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Using Transition Probability Geostatistics With Modflow, Norman L. Jones, J. R. Walker, S. F. Carle Jan 2002

Using Transition Probability Geostatistics With Modflow, Norman L. Jones, J. R. Walker, S. F. Carle

Faculty Publications

This paper describes a technique for applying the transition probability geostatistics method for stochastic simulation to a MODFLOW model. Transition probability geostatistics has several advantages over traditional indicator kriging methods, including a simpler and more intuitive framework for interpreting geological relationships and the ability to simulate juxtapositional tendencies such s fining-upwards sequences. The indicator arrays generated by the transition probability simulation are converted to layer elevation and thickness arrays for use with the new Hydrogeologic Unit Flow (HUF) package in MODFLOW 2000. This makes it possible to preserve complex heterogeneity while using reasonably sized grids.

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Measurement Of The Q2 And Energy Dependence Of Diffractive Dnteractions At Hera: The Zeus Collaboration, S. Chekanov, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Anzivino, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, M. Chiarini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, C. Nemoz, F. Palmonari Jan 2002

Measurement Of The Q2 And Energy Dependence Of Diffractive Dnteractions At Hera: The Zeus Collaboration, S. Chekanov, D. Krakauer, S. Magill, B. Musgrave, A. Pellegrino, J. Repond, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Anzivino, G. Bari, M. Basile, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, G. Cara Romeo, M. Chiarini, L. Cifarelli, F. Cindolo, A. Contin, M. Corradi, S. De Pasquale, P. Giusti, G. Iacobucci, G. Levi, A. Margotti, T. Massam, R. Nania, C. Nemoz, F. Palmonari

Faculty Publications

Diffractive dissociation of virtual photons, γ*p → Xp, has been studied in ep interactions with the ZEUS detector at HERA. The data cover photon virtualities 0.17 < Q2 < 0.70 GeV2 and 3 < Q2 < 80 GeV2 with 3 < MX < 38 GeV, where MX is the mass of the hadronic final state. Diffractive events were selected by two methods: the first required the detection of the scattered proton in the ZEUS leading proton spectrometer (LPS); the second was based on the distribution of MX. The integrated luminosities of the low- and high-Q2 samples used in the LPS-based analysis are ≃ 0.9 pb-1 and ≃ 3.3 pb-1, respectively. The sample used for the MX-based analysis corresponds to an integrated luminosity of ≃ 6.2 pb-1. The dependence of the diffractive cross section on W, the virtual photon-proton centre-of-mass energy, and on Q2 is studied. In the low-Q2 range, the energy dependence is compatible with Regge theory and is used to determine the intercept of the Pomeron trajectory. The W dependence of the diffractive cross section exhibits no significant change from the low-Q2 to the high-Q2 region. In the low-Q2 range, little Q2 dependence is found, a significantly different behaviour from the rapidly falling cross section measured for Q2 > 3 GeV2. The ratio of the diffractive to the virtual photon-proton total cross section is studied as a function of W and Q2. Comparisons are made with a model based on perturbative QCD.

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Water Transport In Polymer Electrolyte Membrane Electrolyzers Used To Recycle Anhydrous Hcl: I. Characterization Of Diffusion And Electro-Osmotic Drag, Sathya Motupally, Aaron J. Becker, John W. Weidner Jan 2002

Water Transport In Polymer Electrolyte Membrane Electrolyzers Used To Recycle Anhydrous Hcl: I. Characterization Of Diffusion And Electro-Osmotic Drag, Sathya Motupally, Aaron J. Becker, John W. Weidner

Faculty Publications

In this paper, diffusion and electro-osmotic drag of water across Nafion® membranes in the presence of HCl are characterized. For all the measurements, one side of the Nafion membrane was in contact with liquid water and the other side with gaseous anhydrous HCl. To characterize diffusion of water, the open-circuit flux of water across a catalyst-coated Nafion 115 membrane was measured as a function of HCl flow rate and temperature at a constant cell pressure of 1 atm. Due to the nature of varying driving force for diffusion as a function of HCl flow rate, the experimental data was analyzed …

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Development Of A Novel Co Tolerant Proton Exchange Membrane Fuel Cell Anode, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang Jan 2002

Development Of A Novel Co Tolerant Proton Exchange Membrane Fuel Cell Anode, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang

Faculty Publications

Typically Pt is alloyed with metals such as Ru, Sn, or Mo to provide a more CO-tolerant, high-performance proton exchange membrane fuel cell (PEMFC) anode. In this work, a layer of carbon-supported Ru is placed between the Pt catalyst and the anode flow field to form a filter. When oxygen is added to the fuel stream, it was predicted that the slow H2 kinetics of Ru in this filter would become an advantage compared to Pt and Pt:Ru alloy anodes, allowing a greater percentage of O2 to oxidize adsorbed CO to CO2. With an anode feed …

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Studies On Capacity Fade Of Spinel-Based Li-Ion Batteries, Ramadass Premanand, Anand Durairajan, Bala Haran, Ralph E. White, Branko N. Popov Jan 2002

Studies On Capacity Fade Of Spinel-Based Li-Ion Batteries, Ramadass Premanand, Anand Durairajan, Bala Haran, Ralph E. White, Branko N. Popov

Faculty Publications

The performance of Cell-Batt® Li-ion cells using nonstoichiometric spinel as the positive electrode material has been studied at different charging rates. The capacity of the cell was optimized based on varying the charging current and the end potential. Subsequent to this, the capacity fade of these batteries was studied at different charge currents. During cycling, cells were opened at intermittent cycles and extensive material and electrochemical characterization was done on the active material at both electrodes. For all charge currents, the resistance of both the electrodes does not vary significantly with cycling. This result is in contrast with cells …

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Modeling The Effects Of Ion Association On Alternating Current Impedance Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn Jan 2002

Modeling The Effects Of Ion Association On Alternating Current Impedance Of Solid Polymer Electrolytes, Changqing Lin, Ralph E. White, Harry J. Ploehn

Faculty Publications

This work presents a rigorous continuum model describing the transport of ions and associated ion pairs in solid polymer electrolytes subjected to small amplitude alternating current (ac) excitation. The model treats ion association as a reversible reaction among ions and ion pairs. Dimensionless governing equations are developed from component mass balances, flux equations based on dilute solution theory, and the Poisson equation. Assuming reversible electrode reactions and electroneutrality, the model equations have an analytical solution. Further simplifications are possible in limiting cases (weak and strong association, zero and infinite frequency excitation), giving expressions consistent with previously published models. We use …

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Robust Software, Michael N. Huhns, Vance T. Holderfield Jan 2002

Robust Software, Michael N. Huhns, Vance T. Holderfield

Faculty Publications

Agents offer a convenient level of granularity at which to add redundancy a key factor in developing robust software. Blindly adding code introduces more errors, makes the system more complex, and renders it harder to understand. However, adding more code can make software better, if it is added in the right way. As this article describes, the key concepts appear to be redundancy and the appropriate granularity.

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A Heuristic For Clock Selection In High-Level Synthesis, J. Ramanujam, S. Deshpande, J. Hong, M. Kandemir Jan 2002

A Heuristic For Clock Selection In High-Level Synthesis, J. Ramanujam, S. Deshpande, J. Hong, M. Kandemir

Faculty Publications

Clock selection has a significant impact on the performance and quality of designs in high-level synthesis. In most synthesis systems, a convenient value of the clock is chosen or exact (and expensive) methods have been used for clock selection. This paper presents a novel heuristic approach for near-optimal clock selection for synthesis systems. This technique is based on critical paths in the dataflow graph. In addition, we introduce and exploit a new figure of merit called the activity factor to choose the best possible clock. Extensive experimental results show that the proposed technique is very fast and produces optimal solutions …

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Address Code And Arithmetic Optimizations For Embedded Systems, J. Ramanujam, S. Krishnamurthy, J. Hong, M. Kandemir Jan 2002

Address Code And Arithmetic Optimizations For Embedded Systems, J. Ramanujam, S. Krishnamurthy, J. Hong, M. Kandemir

Faculty Publications

An important class of problems used widely in both the embedded systems and scientific domains perform memory intensive computations on large data sets. These data sets get to be typically stored in main memory, which means that the compiler needs to generate the address of a memory location in order to store these data elements and generate the same address again when they are subsequently retrieved. This memory address computation is quite expensive, and if it is not performed efficiently, the performance degrades significantly. In this paper, we have developed a new compiler approach for optimizing the memory performance of …

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Strategies For Improving Data Locality In Embedded Applications, N. E. Crosbie, M. Kandemir, I. Kolcu, J. Ramanujam, A. Choudhary Jan 2002

Strategies For Improving Data Locality In Embedded Applications, N. E. Crosbie, M. Kandemir, I. Kolcu, J. Ramanujam, A. Choudhary

Faculty Publications

This paper introduces a dynamic layout optimization strategy to minimize the number of cycles spent in memory accesses in a cache-based memory environment. In this approach, a given multi-dimensional array may have different memory layouts in different segments of the same application if doing so improves data locality (cache behavior) beyond the static approaches that fix memory layouts at specific forms at compile-time. An important characteristic of this strategy is that different memory layouts that a given array will assume at run-time are determined statically at compile-time; however the layout modifications (transformations), themselves, occur dynamically during the course of execution. …

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Longitudinal Dispersion Coefficient In Single-Channel Streams, Z. Q. Deng, L. Bengtsson, V. P. Singh, D. D. Adrian Jan 2002

Longitudinal Dispersion Coefficient In Single-Channel Streams, Z. Q. Deng, L. Bengtsson, V. P. Singh, D. D. Adrian

Faculty Publications

Using a new channel shape equation for straight channels and a more versatile channel shape or local flow depth equation for natural streams a method is developed for prediction of the longitudinal dispersion coefficient in single-channel natural streams, including straight and meandering ones. The method involves derivation of a new triple integral expression for the longitudinal dispersion coefficient and development of an analytical method for prediction of this coefficient in natural streams. The proposed method is verified using 70 sets of field data collected from 30 streams in the United States ranging from straight manmade canals to sinuous natural rivers. …

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Interaction Of Physical And Mental Work, Sukhvinder Singh, Fereydoun Aghazadeh, Thomas G. Ray Jan 2002

Interaction Of Physical And Mental Work, Sukhvinder Singh, Fereydoun Aghazadeh, Thomas G. Ray

Faculty Publications

The objective of the research was to determine the effect of mental load on the physical capacity of an individual. An experiment involving 9 combinations of lifting tasks, 1 lowering task, and 3 treadmill tasks was conducted. Heart rate was measured and maximum acceptable weight of lift was determined using the psychophysical method. A simple multiplication task was used as the mental load. The output variables were determined with and without the mental task. The results indicate that the individual’s physical capacity decreased with the mental task while lifting from floor to knuckle and shoulder to reach lifting heights. © …

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Are Employee Appraisals Making The Grade? A Basic Primer And Illustrative Application Of Federal Private Employment Discrimination Law, Thomas Geu Jan 2002

Are Employee Appraisals Making The Grade? A Basic Primer And Illustrative Application Of Federal Private Employment Discrimination Law, Thomas Geu

Faculty Publications

No abstract provided.

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Trusted Autonomy, Michael N. Huhns, Duncan A. Buell Jan 2002

Trusted Autonomy, Michael N. Huhns, Duncan A. Buell

Faculty Publications

We describe how agents are the right building blocks for constructing trustworthy systems. Robust software and trusted autonomy represent the future for agent technology and software engineering.

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Weaving A Computing Fabric, Michael N. Huhns, Larry M. Stevens, John W. Keele, Jim E. Wray, Warren M. Snelling, Greg P. Harhay, Randy R. Bradley Jan 2002

Weaving A Computing Fabric, Michael N. Huhns, Larry M. Stevens, John W. Keele, Jim E. Wray, Warren M. Snelling, Greg P. Harhay, Randy R. Bradley

Faculty Publications

As sources of information relevant to a particular domain proliferate, we need a methodology for locating, aggregating, relating, fusing, reconciling, and presenting information to users. Interoperability thus must occur not only among the information, but also among the different software applications that process it. Given the large number of potential sources and applications, interoperability becomes an extremely large problem for which manual solutions are impractical. A combination of software agents and ontologies can supply the necessary methodology for interoperability.

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Agents As Web Services, Michael N. Huhns Jan 2002

Agents As Web Services, Michael N. Huhns

Faculty Publications

Web services are extremely flexible. Most advantageously, a developer of Web services need not know who or what will use the services being provided. The paper discusses current standards for Web services, directory services and the Semantic Web. It considers how agents extend Web services in several important ways.

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Agent Societies: Magnitude And Duration, Michael N. Huhns Jan 2002

Agent Societies: Magnitude And Duration, Michael N. Huhns

Faculty Publications

If you only need agents to search the Web for cheap CDs, scalability is not an issue. The Web can support numerous agents if each acts independently. In short order, however, billions of embedded agents that sense their environment and interact with us and other agents will fill our world, making the human environment friendlier and more efficient. These agents will need not only scalable infrastructures and communication services, but also scalable social services encompassing ethics and laws. Research projects are under way around the world to develop and deploy such services. The author takes a look at the critical …

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Judicial Selection And Political Culture, Jonathan L. Entin Jan 2002

Judicial Selection And Political Culture, Jonathan L. Entin

Faculty Publications

This article proceeds in four stages. Part I examines the major rulings, relating to tort reform and school funding, that prompted the harsh and expensive Ohio campaign. Part II compares the process for appointing federal judges, particularly Supreme Court justices, which has also become notably contentious over the past three decades. Part III discusses the trend away from strict limitations on campaign speech by judicial candidates, which combined with the expansive protections afforded to independent expenditures in election campaigns will facilitate sharp rhetoric by those inclined in that direction. Finally, Part IV assesses the prospects for elevating the level of …

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Estimation Of Diffusion Coefficient Of Lithium In Carbon Using Ac Impedance Technique, Qingzhi Guo, Venkat R. Subramanian, John W. Weidner, Ralph E. White Jan 2002

Estimation Of Diffusion Coefficient Of Lithium In Carbon Using Ac Impedance Technique, Qingzhi Guo, Venkat R. Subramanian, John W. Weidner, Ralph E. White

Faculty Publications

The validity of estimating the solid phase diffusion coefficient, Ds, of a lithium intercalation electrode from impedance measurement by a modified electrochemical impedance spectroscopy (EIS) method is studied. A macroscopic porous electrode model and concentrated electrolyte theory are used to simulate the synthetic impedance data. The modified EIS method is applied for estimating Ds. The influence of parameters such as the exchange current density, radius of active material particle, solid phase conductivity, porosity, volume fraction of inert material, and thickness of the porous carbon intercalation electrode, the solution phase diffusion coefficient, and transference number, on the …

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Using Sputter Deposition To Increase Co Tolerance In A Proton-Exchange Membrane Fuel Cell, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang, Steven Shi, Narender Rana, Stephan Grunow, Timothy C. Stoner, Alain E. Kaloyeros Jan 2002

Using Sputter Deposition To Increase Co Tolerance In A Proton-Exchange Membrane Fuel Cell, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang, Steven Shi, Narender Rana, Stephan Grunow, Timothy C. Stoner, Alain E. Kaloyeros

Faculty Publications

Placing a layer of Ru atop a Pt anode increases the carbon monoxide tolerance of proton-exchange membrane fuel cells when oxygen is added to the fuel stream. Sputter-deposited Ru filter anodes composed of a single Ru layer and three Ru layers separated by Nafion-carbon ink, respectively, were compared to Pt, Pt:Ru alloy, and an ink-based Ru filter anodes. The amount of Pt in each anode was 0.15 mg/cm2 and the amount of Ru in each Ru-containing anode was 0.080 mg/cm2. For an anode feed consisting of hydrogen, 200 ppm CO, and 2% O2 (in the form …

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Increasing Proton Exchange Membrane Fuel Cell Catalyst Effectiveness Through Sputter Deposition, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang, Steven Shi, Timothy Stoner, Narender Rana Jan 2002

Increasing Proton Exchange Membrane Fuel Cell Catalyst Effectiveness Through Sputter Deposition, Andrew T. Haug, Ralph E. White, John W. Weidner, Wayne Huang, Steven Shi, Timothy Stoner, Narender Rana

Faculty Publications

Sputter deposition has been investigated as a tool for manufacturing proton-exchange membrane fuel cell (PEMFC) electrodes with improved performance and catalyst utilization vs. ink-based electrodes. Sputter-depositing a single layer of Pt on the gas diffusion layer provided better performance (0.28 A/cm2 at 0.6 V) than sputtering the Pt directly onto a Nafion membrane (0.065 A/cm2 at 0.6 V) and equaled the performance of the baseline for an equivalent Pt loading. Sputter-depositing alternating layers of Pt and Nafion-carbon ink (NCI) onto the membrane did not increase the performance over the baseline as measured in amperes per centimeter squared due …

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Simulating Shape Changes During Electrodeposition: Primary And Secondary Current Distribution, Venkat R. Subramanian, Ralph E. White Jan 2002

Simulating Shape Changes During Electrodeposition: Primary And Secondary Current Distribution, Venkat R. Subramanian, Ralph E. White

Faculty Publications

A technique based on the analytical method of lines is presented for predicting shape changes during electrodeposition. The technique is presented for both primary and secondary current distributions. The method presented does not require iterations for nonlinear Butler-Volmer boundary conditions or changing electrode shapes. The technique is based on a semianalytical method developed earlier for predicting current distributions in electrochemical cells. This technique is attractive because it provides a symbolic solution for the Laplace equation, and hence requires less computation time to perform case studies.

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Electrochemical Filtering Of Co From Fuel-Cell Reformate, Balasubramanian Lakshmanan, Wayne Huang, John W. Weidner Jan 2002

Electrochemical Filtering Of Co From Fuel-Cell Reformate, Balasubramanian Lakshmanan, Wayne Huang, John W. Weidner

Faculty Publications

A proton exchange membrane fuel cell was used as a flow reactor for continuous preferential oxidation of CO over H2 from 1.0% CO in H2 under pulse-potential control. By varying the pulse profile ~e.g., on-time, off-time, pulse potential! the CO and H2 oxidation currents were varied independently. The improvement in faradaic selectivity between CO and H2 oxidation results from the promotion of CO adsorption during the off ~i.e., open-circuit! portion of the pulse. Therefore, during the on portion CO oxidation was preferred while the surface was covered with CO.

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Anodic Behavior Of Ti In Koh Solutions: Ellipsometric And Micro-Raman Spectroscopy Studies, A. Prusi, Lj. Arsov, Bala Haran, Branko N. Popov Jan 2002

Anodic Behavior Of Ti In Koh Solutions: Ellipsometric And Micro-Raman Spectroscopy Studies, A. Prusi, Lj. Arsov, Bala Haran, Branko N. Popov

Faculty Publications

Anodic formation of oxide films on titanium surfaces, in various concentrations of aqueous KOH solutions, have been studied using ellipsometry and micro-Raman spectroscopy. By in situ ellipsometric measurements the coefficient of film thickness growth and indexes of refraction of anodic oxide films have been determined. The voltage at which the oxide film breaks down is strongly dependent on the KOH concentration. Further, the solution concentration strongly influences the potential at which the oxide film is transformed from the amorphous state to crystalline form. Using micro-Raman spectroscopy four crystalline forms of titanium oxides, namely, anatase, brookite, corundum, and rutile, have been …

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Study Of Sn-Coated Graphite As Anode Material For Secondary Lithium-Ion Batteries, Basker Veeraraghavan, Anand Durairajan, Bala Haran, Branko N. Popov, Ronald Guidotti Jan 2002

Study Of Sn-Coated Graphite As Anode Material For Secondary Lithium-Ion Batteries, Basker Veeraraghavan, Anand Durairajan, Bala Haran, Branko N. Popov, Ronald Guidotti

Faculty Publications

Tin-graphite composites have been developed as an alternate anode material for Li-ion batteries using an autocatalytic deposition technique. The specific discharge capacity, coulombic efficiency, rate capability behavior, and cycle life of Sn-C composites has been studied using a variety of electrochemical methods. The amount of tin loading and the heating temperature have a significant effect on the composite performance. The synthesis conditions and Sn loading on graphite have been optimized to obtain the maximum reversible capacity for the composite electrode. Heating the composite converts it from amorphous to crystalline form. Apart from higher capacity, Sn-graphite composites possesses higher coulombic efficiency, …

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Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn Jan 2002

Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn

Faculty Publications

This work presents a mathematical model for charge/discharge of electrochemical capacitors that explicitly accounts for particle-packing effects in a composite electrochemical capacitor consisting of hydrous RuO2 nanoparticles dispersed within porous activated carbon. The model is also used to investigate the effect of nonuniform distributions of salt in the electrolyte phase of the electrode in the context of dilute solution theory. We use the model to compare the performance of capacitors with electrodes made from different activated carbons and to investigate the effects of varying carbon content and discharge current density. Even at low discharge current density, concentration polarization in …

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Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn Jan 2002

Modeling The Effects Of Electrode Composition And Pore Structure On The Performance Of Electrochemical Capacitors, Changqing Lin, Branko N. Popov, Harry J. Ploehn

Faculty Publications

This work presents a mathematical model for charge/discharge of electrochemical capacitors that explicitly accounts for particle-packing effects in a composite electrochemical capacitor consisting of hydrous RuO2 nanoparticles dispersed within porous activated carbon. The model is also used to investigate the effect of nonuniform distributions of salt in the electrolyte phase of the electrode in the context of dilute solution theory. We use the model to compare the performance of capacitors with electrodes made from different activated carbons and to investigate the effects of varying carbon content and discharge current density. Even at low discharge current density, concentration polarization in …

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Contract Rights And Civil Rights, Davison M. Douglas Jan 2002

Contract Rights And Civil Rights, Davison M. Douglas

Faculty Publications

No abstract provided.

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Corporate And Products Identity In The Post-National Economy: Rethinking U.S. Trade Laws, Lan Cao Jan 2002

Corporate And Products Identity In The Post-National Economy: Rethinking U.S. Trade Laws, Lan Cao

Faculty Publications

In the global economy, a General Motors automobile may involve South Korean assembly; Japanese engines; German design and style engineering; Taiwanese, Singaporean, and Japanese small components; British advertising and marketing; and Irish and Barbadian data processing. What is the country of origin of this product? How should U.S. trade laws evaluate a product's origin, if it is a global composite with research, assembly, processing, and manufacturing performed in different countries? Similarly, corporations have become increasingly global in orientation and operations. Even "national" corporations have lost their territorial ties to the state of their nationality. Through a phenomenon termed "global outsourcing" …

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On Revolution And Wetland Regulations, Michael J. Gerhardt Jan 2002

On Revolution And Wetland Regulations, Michael J. Gerhardt

Faculty Publications

No abstract provided.

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