC-MS) to identify ignitable liquids based on similarities between chromatograms of fire debris extracts and those of reference ignitable liquids that have been evaporated (weathered) to different extents. Casework samples often appear to be relatively unweathered (e.g., 40-60%) and conventional wisdom is that the apparent lack of weathering is the result of entrapment; a process by which liquid residues are absorbed into the …

Accelerating Manufacturing Decisions Using Bayesian Optimization: An Optimization And Prediction Perspective, Taofeeq Olajire

Graduate Theses, Dissertations, and Problem Reports (ETD)

Manufacturing is a promising technique for producing complex and custom-made parts with a high degree of precision. It can also provide us with desired materials and products with specified properties. To achieve that, it is crucial to find out the optimum point of process parameters that have a significant impact on the properties and quality of the final product. Unfortunately, optimizing these parameters can be challenging due to the complex and nonlinear nature of the underlying process, which becomes more complicated when there are conflicting objectives, sometimes with multiple goals. Furthermore, experiments are usually costly, time-consuming, and require expensive materials, …

Enabling Cybersecure And Resilient Smart Distribution Grid With Edge Devices, Partha Sarathi Sarker

Graduate Theses, Dissertations, and Problem Reports (ETD)

The smart distribution grid achieves enhanced efficiency and flexibility through the utilization of advanced communication infrastructure, digital devices, and robust computation and control capabilities. Grid-edge devices including distributed energy resources (DERs) like solar photovoltaics (PV), battery storage systems, and intelligent electric loads like electric vehicles and smart appliances, are contributing to the growth of the smart distribution grid. This evolution is transforming the grid into a multifaceted network of interconnected devices and systems, enabling bidirectional data communication and power flows. However, these new layers of data integration and control in the smart grid introduce vulnerabilities to cyberattacks and accidental failures, …

An Empirical Analysis Of Approximation Algorithms For The Unweighted Tree Augmentation Problem, Jacob Thomas Restanio

Graduate Theses, Dissertations, and Problem Reports (ETD)

In this thesis, we perform an experimental study of approximation algorithms for the tree augmentation problem (TAP). TAP is a fundamental problem in network design. The goal of TAP is to add the minimum number of edges from a given edge set to a tree so that it becomes 2-edge connected. Formally, given a tree T = (V, E), where V denotes the set of vertices and E denotes the set of edges in the tree, and a set of edges (or links) L ⊆ V × V disjoint from E, the objective is to find a set of edges …

Design And Validation Of An Aerodynamic System For A Formula Sae® Vehicle Using Vehicle Dynamic Simulation And Experimentation, Evan S. Cole

Graduate Theses, Dissertations, and Problem Reports (ETD)

This thesis presents the design, simulation, and experimental validation for the aerodynamic system for a Formula SAE® vehicle. The Society of Automotive Engineers ® (SAE) hosts a collegiate competition annually called Formula SAE® where students design, fabricate, and test a small “formula style” vehicle. The vehicle performs in relatively slow maneuvers, around different courses and tests to evaluate the vehicle’s overall performance. Over the years, collegiate teams have put significant research into the design and manufacturing of the aerodynamics of these vehicles. In order to justify this undertaking for future teams at West Virginia University’s Formula SAE® program, a comprehensive …

Finite Element Modeling And Analysis Of Breech Face Impressions, James A. Hamilton

Graduate Theses, Dissertations, and Problem Reports (ETD)

Finite element analysis (FEA) is a technique which has not been widely used in Forensic Science in general and firearms examination in particular. The general utility of FEA was assessed by the simulation of scenarios commonly encountered during the investigation of firearm related crimes. As a test, simulations included the perforation of a windshield and sheet metal with a 9 mm projectile, the development of pseudo subclass characteristics during the manufacturing of a breech face, and the impact of a projectile with another projectile in air and with a solid body. Results from the simulations were compared to projectiles and …