Digital Commons Network^™

Design Of Real-Time And Energy-Efficient Driver Assist Systems Using Electroencephalogram And Neuromorphic Computing, Nathan Alan Lutes

Doctoral Dissertations

Despite the technological breakthroughs in advanced driver assist systems, distracted driving persists as a major challenge to roadway safety. This investigation advances the body of knowledge towards a solution by developing an individualized driver-state detection method using electroencephalogram (EEG) and neuromorphic computing to provide a less invasive and more energy efficient ADAS solution. It furthermore explores the changes in brain functional connectivity under distracted conditions to better understand brain state information that could be used for neuro-feedback intervention systems. The first contribution introduces the concept of using Convolutional Spiking Neural Networks (CSNNs) for recognition of patterns with movement-intention predictive power …

Synthesis And Analysis Of Materials For Quantum Devices, Mathew Pollard

Doctoral Dissertations

Quantum materials play a pivotal role in the advancement of next-generation technology. Superconducting quantum computing, dissipationless spintronics, or valleytronics offer promising ways forward beyond traditional chip miniaturization. Josephson Junctions (JJs) have already revolutionized quantum information and high precision detectors. Quantum systems, however, are either hard to control, produce, and/or maintain. This calls for a better understanding of microscopic properties and tuning of these quantum states.

In this work, we experimentally investigated growth methods to control the electric and magnetic properties of Topological Insulator (TI) Sb2Te3 through Cr-doping. Our results demonstrate the onset of a Magnetic Topological Insulator (MTI) and have …

Higher-Order Statistics And Normalized Decay Analysis For Detector Deadtime Characterization, Abdallah Wazzan

Doctoral Dissertations

Detector deadtime limits radiation measurement accuracy at high count rates, yet current methods rely on idealized paralyzable or non-paralyzable models. Real detectors exhibit hybrid behavior requiring advanced characterization approaches. This study explores deadtime characterization using two Monte Carlo simulation approaches: higher-order statistical analysis of inter-arrival times and simplified deadtime correction with hybrid models.

Using MATLAB (PULSE-WIZ), we analyzed full decay curves spanning ~4.5 half-lives of Cobalt-60 and Vanadium-52, examining coefficient of variation (CV), skewness, and kurtosis of inter-arrival times, plus normalized decay curves with Full Width at Half Maximum (FWHM) analysis. Hybrid models incorporated paralyzable and non-paralyzable components with dead …

Tailoring Selected Aerogels To Targeted Applications, Stephen Yaw Owusu

Doctoral Dissertations

Aerogels are ultra-lightweight, porous solid materials characterized by a three-dimensional nanostructured network. Owing to their exceptional physical and chemical properties, aerogels have garnered considerable attention within the materials science community and were recognized by IUPAC in 2022 as one of the top ten emerging technologies in chemistry. Although numerous aerogels have been synthesized, only a few have been effectively tailored for specific applications. Optimizing the properties of known aerogels for targeted uses remains challenging. This dissertation investigates strategies for tailoring aerogels derived from isocyanate-benzoxazine, benzodiazine, and phenolic resins to meet the requirements of various advanced applications. The approaches employed include …

Characterization And Deportment Of Anode Impurities In Copper Electrorefining, Charles Michael Campbell

Doctoral Dissertations

The objective of this research was to study the deportment of the group 15 elements, arsenic, antimony and bismuth during copper electrorefining. Samples were collected from six industrial copper anodes with different compositions. Specimens were physically characterized and electro refined to understand the differences in the behavior of selected impurities. Inclusions in the cast metal structures were characterized using automated scanning electron microscopy and energy dispersive spectroscopy to measure and correlate their size, shape and composition. Arsenic and lead were found to have a positive correlation between concentration and size of inclusions. Using wavelength dispersive spectroscopy, multiphase inclusions were examined, …

Machine Learning Models For Location Prediction, Message Routing And Path Planning For Rescue Of Underground Miners, Abhay Goyal

Doctoral Dissertations

Self-rescue during underground mine disasters is vital for miner safety. Evolving hazards and post-disaster conditions demand solutions that enable navigation under severe communication and computational constraints. Centralized systems often fail in such rugged settings, while decentralized methods—particularly Delay Tolerant Networks (DTNs), proven in battlefields and space missions—offer distinct advantages for underground applications. This research addresses five core challenges: (i) predicting miners’ next locations on low-power devices using points of interest and movement sequences; (ii) delivering timely updates on safe routes, evacuation zones, and hazardous areas; (iii) evaluating energy efficiency and comparing graph-based approaches to existing methods; (iv) enabling edge-ready frameworks, …

Generalizations Of Finiteness Conditions And Extension Monads In Algebras With Infinitely Many Or Infinitary Operations, Danielle Christienne Bowerman

Doctoral Dissertations

In this work, we extend the results of finiteness conditions and extension monads found in Insall from finitely many finitary operations to infinitely many finitary operations, as well as touching on infinitary operations. We also examine varieties of algebras, including the notion of strong varieties introduced in Insall, and common constructions of extension monads in varieties of algebras. We see that for finite collections of algebras of the same signature, the extension monad operation on a variety of algebras commutes with the direct product operation, and all retractions from an enlargement or extension monad are trivial. We also see that …

Applying Human System Integration Principles To The Investigation, Design And Validation Of Interventions For Self-Escape In Underground Mines, Eugene Adubofour Gyawu

Doctoral Dissertations

This dissertation investigates the use of human systems integration (HSI) to develop technologies for miners’ self-escape during a mine emergency, addressing barriers that compromise miner safety during emergencies.

Recognizing the inherently hazardous nature of underground mining, this study has three core objectives: (1) assessing miners' perceptions of proposed self-escape interventions, (2) designing interventions based on these insights, and (3) validating their effectiveness using experimental testing. This work evaluates self-escape interventions for both coal and metal/non-metal miners using scenario-based surveys, information design reviews, label designs and experimental testing methods varying across three distinct studies.

Results reveal that miners identified improvements to …

Quantum And Classical Phase Transitions In Disordered Systems, Gaurav Ramesh Khairnar

Doctoral Dissertations

This work examines the effects of quenched disorder on classical and quantum phase transitions. There are countless examples of phase transitions in nature. Here, we study phase transitions in condensed matter with the help of simple models that focus on the essential unifying features of the problems. We are particularly interested in investigating how the presence of disorder changes the behavior of the system in the vicinity of a phase transition.

Here, we discuss three closely related problems regarding phase transitions. First we consider the behavior of highly diluted magnets with varying dilution levels in order to explain the unusual …

Experimental Study Of Defects In Coaxial Wire-Based Laser Metal Deposition, Remy Mathenia

Doctoral Dissertations

This work seeks to improve the usability and capability of coaxial wire-based laser metal deposition (LMD) through the experimental study of process parameters on output geometry, directional effects, and defect formation. Wire-based LMD is a directed energy deposition (DED) strategy that uses a focused laser heat source to melt and fuse metal wire as it is deposited. This process is used to build parts layer-by-layer until a desired geometry is accomplished. LMD enables the creation of complex components at a high build rate with low material and energy waste. This work focuses on the deposition of titanium wire in the …

Development Of Dual-Scan Nuclear Magnetic Resonance (Nmr) Pulse Programs For Spin-Lattice Relaxation Measurements, Zachary Mayes

Doctoral Dissertations

This research develops and refines the Split Inversion Pulse and Recovery (SIP R) methodology for spin-lattice relaxation (T₁) measurements in NMR spectroscopy. SIP R introduces a two-scan difference technique using a split inversion pulse sequence, where the 180° pulse is split into two 90° pulses phase-shifted with respect to each other. This approach simplifies data fitting, requiring only two parameters to extract T₁ values, compared to the traditional inversion-recovery method, which needs three. The SIP-R-DS and SIP-R-S adaptations extend this framework by incorporating selective NMR resonance excitations, enhancing its applicability to cross-polarization experiments and enabling unobstructed NOE measurements. These adaptations …

Metal-Organic Thin Film Coated On Optical Fiber, Nahideh Salehifar

Doctoral Dissertations

This dissertation explores the development of metal-organic framework (MOF)-based optical fiber sensors for detecting volatile organic compounds (VOCs) at low concentrations (parts-per-billion to parts-per-million). In the first part of the study, theoretical calculations were performed using effective medium approximation (EMA) models, including Lorentz–Lorentz, Maxwell–Garnett, and Bruggeman equations, to predict the refractive index changes of MOFs upon gas adsorption. These models were applied to MOFs such as ZIF-7, ZIF-8, ZIF-90, MIL-101(Cr), and HKUST-1 to evaluate their potential for gas sensing.

In the second part of the dissertation, experimental work was conducted to validate the theoretical predictions. MOF-coated optical fibers were fabricated …

Deep Learning And Adaptive Clustering Approaches For Flood Prediction And Efficient Sensor Placement In Missouri, Fahimeh Sharafkhani

Doctoral Dissertations

Floods represent formidable natural calamities, posing a significant threat to communities and infrastructure due to their unpredictable and often devastating consequences. The occurrence of floods is influenced by a convergence of meteorological, hydrological, and geographical factors, resulting in changes to the patterns of rising water levels. Machine learning models have emerged as favored tools in recent times for modeling water levels and enhancing the precision of flood predictions. This research employs both supervised and unsupervised machine learning models, with the main objective of improving the accuracy of flood predictions and sensor placement. Four distinct deep learning models are used to …

Measurement Method And Applications Of Transfer Function In Rf Desensitization Problem, Xiangrui Su

Doctoral Dissertations

Radio frequency (RF) desensitization issues comprise two components: noise radiation sources and the transfer function from noise sources to the victim antenna. RFI is a critical challenge in modern electronic systems, particularly in densely packed environments. This work presents a comprehensive study of RFI, addressing key aspects through three novel contributions. First, a transfer function measurement method is developed for compact metallic enclosures. This method provides a precise characterization of the electromagnetic (EM) environment within confined spaces, enabling accurate identification of interference pathways. Second, an EM emission management analysis framework is proposed, leveraging transfer functions to quantify and mitigate interference …

Topics On Ai Fairness Preferences In Kidney Transplantation, Mukund Telukunta

Doctoral Dissertations

Modern kidney transplantation incorporates artificial intelligence (AI) decision-support systems which exhibit social discrimination due to biases inherited from training data. Although researchers have proposed various group-based fairness notions to assess biases in AI, it remains uncertain which criterion is most suitable for evaluating biases in such complex healthcare systems. This dissertation explores human perception of fairness to identify the most appropriate fairness criterion for assessing AI tools in kidney transplantation, focusing on the preferences of non-expert (e.g. public, patients) stakeholders. The study examines two distinct AI systems employed in kidney transplantation: a classification model and a regression model. Human subject …

Epitaxial Growth Of Metal-Organic Framwork Thin Films By Electro-Conversion And Electrodeposition, Xiaoting Zhang

Doctoral Dissertations

Electrochemical epitaxy is a facile and inexpensive soft-solution process to fabricate highly ordered thin films. This research focuses on the epitaxial growth of metal-organic framework (MOF) thin films by electrochemical methods which include electro-conversion and electrodeposition.

First, an electrochemical conversion pathway was invented to achieve epitaxial MOF thin films. Epitaxial single-domain Cu-BTC(111) thin films were manufactured by electrochemical oxidation of Cu₂O(111) films electrodeposited on single-crystal Au(111). The single-crystal-like Cu-BTC(111) thin films with out-of-plane and in-plane order provide well-aligned 3.5 Å triangular windows along the [111] direction. Cu-BTC(111) foils were fabricated from the Cu-BTC/Cu₂O system by electrochemical …

Investigation Of Shockwave Behavior To Inform Helmet Design Using Schlieren Imagery And Free-Field Blasts, Cody Jh Thomas

Doctoral Dissertations

"Ballistic resistance of military helmet designs is a prioritized feature to protect warfighters from traumatic brain injury. However, injuries from shock-based threats have not been optimized for warfighter protection and have resulted in the prevalence of blast-induced traumatic brain injury (bTBI). Research gaps were identified in understanding the under wash effect using free field blasts and schlieren imagery. Thus, the following were investigated: (1) overpressure changes on a warfighter’s head due to directionality from a blast, (2) shock wave dampening effects of viscoelastic materials in helmets, and (3) geometric effects of a helmet brim design in the reduction of bTBI. …

Polybenzodiazine Aerogels: All-Nitrogen Analogues Of Polybenzoxazines - Synthesis, Characterization, And Their Application In Carbon Dioxide Capture, Vaibhav Edlabadkar

Doctoral Dissertations

"The rapidly risen concentration of carbon dioxide in the atmosphere over recent years contributed to global warming and ocean acidification. Carbon capture is viewed as an essential tool from keeping atmospheric CO₂ levels from rising further. This thesis focuses on the development of new materials for high capacity and selective adsorption of CO₂. One such material was based on a newly synthesized tetrahydroquinazoline (THQ), which was designed as an all-nitrogen analogue of main-stream benzoxazine monomers. THQ solutions in DMF gelled at 100 °C via HCl-catalyzed ring opening polymerization to polybenzodiazine (PBDAZ) wet gels, which were dried in …

Applications Of Tetramethyl-Guanidine Supported Cationic Transition Metal Sites Towards C─N Bond Construction Methodologies And [3+2] Cycloaddition Reactions, Suraj Kumar Sahoo

Doctoral Dissertations

"We present a family of divalent cationic bipodal and tripodal M(II) reagents (M = Mn, Fe, Co) supported by superbasic tetramethyl-guanidinyl (TMG) residue framework with applications towards C─N bond construction methodologies. These cationic reagents possess unique characteristics since their enhanced Lewis acidity facilitates in situ elaboration of the primary nitrene-transfer product (aziridine). Indeed, further aziridine-ring opening and cycloaddition of several dipolarophiles (nitriles, alkenes, ketones) permits the three-component synthesis of valuable five-membered N-heterocycles, commonly found in pharmaceuticals and agrochemicals.

We undertake a more systematic study to unravel parameters that make certain divalent metal sites more suitable as catalysts for the in-situ …

Development Of Ligands And Metal Complexes With Weakly Coordinating Apical Elements And Their Application To Nitrene Insertion And Addition To C‒H And C=C Bonds, Meenakshi Sharma

Doctoral Dissertations

"We present a family of triangular coinage metal M₃Cl₃ complexes [M = Cu (I), Ag (I)] supported by antimony [Sb (III)], and bismuth [Bi (III)]-centered highly basic tetramethyl-guanidinyl [TMG₃trphen-E] (E = Sb, Bi) ligand frameworks with their applications as catalysts toward the construction of C‒N bond through aziridination and amination reaction methodologies.

The [(TMG₃trphen-Sb)Cu₃(µ-Cl)₃] catalyst gives better yields of aziridines with styrenes than [(TMG3trphen-Bi)Cu₃(µ-Cl)₃] with PhINTs as a nitrene source. However, the catalytic reactivity of both catalysts is enhanced by an electrophilic nitrene, PhINTces for …

Sensor Embedding And Thermal Monitoring Strategies For Laser-Foil-Printing Additive Manufacturing, Tunay Turk

Doctoral Dissertations

"This work investigates Laser Foil Printing (LFP), a novel metal additive manufacturing (AM) process that fabricates parts layer-by-layer using metal foils. To enhance LFP productivity, the process steps were optimized, and an 88.1% reduction in processing duration was achieved. A unique aspect of this study was the introduction of laser polishing as an edge polishing technique within the LFP process. This innovative approach, employing an overlapping spiral pattern, leverages selective laser remelting and erosion to effectively suppress elevated edges. To stabilize the molten melt pool, a discrete spot scanning strategy was implemented. The fabricated parts were subjected to detailed analysis, …

Raft-Based Polymer And Nanoparticle Materials For Traumatic Brain Injury Treatment And Diagnostics, Aaron Priester

Doctoral Dissertations

"Traumatic brain injury (TBI) is a leading cause of death and disability worldwide. Neurodegenerative diseases that develop post-TBI can be, in part, attributed to DNA and cell-damaging reactive oxygen species (ROS) and lipid peroxidation products (LPOx). This thesis focused on overcoming the limits of current TBI material treatment approaches by employing a RAFT (reversible-addition fragmentation chain transfer) polymer approach that incorporated novel therapeutic, diagnostic and peptide-targeting monomers. An improved nanoparticle synthesis approach was also developed. Thiol and thioether-containing monomers neutralize both ROS and LPOx while Gd-containing monomers with enhanced magnetic resonance imaging (MRI) contrast provide diagnostics and material tracking in …

Vibration Modeling Of Rectangular Plates And Application To Solar Cell Dust Mitigation, Jeremiah John Rittenhouse

Doctoral Dissertations

"Many engineering structures can be modeled as rectangular plates, including solar cells. Carefully controlled plate vibration can be useful to solve an engineering problem, such as lunar dust accumulation on solar cells, which blocks light and reduces power generation. For this application, plate vibration at resonance is studied and used experimentally to eject lunar dust from a solar cell.

Piezoelectric actuator placement on the inactive side of a solar cell to induce vibration dust mitigation from the active side of the cell is presented in this work. Three solar cell prototypes were created and tested for efficacy, resulting in an …

Atmospheric Transport Of Radionuclides, Meteorological Data Mining & Synthesis For Site Data Supplementation, Ben Yao Sonpon

Doctoral Dissertations

"This research aligns with the NRC's vision of implementing risk-informed decision-making to support its regulatory charter. The suite of tools developed includes automated procedures for data mining and extracting meteorological (met) data from various national and regional repositories. A second data analytics tool automates the process of data fusion into a uniform format while preserving data fidelity. Autocorrelations were then established, and correlation coefficients were calculated between the Callaway Nuclear Power Plant (Callaway) and nearby off-site weather stations. The complexity of these correlations depends on factors such as physical proximity, geographic features, and topology, potentially necessitating multivariate analysis (MVA). Furthermore, …

Shock Wave And Vortex Ring Dynamics From Explosively Driven Shock Tunnels, Rachel Louise Bauer

Doctoral Dissertations

"Blast and shock tubes are frequently used to create shock waves to study their effects and impacts on structures, humans, and personal protective equipment. These tubes are also found in other industries including wind tunnels for aerodynamic testing, jet engines for propulsion research, spacecraft reentry simulations, and industrial applications such as material testing and high-velocity impact studies. Despite their widespread use, there is no standard design, with variations in geometry, size, and energy sources. Current research only evaluates the peak pressure of the shock wave produced and does not consider the effects of changing the size or geometry of the …

Transport And Plugging Behavior Of Co2-Resistant Preformed Particle Gels In High Conductive Channels For Conformance Control, Adel Alotibi

Doctoral Dissertations

"Improving oil recovery is essential with rising global oil demand and declining production in mature fields. CO₂ flooding has been widely applied as a major Enhanced Oil Recovery (EOR) method due to its effectiveness in boosting oil recovery while enabling safe carbon storage in the subsurface. However, in fractured and highly heterogeneous reservoirs, CO₂ often flows through paths of least resistance, leading to early breakthrough or quick excessive CO₂ production and leaving substantial oil in unswept zones or areas. Traditional in-situ polymer gels have been applied to control CO₂ flooding conformance, their performance has been varied, …

Selected Topics In Blockchain-Aided Iot Inference, Yiming Jiang

Doctoral Dissertations

"Blockchain has recently been considered in the Internet of Things (IoT) to secure data exchanges and storage across various engineering applications. This newly emerging blockchain-aided IoT (BIoT) network has been applied to a great deal of security-related applications. However, the BIoT still has the vulnerability that can be exploited by attackers, potentially impairing the performance of BIoT applications. Despite this, research addressing the vulnerability has been limited. This work presents four studies aimed at addressing critical gaps in current BIoT research.

The first study introduces a Time-Restricted Double-Spending Attack (TR-DSA) model for Proof-of-Work (PoW)-based blockchains, where the adversary only conducts …

Application Of Artificial Intelligence Techniques To Improve Leadership Decision Making With Uncertainty, Michael David Parrish

Doctoral Dissertations

"Every good leader is a good manager, but not every good manager is a good leader. The difference between the leader and the manager is critical decision-making. Today’s decision-making environment is characterized as Volatile, Uncertain, Complex, and Ambiguous (VUCA). With the exponential increase in the technical capabilities of systems, the human has become the weakest link in the use of such systems. To remain relevant, good leaders must continuously adapt to new advances in technology and processes.

The research contributions of this work provide several unique and novel solutions for leaders to utilize artificial intelligence tools to improve and optimize …

Experimental Investgation Of Core Fluid And Heat Transfer Of Pwr By Using Advanced Measurments Techniques, Saud Aldawood

Doctoral Dissertations

This comprehensive study investigates the thermal-hydraulic mechanisms and convective heat transfer characteristics within (PWRs), with a focus on (SMRs) under both single-phase and two-phase bubbly flow conditions. Specifically, the research investigates the complex bubble dynamics in two-phase flow rod bundles, which are crucial for understanding reactor behavior during loss-of-coolant accidents (LOCA). Employing an advanced experimental setup developed at the (mFReel) at MST, this work measures critical parameters such as void fraction, bubble passage frequency, bubble velocity, bubble chord length, and interfacial area concentration (IAC) using a four-tip optical probe across various locations in the rod bundle. The findings reveal that …

On The Importance Of Novel Adsorption Processes And Structured Adsorbents For Biogas Upgrading And Storage, Kyle Newport

Doctoral Dissertations

The current adsorption processes investigated for biogas upgrading encounter severe challenges with regards to both adsorbents and processes, which necessitate the design and development of novel approaches to effectively separate carbon dioxide from methane and, hence, produce pipeline-grade renewable natural gas (RNG) as a fuel. These key challenges include (i) moderate CO2/CH4 selectivity, (ii) relatively long cycle times, (iii) high regeneration energy requirements, (iv) high-pressure drop, and (v) short adsorbent lifetime. The current biogas upgrading processes typically rely on pressure swing adsorption (PSA) or temperature swing adsorption (TSA). While PSA cycles are fast, the system requires large amounts of energy …