Digital Commons Network^™

Some Statistical Inferences For The Bivariate Exponential Distribution, Bruce Mohr Bemis

Doctoral Dissertations

"The bivariate exponential distribution is neither absolutely continuous nor discrete due to the property that there is a positive probability that the two random variables may be equal. Basic properties of the distribution are presented as well as methods of parameter estimation including maximum likelihood. The distribution is shown to satisfy the usual regularity conditions in spite of its possession of a singularity. The maximum likelihood estimates are asymptotically efficient. Two other methods of estimation are compared with the maximum likelihood method in terms of efficiency. Tests of the hypothesis that two random variables each have independent exponential distributions versus …

Special Subrings Of Real, Continuous Functions, Paul Marlin Harms

Doctoral Dissertations

"Some lattice-ordered subrings of C(X) containing C*(X) are examined where X is a completely regular space. Each realcompact spaceY between [v]x and ßx is associated with a lattice-ordered subring of C(X) which is isomorphic to C(Y) and contains C*(X). The cardinal number of (ßX - [v]X) is a lower bound for the cardinal number of these subrings. Every prime ideal in each of these subrings is comparable with the intersection of the subring and a maximal ideal in C(X). The structure space of maximal ideals is studied for special subrings in C(X) containing C_K(X), the continuous functions of …

Structure And Properties Of Silver Borate Glasses, Edward Nashed Boulos

Doctoral Dissertations

"Clear glasses form in the system Ag₂O-B₂O₃ up to about 35 mol.% (65 wt.%) Ag₂O. Infrared absorption, thermal expansion and density data indicated an analogy to the Na₂O-B₂O₃ system. Pentaborate-triborate group pairs appear to be formed upon the addition of Ag₂O to B₂O₃ up to 20 mol.% Ag₂O and diborate groups from 20 to 33 mol.% Ag₂O. This interpretation is supported by the comparison of the infrared absorption spectra of quenched and crystallized glasses. One crystallization product ,Ag₂O.4B₂O₃, has been identified previously. A new compound starts to appear at 28 mol.% Ag₂O. Silver is generally present as a network modifier …

Trace Base Metals, Petrography, Rock Alteration Of The Productive Tres Hermanas Stock, Luna County, New Mexico, Peethambaram Doraibabu

Doctoral Dissertations

"Zinc, lead and minor copper-bearing manto-type and vein- type deposits occur in Paleozoic sedimentary rocks adjoining the Tres Hermanas quartz monzonite stock, Luna County, New Mexico. In an attempt to prove or disprove a possible genetic relationship between these mineral deposits and the stock, 99 half-mile or closer orthogonal grid samples from the stock and 22 soil samples from a connecting alluvial area to the north were analysed by atomic absorption technique for trace contents of zinc, lead and copper. Thirty-two of the rock samples were selected on a wider grid and petrographically studied and modal analyses calculated. Argillic, sericitic …

X-Ray And Mössbauer Spectroscopy Studies Of The Silicon-Antimony And Bismuth-Antimony Alloys, James Ralph Teague

Doctoral Dissertations

"X-ray and Mossbauer spectroscopy were used to investigate two antimony alloys, Bi-Sb and Si-Sb, showing semiconductorsemimetallic transitions or vice versa, depending on the antimony concentration in the host lattice. Resistivity and density measurements were found to be helpful in the analysis of the results. X-ray studies for dislocation-free antimony-doped silicon showed that the lattice constant of the alloy increased as the antimony concentration increased from 10¹⁸ to 10¹⁹ Sb atoms/cc. Rather good agreement was found between theoretical and experimental changes in lattice constant for dislocation-free silicon. Mössbauer studies showed that the isomer shift decreased linearly with increasing antimony concentration, which …

Chlorobenzene As A Differentiating Solvent For The Oscillometric Titration Of Weak Organic Bases, K Jagan Mohan Rao

Doctoral Dissertations

No abstract provided.

Asymmetric Grignard And Meerwein-Ponndorf-Verley Reductions Long Range Asymmetric Synthesis And The Reduction Of Perfluoroalkyl Carbonyl Compounds, Robert Worrell Ridgway

Doctoral Dissertations

No abstract provided.

Radiative Mean Lives Of Some Excited Electronic Terms In Atomic And Ioniccarbon Using Beam-Foil Excitation, David John Pegg

Doctoral Dissertations

No abstract provided.

A Practical Comparison Of Atomic Fluorescence Flame Spectrometry With Atomic Absorption Flame Spectrometry, Michael Andrew Pleva

Doctoral Dissertations

No abstract provided.

One-Center Expansion Wave Functions And The Hellmann-Feynman Theorem, James Joseph Eberhardt

Doctoral Dissertations

No abstract provided.

Studies On The Biology Of Indo-Pacific Terebridae, Bruce A. Miller

Doctoral Dissertations

No abstract provided.

Polyphenol Oxidase And Phenolics As Related To Single Gene Resistance Of Tomato To Phytophthora Infestans, Richard Scott Warren

Doctoral Dissertations

No abstract provided.

Study Of Ellipsoidal Symmetry Relations In Heavily Doped N-Germanium, Dwight Morton Harris

Doctoral Dissertations

No abstract provided.

Genetics Of An Albino Mutant In Smooth Bromegrass (Bromus Inermis Leyss), Muhammad Nasiruddin

Doctoral Dissertations

No abstract provided.

Psychological Thought Within The Context Of The Scientific Revolution, 1665-1700, Barbara Carr Ross

Doctoral Dissertations

No abstract provided.

Selective Attention Behavior As Predicted By Adler's Social Interest Hypothesis, R John Huber

Doctoral Dissertations

No abstract provided.

The Microbial Ecology Of Sulfur Transformations In Oyster Pond, Woods Hole, Massachusetts, Frank W. Barvenik

Doctoral Dissertations

No abstract provided.

Search Algorithms For The Simple Plant Location Problem, John Bruce Prater

Doctoral Dissertations

"Two algorithms are developed, one exact, one approximate, for finding solutions to the simple plant location problem. Theorems are proved which give sufficient conditions for the inclusion of a plant in the optimal solution. The exact algorithm which is developed is similar to the Branch and Bound method. The approximate technique consists of a directed search through the solution tree for the problem, followed by terminal iterations. The terminal iterations are justified by empirical results obtained from a preliminary version of the technique and a theorem which is proved. Statistics from the results of applying the algorithm to a large …

Use Of The Turbulence Kinetic Energy Equation In Prediction Of Nonequilibrium Turbulent Boundary Layers, William Madison Byrne Jr.

Doctoral Dissertations

"A differential method is proposed for the prediction of a broad range of turbulent boundary layers of engineering and scientific interest. A digital computer program is presented which is applicable to boundary layers with positive, negative, and zero pressure gradient in the main-stream direction as well as boundary layers with suction, blowing or zero mass addition at the wall. The turbulence kinetic energy equation is solved simultaneously with the longitudinal momentum and continuity equations to provide an independent means for determining the effective viscosity which makes allowance for "history" effects in the flow. It is shown that the prediction method …

Absolute Excitation Cross Sections Of He⁺ In 20-100 Kev He⁺-He Collisions Using Energy-Loss Spectrometry, Donald Roy Schoonover

Doctoral Dissertations

"Application of positive-ion energy-loss spectrometry has been extended to include experimental determination of absolute excitation cross sections of ground state helium ions. Helium ion-atom collisions were studied for impact energies ranging between 20-100 keV, in 10 keV intervals. The data were taken with an apparatus resolution between 0.6-o.8 eV FWHM. Cross sections for transitions from ground state to the second and third principal quantum levels of the ion plotted as a function of impact energy were still rapidly increasing at 100 keV. The cross sections at this energy were 1.64(± 0.28) x 10⁻¹⁸cm² for He⁺(l²s_1/2) -> He⁺(n = …

Higher Space Mode Analysis Of A Large Cylindrical Pulsed H₂O System, Harold David Hollis

Doctoral Dissertations

"By utilizing a geometrically centered pulsed source internal to a large (B²_g) ≈ 0.002) cylindrical H₂O system, the neutron flux was measured as a function of position and time. A least square fit of the data yielded the fundamental and five higher decay constants and amplitudes of the thermal neutron flux. Symmetrical and enhanced neutron densities were obtained as a result of the internal source. Long waiting times were unnecessary and data acquisition was accelerated.

The decay constants were found to be independent of position, pulse width, counting time and rates, method of normalization, or waiting time. …

Development And Application Of Cartesian Tensor Mathematics For Kinematic Analysis Of Spatial Mechanisms, Robert Myrl Crane

Doctoral Dissertations

"The complexity of spatial mechanisms in themselves and the absence of an attractive analytical tool for their study has left this field of engineering analysis largely unexplored. In recent years several analytic methods have emerged. One of the most attractive of these is the tensor method. Literature surveys reveal that the tensor method is largely unexploited in the U.S.A., with regard to spatial mechanisms as well as simpler kinematic problems. The purpose of this work is to develop tensor mathematics for application to the kinematic analysis of spatial mechanisms. Methods are developed for position solutions and the determination of velocities …

A Fundamental Investigation Of The Gas Phase Polymerization Of Styrene And Vinyl Type Monomers In A Low Power Inductively Coupled 4 Mhz Rf Plasma, L. F. Thompson

Doctoral Dissertations

"A study has been made on the plasma polymerization of styrene and vinyl type monomers in a cold, low power, inductively-coupled RF plasma. All vinyl type monomers yielded an insoluble, crosslinked film which was slightly colored. A kinetic study is reported for styrene. The effects of power level, bleed rate of monomer, pressure and reactor geometry on the rate of polymer formation are reported. A mechanism is postulated for plasma polymerization. It was found that the initiation step was the rate controlling step and that the reaction followed a cationic polymerization scheme. Both crosslinking and discoloration of the polymers occur …

A Quasi-Lattice Model Of Simple Liquids, Jesse Herbert Collins

Doctoral Dissertations

"A cellular model of simple liquids is proposed which eliminates the objectionable feature of long range order found in other cell models. The volume is divided into N identical spherically symmetric cells, each occupied by one molecule. The cell-center density distribution relative to an average given cell center forms a series of Gaussian peaks whose width is proportional to the square root of the distance from the given cell center. The number of cell centers and average radial distance represented by each of the peaks correspond to a face-centered cubic lattice. The molecular pair distribution function is determined for several …

A Simulation And Diagnosis System Incorporating Various Time Delay Models And Functional Elements, David Michael Rouse

Doctoral Dissertations

"The application of digital simulation to all phases of digital network design is considered here as oppossed [sic] to development of simulation for one or two restricted parts of the digital process. For this reason a simulator is presented which can be consistent by varying the level of expression from the simulation of architectural structures to such detailed simulation requirements as race analysis of asynchronous sequential circuits. In order to make system simulation more than just an idea, it must be capable of handling large circuits in reasonable times. It is demonstrated that functional simulation has the potential to increase …

Discrimination Of Signal And Noise Events On Seismic Recordings By Linear Threshold Estimation Theory, David Nuse Peacock

Doctoral Dissertations

"The object of this study is the investigation of a linear threshold element technique for identifying surface multiples on a single seismic trace. Traces of seismic events were generated which contained primaries, surface multiples, and various levels of Gaussian random noise. Since it was necessary to separate the events as much as possible, the traces were subjected to pulse-compression deconvolution processing prior to LTE analysis. Mean frequency, peak frequency, amplitude spectrum variance, periodicity, and polarity were employed as pattern parameters. A set of weights was found that would maximize the moment of inertia of the S line distribution of the …

An Investigation Of Nucleate And Film Boiling Heat Transfer From Copper Spheres, William David Hardin

Doctoral Dissertations

"This study consisted primarily of a laboratory investigation involving nucleate and film boiling heat transfer from copper spheres with saturated liquid nitrogen at atmospheric pressure. An initial study was directed towards obtaining reproducible boiling heat flux versus ΔT curves in the nucleate boiling region from surface conditions created by single and/or multiple glass bead peenings. The variables of bead size, nozzle line operating pressure, and distance a copper surface should be placed from the nozzle outlet were checked. The results indicated that a final peening of the surface with 0.0017-0.0035 inch diameter glass beads, a nozzle line pressure of approximately …

Some Effects Of Oh Groups On Sodium Silicate Glasses, Mokhtar Sayed Maklad

Doctoral Dissertations

"Glasses of various compositions in the Na₂O-SiO₂ system were prepared with different levels of OH concentration. Phase separation kinetics, thermal expansion, radiation induced optical absorption, and internal friction of these glasses were studied. The increase in OH content in these glasses was found to (a) enhance the rate of phase separation; (b) increase thermal expansion above the glass temperature and change the dilatometric softening temperature in a way that depends on microstructure; (c) increase the radiation induced optical absorption bands associated with positive hole centers and decrease those associated with electron trap centers; and, (d) decrease the low temperature alkali …

The Electrochemical Oxidation Of 1-Pentyne On Platinum And Gold, Michael Jensen Danielson

Doctoral Dissertations

"The anodic oxidation of 1-pentyne was studied at 70°C on Pt and Au electrodes in solutions of H₂SO₄, K₂SO₄, K₂CO₃, and KOH. Pt was studied in a pH range of 0.35 - 12.7 and Au in a range of 10.9 - 12.7. Reaction rates were measured as a function of potential, pH, temperature, and 1-pentyne partial pressure. The coulombic efficiencies for the oxidation to CO₂ were 77 percent in 1 N H₂SO₄ and 69 percent in 1 N KOH on Pt and 43 percent in 1 N KOH on Au. The kinetic parameters on Pt were [partial derivative]V/[partial derivative]log i …

The Reaction Of N-Sulfinylamines With Diazoalkanes, Harry R. Musser

Doctoral Dissertations

"The photochemical decomposition of diphenyldiazomethane in the presence on N-sulfinylamines leads to ketimines. By-products include tetraphenylethylene, benzophenone, thiobenzophenone, and benzophenone azine. This reaction is the first example of carbene addition to a non-carbon containing multiple bond system. Evidence indicates that the carbene adds to the N=S bond of the N-sulfinylamine to give the corresponding thiaziridine-S-oxide which spontaneously decomposes to give ketimine and SO. In the dark N-sulfinylaniline catalyzes the decomposition of diazoalkanes to carbenes. This decomposition presumably takes place through a thiatriazole-1-oxide intermediate. The carbene then reacts either with N-sulfinylaniline to form ketimine, after loss of SO, or with diazoalkane …