Digital Commons Network^™

Nmr Investigations Of Biomass-To-Fuel Conversions By Hydrothermal Processes, Wenjia Zhang

Doctoral Dissertations

"Biofuels have gained significant attention as the most promising alternative energy and fuel supply for the near future because of two dominant reasons: first, biofuels are environmentally friendly; and second, they afford a sustainable technology. Biofuels can be synthesized from biomass by several different processes, among which, hydrothermal conversion is considered to be more energy efficient. However, scientific efforts to improve hydrothermal biomass-to-fuel (HT-BTF) conversion efficiencies are severely limited because little is known about the salient reaction mechanisms and intermediates. This study is aimed at a better understanding of the hydrothermal biomass degradation kinetics by advanced NMR spectroscopy and, accordingly, …

Investigating The Source Of Thermal Anomalies In The Northern United Arab Emirates (Uae) Desert Using Geophysical Methods, Khalid Ahmad

Doctoral Dissertations

"We conducted geophysical surveys to investigate the source of thermal anomalies and to delineate any potential water transport pathways from the recharge zones in the Oman Mountains to the location of the temporal thermal anomalies within the desert plain of the United Arab Emirates (UAE). In the visible region of the spectrum of both ASTER and MODIS satellite images, the desert plain of the UAE appears as a bare sandy surface. However, detailed examination of these images in the thermal bands reveal cooler thermal anomalies within the desert plain following major rainfall events. This anomaly has a cooler surface of …

Deadlock Detection And Dihomotopic Reduction Via Progress Shell Decomposition, David Andrew Cape

Doctoral Dissertations

"Deadlock detection for concurrent programs has traditionally been accomplished by symbolic methods or by search of a state transition system. This work examines an approach that uses geometric semantics involving the topological notion of dihomotopy to partition the state space into components, followed by an exhaustive search of the reduced state space. Prior work partitioned the state-space inductively; however, this work shows that a technique motivated by recursion further reduces the size of the state transition system. The reduced state space results in asymptotic improvements in overall runtime for verification. Thus, with efficient partitioning, more efficient deadlock detection and eventually …

Intelligent Power System Operation In An Uncertain Environment, Yusuf Yare

Doctoral Dissertations

"This dissertation presents some challenging problems in power system operations. The efficacy of a heuristic method, namely, modified discrete particle swarm optimization (MDPSO) algorithm is illustrated and compared with other methods by solving the reliability based generator maintenance scheduling (GMS) optimization problem of a practical hydrothermal power system. The concept of multiple swarms is incorporated into the MDPSO algorithm to form a robust multiple swarms-modified particle swarm optimization (MS-MDPSO) algorithm and applied to solving the GMS problem on two power systems. Heuristic methods are proposed to circumvent the problems of imposed non-smooth assumptions common with the classical approaches in solving …

Effect Of Structure And Plasticizer On The Glass Transition Of Adsorbed Polymer, Boonta Hetayothin

Doctoral Dissertations

"The effect of molecular mass on adsorbed poly(methyl methacrylate) (PMMA) on silica was determined using temperature-modulated differential scanning calorimetry (TMDSC). A two-component model, based on loosely-bound polymer (glass transition temperature, T_g, similar to that of bulk) and tightly-bound polymer (T_g higher than that of bulk) was used to interpret the thermograms. Similar amounts of tightly-bound polymer were found for 450 and 85 kDa PMMA (0.78 mg/m²), while the 32 kDa sample had a smaller amount (0.48mg/m²). A comparison of adsorbed PMMA, poly(vinyl acetate) (PVAc), and poly(methyl acrylate) (PMA) on silica was made using the same technique. The …

Theoretical Study Of Electron Impact-Ionization Of Molecules, Ola Al-Hagan

Doctoral Dissertations

"There has been impressive progress in the area of theoretical treatments of electron impact ionization (e,2e) of atoms and molecules in the last decade. Most recently, low to intermediate incident electron energies have been reported for molecular systems. In this dissertation, different theoretical models will be used to calculate the fully differential cross section (FDCS) for (e,2e) processes for low to intermediate incident electron energies for a variety of final state electron angles and energies for the diatomic molecules H₂ and N₂, the triatomic molecule H₂O, and the biomolecule HCOOH.

In addition, there has been a large amount of interest …

Computational Methods For The Discovery And Analysis Of Genes And Other Functional Dna Sequences, Cyriac Kandoth

Doctoral Dissertations

"The need for automating genome analysis is a result of the tremendous amount of genomic data. As of today, a high-throughput DNA sequencing machine can run millions of sequencing reactions in parallel, and it is becoming faster and cheaper to sequence the entire genome of an organism. Public databases containing genomic data are growing exponentially, and hence the rise in demand for intuitive automated methods of DNA analysis and subsequent gene identification. However, the complexity of gene organization makes automation a challenging task, and smart algorithm design and parallelization are necessary to perform accurate analyses in reasonable amounts of time. …

Protein Secondary Structure Prediction Using Blast And Relaxed Threshold Rule Induction From Coverings, Leong Lee

Doctoral Dissertations

"Protein structure prediction has always been an important research area in bioinformatics and biochemistry. Despite the recent breakthrough of combining multiple sequence alignment information and artificial intelligence algorithms to predict protein secondary structure, the Q₃ accuracy of various computational prediction methods rarely has exceeded 75%; this status has changed little since 2003 when Rost stated that "the currently best methods reach a level around 77% three-state per-residue accuracy." The application of artificial neural network methods to this problem is revolutionary in the sense that those techniques employ the homologues of proteins for training and prediction. In this dissertation, a different …

Synthesis And Characterization Of Conducting Polymer Nanostructures And Their Application In Sensors, Zhe-Fei Li

Doctoral Dissertations

"A one-step synthesis technique has been used to fabricate sensors by growing polyaniline nanofibers and polyaniline/metal nanocomposites in the active area of an interdigitated electrode array. Polyaniline nanofiber sensors can be fabricated by irradiating an aqueous precursor solution containing aniline, HCl, a metal salt, and ammonium persulfate (APS) with a high pressure Hg lamp. The sensors are ready for operation after polymerization is complete, and no additional processing steps are necessary. These sensors showed faster and more intensity response to various organic vapors than conventional bulk polyaniline sensors due to their larger surface area. A chemisorption model and a diffusion …

Haart Drugs Induce Oxidative Stress And Mitochondrial Dysfunction In Blood-Brain Barrier, Kalyan Reddy Manda

Doctoral Dissertations

"The era of highly active antiretroviral therapy (HAART) has controlled AIDS and its related disorders considerably; however, the prevalence of HIV-1-associated neurocognitive disorders (HAND) has been on the rise in the post-HAART era. In view of these developments, we investigated whether a HAART drug combination of 3'-Azido-2', 3'-deoxythymidine (AZT) and Indinavir (IDV) can alter the functionality of the blood-brain barrier (BBB) endothelial cells, thereby exacerbating the condition. Viability of hCMEC/D3 cells (in vitro model of BBB) that were exposed to the drugs was significantly reduced after a 72 hr treatment, in a dose-dependent manner. Reactive oxygen species (ROS) were highly …

Chemical Bath Deposition And Electrodeposition Of Epitaxial Semiconductor Materials For Application In Photovoltaic Devices, Guojun Mu

Doctoral Dissertations

"This dissertation investigates the chemical bath deposition of zinc oxide and electrodeposition of cuprous iodide on polycrystalline and single crystal substrates. Paper I describes the chemical bath deposition and characterization of titled epitaxial zinc oxide nanospears on Si(001) single crystal substrate. In Paper II, the chemical bath deposition of zinc oxide nanospears from highly alkaline solutions is discussed in detail, including a thermodynamic calculation of saturation and speciation of Zn(II) in aqueous solution, and a kinetic study of the deposition process. In this paper the epitaxial zinc oxide is reported grown on Au(100), (110), and (111) single crystals. Paper III …

Sensor Data-Based Decision Making, Ahmet Soylemezoglu

Doctoral Dissertations

"Increasing globalization and growing industrial system complexity has amplified the interest in the use of information provided by sensors as a means of improving overall manufacturing system performance and maintainability. However, utilization of sensors can only be effective if the real-time data can be integrated into the necessary business processes, such as production planning, scheduling and execution systems. This integration requires the development of intelligent decision making models that can effectively process the sensor data into information and suggest appropriate actions. To be able to improve the performance of a system, the health of the system also needs to be …

Adaptive Resource Allocation For Cognitive Wireless Ad Hoc Networks, Behdis Eslamnour

Doctoral Dissertations

"Widespread use of resource constrained wireless ad hoc networks requires careful management of the network resources in order to maximize the utilization. In cognitive wireless networks, resources such as spectrum, energy, communication links/paths, time, space, modulation scheme, have to be managed to maintain quality of service (QoS). Therefore in the first paper, a distributed dynamic channel allocation scheme is proposed for multi-channel wireless ad hoc networks with single-radio nodes. The proposed learning scheme adapts the probabilities of selecting each channel as a function of the error in the performance index at each step.

Due to frequent changes in topology and …

Development Of Embedded Modulated Scatterer Technique: Single- And Dual-Loaded Scatterers, Kristen M. Donnell

Doctoral Dissertations

"Health monitoring of infrastructure is an important ongoing issue. Therefore, it is important that a cost-effective and practical method for evaluating complex composite structures be developed. A promising microwave-based embedded sensor technology is developed based on the Modulated Scatterer Technique (MST). MST is based on illuminating a probe, commonly a dipole antenna loaded with a PIN diode (also referred to as a single-loaded scatterer, or SLS), with an electromagnetic wave. This impinging wave induces a current along the scatterer length, which causes a scattered field to be reradiated. Modulating the PIN diode also modulates the signal scattered by the probe, …

Adsorption And Segmental Dynamics Of Acrylate And Methacrylate Polymers Adsorbed On A Silica Surface, Piyawan Krisanangkura

Doctoral Dissertations

"Poly(isopropyl acrylate)-d₇ (PIPA- d₇) was studied using ²H solid-state NMR and modulated differential scanning calorimetry (MDSC). The polymer was deuterated on the methyl groups and side-chain methine. The PIPA- d₇ was adsorbed onto Cab-O-Sil silica. These two types of deuterons each showed their own characteristic deuterium nuclear magnetic resonance (NMR) spectra for bulk PIPA- d₇. The ²H NMR spectra of adsorbed PIPA- d₇ samples showed the presence of heterogeneity of the segmental dynamics. A residual powder pattern was found in the spectra of the surface samples at higher temperatures, indicating that the segments were tightly attached to the silica. The …

Dead Time And Count Loss Determination For Radiation Detection Systems In High Count Rate Applications, Amol Patil

Doctoral Dissertations

"This research is focused on dead time and the subsequent count loss estimation in radiation detection systems. The dead time is the minimum amount of time required between two events to permit detection of those events individually by a radiation detection system. If events occur during the system dead time, they are lost. Such lost information can be important in many applications including high-precision spectroscopy, positron emission tomography (PET), and the scanning of spent nuclear fuel. Understanding of the behavior of radiation detection systems is important; thus this work included a comprehensive review of dead time and pulse pile-up models …

Identifying Multiple Steady States In The Design Of Reactive Distillation Processes, Thomas Karl Mills

Doctoral Dissertations

"Global homotopy continuation is used to identify multiple steady states in ideal reactive flash and reactive distillation systems involving a reaction of the form A+B [symbol for <--> C taking place in the liquid phase. The choice of specifications has an influence on the existence of multiple solutions for both the flash and the column. For the flash, specification of the heat input or withdrawal can give rise to multiplicities while specification of the split fraction does not. Specification of one internal energy balance variable and one external material balance variable does not produce multiplicities in the column; however, specification of …

Analysis Of Laminated Architectural Glazing Subjected To Combined Wind And Debris Impact Loading, Mahesh Shibarooru Shetty

Doctoral Dissertations

"Laminated glazing has been a popular form of window glazing in recent years and is found to be effective during extreme weather conditions like hurricane. Laminated glass is composed of two glass layers with a polymer as an interlayer. The main objective of this work involves studying the stress response, failure and damage analysis of rectangular laminated architectural glazing against combined wind and windborne debris impact. Here both small-hard (like roof gravel) and large-soft (like timber) windborne debris are considered. The stress response of the rectangular laminated architectural glazing was modeled using the finite element code ABAQUS. The effect of …

A Study Of The Growth And Structure Of Chromium And Iron Oxide Films On Pd(001) Using X-Ray Photoelectron Diffraction And Low Energy Electron Diffraction, Tina Dhekial-Phukan

Doctoral Dissertations

"In this study, attempts were made to grow well-ordered chromium- and iron-oxide films on a Pd(001) surface, and two sample preparation techniques, the multilayer and the sequential growth techniques, were used to grow these transition metal oxide films. The study is a part of a larger project that aims to look into the interaction between metal substrates and the overlayers grown on them. Previous studies of oxide films on Ag(001) resulted in the growth of 4-fold and 3-fold symmetry oxide structures from the multilayer and sequential growth techniques respectively. The present investigation's goal was to study how the growth of …

Application Of Quality Engineering To Investment Portfolio Selection And Optimization, Vivek Kulinchandra Jikar

Doctoral Dissertations

"The Taguchi System of Quality Engineering (TSQE) is a widely accepted philosophy and set of tools and techniques to rapidly design and manufacture high quality, low cost products and services. It is heavily focused on creating stable system designs that allow a product or system to perform as desired by customers in the environment of their choice. This research demonstrates the power of the TSQE to manage an investment portfolio. In particular, it uses the concept of design stability to select investments and optimize portfolios. It proposes a new design stability-based investment screening metric and discusses its application. Further, this …

Capillary Electrophoresis Of Pteridines In Urine And Plants And Quantification Of Pharmaceutical And Personal Care Products In Missouri Waste Water, Stephen E. Gibbons

Doctoral Dissertations

"Capillary electrophoresis (CE) is a powerful technique that separates molecules based on their respective charge and hydrodynamic size. The major advantages of CE are high separation efficiency, small sample volume requirements, simple to no sample preparation and often organic solvents are not required for the separation.

The work presented in this dissertation utilized capillary electrophoresis for the analysis two different classes of compounds in different matrices. The first project investigated pteridines in urine and plants. The second project investigated pharmaceutical and personal care products (PPCP's) in Missouri waste water.

As cancer continues to be one of the top three causes …

Dynamic Reconfiguration And Control Of Smart Power Systems, Pinaki Mitra

Doctoral Dissertations

"To address the increasing demand and complexity, modern power systems need intelligence at almost all levels which can transform them into 'smart' power systems. The term 'smart power systems' not only refers to the terrestrial power systems with a significant penetration of distributed energy resources and energy storage such as plug-in electric vehicle parking lots (SmartParks), but also includes other isolated power systems, such as the power systems of naval electric ships. The research presented in this dissertation contributes to the dynamic reconfiguration and control of both terrestrial and ship power system with the application of computational intelligence methods.

In …

Improvised Explosive Device Crater Repair For Enduring Route Remediation, Daniel Roman Kienitz

Doctoral Dissertations

"Recent road repairs performed on main supply routes (MSRs) and alternative supply routes (ASRs) in Iraq and Afghanistan revealed several deficiencies in current repair techniques. Temporary solutions such as aggregate backfill, asphalt, and traditional concrete repairs were unacceptable due to the ease of emplacement of additional improvised explosive devices (IEDs). In addition to the threat of IED placement, the threat from exposure of the repair teams to enemy attack during placement and curing was substantial. In order to address these problems, this project investigated rapid hardening materials for improvised explosive device crater repair. A laboratory test program along with performance …

A Mixed Method Case Study : Bar-On Eq-I Framework Of Emotional Intelligence And The School Leadership Experiences Of Principals Who Completed An Urban Leadership Program In Northern California, Jasvinder Kaur

Doctoral Dissertations

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At The Crossroads Of Learning And Culture : Identifying A Construct For Effective Computer-Assisted Language Learning For English Language Learners, Yun Shaw

Doctoral Dissertations

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A Critical Inquiry Into The Perspectives Of African Americans Who Consider Themselves Equal To Other U.S. Citizens, Melba Beals

Doctoral Dissertations

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Interactions In A Two-Way Immersion Program : Impact And Challenges, Yoko Koki

Doctoral Dissertations

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Living Positively: Narratives Of Forgiveness And Imagination Among Women With Hiv, Hamaseh Kianfar

Doctoral Dissertations

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Kindergarten Teachers' Perceptions Of Kindergarten Readiness, Nancy Cappelloni

Doctoral Dissertations

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The Effects Of Using Screencasting As A Multimedia Pre-Training Tool To Manage The Intrinsic Cognitive Load Of Chemical Equilibrium Instruction For Advanced High School Chemistry Students, Ramsey Musallam

Doctoral Dissertations

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