Digital Commons Network^™

Multiple Differential Study Of Fragmentation Processes In 75 Kev Proton-Molecular Hydrogen Collisions, Kisra Nayomal Egodapitiya

Doctoral Dissertations

"Double Differential Cross Sections (DDCS) were measured for single ionization of H₂ by 75 keV proton (p) impact as a function of the projectile scattering angle (θp) for a fixed energy loss (ΔE) for two different target-collimating slit distances, which determined the width of the projectile wave packet (Δx). In one case Δx was larger than the inter-nuclear separation of the H₂ molecule (coherent projectile beam), while for the other case it was much smaller than the inter-nuclear separation (incoherent projectile beam). A Young type interference pattern was observed in the coherent data, but this was not present in the …

First-Principles Studies Of Complex Hydrides For Li-Ion Battery And Hydrogen Storage Applications, Timothy Hudson Mason

Doctoral Dissertations

"We employ density functional theory in a computational study of two energy storage systems.

In the first, we explore the thermodynamic viability of light metal hydrides as a high capacity Li-ion battery negative electrode. Given a set of solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble as a function of lithium electrochemical potential. We present computational results for several new conversion reactions with predicted capacities between 2400 and 4000 mAhg⁻¹ that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway …

Two New Spline-Based Methods And Real Data Applications: High-Resolution Receiver Function Calculations From Teleseismic Broadband Waveforms And High-Accuracy Practical Potential-Field Integral Transformations, Bingzhu Wang

Doctoral Dissertations

"While receiver function (RF) calculation is fundamentally important and widely used, it is not well solved due to unstable deconvolution. A spline-based RF calculation method was proposed and it is demonstrated that both individual RFs and the stacked RF calculated with the spline method have sharper peaks than those with the water-level spectral division method and the iterative deconvolution method. At the common peaks on the stacked RFs, there are close similarities for all three RF calculation methods. The better calculated RFs with the spline method lead to improved H - K analysis and improved determination of the optimal Moho …

Hardware Emulation Of Wireless Communication Fading Channels, Fei Ren

Doctoral Dissertations

"This dissertation investigates several main challenges to implementing hardware-based wireless fading channel emulators with emphasis on incorporating accurate correlation properties. Multiple-input multiple-output (MIMO) fading channels are usually triply-selective with three types of correlation: temporal correlation, inter-tap correlation, and spatial correlation. The proposed emulators implement the triply-selective fading Channel Impulse Response (CIR) by incorporating the three types of correlation into multiple uncorrelated frequency-flat Rayleigh fading waveforms while meeting real-time requirements for high data-rate, large-sized MIMO, and/or long CIR channels. Specifically, mixed parallel-serial computational structures are implemented for Kronecker products of the correlation matrices, which makes the best tradeoff between computational speed …

Interfacial Effects On Dielectric Properties Of Polymer-Particle Nanocomposites, Sasidhar Siddabattuni

Doctoral Dissertations

"Dielectric materials that are capable of efficiently storing large amounts of electrical energy are desirable for many electronic and power devices. Since the electrical energy density in a dielectric material is limited to εV_b²/2, where ε is the dielectric permittivity of the material and V_b is the breakdown strength, increased permittivity and breakdown strength are required for large energy storage density. Interfacial effects can influence the dielectric properties, especially dielectric breakdown resistance in polymer-particle nanocomposites. Several functional organophosphates were used to modify the surface of titania and barium titanate nanofiller particles in order to achieve covalent interface …

Architecture Value Mapping: Using Fuzzy Cognitive Maps As A Reasoning Mechanism For Multi-Criteria Conceptual Design Evaluation, Atmika Singh

Doctoral Dissertations

"The conceptual design phase is the most critical phase in the systems engineering life cycle. The design concept chosen during this phase determines the structure and behavior of the system, and consequently, its ability to fulfill its intended function. A good conceptual design is the first step in the development of a successful artifact. However, decision-making during conceptual design is inherently challenging and often unreliable. The conceptual design phase is marked by an ambiguous and imprecise set of requirements, and ill-defined system boundaries. A lack of usable data for design evaluation makes the problem worse. In order to assess a …

Robust Adaptive Filtering Algorithms For System Identification And Array Signal Processing In Non-Gaussian Environment, Tiange Shao

Doctoral Dissertations

"This dissertation proposes four new algorithms based on fractionally lower order statistics for adaptive filtering in a non-Gaussian interference environment. One is the affine projection sign algorithm (APSA) based on L₁ norm minimization, which combines the ability of decorrelating colored input and suppressing divergence when an outlier occurs. The second one is the variable-step-size normalized sign algorithm (VSS-NSA), which adjusts its step size automatically by matching the L₁ norm of the a posteriori error to that of noise. The third one adopts the same variable-step-size scheme but extends L₁ minimization to Lp minimization and the variable step-size normalized fractionally lower-order …

Applied Palynology: Multidisciplinary Case Studies From Egypt, Gulf Of Mexico And Usa, Mohamed K. Zobaa

Doctoral Dissertations

"Various applications of palynology have been used to study case studies from four different parts of the world, namely northern Egypt, offshore Gulf of Mexico, eastern Tennessee (USA), and New Orleans, Louisiana (USA). In these case studies, palynomorphs (spores, pollen, dinoflagellate cysts, and algae) have been utilized to define zones of hydrocarbon potential, reconstruct paleoenvironmental and paleoclimatic conditions, constrain the ages of the studied rock sequences, and express its potential as a replacement proxy for some expensive organic geochemical analyses. The ability to detect past hurricane activities and their associated damage to the geologic record is here presented as a …

Ceeme: Compensating Events Based Execution Monitoring Enforcement For Cyber-Physical Systems, Thoshitha T. Gamage

Doctoral Dissertations

"Fundamentally, inherently observable events in Cyber-Physical Systems with tight coupling between cyber and physical components can result in a confidentiality violation. By observing how the physical elements react to cyber commands, adversaries can identify critical links in the system and force the cyber control algorithm to make erroneous decisions. Thus, there is a propensity for a breach in confidentiality leading to further attacks on availability or integrity. Due to the highly integrated nature of Cyber-Physical Systems, it is also extremely difficult to map the system semantics into a security framework under existing security models. The far-reaching objective of this research …

Hilbert Transform Applications In Signal Analysis And Non-Parametric Identification Of Linear And Nonlinear Systems, Zuocai Wang

Doctoral Dissertations

"Hilbert Huang Transform faces several challenges in dealing with closely-spaced frequency components, short-time and weak disturbances, and interrelationships between two time-varying modes of nonlinear vibration due to its mixed mode problem associated with empirical mode decomposition (EMD). To address these challenges, analytical mode decomposition (AMD) based on Hilbert Transform is proposed and developed for an adaptive data analysis of both stationary and non-stationary responses. With a suite of predetermined bisecting frequencies, AMD can analytically extract the individual components of a structural response between any two bisecting frequencies and function like an adaptive bandpass filter that can deal with frequency-modulated responses …

Alloy Dissolution In Argon Stirred Steel, Darryl S. Webber

Doctoral Dissertations

"Alloying is required for the production of all steel products from small castings to large beams. Addition of large quantities of bulk alloys can result in alloy segregation and inconsistent alloy recovery. The objective of this research was to better understand alloy dissolution in liquid steel especially as it relates to Missouri S&Ts' patented continuous steelmaking process. A 45-kilogram capacity ladle with a single porous plug was used to evaluate the effect of four experimental factors on alloy dissolution: alloy species, alloy size or form, argon flow rate, and furnace tap temperature. Four alloys were tested experimentally including Class I …

Ozone And Terpene Reactions On Indoor Surfaces: Reaction Rates And Implications For Indoor Air Quality, Shi Shu

Doctoral Dissertations

No abstract provided.

Diesel Particulate Matter Dispersion Analysis In Underground Metal/Nonmetal Mines Using Computational Fluid Dynamics, Yi Zheng

Doctoral Dissertations

"Diesel Particulate Matter (DPM) is a natural by-product from operating diesel engines. Since diesel power is a major source of energy for mining operations today, the adverse health effects of DPM are of a great concern. To thoroughly resolve DPM problems, it is critical that DPM propagation characteristics be understood to arrive at a sensible and practical method for addressing DPM-related issues. To achieve this, a computational fluid dynamics (CFD) method is used to simulate DPM dispersion and to predict its concentration distribution. Industrial field studies were reconstructed to evaluate the possibility of different CFD models. Experiments were also carried …

Epitaxial Electrodeposition Of Metal Oxide Films And Superlattices Which Exhibit Resistance Switching, Rakesh V. Gudavarthy

Doctoral Dissertations

"This dissertation presents an investigation of the electrodeposition of metal oxide films and superlattices on conducting polycrystalline and single crystal substrates. In the first part of the study, electrodeposition of magnetite (Fe₃O₄) films and superlattices in the magnetite/zinc ferrite system which exhibit resistance switching is studied. Paper I reports the electrodeposition of superlattices in the magnetite/zinc ferrite system and shows that only superlattices exhibit multistate resistance switching. In paper II, simple polycrystalline magnetite films electrodeposited on stainless steel crystals exhibit multistate resistance switching which can be tuned by controlling the composition of the films. Paper II describes the epitaxial electrodeposition …

A Geological And Geophysical Study Of The Tendaho Graben In The Afar Depression, Ethiopia: Insights Into Transitional Continental Rifting, David Lee Bridges

Doctoral Dissertations

"A detailed magnetic and gravity study across the Tendaho Graben (the Red Sea propagator within the Afar Depression, Ethiopia) revealed features that can best be interpreted as a continental rift undergoing oceanization. This NW-trending extensional structure is ~50 km wide and it is confined within well-developed NW-trending boarder faults that deform the 2 km thick and ~ 2 Ma basaltic flows of the Afar Stratoids. The age of the basaltic flows becomes progressively younger inward from the boarder faults until it reaches ~30,000 years close to the rift axis. The central part of the Tendaho Graben is characterized by a …

Postcyclic Behavior Of Low-Plasticity Silt, Shuying Wang

Doctoral Dissertations

"Liquefaction of low-plasticity silt has been reported during earthquakes in the recent past. Excess pore pressure builds up due to the dynamic loading and then dissipates. The postcyclic behavior of low-plasticity silt was investigated in this research for materials obtained from the Mississippi River Valley. The experimental program involved specimen preparation using a slurry consolidation approach. A special technique was developed for specimen movement, reducing the testing program time by half. Both static and cyclic triaxial tests were conducted to confirm the ability to prepare replica specimens. In order to characterize the monotonic behavior, triaxial tests were conducted to determine …

Advanced Composites Using Non-Autoclave Processes: Manufacturing And Characterization, V. G. K. Menta

Doctoral Dissertations

"The objective of the present study is to develop non-autoclave processes to manufacture high performance composites for aerospace applications. In Paper 1, vacuum assisted resin transfer molding (VARTM) process was developed for elevated temperature composites. Use of VARTM process for fabricating high temperature resins presents unique challenges such as high porosity and low fiber volume contents. Two different vacuum bagging methods: Seeman Composite Resin Infusion Molding Process (SCRIMP) and Double Vacuum Bagging Infusion (DVBI) process were evaluated. Flow simulation tool was used to predict key flow parameters needed for the successful infusion. In Paper 2, honeycomb sandwich panels were manufactured …

Development Of A Versatile Man-Portable Obscurant Aerosol Generator: Characterization Of Aerosols In Laboratory And Field Environments, Robert William Schaub

Doctoral Dissertations

"The objective of research presented in this dissertation was to develop a readily deployable and environmentally benign obscurant system operating with a single liquid for the visible and near infrared regions. To achieve this objective, research efforts were directed in two areas: i. Evaluating suitable biogenic oils to replace the United States Army's "Fog Oil" as the obscurant fluid. ii. Design, fabrication and validation of a prototype man-portable / vehicle mountable modular obscurant aerosol generator. Petroleum middle distillate - "Fog Oil" has been the material of choice for wide area obscuration for several decades. Large quantities (thousands gallons) of the …

Part-I Characterization Of Phorbol Ester; The Predominant Toxic Component Of Jathropha Curcas And Development Of An Efficient Process For The Detoxification Of Jathropha Curcas Meal Part-Ii Quantification Of 2-Hydroxy-4-(Methylthio) Butanoic Acid And Pantothenic Acid In Bovine Serum And Sea Water Matrices, Balaji Viswanathan

Doctoral Dissertations

"Jatropha curcas is has often been touted as the most sustainable biofuel source. Jatropha curcas is a drought resistant perennial plant belonging to the Euphorbiaceae family. Interest in this plant as a biofuel source is related to high lipid (triglyceride) content of its seeds. However, economics of jatropha as a biofuel source has been marred by the toxicity of the oil and its protein rich meal. As a result of high toxicity the protein rich meal is used only as a very low or no economic value organic fertilizer. Economic return from jatropha can be dramatically enhanced through development of …

Investigation Of Occurrence, Elimination And Degradation Of Pharmaceutical And Personal Care Products In Drinking Water Using Liquid Chromatography-Tandem Mass Spectrometry, Chuan Wang

Doctoral Dissertations

"Pharmaceutical and personal care products have benefited humans and animals around the world. However, their presence in natural and treated water system as emerging contaminates may have potentially adverse effects on the aquatic environment and cause development of bacterial resistance. In this research project, a comprehensive liquid chromatography tandem mass spectrometry method has been developed and validated for the analysis of sixteen pharmaceutical compounds using solid phase extraction. Treated and untreated water samples collected across Missouri from water treatment facilities were analyzed to access the distribution of sixteen pharmaceutical compounds in both winter and summer seasons. The results of the …

Absorbing State Transitions In Clean And Disordered Lattice Models, Man Young Lee

Doctoral Dissertations

"Nonequilibrium systems can undergo continuous phase transitions between different steady states. These transitions are characterized by collective fluctuations over large distances and long times similar to the behavior of equilibrium critical points. They also can be divided into different universality classes according to their critical behavior.

This dissertation considers two types of nonequilibrium transitions. First study concerns absorbing state transitions on a randomly diluted lattice. Second study deals with nonequilibrium models with several absorbing states. We investigate two specific nonequilibrium lattice models, i.e., the contact process and the generalized contact process by means of both theoretical and computational approaches.

In …

Aerogels And Films Through Free Radical Polymerization, Anand G. Sadekar

Doctoral Dissertations

"Aerogels are porous lightweight materials, unique among all solids in terms of low density, low thermal conductivity, low dielectric constants and high acoustic attenuation. The penalty for those exceptional properties is fragility. That issue has been addressed by bridging covalently (crosslinking) the elementary nanoscopic building blocks of silica aerogels with polymers. To streamline the crosslinking process we synthesized a bidentate free radical initiator (Si-AIBN) that gets attached on the skeletal nanoparticles and induces crosslinking by surface initiated polymerization (SIP). Here, we extend the scope of Si-AIBN in two directions: (a) we demonstrate extremely adhering, covalently attached polymer coatings on oxidized …

Assessing System Architectures: The Canonical Decomposition Fuzzy Comparative Methodology, Jason Paul Dauby

Doctoral Dissertations

"The impacts of decisions made during the selection of the system architecture propagate throughout the entire system lifecycle. The challenge for system architects is to perform a realistic assessment of an inherently ambiguous system concept. Subject matter expert interpretations, intuition, and heuristics are performed quickly and guide system development in the right overall direction, but these methods are subjective and unrepeatable. Traditional analytical assessments dismiss complexity in a system by assuming severability between system components and are intolerant of ambiguity. To be defensible, a suitable methodology must be repeatable, analytically rigorous, and yet tolerant of ambiguity. The hypothesis for this …

Cross-Layer Design For Network Performance Optimization In Wireless Networks, Xuan Gong

Doctoral Dissertations

"In this dissertation, I use mathematical optimization approach to solve the complex network problems. Paper l and paper 2 first show that ignoring the bandwidth constraint can lead to infeasible routing solutions. A sufficient condition on link bandwidth is proposed that makes a routing solution feasible, and then a mathematical optimization model based on this sufficient condition is provided. Simulation results show that joint optimization models can provide more feasible routing solutions and provide significant improvement on throughput and lifetime. In paper 3 and paper 4, an interference model is proposed and a transmission scheduling scheme is presented to minimize …

Modeling Of Novel Coaxial Cable Bragg Grating Sensor By Coupled Mode Theory, Songping Wu

Doctoral Dissertations

"A new sensor based on the novel concept of coaxial cable Bragg grating (CCBG) has been developed for the integrity of civil infrastructure monitoring. In this dissertation work, fundamental research is conducted in sensor modeling and applications, which correspond to the first four papers of the dissertation. A coupled mode theory (CMT) is first applied to establish a physics-based model for CCBG. A numerical solution of the coupled wave equations for CCBG has been derived and validated. As an indicator of sensor sensitivity, the quality factor (Q-factor) of CCBG as a function of sensor structural/material parameters was analytically investigated by …

Probability Theory On Time Scales And Applications To Finance And Inequalities, Thomas Matthews

Doctoral Dissertations

"In this dissertation, the recently discovered concept of time scales is applied to probability theory, thus unifying discrete, continuous and many other cases. A short introduction to the theory of time scales is provided. Following this preliminary overview, the moment generating function is derived using a Laplace transformation on time scales. Various unifications of statements and new theorems in statistics are shown. Next, distributions on time scales are defined and their properties are studied. Most of the derived formulas and statements correspond exactly to those from discrete and continuous calculus and extend the applicability to many other cases. Some theorems …

Receiver Function Studies Of Crustal Structure, Composition, And Evolution Beneath The Afar Depression, Ethiopia, Sattam A. Almadani

Doctoral Dissertations

"The dissertation utilizes a set of sophisticated computer programs developed at the Geophysics group at Missouri S&T to characterize crustal properties beneath the Afar Depression in Ethiopia where extensional tectonics dominates. In this study, measurements of crustal thickness (H), crustal mean Vp/Vs [which is related to Poisson's ratio (Σ)], and the sharpness of the Moho (R) were determined using teleseismic data from 18 broadband seismic sensors that we deployed along a profile of 250 km long with a station spacing of ~ 10 km. The stations had been recording continuously for an entire year from December 2009 until December 2010. …

Strength Adjustable Preformed Particle Gels For Conformance Control, Jia Zhou

Doctoral Dissertations

"Reservoir heterogeneity and early water breakthrough (also known as fingering) represent two of the greatest challenges to recover crude oil efficiently. Gel treatments have been implemented as a cost-effective method to plug high permeability zones and thus improve sweep efficiency in reservoirs. However, when extensive cross-flows exist between formation layers, gel treatments become less efficient. Polymer was used in polymer flooding to increase the viscosity of the injected fluids and to correct the fingering problem. However, such treatment may be uneconomical since dramatic viscosity loss (80-90%) is caused by shearing degradation during the injection process near the wellbore.

This research …

Development Of A Simple Vibration Model For Predicting The Structural Dynamics Of An Hcci Engine, Jeffery A. Massey

Doctoral Dissertations

"The hypothesis tested in this work is that the surface vibration and radiated sound of an engine operating under HCCI combustion is dominated by the free vibration response of the engine's structural components to an impulsive loading brought about by the rapid energy release of the HCCI combustion process. Recent work by the author has shown that classical vibration theory describing the dynamic response of a single-degree-of-freedom (SDOF) oscillator may capture the major characteristics of the engine surface vibrations. Through an experimental investigation of HCCI combustion engine dynamics this model has been developed further.

A band level analysis of measured …

Preliminary Model Development Of Metal Complexation Of Polyester Derivatives Of 2,2'-Biimidazole, Shelonda Rena Taylor Finch

Doctoral Dissertations

"The objective of this study was to develop a chemical model for metal ion complex formation by a macroligand system with multi-metal binding sites using 2,2'-biimidazole as the starting molecule of the ligand system. Prior studies in this laboratory guided the selection of diesters and hydroxyethyl derivatives of 2,2'-biimidazole as model monomers. In addition, metal ion complexation studies with 2,2'-biimidazole derivatives were conducted. As a result, crystal structures of 1,1'-di(methylpropionato)-2,2-biimidazole, 2,2'-bis(1H-imidazolium) dinitrate and silver 2,2'-bis(1H-imidazolium) trinitrate, were reported. The crystal structures indicated a dependence upon the binding ability of the protonated 2,2'-biimidazole and counter ions. transesterification of the diesters and …