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Doctoral Dissertations

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Cell Model Of A Fluid With Hard-Core Repulsive Long-Range Attractive Potential, Ralph G. Tross Jan 1968

Cell Model Of A Fluid With Hard-Core Repulsive Long-Range Attractive Potential, Ralph G. Tross

Doctoral Dissertations

"A model of a one-dimensional fluid is investigated in which the praticles [sic] are embedded in a cellular space grid and interact with a modified Lennart-Jones potential. It is shown that with an appropriate change in the potential function the model is also suitable for a two- or three-dimensional fluid with more restricted interactions. The man-fermion-like nature of the system resulting from the hard-rod repulsive part of the modified Lennard-Jones potential makes possible an isomorphism between occupation numbers (number operators) and spin states (spin operators) of an Ising ferromagnet, permitting a convenient mathematical formulation of the problem in terms of …


A Numerical Simulation Of Pressure Distribution And Radius Of Drainage In Infinite Radial Aquifers - Constant Rate Case, Alton John Nute Jan 1968

A Numerical Simulation Of Pressure Distribution And Radius Of Drainage In Infinite Radial Aquifers - Constant Rate Case, Alton John Nute

Doctoral Dissertations

"The diffusivity equation for the transient flow of slightly-compressible liquids has been solved for infinite radial aquifers, subject to constant terminal rates, by employing a Romberg integration of the Van Everdingen - Hurst explicitly solution over the transformed integral limits for .01̲TD>500, the classical solutions presented by Carslaw and Jaeger, Mortada, Theis, and others are incorporated in the digital analysis to yield dimensionless pressures for 40 selected dimensionless radius (RD) ratios between 1 and 64 for dimensionless time values of .0005 to 1000.0. A new expression for dimensionless pressure-distribution, PD'(RD, TD), as a fraction of well bore pressure drop …


Recombination Statistics For The Neutron-Induced Base Current Component, Ming-Chwan Chow Jan 1968

Recombination Statistics For The Neutron-Induced Base Current Component, Ming-Chwan Chow

Doctoral Dissertations

"This paper presents a derivation of the recombination statistical model for the neutron-induced base current component. The derivation was based on the assumptions: 1) the current equation for the induced current component developed by Goben is valid; 2) the Shockley-Read-Hall statistics for holes and electrons are applicable; and 3) the recombination statistics derived by Sah, Noyce and Shockley, for sites in the bulk space-charge region are valid. Several examples were presented to emphasize accuracy of this derived model for predictions. This paper shows that the recombination process may be described by a mathematical model, recombination statistics which depend on the …


Surface Self-Diffusion On Nickel (111) By Radioactive Tracers, James Ronald Wolfe Jan 1968

Surface Self-Diffusion On Nickel (111) By Radioactive Tracers, James Ronald Wolfe

Doctoral Dissertations

"Surface self-diffusion coefficients have been measured by a radioactive tracer method over the temperature range 614⁰ to 840⁰C on nickel (111) surfaces characterized by LEED. Previously unrecognized tracer evaporation during surface diffusion resulted in restricted spreading of the tracer at higher temperatures. A theoretical treatment of the tracer evaporation phenomenon is presented and subsequently used in the analysis of the data. The temperature dependence of the surface self-diffusion coefficient (Ds) for nickel (111) can be represented, over the experimental temperature range, by a single Arrhenius type relationship...Arguments are presented to justify an adatom surface diffusion mechanism which is …


The Identification And Evaluation Of Toxic Effects Of Organic Micropollutants, John Warren Smith Jan 1968

The Identification And Evaluation Of Toxic Effects Of Organic Micropollutants, John Warren Smith

Doctoral Dissertations

No abstract provided.


A Study Of Succinic Dehydrogenase, Indole Acetic Acid Oxidase, Nitrate Reductase And Cytochrome C Reductase In Hygrophorus Conicus, Jagdish M. Mehta Jan 1968

A Study Of Succinic Dehydrogenase, Indole Acetic Acid Oxidase, Nitrate Reductase And Cytochrome C Reductase In Hygrophorus Conicus, Jagdish M. Mehta

Doctoral Dissertations

"The activity of the enzyme succinic dehydrogenase (succinate : phenazine methosulfate oxidoreductase, EC 1.3.99.1) of Hygrophorus conicus, a member of a class of fungi known as basidiomycetes, was found to be stimulated by nitrate. Two substances were tested as electron acceptors in the measurement of succinic dehydrogenase activity. Of the two substances tried, phenazine methosulfate and brilliant cresyl blue, the former was found to be the best. Nicotinamide adenine dinucleotide (NAD⁺) was a necessary cofactor for the enzyme and could be readily dissociated from the enzyme. The enzyme has the properties of a high molecular weight nucleo- or lipoprotein.

The …


Multiport Synthesis With Multi-Layered Distributed Parameter Rc Networks, Walter Ronald Koenig Jan 1968

Multiport Synthesis With Multi-Layered Distributed Parameter Rc Networks, Walter Ronald Koenig

Doctoral Dissertations

"Synthesis and design techniques for multiport, multilayered, distributed parameter RC networks are investigated in this dissertation. The basic building block is a network section of uniform width consisting of alternate layers of resistive and dielectric materials on top of a perfectly conducting plane. The resulting network is composed of a cascade of these sections with all access terminals at one end of the cascaded network. The terminals at the other end are either open circuited or short circuited. A method is discussed for synthesizing a network from a prescribed network admittance matrix. An approximation technique is given for obtaining a …


Optical Reflectance Spectra Of Chromium (Iii) In Mgo-Ss, Thomas Spencer Montgomery Jan 1968

Optical Reflectance Spectra Of Chromium (Iii) In Mgo-Ss, Thomas Spencer Montgomery

Doctoral Dissertations

"The valence state and coordination site of the transition-metal ion, chromium, was investigated in a MgO host lattice. The chromium ion incorporated into poly-crystalline MgO by quenching from elevated temperatures allowed investigation of a single crystalline phase, MgO-solid solution (ss). The chromium ion was confirmed to occur in the trivalent state and to occupy octahedral cation sites in the MgO lattice by the use of optical reflectance spectroscopy. The effect of the concentration of the chromium ion on the crystal field splitting energy, 10 Dq, permitted analysis over a range of Dq/B values. In conjunction, MgO-ss lattice parameters examined as …


Signal Theoretic Characterization Of A Function Using Positive Exponential Basis Functions, James Julius Baremore Jan 1968

Signal Theoretic Characterization Of A Function Using Positive Exponential Basis Functions, James Julius Baremore

Doctoral Dissertations

"A signal theory characterization of a time function or signal is a representation of the function throughout a sample interval by an orthogonal basis function expansion. The characterization described here obtains the coefficients in the expansion by processing the input waveform, in real time, through a system of three terminal passive RC filters. The outputs of the filters are sampled periodically and the coefficients of the basis function expansion in that interval are related to these values. The basis functions result from an exponential transformation applied to the Legendre polynomials and are orthogonal in time over the sample interval. The …


Analysis Of A Focus Log Electrode In A Non Homogeneous Medium, John Julian Zenor Jan 1968

Analysis Of A Focus Log Electrode In A Non Homogeneous Medium, John Julian Zenor

Doctoral Dissertations

"The mathematical model presented for the focused logging system is applicable to any resistance logging tool of the electrode type. Horizontal or cylindrical resistance interfaces may be included in any combinations. The tool and its environment are compartmentalized, and the integral form of the condition for continuity of current is applied to each compartment. Acceleration methods are applied to the iterative solution of the resulting large-scale system of linear equations. Two specific models are presented, one for the study of the effects of invasion and the other for the study of the effects of bed thickness on the apparent resistivity …


Studies Of Toluidine Blue For Inducing Haploidy In Lycopersicon Esculentum And Zea Mays, Salih Aziz Al-Yasiri Jan 1967

Studies Of Toluidine Blue For Inducing Haploidy In Lycopersicon Esculentum And Zea Mays, Salih Aziz Al-Yasiri

Doctoral Dissertations

No abstract provided.


Histochemical And Morphological Analysis Of In Vitro Cultured Embryos Of Pelargonium X Hortorum Bailey, In Comparison To Normal In Vivo Embryology And Seedling Differentiation, Franklin Scott Adams Jan 1967

Histochemical And Morphological Analysis Of In Vitro Cultured Embryos Of Pelargonium X Hortorum Bailey, In Comparison To Normal In Vivo Embryology And Seedling Differentiation, Franklin Scott Adams

Doctoral Dissertations

No abstract provided.


Nucleophilic Displacement At The 3-Position Of 1,2,3,6-Tetrahydropyridines, William Ernest Krueger Jan 1967

Nucleophilic Displacement At The 3-Position Of 1,2,3,6-Tetrahydropyridines, William Ernest Krueger

Doctoral Dissertations

No abstract provided.


Electron Density Measurements In The Lower Ionosphere By A Rocket Borne Radio Propagation Method, Lee Edward Larson Jan 1967

Electron Density Measurements In The Lower Ionosphere By A Rocket Borne Radio Propagation Method, Lee Edward Larson

Doctoral Dissertations

No abstract provided.


Resonance Energy Transfer Studies: Dependence Of Transfer Properties On The Structure Of The Donor Molecule, Barton Stephen Solomon Jan 1967

Resonance Energy Transfer Studies: Dependence Of Transfer Properties On The Structure Of The Donor Molecule, Barton Stephen Solomon

Doctoral Dissertations

No abstract provided.


Physiological Factors In The Etiology And Alleviation Of Salt-Induced Decline Of Roadside Maples And Pines, John Bernard Kotheimer Jan 1967

Physiological Factors In The Etiology And Alleviation Of Salt-Induced Decline Of Roadside Maples And Pines, John Bernard Kotheimer

Doctoral Dissertations

No abstract provided.


The Chemistry Of Vitreoscilla Cell Envelopes, Gerard O'Leary Jr. Jan 1967

The Chemistry Of Vitreoscilla Cell Envelopes, Gerard O'Leary Jr.

Doctoral Dissertations

No abstract provided.


Aspects Of Membrane Structure And Function In Streptococcus Faecium, James Joseph Burke Jr. Jan 1967

Aspects Of Membrane Structure And Function In Streptococcus Faecium, James Joseph Burke Jr.

Doctoral Dissertations

No abstract provided.


The Stability Constants Of Indium(Iii) Complexes With Chloroacetate, 2-Chloropropionate And 3-Chloropropionate Anions, Edwin Ellison Hach Jr. Jan 1967

The Stability Constants Of Indium(Iii) Complexes With Chloroacetate, 2-Chloropropionate And 3-Chloropropionate Anions, Edwin Ellison Hach Jr.

Doctoral Dissertations

No abstract provided.


Synthesis And Attempted Resolution Of 4-Hydroxymethyl Cyclohexanone Oxime, Canan Avunduk Bonnice Jan 1967

Synthesis And Attempted Resolution Of 4-Hydroxymethyl Cyclohexanone Oxime, Canan Avunduk Bonnice

Doctoral Dissertations

No abstract provided.


Alpha-Arylisoborneols: An Investigation Of The Ord And Cd And A Study Ofthe Ritter Reaction, John Joseph Santos Jan 1967

Alpha-Arylisoborneols: An Investigation Of The Ord And Cd And A Study Ofthe Ritter Reaction, John Joseph Santos

Doctoral Dissertations

No abstract provided.


The Characterization And Cytochemical Localization Of The Adenosine Phosphate Hydrolases In The Gliding Bacterium Vitreoscilla, Jeffrey Carleton Burnham Jan 1967

The Characterization And Cytochemical Localization Of The Adenosine Phosphate Hydrolases In The Gliding Bacterium Vitreoscilla, Jeffrey Carleton Burnham

Doctoral Dissertations

No abstract provided.


Investigations Into The Synthesis Of Potential Macrocyclic Ring-Chain Tautomers And Model Compounds, Ronald John Panicci Jan 1967

Investigations Into The Synthesis Of Potential Macrocyclic Ring-Chain Tautomers And Model Compounds, Ronald John Panicci

Doctoral Dissertations

No abstract provided.


A Kinetic Study Of The Gas Phase Photobromination Of Trichlorosilane, Bernard Launcelot Mahoney Jr. Jan 1967

A Kinetic Study Of The Gas Phase Photobromination Of Trichlorosilane, Bernard Launcelot Mahoney Jr.

Doctoral Dissertations

No abstract provided.


The Preparation And Structural Studies Of Some Anhydrous Fluorostannates, Peter John Moehs Jan 1967

The Preparation And Structural Studies Of Some Anhydrous Fluorostannates, Peter John Moehs

Doctoral Dissertations

No abstract provided.


A Study Of The Radiation Chemistry Of Aqueous Cysteine Solutions, John Lucian Festa Jan 1967

A Study Of The Radiation Chemistry Of Aqueous Cysteine Solutions, John Lucian Festa

Doctoral Dissertations

No abstract provided.


An Investigation Of The Creep Characteristics Of Portland Cement Mortar Under Static And Dynamic Strain, Ikram-Ul-Haq Dar Jan 1967

An Investigation Of The Creep Characteristics Of Portland Cement Mortar Under Static And Dynamic Strain, Ikram-Ul-Haq Dar

Doctoral Dissertations

"The combined effect of static and dynamic loads on design of underground openings is currently receiving much attention. It is known that the time-dependent behavior of rock is considerably different when a dynamic load is superimposed on prestressed rock. The shape of an underground opening has a definite influence on the magnitude of the local stresses and these may be significantly larger than those due to the weight of the overlying rock alone. Under these conditions, even a small dynamic load in the form of vibrations caused by blasting, drilling and related operations may increase the stress beyond a critical …


Study Of Resonance Effects In Allenic And Related Systems, Robert Andrew Steinkamp Jan 1967

Study Of Resonance Effects In Allenic And Related Systems, Robert Andrew Steinkamp

Doctoral Dissertations

"In order to investigate the possibility of resonance effects through a non-coplanar substituted acetylene, synthesis of bis-(2,5,8-trimethyl-l-naphthyl)-acetylene was attempted. Condensation of acetylene with 2,5,8-trimethyl-l-tetralone to yield an acetylenic glycol followed by dehydration and dehydrogenation was expected to yield the desired non-coplanar acetylene. Comparison of its ultraviolet spectrum with that of di-l-naphthyl-acetylene would have suggested the true nature of the acetylene pi cloud. The acetylene condensation was unsuccessful, however.

Substituted allenes, which contain one sp hybridized carbon atom, were then successfully synthesized for a similar analysis of potential resonance effects. A series of para-substituted 4-phenyl-2-methylbutadienoic acids were synthesized and their pKa's …


Kilocycle Range Dislocation Damping In Dilute Magnesium Alloy Single Crystals, Robert Ray Nothdurft Jan 1967

Kilocycle Range Dislocation Damping In Dilute Magnesium Alloy Single Crystals, Robert Ray Nothdurft

Doctoral Dissertations

"The kilocycle range dislocation damping and Young's modulus of single crystals of magnesium and single crystals of magnesium containing small additions of lithium, zinc, or aluminum have been studied as a function of strain amplitude, temperature, and time during annealing and following a high strain amplitude vibration. The data are compared to the Granato-Lücke theory of dislocation damping, the Granato-Hikata-Lücke theory for the recovery of damping following plastic deformation, and the Yamafuji-Bauer theory for the recovery of damping following a high strain amplitude vibration. Reasonable qualitative agreement is obtained between the Granato-Lücke theory and the observed dependence of the damping …


A Study Of Surface And Geometric Effects On The Nucleate Boiling Of Liquid Nitrogen And Liquid Argon From Atmospheric To The Critical Pressure, Calvin Benson Cobb Jan 1967

A Study Of Surface And Geometric Effects On The Nucleate Boiling Of Liquid Nitrogen And Liquid Argon From Atmospheric To The Critical Pressure, Calvin Benson Cobb

Doctoral Dissertations

"A maximum heat flux correlation was derived for corresponding states liquids and subsequently verified by the data collected in this study as well as data presented in the literature. By applying this correlation, one can predict maximum heat flux values at high pressures from maximum heat flux values measured at low pressures; however, to apply the correlation it is necessary to have at least one maximum heat flux value and the saturation temperature at which it was determined.

Contrary to existing correlations, it is shown that for any nucleate boiling heat transfer correlation to be truly general, it must include …