Digital Commons Network^™

Novel Inference Methods For Generalized Linear Models Using Shrinkage Priors And Data Augmentation., Arinjita Bhattacharyya

Electronic Theses and Dissertations

Generalized linear models have broad applications in biostatistics and sociology. In a regression setup, the main target is to find a relevant set of predictors out of a large collection of covariates. Sparsity is the assumption that only a few of these covariates in a regression setup have a meaningful correlation with an outcome variate of interest. Sparsity is incorporated by regularizing the irrelevant slopes towards zero without changing the relevant predictors and keeping the resulting inferences intact. Frequentist variable selection and sparsity are addressed by popular techniques like Lasso, Elastic Net. Bayesian penalized regression can tackle the curse of …

An Instrumental Case Study: Growth Mindset Instructional Best Practices For Learning Disabled Students, Brenda L. Cornell

Electronic Theses and Dissertations

The problem that drove this study was that students who struggle in school, especially those with a non-intelligence-based learning disability, suffer from a fixed mindset after years of feelings of failure in school. This mindset causes them to develop maladaptive approaches to learning that inhibit success. The purpose of this study was to describe the best practices of reading teachers who have a reputation for high student achievement and who adhere to a growth mindset in an effort to build a growth mindset culture with their students. This qualitative instrumental case study was conducted through interviews of eleven reading teachers/specialists …

The Effects Of 1:1 Technology On African American Students' Achievement In Algebra And English, Chad Bryan Wolf

Electronic Theses and Dissertations

Abstract

Many educational leaders have questioned whether the increased availability of technology in classrooms helps to increase student achievement and narrow the persistent achievement gap between African American and White students in the United States. School leaders have made large investments to provide every student with an Internet-capable mobile device. These 1:1 initiatives have grown in popularity in the U.S., and specifically in Texas. The research on 1:1 technology programs, however, has been mixed and sometimes contradictory. The purpose of this study was to determine if a 1:1 technology program increased student achievement for African American students and if it …

Teaching Decoding Through Constant Time Delay To Students With Severe Disabilities And Verbal Difficulties, Julia Dean

Electronic Theses and Dissertations

The purpose of this study was to examine the effects of constant time delay on decoding letter sounds within consonant-vowel-consonant words and to read constant-vowel-constant words skills for students with severe disabilities and verbal difficulties. This study used a multiple probe across participants design with four students with severe intellectual and/or development disabilities. Results indicated a functional relation between the use of constant time delay and decoding of CVC words. Additionally, students were able to maintain and generalize learning. Results were similar to other studies which implemented constant time delay to promote emergent literacy skills. Practitioners can use constant time …

Supplemental Instruction In First-Year Chemistry Courses: Efficacy And Gender Balance, Deidre R. Johnson

Electronic Theses and Dissertations

Increasing student success and retention rates are top goals for many higher education institutions. Supplemental Instruction (SI) is a widely used academic support program designed to increase students’ academic performance and provide students the learning skills they need to persist to graduation. Unfortunately, a lack of time, personnel, and resources often prevent in-depth, meaningful analysis on the effectiveness of SI programs. This study examined the relationship of attending SI sessions for first-year chemistry courses to student grade outcomes and retention rates for attendees. The gender of SI leaders and SI participants was also assessed to determine if leader and participant …

Investigation Of Multiple Imputation Methods For Categorical Variables, Samantha Miranda

Electronic Theses and Dissertations

We compare different multiple imputation methods for categorical variables using the MICE package in R. We take a complete data set and remove different levels of missingness and evaluate the imputation methods for each level of missingness. Logistic regression imputation and linear discriminant analysis (LDA) are used for binary variables. Multinomial logit imputation and LDA are used for nominal variables while ordered logit imputation and LDA are used for ordinal variables. After imputation, the regression coefficients, percent deviation index (PDI) values, and relative frequency tables were found for each imputed data set for each level of missingness and compared to …

Encephalization In Commensal Raccoons: A Unique Test Of The Cognitive Buffer Hypothesis, Peter M. Anderson

Electronic Theses and Dissertations

This study investigated selective pressures associated with encephalization in mammals and discussed broader implications. Relative brain size as measured by EQ (Encephalization Quotient) was compared between ecological categories. Omnivores had higher average EQ than ecological specialists. Since specialists are disproportionately affected by extinction events, selection for ecological generalism is proposed as encephalization mechanism. This mechanism may reinforce the more widely known Cognitive Buffer Hypothesis (CBH)—the idea that possessing relatively large brains has buffered lineages against environmental change. CBH is tested here by comparing EQs in Procyon lotor (raccoon) in urban and rural environments. CBH predicts that raccoons in the most …

Storm Sampling To Assess Inclement Weather Impacts On Water Quality In A Karst Watershed: Sinking Creek, Watauga Watershed, East Tennessee, Porcha Mccurdy

Electronic Theses and Dissertations

Escherichia coli changes in Sinking Creek, an impaired water body in the Watauga watershed of northeast Tennessee, were assessed during storm events using water samples collected with ISCO automated samplers during eight storms at two locations. Turbidity and electrical conductivity (EC) data loggers were deployed in the creek, and dissolved oxygen (DO) was measured in situ to test the stream’s water quality and reaction to inclement weather. Cotton fabric was deployed at both locations and sent to an external lab to test for the presence of Optical Brighteners (OB), which are indicators of residential wastewater. E. coli and turbidity at …

Photocatalytic Carbon Dioxide Reduction With Zinc(Ii) Dipyrrin Photosensitizers And Iron Catalyst, Senan Rasheed

Electronic Theses and Dissertations

Much of the energy used in the United States and around the globe is obtained from petroleum, natural gas, and coal. Photocatalytic CO₂ reduction can be used to transform CO₂ to useful fuels and making fossil fuels more renewable. Input of energy is required, and the sun can provide the required energy for this transformation. Photosensitizer, catalyst, and electron donor are required for photocatalytic CO₂ reduction.

Due to lack of earth-abundant sensitizers, zinc dipyrrin complexes were synthesized by previous group members and have been used as photosensitizers in this research. The ground and excited state electrochemical properties …

Mesoporous Adsorbents For Perfluorinated Compounds, Bertha Lotsi

Electronic Theses and Dissertations

Effective adsorbents for polyfluorinated compounds (PFCs) were successfully prepared. And they were tested in the adsorption of perfluorooctanoic and perfluorooctanesulfonic acids. Bridged silsesquioxanes containing secondary and tertiary amino groups were synthesized by sol-gel condensation of bis[3-(trimethoxysilyl)propyl]amine and bis[3-(methylamino)propyl]-trimethoxysilane in acidic media with surfactants. Obtained materials are mesoporous with a high BET surface area. They combine high structural stability with a high concentration of surface amino groups serving as adsorption sites. Batch adsorption tests demonstrated their extremely high adsorption capacity on PFCs: in some experiments, it reached up to 88% of the adsorbent weight. Adsorption of PFCs changed the surfaces of …

Immobilization Of Phosphotungstic Acid On Silica Surface For Catalytic Alkylation Of Aromatic Compounds, Anastasia Kuvayskaya

Electronic Theses and Dissertations

Superacidic mesoporous materials containing covalently embedded PTA were synthesized by sol-gel method. Tetraethyl orthosilicate (TEOS) and phosphotungstic acid (PTA) were used as precursors in the synthesis, ionic and nonionic surfactants were used as pore-forming agents, the reaction proceeded in acidic media. TEM images revealed mesoporous structure with embedded PTA clusters. FT-IR spectra of obtained materials contained characteristic bands of PTA at 957 cm-1. Synthesized catalysts had high BET surface area and high concentration of acidic sites. Alkylation of 1,3,5-trimethylbenzene by 1-decene demonstrated high catalytic activity. The catalyst obtained with Pluronic P123 as a template was the most effective and resulted …

Computational Quantum Study Of Intermediates Formed During The Partial Oxidation Of Melatonin, Oladun Oladiran

Electronic Theses and Dissertations

Melatonin is a neurohormone produced by the pineal gland in the brain. It functions as an antioxidant to scavenge free radicals. Free radicals are reactive species; they often oxidize the cells leading to oxidative stress which may lead to severe health complications. Reaction of melatonin with free radicals is known to be stepwise, as such the stability of the intermediates can be examined. Thus, the possibility of using melatonin as an in vivo spin trap can be determined. Spin traps allow characterization of unstable radical species using electron spin resonance spectroscopy. In this research, ab initio quantum chemistry techniques were …

Changes In Land Use Land Cover (Lulc), Surface Water Quality And Modelling Surface Discharge In Beaver Creek Watershed, Northeast Tennessee And Southwest Virginia, Tosin James

Electronic Theses and Dissertations

Beaver Creek is an impaired streams that is not supporting its designated use for recreation due to Escherichia coli (E.coli), and sediment. To address this problem, this thesis was divided into two studies.

The first study explored changes in Land Use Land Cover (LULC), and its impact on surface water quality. Changes in E.coli load between 1997-2001 and 2014-2018 were analyzed. Also, Landsat data of 2001, and 2018 were examined in Terrset 18.31. Mann-Whitney test only showed a significant reduction in E.coli for one site. Negative correlation was established between E.coli load, and Developed LULC, Forest LULC, and …

Blended Learning Integration: Student Motivation And Autonomy In A Blended Learning Environment, Cheryl Mchone

Electronic Theses and Dissertations

The purpose of this study was to analyze teacher perceptions on the relationship of technology and student academic behaviors and performance in the blended learning environment across 9^th through 12^th grade within east Tennessee and to identify the components of blended learning and pedagogical practices that enhance students’ academic behaviors. Specifically, this study is an analysis of how student motivation and student autonomy relate to technology implementation and face-to-face instruction within blended learning environments.

The participants of this study were teachers within 2 school districts in East Tennessee. All high school teachers within the participating school districts received …

An Analysis Of The First Passage To The Origin (Fpo) Distribution, Aradhana Soni

Electronic Theses and Dissertations

What is the probability that in a fair coin toss game (a simple random walk) we go bankrupt in n steps when there is an initial lead of some known or unknown quantity $m? What is the distribution of the number of steps N that it takes for the lead to vanish? This thesis explores some of the features of this first passage to the origin (FPO) distribution. First, we explore the distribution of N when m is known. Next, we compute the maximum likelihood estimators of m for a fixed n and also the posterior distribution of m when …

Archaeological, Geophysical, And Geospatial Analysis At David Crockett Birthplace State Park, In Upper East Tennessee, Reagan Cornett

Electronic Theses and Dissertations

A geophysical survey was conducted at David Crockett Birthplace State Park (40GN205, 40GN12) using ground-penetrating radar (GPR) and magnetometry. The data indicated multiple levels of occupation that were investigated by Phase II and Phase III archaeological excavations. New cultural components were discovered, including the remnants of a Protohistoric Native American structure containing European glass trade beads and Middle Woodland artifacts that suggest trade with Hopewell groups from Ohio. A circular Archaic hearth was uncovered at one meter below surface and similar deep anomalies were seen in the GPR data at this level. A semi-automated object-based image analysis (OBIA) was implemented …

Ontogenetic And Adult Shape Variation In The Endocast Of Tapirus: Implications For T. Polkensis From The Gray Fossil Site, Thomas M. Gaetano

Electronic Theses and Dissertations

Endocranial morphology provides evidence of sensory ecology and sociality of extinct vertebrates. The Earliest Pliocene Gray Fossil Site (GFS) of NE Tennessee features a conspicuous dominance of skeletal elements belonging to the dwarf tapir, Tapirus polkensis. Numerous individuals in one fossil locality often suggests gregarious behavior, but sociality in T. polkensis contradicts behavior documented for extant Tapirus species. I test T. polkensis for variation in sensory and social ecology using computed tomography and 3D digital endocasts from an ontogenetic sequence. I compare the T. polkensis endocasts with extant Tapirus species using Encephalization Quotients (EQs) and 3D geometric morphometrics. Results …

A Tale Of Two Species: Black-Tailed And White-Tailed Prairie Dog Biogeography From The Last Interglacial To 2070, April Dawn Bledsoe

Electronic Theses and Dissertations

Ecological niche models (ENMs) were created for White-tailed and Black-tailed prairie dogs and projected into the Last Interglacial (LI), the Last Glacial Maximum (LGM), and mid-Holocene (mid-H) to discern possible past suitable habitat for both species. Additionally, ENMs were projected into the future year 2070 representative concentration pathways (RCPs) 2.6 and 8.5 to discern how climate change may affect future habitat suitability. Kernel density estimations, minimum convex polygons, and median distribution centers of White-tailed and Black-tailed occurrence records were examined between time-periods to discern the effects of anthropogenic westward expansion on both species’ distributions. Current ENMs were constructed from commonly …

Trends In Advertising: How The Rise In Artificial Intelligence May Influence The Field Of Content Strategy, Joel Eaton

Electronic Theses and Dissertations

Whereas prior research on artificial intelligence has dealt with automation in fields like medicine, engineering, and computer science, this research study seeks to answer the question, “To what extent can AI be creative in the context of content strategy?” To answer this, this study employs content analysis using 16 online news and blog articles from primarily marketing organizations to identify and explain key variables surrounding the relationship between the computer and the creative professional. This study has found that the core belief that AI will play the future role of creative assistant in the context of content strategy is shared …

Stacking The Odds For Better Gpr: An Antenna Comparison, Montana Kruske

Electronic Theses and Dissertations

Ground penetrating radar (GPR) is limited by depth penetration and signal-to-noise ratio (SNR), impacting the ability to resolve subsurface features. Stacking, a process of averaging multiple scans in the same location, improves SNR. Digital antennas are capable of stacking at much higher rates than analog antennas. Four sites were examined using a GSSI SIR-4000 GPR unit with a 400 MHz analog antenna and a 350 MHz digital “hyperstacking” (350 HS) antenna. Sites represent various soil conditions, with known features. Data were compared qualitatively and quantitatively for differences in antenna outputs. Visual inspection of radargrams indicate a reduction in noise in …

Gender, Race, And Childhood Abuse As Predictors Of Borderline Personality Disorder, Olivia Moses

Electronic Theses and Dissertations

Borderline Personality Disorder (BPD) is a debilitating personality disorder that impacts anywhere between 1% to 5% of Americans. Studies claim that women are significantly more at risk than men to suffer from this disorder and may experience stronger symptoms. Previous research has found that victims of childhood abuse such as sexual abuse, physical abuse, and neglect are more at risk for developing Borderline Personality Disorder as adults, particularly when abuse is paired with genetic susceptibility. Some researchers claim that there are no detectable racial differences in Borderline Personality Disorder, but previous studies often have very small sample sizes taken from …

Trees With Unique Italian Dominating Functions Of Minimum Weight, Alyssa England

Electronic Theses and Dissertations

An Italian dominating function, abbreviated IDF, of $G$ is a function $f \colon V(G) \rightarrow \{0, 1, 2\}$ satisfying the condition that for every vertex $v \in V(G)$ with $f(v)=0$, we have $\sum_{u \in N(v)} f(u) \ge 2$. That is, either $v$ is adjacent to at least one vertex $u$ with $f(u) = 2$, or to at least two vertices $x$ and $y$ with $f(x) = f(y) = 1$. The Italian domination number, denoted $\gamma_I$(G), is the minimum weight of an IDF in $G$. In this thesis, we use operations that join two trees with a single edge in order …

Case Study Of Special Educator's Pegagogical Practices Beyond Year One Of Teacher Residency., Ryan Derek Derousselle

Electronic Theses and Dissertations

The Higher Education Opportunity Act of 2008 in conjunction with Teacher Quality Partnerships requires university-based teacher education programs to develop and sustain highquality teachers (United States Department of Education, 2017). Teaching is a science grounded in a body of literature supported by effective research-based techniques. The purpose of this qualitative research study was to examine co-teaching influences on the first-year teaching practices of special educators trained in a university-based teacher residency program. Specifically, this study investigated which co-teaching strategies, if any, did special education residents implement as the teacher of record. Through the lens of social development theory, this research …

A Causal Comparative Analysis Of The Academic Self-Efficacy Of Black Male High School Students Taught By A Black Or White Male Teacher., Joseph Jones Jr.

Electronic Theses and Dissertations

The airm of this study was to determine if there was a difference in the academic-self efficacy among Black male students taught by a Black Male teacher compared to the academic self-efficacy of Black male students that are taught by a Whilte male teacher. Academically, Black male students lag behind their peers in academic achievement indicators such as grade point average, standardized test scores, and high school graduation rates (Schottt Report, 2015). Existing literature regarding Black male academic achievement focuses on exploring the academic achievement gap that exists, but little to no research investigates how to close that gap. Using …

An Unusual Mastodon Revisited: Providing A Regional Focus For Mammut Americanum (Proboscidea, Mammutidae) In The Southeast, Matthew Inabinett

Electronic Theses and Dissertations

A century ago, two large American mastodon Mammut americanum specimens from coastal South Carolina were mounted for display at Amherst College. Their robust build, broad and pentalophodont third molars, and well-developed mandibular tusks were noted as unusual. Here, these specimens are redescribed; three additional mastodon mandibles from the same region of South Carolina are also described. Though collection information on these specimens is sparse, they appear to span >150 ka in the Middle to Late Pleistocene, and probably include the first report of Mammut from the earliest-Rancholabrean Ten Mile Hill Formation. Some “unusual” features — moderately to extremely broad third …

Knot Flow Classification And Its Applications In Vehicular Ad-Hoc Networks (Vanet), David Schmidt

Electronic Theses and Dissertations

Intrusion detection systems (IDSs) play a crucial role in the identification and mitigation for attacks on host systems. Of these systems, vehicular ad hoc networks (VANETs) are difficult to protect due to the dynamic nature of their clients and their necessity for constant interaction with their respective cyber-physical systems. Currently, there is a need for a VANET-specific IDS that meets this criterion. To this end, a spline-based intrusion detection system has been pioneered as a solution. By combining clustering with spline-based general linear model classification, this knot flow classification method (KFC) allows for robust intrusion detection to occur. Due its …

Synthesis And Characterization Of Carbon Monoxide Producers Bipyridine Flavonolate Palladium(Ii) And Platinum(Ii) Complexes: Potential Anti-Cancer Agents, Sarah Whitfield

Electronic Theses and Dissertations

Novel designed metal ligand complexes as prodrugs are useful in the effort to find more effective and selective anti-cancer treatments. Carbon monoxide, CO, is known to induce mitochondrial collapse in cancer cells. Herein is described the synthesis of seven novel bipyridine flavonolate palladium(II) and platinum(II) complexes with the property of releasing carbon monoxide, and their characterization with FTIR, UV-Vis, fluorescence, NMR, and ESI mass spectra. Their ability to release carbon monoxide was investigated through oxygenation reaction under various conditions of temperature and light irradiation. The nitroxygenation reaction of the palladium complexes was also studied with nitrosyl hydride, HNO, generated in …

Characterization Of Surface Karst Using Lidar And Field Traverses, Fort Hood Military Installation, Coryell County, Texas, Heather Jaclyn Dailey

Electronic Theses and Dissertations

The Fort Hood Military Installation is a karst landscape that has been significantly altered for training exercises that include heavy vehicle maneuvers and simulated combat. Traditional karst surveys are often time-consuming and require extensive field analyses to adequately characterize large areas. Bias is given to areas that are most easily accessible and false negatives are common. Previous studies conducted in the eastern and western portion of the base have understated the abundance and spatial distribution of karst, particularly in the western portion.

This study used field traverses and 0.5-meter Light Detection and Ranging (LiDAR) data to characterize surface karst depressions, …

Applications Of Digital Remote Sensing To Quantify Glacier Change In Glacier And Mount Rainier National Parks, Brianna Clark

Electronic Theses and Dissertations

Digital remote sensing and geographic information systems were employed in performing area and volume calculations on glacial landscapes. Characteristics of glaciers from two geographic regions, the Intermountain Region (between the Rocky Mountain and Cascade Ranges) and the Pacific Northwest, were estimated for the years 1985, 2000, and 2015. Glacier National Park was studied for the Intermountain Region whereas Mount Rainier National Park was representative of the glaciers in the Pacific Northwest. Within the thirty year period of the study, the glaciers in Glacier National Park decreased in area by 27.5 percent while those on Mount Rainier only decreased by 5.7 …

Using Saddlepoint Approximations And Likelihood-Based Methods To Conduct Statistical Inference For The Mean Of The Beta Distribution, Bryn Brakefield

Electronic Theses and Dissertations

The prevalence of conducting statistical inference for the mean of the beta distribution has been rising in various fields of academic research, such as in immunology that analyzes proportions of rare cell population subsets. For our purposes, we will address this statistical inference problem by using likelihood-based applications to hypothesis testing, along with a relatively new statistical method called saddlepoint approximations. Through simulation work, we will compare the performance of these statistical procedures and provide both the statistical and scientific communities with recommendations on best practices.