Digital Commons Network^™

Mechanical Properties Of The Intermetallic Compound Cafe2as2 At Small Length Scales, John Sypek

Doctoral Dissertations

Nanotechnology has paved the way for the research and development of new classes of materials and how we use them. With the desire to decrease the size of devices all while having advanced properties, research in this field and the development of small-scale experimental techniques has become significantly important. Materials can deform in elastically or plastically when an external load is applied. If elastically deforming a material, the material can then fully recover when unloading and there is no permanent damage to the shape or the structure of the material. When plastically deforming, this means that the materials shape cannot …

Estimating Short-Term Synaptic Plasticity From Pre- And Postsynaptic Spiking, Abed Ghanbari

Doctoral Dissertations

Fast information transmission in neural networks is heavily influenced by short-term synaptic plasticity (STP), and the type and timescale of STP varies by cell-type and brain region. Although STP has been widely characterized in vitrofrom recordings of postsynaptic potentials or currents, characterizing STP in in vivoin behaving animals is difficult due to the lack of large-scale intracellular recordings. Here, we use paired extracellular observations to estimate the short-term dynamics of synaptic transmission from spikes alone. We introduce an augmented generalized linear model (GLM) that includes a dynamic functional connection as well as several, non-synaptic factors that alter spike …

Software Tools For Dna Motif Similarity Comparison And Analysis, Ngoc Tam Le Tran

Doctoral Dissertations

Binding site motifs are short sequences of similar patterns found in DNA or protein. They have an important role in Bioinformatics as they reveal the transcription factors that control the gene expression. Hence, several motif discovery tools have been developed. We reviewed nine Web tools for finding binding site motifs in ChIP-Seq data. The results showed that they reported various results for an identical dataset. This is largely due to the fact that different tools use different strategies and possess unique features for detecting the motifs. Therefore, using multiple tools and methods is generally advised because the motifs commonly reported …

Influence Of Northward Redistribution Of Marine Prey And Predator Species On The Trophic Dynamics Of Environmental Contaminants And Nutrients In Arctic Marine Food Webs, Sara Pereira Pedro

Doctoral Dissertations

The northward-range expansion of sub-Arctic species is altering species interactions, affecting the dynamics of nutrients and contaminants, in Arctic food webs. Arctic marine piscivores are switching from a diet historically dominated by Arctic cod to one comprised of sub-Arctic capelin and sand lance. Another change is the occurrence of killer whales in the Arctic and the presumed switch from a fish-based diet in temperate waters to one richer in marine mammals in the Arctic. My goal was to evaluate some of the consequences of these climate-driven ecological changes, by comparing contaminant and nutrient concentrations in shifting Arctic marine communities. Potentially …

Topology Optimization With Geometric Primitives, Shanglong Zhang

Doctoral Dissertations

Structural shapes that can be described by geometric primitives such as bars and plates are commonly encountered in mechanical, aerospace and civil structures. In this thesis, I determine the optimal layout of a set of geometric primitives within a design envelope using topology optimization techniques. To perform the structural and sensitivity analyses of these structures, the geometric primitives are mapped onto a continuous density field defined over a fixed finite element grid via the geometry projection method. As a result, the optimal topology can be more easily fabricated by joining stock structural shapes through various means. Previous works on geometry …

Determining The Efficacy Of Insulin For Use In Factor Delivery Device For Tendon Healing And Regeneration, Daisy Ramos

Doctoral Dissertations

Tendon injuries account for roughly half of the 33 million musculoskeletal injuries that occur every year. Of all patients seeking nonsurgical treatment, 29% eventually require surgery. The use of autografts, allografts, and xenografts have limitations associated with donor site morbidity, availability, and immunogenicity. Tissue engineering has emerged as a feasible approach to find treatments for injuries requiring tissue replacement through biodegradable scaffolds, stem cells, and biomolecules.

Tissue engineering scaffolds serve to provide a temporary, biomimetic template for cells, as well as act as delivery vehicles for biomolecules, such as growth factors. Growth factors have been widely popular in tissue engineering …

Accelerating Reactive-Flow Simulations Via Vectorized Chemical Kinetic Evaluation, Nicholas Curtis

Doctoral Dissertations

This work details efforts to reduce the cost of using detailed chemical kinetic modeling in realistic reactive-flow simulations, utilizing analytical Jacobian evaluation and vectorized-computing on the central processing unit (CPU), graphics processing unit (GPU) and other hardware-accelerators.

The first part of this thesis investigated GPU-based ordinary differential equation (ODE) methods for stiff chemical kinetics. A fifth-order implicit Runge--Kutta method and two fourth-order exponential integration methods were implemented for the GPU and paired with the analytical chemical kinetic Jacobian software pyJac. The performance of each algorithm was compared with a commonly used CPU-based implicit integrator CVODEs. The implicit Runge--Kutta method running …

Hierarchical Structures For High Dimensional Data Analysis, Mahmoodreza Jahanseirroodsari

Doctoral Dissertations

The volume of data is not the only problem in modern data analysis, data complexity is often more challenging. In many areas such as computational biology, topological data analysis, and machine learning, the data resides in high dimensional spaces which may not even be Euclidean. Therefore, processing such massive and complex data and extracting some useful information is a big challenge. Our methods will apply to any data sets given as a set of objects and a metric that measures the distance between them.

In this dissertation, we first consider the problem of preprocessing and organizing such complex data into …

Electric Form Factor Of The Neutron From Asymmetry Measurements, Richard Frederick Obrecht Jr

Doctoral Dissertations

The overwhelming majority of visible mass in the universe is composed of protons and neutrons, collectively known as nucleons, which are arguably the most important strongly interacting systems to study. A nucleon may naively be thought of as a composite object built out of three non-interacting sub-objects, known as quarks, in the large energy limit; however, the structure of the nucleon is much more complicated, and consequently far richer, than a simple valence-quark picture. There are sea quarks in addition to valence quarks that interact strongly via the exchange of gluons resulting in a complex vacuum structure, and the collective …

Insights Into Well Performance And Completion Optimization Using A Coupled Fracfocus And Drillinginfo Database, Mustafa A. Al-Alwani

Doctoral Dissertations

“The hydraulic fracturing designs, drilling, and completion trends are undergoing continuous change as the oil and gas industry pushing the boundaries of the traditional designs to increase wells productivity and meet the energy demand. The lateral length in addition to the amount of proppant and water used in well stimulation have witnessed a paradigm shift over the past few years. The motivation for this work began with a desire to better understand well performance as a function of the type of fracturing fluid treatment applied. An early objective was to compare whether East Texas Cotton Valley wells stimulated with water …

Development Of Functional Ionic Liquids For Separation And Recovery Of Rare Earth Elements, Mostafa Khodakarami

Doctoral Dissertations

“This research focused on the design and synthesis of task-specific ionic liquids for enhanced extraction and separation of rare earth elements (REEs). Two novel ammonium-based functional ionic liquids (FILs) with oxygen donating groups: trioctyl(2-ethoxy-2-oxoethyl)ammonium dihexyl diglycolamate, [OcGBOEt][DHDGA], and tricaprylmethylammonium dihexyl diglycolamate, [A336][DHDGA] were synthesized and tested for the recovery and separation of selected REEs from aqueous solutions. Functionalities with different denticities were incorporated into both anionic and cationic parts of ionic liquids, which are solely composed of incinerable atoms including C, H, O, and N. The structural, physical, and chemical properties of the synthesized FILs were studied using nuclear magnetic …

Design And Performance Of Fiber-Reinforced Concrete With Adapted Rheology For Construction And Repair Of Bridge Structures, Ahmed Abdelrazik

Doctoral Dissertations

“The objective of this document is to design high-performance fiber-reinforced self-consolidating concrete (FR-SCC) for infrastructure repair and fiber-reinforced super-workable concrete (FR-SWC) for bridge construction. The investigated fibers included propylene synthetic fibers, hooked steel fibers, double and triple hooked steel fibers, hybrid crimped steel fiber and polypropylene multifilament fibers, and micro-macro steel fibers. The fiber volume varied between 0 and 0.75%. An expansive agent (EA) was incorporated to compensate for shrinkage and induce compression in the concrete at early age. Two types of EA (G and K) were employed at 0 to 8%, by mass of binder. The investigated FRSCC and …

Feasibility And Assessment Of Using Recycled Rubber For Infrastructure Applications, Ahmed A. Gheni

Doctoral Dissertations

“The United States needs to mine billions of tons of raw natural aggregate each year. At the same time, millions of scrap tires are stockpiled every year. Therefore, replacing natural aggregate with recycled crumb rubber aggregate will be beneficial to the construction industry and environment. This research aimed to investigate the feasibility of using recycled rubber in new construction applications. Based on size, recycled rubber was selected to match its natural counterpart. Different ratios of recycled crumb rubber were used as a fine aggregate replacement in concrete masonry units (CMUs) where the rubberized units showed a lower unit weight, higher …

Design, Fabrication, And Characterization Of Functionally Graded Materials, Sreekar Karnati

Doctoral Dissertations

“The aim of this research was to investigate the feasibility of fabricating custom designed, graded materials using Laser Metal Deposition (LMD) that will cater for functionality and unconventional repair. The ultimate goal of the project is to establish the versatility of LMD for fabricating advanced materials and tackling problems that have been conventionally difficult or in cases infeasible. In order to accomplish these goals, this research involved investigations into, the feasibility of using elemental powders as modular feedstocks, the feasibility of fabricating tailored gradients with these custom compositions, and finally leveraging the advantages of grading materials using LMD to successfully …

Designing Bifunctional Materials For In-Situ Capture And Conversion Of Volatile Organic Compounds, Anirudh Krishnamurthy

Doctoral Dissertations

”Volatile organic compounds (VOCs) are a class of organic liquid compounds with low vapor pressures, which enables them to vaporize at ambient conditions. VOCs are largely toxic, carcinogenic, and mutagenic, and have profound adverse effects on human health and the ecological environment. Many VOCs cause ruinous health effects even at very low concentrations (ppm) and therefore control of these organic compounds is essential for ensuring good air quality. A large portion of VOCs cause catastrophic health effects such as cancer or liver damage even at very low concentrations (ppm), and the control of these compounds is vital in ensuring good …

Use Of Wicking Geotextile To Dehydrate Road Embankments, Chuang Lin

Doctoral Dissertations

“Excess water within a pavement structure is the major cause of pavement deteriorations. A roadway is often constructed with soils compacted at the optimum water contents to achieve the best performance. After construction, the soil water content variation is controlled by the ambient environment. The base course aggregate is very sensitive to water content variations. Unfortunately, conventional drainage system can only drain gravity water, but not capillary water, and it cannot work under unsaturated conditions. Consequently, no matter how well the road is constructed, the water content is expected to increase with time and the excess water will inevitably accelerate …

Three-Dimensional Nanotube Arrays For Solar Energy Harvesting And Production Of Solar Fuels, Wipula P. R. Liyanage

Doctoral Dissertations

"Over the past decade extensive research has been carried out on photovoltaic semiconductors to provide a solution towards a renewable energy future. Fabricating high-efficiency photovoltaic devices largely rely on nanostructuring the photoabsorber layers due to the ability of improving photoabsorption, photocurrent generation and transport in nanometer scale. Vertically aligned, highly uniform nanorods and nanowire arrays for solar energy conversion have been explored as potential candidates for solar energy conversion and solar-fuel generation owing to their enhanced photoconversion efficiencies.

However, controlled fabrication of nanorod and especially nanotube arrays with uniform size and shape and a pre-determined distribution density is still a …

Nanoscale Solidification Of Metals By Atomistic Simulations: From Nucleation To Nanostructural Evolution, Avik Mahata

Doctoral Dissertations

"Homogeneous nucleation during solidification in Al (fcc), Fe (bcc) and Mg (hcp) is studied by million-atom molecular dynamics (MD) utilizing the second nearest neighbor modified embedded atom method (2NN-MEAM) potentials. Spontaneous homogenous nucleation from the melt was produced without any influence of pressure, free surface effects and impurities. We also study the effect on the simulation size on homogenous nucleation and the heterogeneity in homogenous nucleation. The heterogeneity in homogenous nucleation originates from the twins, grain boundaries and short range order in the liquid during the initial stages of solidification.

To study the solid-liquid coexistence in binary Al alloys, interatomic …

Development Of A Switchable Radioisotope Generator, Kyle Mitchell Paaren

Doctoral Dissertations

The Switchable Radioisotope Generator utilizes alpha-induced reactions to produce a combination of photons, neutrons, and protons with varying fluxes dependent on target materials and source geometry. The activity/strength of the secondary radiation is further controlled by manipulating the number of alpha particles that can interact with the target material(s). Analytical equations were solved to confirm secondary radiation production from target materials using average cross sections from TENDL data. TENDL and JENDL data was confirmed by analytically solving for the total alpha-induced cross sections. This information was used to produce the provisional and utility Patent No: US20190013109A1. TENDL data was then …

Active-Passive Dynamic Consensus Filters: Theory And Applications, John Daniel Peterson

Doctoral Dissertations

”This dissertation presents a new method for distributively sensing dynamic environments utilizing integral action based system theoretic distributed information fusion methods. Specifically, the main contribution is a new class of dynamic consensus filters, termed active-passive dynamic consensus filters, in which agents are considered to be active, if they are able to sense an exogenous quantity of interest and are considered to be passive, otherwise, where the objective is to drive the states of all agents to the convex hull spanned by the exogenous inputs sensed by active agents. Additionally, we generalize these results to allow agents to locally …

Plasmonic Metamaterial For Structural Color Printing And Spontaneous Emission Control, Wei Wang

Doctoral Dissertations

”Plasmon polaritons or plasmons are a collective oscillation movement of free electrons in metal at optical frequencies. The frequency-dependent complex dielectric function makes the metal property at optical frequencies behave totally different with that at other spectral ranges with lower frequency such as infrared and microwaves. This novel property makes the so called plasmonics or nanoplasmonics a rapid growing research field over the past few years. Many innovative concepts and applications have been developed such as perfect absorber, structural color printing, and quantum emitter spontaneous emission enhancement.

In this dissertation two of the most important applications will be addressed. The …

Build Strategy Investigation Of Ti-6al-4v Produced Via A Hybrid Additive Manufacturing Process, Lei Yan

Doctoral Dissertations

“Till now, laser metal deposition (LMD) has been developed with the capability of near-net shape high-performance metal parts fabrication, especially complicated titanium alloys, nickel alloys, and aluminum alloys. However, LMD processed parts usually do not meet end-use requirements without post treatments. In-process part quality inspection and inner features machining are impossible within a single LMD process. Hybrid additive manufacturing (HAM), which integrates additive and subtractive manufacturing in one process, has been proposed to increase the feasibility of complex parts fabrication. This dissertation aims to improve the applications of Ti-6Al-4V parts fabricated via a HAM technique. The first research topic is …

Intelligent Data-Driven Decision-Making To Mitigate Or Stop Lost Circulation, Husam Hasan Alkinani

Doctoral Dissertations

”Lost circulation is a challenging problem in the oil and gas industry. Each year, millions of dollars are spent to mitigate or stop this problem. The aim of this work is to utilize machine learning and other intelligent solutions to help to make better decision to mitigate or stop lost circulation. A detailed literature review on the applications of decision tree analysis, expected monetary value, and artificial neural networks in the oil and gas industry was provided. Data for more than 3000 wells were gathered from many sources around the world. Detailed economics and probability analyses for lost circulation treatments’ …

Plenum-To-Plenum Heat Transfer Characteristics Under Natural Circulation In A Scaled-Down Prismatic Modular Reactor, Salman Mohammed Alshehri

Doctoral Dissertations

“Gas-cooled reactor (GCR) is being developed under the Next Generation Nuclear Plant Program (NGNP) in nuclear engineering studies. As the world searches for an energy source with high energy density, clean, abundant, and storable nature to avoid global warming issues, GCR seems to be a promising solution, particularly the possibility of producing hydrogen. Studying and developing the safety analysis and GCR technologies are required for the optimum design and safety of GCR system. Multiphase Reactors Engineering and Applications Laboratory (mReal) at Missouri University of Science and Technology (S&T) has developed a natural convection heat transfer test facility with one riser …

Design And Characterization Of A Strong Positron Source At The Mstr Beam Port, Raed Atiah Alsulami

Doctoral Dissertations

“For many years, slow positron sources have found uses in diverse fields including medical physics, nuclear physics, biology, surface science, exotic atom research and space science. The purpose of this work is to design and optimize a reactor-based positron source at the Missouri University of Science and Technology Reactor (MSTR) beam port and quantify its intensity. Monte Carlo simulations using the MCNP6 code were used to model the positron production and moderation processes at the MSTR beam port. The thermal neutron flux at the beam port was determined experimentally and used in the source definition of the radiation transport simulations. …

Computational Fluid Dynamics Modeling And Comparison Of Advanced Techniques For Heat Transfer Augmentation For Nuclear Applications, Salman Mohammed Alzahrani

Doctoral Dissertations

“Passive safety is the most important feature of NuScale’s reactor designs. Twist tape is one passive heat enhance heat technique. The present research investigated thermo-hydraulic characteristics of natural and forced convection of water under different configurations of twisted tape inserted in tube as well as NuScale rod bundles for uniform wall heat flux using computational fluid dynamics (CFD) using ANSYS Fluent 18.1. Results for twist tape inserted in tube under natural circulation showed that heat transfer enhanced and pressure drop increased to 28% and 102.8% over the plain tube respectively. Regularly spaced tapes, and different widths of the twisted tapes …

Characterization Of Aerosols In An Underground Mine, Arash A. Habibi

Doctoral Dissertations

“Diesel-powered engines are a common source of submicron carbon-rich particles. Characterizing morphological and physical attributes of diesel agglomerates is therefore of great importance to be able to identify the source and improve removal technology. Size-segregated sampling was conducted in two phases of underground experiments. Scanning transmission electron microscopy and fast mobility particle sizers were used to determine the size distribution of agglomerates based on particle mobility and projected area diameter. Controlled zone sampling test results were used to determine the morphological characteristics of agglomerates for specific types of diesel equipment both with and without removal strategies. Changes in fractal dimension, …

Scaleable Nanomanufacturing Of Metasurfaces Using Microsphere Photolithography, Chuang Qu

Doctoral Dissertations

“The cost-effective manufacturing of metasurfaces over large areas is a critical issue that limits their implementations. Microsphere photolithography (MPL) uses a scalable self-assembled microsphere array as an optical element to focus collimated light to nanoscale photonic jets in a photoresist layer. This dissertation investigates the fabrication capabilities, process control, and potential applications of MPL. First, the MPL concept is applied to the fabrication of metasurfaces with engineered IR absorption (e.g. perfect absorption with multiband/broadband and wavelength/polarization dependences). Improving the patterning of the photoresist requires a fundamental understanding the photochemical photonic jet interactions. The dissertation presents a model of the MPL …

Provenance, Redox Conditions, And Diagenesis Of Shales In Chang 7 Member Of Upper Triassic Yanchang Formation, Ordos Basin, China, Bin Sun

Doctoral Dissertations

“This study aims to decipher provenance, redox conditions, and burial history of shales in Chang 7 Member of Upper Triassic Yanchang Formation, Ordos Basin, China. The first paper discusses the origins of single-channeled, vertical, sinuous, and calcite-bitumen-filled cracks in the shales. Results show that in early diagenesis, unconsolidated mud was expanded open by escaping gases produced during organic matter maturation under hydrothermal influences. Calcite initially filled the cracks; bitumen and pyrite came in later and occupied the cracks in various ways. Compaction occurred next and folded the calcite- and bitumen-filled cracks into sinuous shapes. The second paper uses geochemical and …

On Developing A Graphitic White Iron For Metal-To-Metal Wear Systems, Jie Wan

Doctoral Dissertations

"This research addressed heat dissipation issues related to the adhesive wear observed in metal-to-metal wear systems, by developing a graphitic white iron to increase thermal diffusivity of the wear components. One of the premium materials commonly used in current metal-to-metal wear systems is Fe15Mo18Cr and field returned parts were characterized as part of this study. Failure analysis showed that white layers were formed on the wearing surface due to frictional heating and surface deformation. These white layers were extremely brittle and could be fractured easily during use, which in turn led to micro-galling defects that caused parts leakage. Increasing thermal …