Digital Commons Network^™

Methods For Improving Potassium Fertilizer Recommendations For Corn In South Dakota, Andrew J. Ahlersmeyer

Electronic Theses and Dissertations

Corn (Zea mays L.) is a vital commodity in South Dakota’s agricultural sector. Optimal corn production occurs when there are sufficient mineral nutrients in the soil, especially potassium (K). Applications of K fertilizer are used when soil test K (STK) levels are deficient. Therefore, producers need reliable, thoroughly tested fertilizer recommendations to make profitable decisions and maintain environmental stewardship. South Dakota K fertilizer recommendations have not been updated in nearly 20 years. Simultaneously, changes in corn genetics, management practices, and climate patterns suggest that the critical soil test value (CSTV) for STK may have shifted in that same time frame. …

Effects Of Dietary Genistein And Fugacity Modelling In An Aquaculture System, Travis Schaeffer

Electronic Theses and Dissertations

Fish production from aquaculture has continued to grow over the past several decades, with finfishes being fed formulated, fish meal-based diets supporting most of that industry’s growth. However, increased demand and costs, coupled with static volume and erratic supplies of fish meal, has resulted in the use of alternative plant-derived protein sources. A common oilseed protein source is soybean meal (SBM), because of its protein content and amino acid profile; however, it also contains multiple anti-nutritional factors, including phytoestrogens. Phytoestrogens are naturally produced, estrogenmimicking compounds, with isoflavones receiving the most investigation as higher levels of these compounds occur within SBM. …

Identification And Quantification Of Novel Antimicrobials, Hazera Khatun Koly

Electronic Theses and Dissertations

No abstract provided.

A Class Of Regression Models For Pairwise Comparisons Of Forensic Handwriting Comparison Systems, Cami M. Fuglsby

Electronic Theses and Dissertations

Handwriting analysis is a complex field largely living in forensic science and the legal realm. One task of a forensic document examiner (FDE) may be to determine the writer(s) of handwritten documents. Automated identification systems (AIS) were built to aid FDEs in their examinations. Part of the uses of these AIS (such as FISH[5] [7],WANDA [6], CEDAR-FOX [17], and FLASHID®2) are tomeasure features about a handwriting sample and to provide the user with a numeric value of the evidence. These systems use their own algorithms and definitions of features to quantify the writing and can be considered a black-box. The …

Addressing Soil Carbon Sequestration Response From Multispecies Dairy Forage Systems And Modeling Rangeland Beef Cow Dry Matter Intake Using Precision Enteric Emissions Measurements, Lillian J. Mcfadden

Electronic Theses and Dissertations

Regenerative agriculture is a pressing matter for the dairy industry to address cropland sustainability and carbon sequestration. One regenerative management practice that has been identified to help with row crop sustainability for key metrics like soil organic carbon (SOC) is complex covers. When producers use complex covers one of the main challenges is that it takes time to detect a change in SOC. However, simulation models are a tool that can be used to help determine if a regenerative practice is a strategy that gives the best results (i.e., increased SOC) while aligning with long-term production goals. Therefore, our objectives …

Improving The Utility Of Precision Agriculture Through Machine Learning And Climate-Smart Practices, Skye Brugler

Electronic Theses and Dissertations

Climate Smart Practices are management strategies that focus on increasing soil and crop productivity, utilize site-specific strategies to increase resiliency against the effects of climate change, and mitigate these negative effects by reducing greenhouse gas (GHG) emissions. Decision Support Systems (DSSs) using machine learning (ML) can adjust models based on new information and help farmers make climate smart decisions within their operation. The 4R nutrient management model of right source, rate, location, and time also demonstrates a framework that may be considered climate smart by improving soil and crop productivity. However, when initially conceptualized, the 4R model did not consider …

Advanced Analytical Techniques For The Analysis Of Toxic Inhaled Agent Exposure And Pharmacokinetic Investigation, Sharmin Sultana

Electronic Theses and Dissertations

Toxic inhalation agents (TIAs) (i.e., chlorine (Cl2), cyanide (HCN), etc.) are highly poisonous. However, they have a variety of industrial uses, such as health, agro-food, building, textiles, transport, leisure activities, cosmetics, etc. In addition, TIAs can be used as chemical agents in terrorist events or conventional warfare. The ability to detect TIAs in biological and environmental samples is important for preparing use, determining individual exposure, limiting hazardous exposure, etc. Therefore, developing simple and sensitive analytical methods for TIAs, TIA metabolites, and antidotes for those toxic agents is very important. The focus of this study was chlorine and cyanide. Chlorine is …

Firm-Level Political Risk And Corporate R&D Investment, Emmanuel Boah

Electronic Theses and Dissertations

I examine how firms make R&D investment decisions during periods of political uncertainty. To minimize stickiness and overly generalized assumptions, I employ quarterly data. I find that firms invest more in R&D when facing high levels of political risk. The results suggest that this positive relationship between political risk and R&D investment is more pronounced for competitive and politically sensitive firms. Additionally, the positive association is evident among firms with higher growth opportunities and more liquid assets. The results are robust to the test for correlation, addressing endogeneity, and alternative proxies adopted for the variables of interest. Overall, the findings …

Assessing How Long-Term Conservation Agricultural Practices Impact Soil Properties And Soil, Water, And Nutrient Dynamics Through Soil Profile, Ajoy Kumar Saha

Electronic Theses and Dissertations

No abstract provided.

Probing Signal-Based Data-Driven Modeling Of Power Electronics Smart Converter Dynamics Using Power Hardware-In-The-Loop, Nischal Guruwacharya

Electronic Theses and Dissertations

The main objective of this dissertation is to develop a generalized simulation and modeling framework for extracting dynamics of power electronic converters (PECs) with grid support functions (GSFs) and validate model accuracy through experimental comparison with physical measurements. The dynamic models obtained from this modeling framework aim to facilitate accurate dynamic analysis of a highly integrated power system comprising inverter-based resources (IBRs), specifically for stability assessment. These dynamic models helped in reducing simulation time and computational complexity, thereby enhancing efficiency. Moreover, it provides valuable insights for utilities and grid operators involved in effective system planning, operation, and dispatch. The dynamics …

Walleye Feeding, Movements, And Energetics Reveal The Importance Of Connected Wetlands In Glacial Lakes, Logan M. Cutler

Electronic Theses and Dissertations

Fish require a variety of resources including prey, thermal refugia, and different physical habitat characteristics to grow and reproduce. All necessary resources are rarely provided by a single habitat, resulting in tradeoffs between occupying different habitats; therefore, the ability to move among heterogenous habitats is critical. These tradeoffs may occur in lakes with connected wetlands where the main lake habitats tend to be more thermally stable, but wetlands often provide more diverse and abundant prey. For my second chapter, I compared prey diversity and abundance as well as Walleye (Sander vitreus) diets and condition in a large glacial lake (Lake …

Pedagogical Content Knowledge (Pck) Change And Professional Development For Educators: An Assessment Of A Master’S In Chemistry Program For High School Science Teachers, Mary Charlotte Bautista

Electronic Theses and Dissertations

The M.S. Chemistry – Chemical Education Specialization program at South Dakota State University provides in-depth general chemistry coursework to in-service high school science teachers in a virtual format. The goal of the program is for the teachers enrolled to become more effective teachers while gaining content knowledge in chemistry; in essence, to increase their pedagogical content knowledge (PCK). The aim of this study is to follow participants through their experience in this program in order to understand how the program’s requirements enhance its participants’ teaching and learning. A narrative framework follows one participant through their two-year experience in the program, …

Cytotoxicity Profiling And Apoptotic Potential Of Carboxylic Acids-Based Deep Eutectic Solvents On Mammalian Cell Lines, Mavis Korankye

Electronic Theses and Dissertations

In the past few years, there has been a notable surge in demand for high-purity medicines due to the prevalence of chronic diseases such as cancer, hypertension, diabetes, cardiovascular diseases, and neurological disorders. Considerable efforts have been dedicated to discovering new solvents that are environmentally friendly and cost-effective that are well-suited for industrial applications. Deep eutectic solvents have gained recognition as a highly promising alternative to organic solvents and ionic liquids due to their easily sourced raw materials, simple and cheap preparation methods, high tunability, low volatility, low toxicity, and biodegradability. The industrial utilization of deep eutectic solvents (DESs) is …

Indigenous Toxin Affects Cell Viability, While An Artificial Proteolytic Queueing Causes The Upregulation Of Specific Genes, Mohammed Salahuddin

Electronic Theses and Dissertations

Studying bacterial physiology is crucial to understand the fundamental mechanisms that govern bacterial growth, survival, and adaptation. This thesis combines two chapters investigating bacterial physiology by studying important cellular processes like bacterial toxin-antitoxin systems and proteolytic pathways. The first chapter involves studying bacterial toxin-antitoxin systems to understand the regulation and function of hypothetical toxin-antitoxin (TA) systems of bacteria and the effects of these TA systems on bacterial growth and survival. The emergence of these genetic modules in bacterial research and the unrevealing of some of their important roles in cell physiology in recent years has drawn much attention in scientific …

Evaluating Precision Supplementation Technology And Mathematical Nutrition Models For The Development Of Heifers Grazing Dormant Rangeland In Western South Dakota, Anna Katherine Dagel

Electronic Theses and Dissertations

The Great Plains supports about 40-50% of beef cattle production in the United States. Consequently, the beef cow-calf sector provides a large economic impact for states located within the Northern Great Plains (South Dakota Department of Agriculture, 2021). Producing profitable rangeland beef cattle through an economically efficient cowcalf operation presents several challenges. These challenges include providing adequate nutrition to meet the needs of growing heifers on rangelands, which requires additional labor and feed/supplement to achieve desired rates of gain and reach a target body weight, resulting in reproductive success. Implementation of precision livestock technology (PLT) and the use of precision …

Automatic Data-Driven Partitioned Modeling Of Power System Dynamics With Smart Power Electronic Inverters, Sunil Subedi

Electronic Theses and Dissertations

The primary aim of this dissertation is to provide an efficient statistical modeling and simulation technique for extracting the dynamics of converter-dominated power systems (CDPS) with the device level details using the least amount of computation time while maintaining a reasonable level of accuracy. These test cases are intended for use by power system researchers that need to develop test cases that can perform accurate dynamic analysis on a high integration of inverter-based resources (IBRs) for stability analysis while speeding up simulation time and reducing computational complexity. Additionally, utilities/grid operators must properly plan, operate, and dispatch. Case studies that can …

Simulating The Impact Of Emissions Control On Economic Productivity Using Particle Systems And Puff Dispersion Model, Najam Khan

Electronic Theses and Dissertations

A simulation platform is developed for quantifying the change in productivity of an economy under passive and active emission control mechanisms. The program uses object-oriented programming to code a collection of objects resembling typical stakeholders in an economy. These objects include firms, markets, transportation hubs, and boids which are distributed over a 2D surface. Firms are connected using a modified Prim’s Minimum spanning tree algorithm, followed by implementation of an all-pair shortest path Floyd Warshall algorithm for navigation purposes. Firms use a non-linear production function for transformation of land, labor, and capital inputs to finished product. A GA-Vehicle Routing Problem …

The Role Of Cadherins And Ryk On Metastasis And Invasion In Triple Negative Breast Cancer Cell Model: Hs578t/Hs578ts(I)8, Ibis Iser

Electronic Theses and Dissertations

Breast cancer is a major cause of death among women in European and North American countries, even with improved methods for diagnosis and therapy. The mortality of breast cancer is mainly due to the migration of the primary tumor to distinct sites in the body and is very common in triple negative breast cancer (TNBC). This type of breast cancer affects younger woman and has a high recurrence rate. Unfortunately, TNBC is extremely difficult to control because of the absence of specific targets for treatment. Therefore, our research aim is to discover new therapeutic targets and identify novel approaches for …

The Live Bait Trade As A Pathway Of Inland Invasive Fish Species Introductions, Hannah Mulligan

Electronic Theses and Dissertations

Freshwater systems are susceptible to numerous anthropogenic pathways of invasive species introductions and subsequent establishment. Once establishment occurs, invasive species not only impact biodiversity, ecosystem function, and human health, but also cost the global economy billions of dollars every year. Recreational fishing is one of the most prevalent pathways for invasive species introductions in freshwater systems due to increased propagule pressure from boating and angling activity. Within recreational fishing, the live bait trade represents a secondary pathway whereby anglers illegally release baitfish (and water) that may contain invasive species. Preventative actions, including regulations, education, and inspections have been implemented to …

Understanding The Role Of Hba/Hbd Variations On Deep Eutectic Solvent Properties And Activity Using Acetylsalicylic Acid As A Model Drug, Michael Frimpong

Electronic Theses and Dissertations

Deep eutectic solvents (DES) are emerging as a versatile class of solvents, attracting considerable attention for their unique solvent properties and potential applications. This study examines the effects of variations in combinations as well as molar ratios of hydrogen-bond acceptor (HBA) and hydrogen-bond donor (HBD) on the structure of DES. It further explores the structure-activity relationship, measured using the rate of acetylsalicylic acid (ASA) degradation in the solvent. The project is based on the model that variations in HBA/HBD combinations and their relative molar ratios impact the solvent structure (hydrogen bonding), observable in physicochemical measurements, infrared (IR), and nuclear magnetic …

Effects Of Agricultural Chemicals On Native Plants Of The Northern Great Plains, Gabrielle Bolwerk

Electronic Theses and Dissertations

Agricultural chemicals are ubiquitous on the Northern Great Plains landscape and have negative impacts on non-target plant communities, even at small doses. Northern Great Plains grassland plant communities may experience herbicide drift from agricultural fields or be subject to livestock pharmaceuticals in grazing lands. My research objective was to evaluate if and how native plants are affected by agricultural chemical presence at different concentrations. In Chapter 2, I studied the effect of different concentrations of three common agricultural herbicides (2,4-D, atrazine, and trifluralin) on the germination, emergence, and growth of native plant species of the Northern Great Plains. I performed …

Advancement Via Individual Determination And Its Impact On The Academic Achievement Of African American Male Students, Christerpher L. Turner

Electronic Theses and Dissertations

The purpose of this study was to evaluate the effectiveness of the Advancement Via Individual Determination (AVID) program and its impact on the academic achievement of African American and White male students. A causal-comparative quantitative design was used as the methodology for this study. For this study, the academic achievement of AVID and non-AVID African American and White male students was measured by comparing their Algebra 1 scores. The sample included data from approximately 550 African American and White male high school students in a suburban school district in Texas. Student achievement data were collected and analyzed using a statistical …

Adaptive Microlearning: An Empirical Study Among The Students In The Rural Areas Of China, Jingwei Liu

Electronic Theses and Dissertations

Through multiple educational reforms, China has pursued developing well-rounded learners with solid content knowledge, higher-order thinking skills, and the ability to transfer knowledge to real-world problem spaces. The imbalance of learning resources between urban and rural China, however, has caused disadvantages for learners in rural China to gain access to quality educational opportunities necessary for becoming well-rounded learners. Luckily, the quickly growing Internet service coverage in rural China makes educational interventions possible. Online intervention aiming for many qualities of well-rounded learners, such as deeper learning, is particularly promising.

The purpose of this study was to investigate the potential of adaptive …

Assessments Of Water Chemistry And Fish Community Structure In The Buffalo Creek Watershed, Tributary To The Allegheny River In Armstrong And Butler Counties, Pennsylvania, Kathleen Wilson

Electronic Theses and Dissertations

The Buffalo Creek watershed has experienced water quality impairments for various reasons, including but not limited to, agricultural influence, abandoned mine drainage (AMD), on-site wastewater malfunction, and stormwater. The source and cause of the most prevalent impaired areas remains unknown. The goal of this study was to analyze water chemistry using state water quality standards and mass ratio analysis, then to conduct fish community analysis. We found toxic metal pollution across the watershed, with iron, cadmium, copper, and selenium frequently exceeding criteria. We determined which streams are polluted by resource extraction activities by conducting mass ratio analysis. We found conventional …

Revelations In The Blood: Determination Of Biomarkers And Analytes, Jeremiah Jamrom

Electronic Theses and Dissertations

Changes in body chemistry have long been utilized as a tool for medical diagnosis. Whether blood panel, toxin level, antigen testing or any of the myriad other tests performed annually, searching for molecules which confer health status is a long-established practice. These tests give physicians more information and allow them to make a more accurate diagnosis, from which appropriate treatment can stem. Awareness of, and the subsequent search for, biomarkers for disease states have grown substantially in the past years as analytical, biochemical, and instrumental techniques have become more precises and powerful. In an era of increasingly personalized medicine, novel …

Speciated Isotope Dilution Mass Spectrometry In Combination With Thor’S Hammer Metaspike Technology For The Assessment Of Low-Level Biomarkers For Human Health Evaluation, Ashley Ebert

Electronic Theses and Dissertations

Our research team has been focused on quantifying important biological analytes in human blood samples to delineate the biochemical processes underlying certain states of dysfunction and evaluate treatment efficacy. These efforts have been guided by laboratory measurements with the input of medical experts. Speciated isotope dilution mass spectrometry (SIDMS) explained in detail in EPA Method 6800 has been successfully applied in the quantification of an important biomarker analyte for immune function and detoxification processes: glutathione. Past research has proven the molecule a biomarker for autism spectrum disorder (ASD) in the form of the reduced/oxidized glutathione (GSH/GSSG) ratio, and literature has …

Quantum Computations And Molecular Dynamics Simulations: From The Fundamentals Of Antimicrobial Resistance To Neurological Diseases, Angel Tamez

Electronic Theses and Dissertations

Biophysical phenomena are modeled using a combination of quantum and classical methods to interpret and supplement three distinct and diverse problems in this dissertation. In the first project, decarboxylation reactions are ubiquitous across chemical and biological disciplines, yet the origin of non-catalytic solvent effects remains elusive. Specific solvent structure and energetics have not been well described for the monoanion of malonate, nor corrected from the gas-phase charge-assisted intramolecular hydrogen bond model known as “pseudochair”. In the aqueous phase, a low-lying energy conformer known as the “orthogonal conformation” is computed to be preferred by a three-water cluster of hydrogen bonding over …

Hydrologic Modeling With Remote Sensing For The Estimation Of Groundwater Resources Within The Sand River Catchment, South Africa, Sophia Bakar

Electronic Theses and Dissertations

The Sand River Catchment is an important tributary of the transboundary Limpopo River in South Africa, which spans Botswana, Mozambique, South Africa, and Mozambique. Groundwater is a critical resource in the region, especially in the context of population growth and climate change. Data are needed for proper management of these water resources. In regions where groundwater data are sparse in time, space, or both, the most promising solutions come from satellites and hydrologic models. Regional literature suggests that the Soutpansberg Mountains, located within the Sand Catchment, are high-elevation water towers with uncertain groundwater resources. Improved understanding of groundwater resources in …

Comparing The Effectiveness Of Traditional Taped-Problems Intervention With A Remote Delivery Version For Increasing Math Fact Fluency, Cortney Chelecki

Electronic Theses and Dissertations

The knowledge of math fact fluency skills is crucial for children to develop both related and subsequent necessary math skills. Students require fluency in basic math facts in order to successfully understand and perform more complicated math problems. Research has shown that students demonstrating math skill deficits are likely to have limited cognitive capacity to devote to higher math tasks, and also suffer from math-related anxiety, a lack of engagement, and limited vocational and career opportunities (Delli Sante et al., 2001; Gersten & Chard, 1999; Parkhurst et al., 2010; Poncy et al., 2007; Riconscente, 2013). During the COVID-19 pandemic, all …

Implications Of Individuals With Music Learning Experience Using A Segmented Multimedia Lesson In A Non-Music Discipline, Cheryl Farren Tkacs

Electronic Theses and Dissertations

The purpose of this study was to investigate how prior music learning experience relates to learning with multimedia resources in non-music disciplines. Specifically, whether years of music learning experience, type of music learning experience, or type of multimedia were associated with task scores and task duration in a non-music discipline. The study revealed the transferable benefits of music learning experience to learning outcomes in other disciplines. Encouraging music studies as part of the base curriculum is thus strongly encouraged. However, as years of music learning and the presence or absence of segmenting in multimedia learning resources were not found to …