Digital Commons Network^™

Glycerin Reformation In High Temperature And Pressure Water, Jason W. Picou

Doctoral Dissertations

"The noncatalytic reformation of glycerin in supercritical water was studied in a Haynes 282 tubular reactor. In order to determine which parameters were the most influential, a 2³ experimental matrix was conducted, with temperatures of 500 and 700⁰C, water/glycerin molar ratios of 3:1 and 13:1, and residence times of 30 and 90 seconds, all at a pressure of 24 MPa. It was found that temperature had the largest effect on the two gasification parameters deemed most important, gasification percentage and hydrogen yield. Based on this, the effect of temperature was further investigated by looking at 5⁰C intervals from 500 to …

Characterization Of Wave Transport In Non-Conservative Media With Random And Correlated Disorder, Benjamin Henry Payne

Doctoral Dissertations

"Passive quasi-one-dimensional random media exhibit one of the three regimes of transport - ballistic, diffusive, or Anderson localization - depending on system size. The ballistic and diffusion approximations assumes particle transport, whereas Anderson Localization occurs when wave self-interference effects are dominant. When the system contains absorption or gain, then how the regimes can be characterized becomes unclear. By investigating theoretically and numerically the ratio of transmission to energy in a random medium in one dimension, we show this parameter can be used to characterize localization in random media with gain. Non-conservative media implies a second dimension for the transport parameter …

Synthesis And Applications Of Imidazolium-Based Ionic Liquids And Their Polymer Derivatives, Woon Su Oh

Doctoral Dissertations

"Imidazolium-based ionic liquids have been increasingly used as green solvents to replace the volatile and relatively toxic organic solvents, in homogeneous and heterogeneous catalysis, materials science, nano materials, lithium ion batteries, and separation technology. Section 1 describes the modulating effect of the imidazolium based room temperature ionic liquids (RTILs) on the critical micelle concentrations (CMC) of surfactants. CMC of sodium dodecyl sulfate (SDS), an anionic surfactant, has been investigated in aqueous solutions of a variety of room temperature ionic liquids (RTILs). CMC values decrease with increasing alkyl chain-length and with fluorinated side chains on the imidazole moiety. In section 2, …

The Risk Mitigation Strategy Taxonomy And Generated Risk Event Effect Neutralization Method, Daniel A. Krus

Doctoral Dissertations

"In the design of new products and systems, the mitigation of potential failures is very important. The sooner in a product's design mitigation can be performed, the lower the cost and easier to implement those mitigations become. However, currently, most mitigations strategies rely on the expertise of the engineers designing a product, and while models and for failure modes do exist to help, there are no guidelines for performing product changes to reduce risk. To help alleviate this, the risk mitigation strategy taxonomy is created from an empirical collection of mitigation strategies used in industry for failure mitigation, creating a …

Evolutionary Computing Driven Search Based Software Testing And Correction, Joshua Lee Wilkerson

Doctoral Dissertations

"For a given program, testing, locating the errors identified, and correcting those errors is a critical, yet expensive process. The field of Search Based Software Engineering (SBSE) addresses these phases by formulating them as search problems. This dissertation addresses these challenging problems through the use of two complimentary evolutionary computing based systems. The first one is the Fitness Guided Fault Localization (FGFL) system, which novelly uses a specification based fitness function to perform fault localization. The second is the Coevolutionary Automated Software Correction (CASC) system, which employs a variety of evolutionary computing techniques to perform testing, correction, and verification of …

Updated Eor Screening Criteria And Modeling The Impacts Of Water Salinity Changes On Oil Recovery, Ahmad Aladasani

Doctoral Dissertations

"Developing technologies for enhanced oil recovery (EOR) from existing oil fields would supply the world's energy needs for several decades. The application of EOR in many major oil-producing countries remains in its conceptual stage. Thermal and gas EOR methods achieve high incremental rates; however, their application range has not broadened significantly as they have matured, while the rate at which new, promising EOR methods such as Low-salinity water flooding (LSWF) are being implemented is alarming. Despite, the potential of LSWF its development and application has been hindered by the lack of consensus concerning its recovery mechanism(s). Every oil reservoir has …

Electrodeposition And Electrochemical Reduction Of Epitaxial Metal Oxide Thin Films And Superlattices, Zhen He

Doctoral Dissertations

"The focus of this dissertation is the electrodeposition and electrochemical reduction of epitaxial metal oxide thin films and superlattices. The electrochemical reduction of metal oxides to metals has been studied for decades as an alternative to pyrometallurgical processes for the metallurgy industry. However, the previous work was conducted on bulk polycrystalline metal oxides. Paper I in this dissertation shows that epitaxial face-centered cubic magnetite (Fe₃O₄) thin films can be electrochemically reduced to epitaxial body-centered cubic iron (Fe) thin films in aqueous solution on single-crystalline Au substrates at room temperature. This technique opens new possibilities to produce special epitaxial metal/metal oxide …

Periodic Q-Difference Equations, Rotchana Chieochan

Doctoral Dissertations

"The concept of periodic functions defined on the real numbers or on the integers is a classical topic and has been studied intensively, yielding numerous applications in every kind of science. It is of importance that the real numbers and the integers are closed with respect to addition. However, for a number q > 1, the so-called q-time scale, i.e., the set of nonnegative integer powers of q, is not closed with respect to addition, and therefore it was not possible to define periodic functions on the q-time scale in an obvious way. In this thesis, this important open problem has …

The Pricing Of Multiple Exercisable American-Style Real Options, Yu Meng

Doctoral Dissertations

"Real options embedded in a project provide management with the flexibility to alter initial investment decisions, thus making them a practical tool for project planning and budgeting. Additional values are contributed to the underlying project due to the flexibilities that are provided by real options. This dissertation presents two models for pricing multiple exercisable American real options, one that employs the binomial tree method and the other one that employs the finite difference method. Different examples of multiple exercisable real options are discussed to demonstrate the two pricing models. Interactions between options and reality constraints are also considered. These two …

Complex Oxides As Novel Transparent Conductors, Altynbek Murat

Doctoral Dissertations

"Ab-initio density functional approach is employed to investigate the structural, optical, and electronic properties of twelve undoped (non)stoichiometric multicomponent oxides with layered structure RAMO₄ [R³⁺ =In or Sc, A³⁺ =Al or Ga, and M²⁺ - Ca, Cd, Mg, or Zn], as candidates for novel transparent conducting oxides. The compositional complexity of RAMO₄ leads to a wide range of band gaps varying from 2.45eV for InGaCdO₄ to 6.29 eV for ScAlMgO₄. We find that despite the different band gaps in the constituent binary oxides, namely, 2-4 eV in CdO, In₂O₃, or AnO; 5-6 eV for Ga₂O₃ or Sc₂O₃; and 7-9 eV …

Data Fusion By Using Machine Learning And Computational Intelligence Techniques For Medical Image Analysis And Classification, Beibei Cheng

Doctoral Dissertations

"Data fusion is the process of integrating information from multiple sources to produce specific, comprehensive, unified data about an entity. Data fusion is categorized as low level, feature level and decision level. This research is focused on both investigating and developing feature- and decision-level data fusion for automated image analysis and classification. The common procedure for solving these problems can be described as: 1) process image for region of interest' detection, 2) extract features from the region of interest and 3) create learning model based on the feature data. Image processing techniques were performed using edge detection, a histogram threshold …

Complex Scaling Behavior In Animal Foraging Patterns, Prabhavi Kaushalya Premachandra

Doctoral Dissertations

This dissertation attempts to answer questions from two different areas of biology, ecology and neuroscience, using physics-based techniques. In Section 2, suitability of three competing random walk models is tested to describe the emergent movement patterns of two species of primates. The truncated power law (power law with exponential cut off) is the most suitable random walk model that characterizes the emergent movement patterns of these primates. In Section 3, an agent-based model is used to simulate search behavior in different environments (landscapes) to investigate the impact of the resource landscape on the optimal foraging movement patterns of deterministic foragers. …

Chelating Compounds As Potential Flash Rust Inhibitors And Melamine & Aziridine Cure Of Acrylic Colloidal Unimolecular Polymers (Cups), Jigar K. Mistry

Doctoral Dissertations

Waterborne coatings on ferrous substrates usually show flash rusting which decreases the adhesion of the coating and the corrosion products can form a stain. Chelating compounds were investigated as potential flash rust inhibitors. Compounds being evaluated include amine alcohols, diamines and sulfur containing amines. A new corrosion inhibitor 2,5-bis(thioaceticacid)-1,3,4-thiadiazole (H2ADTZ) was synthesized and its performance characteristics were evaluated. It was noted that the observed structure of 1,3,4-thiadiazolidine-2,5-dithione (also known as 2,5-dimercapto-1,3,4-thiadiazole (DMTD or DMcT)) has been previously reported in three different tautomeric forms including -dithiol and -dithione. The relative stability of each form as well as the synthesis and characterization …

An Improved Dipole-Moment Model Based On Near-Field Scanning For Characterizing Near-Field Coupling And Far-Field Radiation From An Ic, Zhenwei Yu

Doctoral Dissertations

"Radio Frequency Interference (RFI) problems are critical issues in wireless platform design. The accurate noise model of integrated circuits (ICs) is needed to help designers to diagnose and predict RFI problems. In this dissertation, an improved IC radiated emission model based on near-field measurements is proposed. The regularization technique and the truncated SVD method are employed together with the least square method to calculate the dipole moments from the near-field data. This dipole model has clear physical meaning: the electric and magnetic dipoles represent the voltage and the current in the circuit, respectively. One application of this dipole model is …

Lifetime Prediction And Confidence Bounds In Accelerated Degradation Testing For Lognormal Response Distributions With An Arrhenius Rate Relationship, Steven Michael Alferink

Doctoral Dissertations

"Determining the lifetime of a product is an important component of quality assurance. Traditional life testing methods are infeasible for products that have been designed to have a very long lifetime because they require a lengthy testing period. An alternative method is accelerated degradation testing, where a response variable determining the usability of the product is measured over time under multiple accelerating stress levels. The resulting data are then used to predict the life distribution of the product under the design stress level. In this dissertation, several methods are proposed and studied for obtaining prediction bounds for the lifetime of …

Mantle Flow And Lithosphere-Asthenosphere Coupling Beneath The Southwestern Edge Of The North American Craton: Constraints From Shear-Wave Splitting Measurements, Hesham A. Refayee

Doctoral Dissertations

"High-quality broadband seismic data recorded by the USArray and other stations in the southwestern United States provide a unique opportunity to test different models of anisotropy-forming mechanisms in the vicinity of a cratonic edge. Systematic spatial variations of anisotropic characteristics are revealed by 3027 pairs of splitting parameters measured at 547 broadband seismic stations. The western and southern edges of the North American craton show edge-parallel fast directions with larger-than-normal splitting times, and the continental interior is characterized by smaller splitting times spatially consistent fast directions that are mostly parallel to the absolute plate motion direction of North America. Except …

Nitrification Performance Of Activated Sludge Under Low Dissolved Oxygen Conditions, Guoqiang Liu

Doctoral Dissertations

"The combined effects of solids retention time (SRT) and dissolved oxygen (DO) concentration on nitrification, nitrifying bacterial communities, and aeration needs in the activated sludge process were studied. Nitrification was almost completed in the 10, 20, and 40-day SRT reactors with a minimum DO of 0.37, 0.25, and 0.16 mg/L, respectively. Under long-term low DO conditions, the endogenous decay of nitrifiers was slowed down and then nitirfier biomass concentration increased, thereby reducing the adverse effect of low DO on nitrification. Under long-term low DO conditions, the oxygen affinity of nitrite-oxidizing bacteria (NOB) increased significantly and as a result, NOB became …

Plate Kinematics Of The Afro-Arabian Rift System With An Emphasis On The Afar Depression, Helen Carrie Bottenberg

Doctoral Dissertations

This work utilizes the Four-Dimensional Plates (4DPlates) software, and Differential Interferometric Synthetic Aperture Radar (DInSAR) to examine plate-scale, regional-scale and local-scale kinematics of the Afro-Arabian Rift System with emphasis on the Afar Depression in Ethiopia. First, the 4DPlates is used to restore the Red Sea, the Gulf of Aden, the Afar Depression and the Main Ethiopian Rift to development of a new model that adopts two poles of rotation for Arabia. Second, the 4DPlates is used to model regional-scale and local-scale kinematics within the Afar Depression. Most plate reconstruction models of the Afro-Arabian Rift System relies on considering the Afar …

Quantitative Analysis Of Co-Enzyme A In A Plant Tissues And Cancer Biomarkers In Urine Samples By Using Capillary Electrophoresis And Liquid Chromatography-Mass Spectrometry, Yongqing Jiang

Doctoral Dissertations

"Despite continuous effort and progress in cancer detection and therapy, cancer remains one of our greatest health concerns because of its low survival rate and rapid incidence increase. One reason for this is the late detection and therefore pre-cancer diagnosis is crucial. In pre-cancer studies, cancer biomarkers become significant because of the useful information it contains such as possible cancer type and stage. Separation and detection technique plays an important role in cancer biomarker identification.

Coenzyme A (CoA) facilitates more than 100 chemical reactions in cells. Because of its low abundance accumulated in cells, it is critical to develop a …

Spatial-Temporal Reasoning Applications Of Computational Intelligence In The Game Of Go And Computer Networks, Tae-Hyung Kim

Doctoral Dissertations

"Spatial-temporal reasoning is the ability to reason with spatial images or information about space over time. In this dissertation, computational intelligence techniques are applied to computer Go and computer network applications. Among four experiments, the first three are related to the game of Go, and the last one concerns the routing problem in computer networks.

The first experiment represents the first training of a modified cellular simultaneous recurrent network (CSRN) trained with cellular particle swarm optimization (PSO). Another contribution is the development of a comprehensive theoretical study of a 2x2 Go research platform with a certified 5 dan Go expert. …

Sustainable Engineering Practices In Transportation Projects, Kiran Rangarajan

Doctoral Dissertations

"Sustainability has become an important issue in transportation and infrastructure development projects. While several agencies are trying to incorporate a range of sustainability measures in their goals and missions, only a few planning agencies have been able to implement these policies and they are far from perfect. The low rate of success in implementing sustainable policies is primarily due to incomplete understanding of the system and the interaction between various elements of the system. The conventional planning efforts focuses mainly on performance measures pertaining to the system and its impact on the environment but seldom on the social and economic …

The Effects Of Personal Protective Respirators On Human Motor, Visual, And Cognitive Skills, Anas Ahmed Alghamri

Doctoral Dissertations

"In oxygen-deficient or toxic environments in which controlling the hazard is not feasible, workers wear personal protective respirators. Hazard controls include but are not limited to engineering controls, such as ventilation, and substituting less hazardous materials. However, respirator selection and the design of tasks that require respirators are critical issues. Understanding the effects of respirators on human abilities is critical to respirator selection and therefore to the safety and efficiency of workers. This research investigated the effect of respirators on human abilities. A review of the relevant literature was conducted, revealing that respirators can affect physiological, psychological, motor, and visual …

Investigation Of Biomarkers For Noninvasive Early Diagnosis Of Cancer, Sanjeewa Bandara Gamagedara

Doctoral Dissertations

"Cancer is the second leading cause of death worldwide, and deaths from cancer worldwide are projected to continue rising, with an estimated 12 million deaths in 2030. Cancer occurs when cells in a part of the body begin to grow out of control. It develops very rapidly, and early diagnosis offers a greater chance of successful treatment and a higher survival rate. Biomarkers are good potential tools for early diagnosis. The main hypothesis of this study is that the levels of certain metabolites present in human urine can indicate the current or future behavior of cancer. Therefore, these studies focused …

Numerical Simulations Of Fracture Propagation And Sealing: Implications For Wellbore Strengthening, Saeed Salehi

Doctoral Dissertations

"To mitigate the small tolerance between pore pressure and fracture gradients an engineering practice referred to as "wellbore strengthening" is conducted to increase the fracture gradient. The method relies on propping and/or sealing the fractures with specially designed materials. Different competing theories exist for physical wellbore strengthening mechanisms which can be categorized into two groups. The first group explains that strengthening happens as a result of increasing wellbore hoop stress when fractures are sealed while the second group emphasis is on fracture tip isolation with suitable materials and enhancing fracture propagation pressure. The numerical models and lab experiments …

Modeling Aperture Radiation For Rf Interference Applications, Liehui Ren

Doctoral Dissertations

"The first topic proposes a rigorous method of moments(MoM) solution to evaluate the shielding effectiveness of a metallic enclosure with apertures on top wall by formulating a pair of coupled mixed potential integral equations (MPIEs). Application of Ewald transform to the computation of Green's function in the cavity yields fast convergence of series summation. Good agreements with a commercial tool, EMC studio, have proved the effectiveness of the proposed approach.

The second topic deals with prediction of electromagnetic interference radiation from components or interconnects in a printed circuit board by using convolution of the half-space Green's functions and the equivalent …

Analyzing Risk And Catastrophic Accidents: Using Lopa And Human Factors To Improve Safety In Generic Projects, Siddharth B. Damle

Doctoral Dissertations

"Risk assessment and identification in the early stages of any project is critical to the success of that project from time, budget and cost prespective [sic]. Identifying unacceptable risks and making provisions to mitigate those, can reduce the uncertainty in the project and ensure its smooth completion and closure. Various techniques have been developed over time to identify and quantify risks. Inspite of all the available research on risk management tools, accidents continue to happen and projects consistently fail.

The objective of this study is to first, determine the generic risks that can be encountered by a project. A list …

Design And Experimental Study Of Turbo Equalization For Multiple Antenna Systems, Amirhossein Rafati

Doctoral Dissertations

"Multiple-input multiple-output (MIMO) wireless communication systems have attracted a lot of interest in the past decade due to their capability in delivering high spectral efficiency as well as their robust performance against fading. In MIMO inter-symbol interference (lSI) channels, a severe interference problem occurs due to the lSI and co-channel interference. Thus, the error propagation problem becomes more serious, and its mitigation has to be considered when designing the receiver. In this regard, a turbo equalizer which exchanges soft information between the equalizer and the decoder has been shown to be an effective method to combat the lSI caused by …

Economics And Finance On Time Scales, Julius Severin Heim

Doctoral Dissertations

"This thesis consists of 6 papers that investigate models in economics and finance based on so-called dynamic equations on time scales. The first paper covers multiplier-accelerator models that can be described by linear second-order dynamic equations. The possibility of taxes as well as the possibility of foreign trade is taken into consideration. The second paper discusses cobweb models, which describe cyclical supply and demand in markets, where the supply is determined before the observation of the price. Cobweb models that can be formulated with first-order linear, second-order linear, and nonlinear dynamic equations are being considered. The third and fourth papers …

Friction Stir Welding Of High Temperature Alloys, Jiye Wang

Doctoral Dissertations

"Friction stir welding (FSW) of Ti-6Al-4V alloy, nickel-based and iron-based oxide dispersion strengthened (ODS) alloys (MA754 and MA956) has been studied. The main aspects covered include tool evaluation, microstructural evolution, mechanical properties, and correlation between processing, microstructure and mechanical properties. Tool performance study was carried out for Ti-6Al-4V alloy with refractory tools made of W-1.1%La₂O₃ and two different grades of WC-Co based materials. The results showed that tool degradation can be attributed to mechanical and chemical interaction with processed material. The nature of tool-workpiece interaction was tool material dependent and influenced the resultant microstructure and weld quality in the stirred …

Identification And Visualization Of Electromagnetic Coupling Paths & Nonlinear Capacitors For Esd Protection, Hongyu Li

Doctoral Dissertations

"The first topic of this dissertation focuses on developing methods to identify and visualize electromagnetic coupling paths. The basis of the approach is to utilize an analogy between electromagnetic energy flow and fluid flow. This allows one to apply the theories and algorithms of fluid dynamics to electromagnetics and thereby to visualize the electromagnetic energy flow. This in turn can be utilized to identify the electromagnetic coupling path.

The second topic of this dissertation investigates the nonlinearity of capacitors and suggests improved trade-off between electrostatic discharge (ESD) protection and data bandwidth by using the antiferroelectric (AFE) capacitors as ESD protection. …