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The Essential Elements Of Adolescent-Friendly Care In School-Based Health Centers: A Mixed Methods Study Of The Perspectives Of Nurse Practitioners And Adolescents, Alison Moriarty Daley

Doctoral Dissertations

The Essential Elements of Adolescent-Friendly Care in School-Based Health Centers: A Mixed Methods Study of the Perspectives of Nurse Practitioners and Adolescents

Alison Moriarty Daley Ph.D.

University of Connecticut, 2016

The majority of the morbidity and mortality among adolescents results from preventable causes including risk-taking behaviors and injuries. Preventive care for this population therefore includes anticipatory guidance and screening aimed at reducing these risks. However, the rates of engagement in preventive care decline steadily throughout adolescence. School-based health centers (SBHCs) have been identified as an adolescent-friendly community resource for preventive care. The purpose of this study was to identify the …

Cation Contamination In Polymer Electrolyte Fuel Cells: Impacts, Mechanisms, And Mitigation, Md. Aman Uddin

Doctoral Dissertations

Polymer electrolyte fuel cells (PEFCs), a promising source of clean energy in automotive application, still require durability improvement before commercialization. Cationic contaminants originated from either the ambient air (e.g. roadside contaminants) or from the corrosion of stack and balance of plant components can significantly decrease the performance and life time of PEFCs.

This work is focused on the experimental and theoretical study of the effects of cationic contaminants on the performance of PEFCs. Specifically, this work assesses the impact of a foreign cation on the durability of PEFCs, clarify the mechanisms responsible for the performance degradation, devise performance recovery strategies …

"Smoking-Gun" Observables Of Magnetic Reconnection: Spatiotemporal Evolution Of Electron Characteristics Throughout The Diffusion Region, Jason Shuster

Doctoral Dissertations

How does magnetic reconnection happen in a collisionless plasma? Knowledge of electron-scale dynamics is necessary to answer this outstanding question of plasma physics. Based on fully kinetic particle-in-cell (PIC) simulations of symmetric reconnection, the spatiotemporal evolution of velocity distribution functions in and around the electron diffusion region (EDR) elucidates how electrons are accelerated and heated by the cooperating reconnection electric and normal magnetic fields. The discrete, triangular structures characteristic of EDR distributions rotate and gyrotropize in velocity space as electrons remagnetize, forming multicomponent arc and ring structures. Further downstream, exhaust electrons are found to exhibit highly structured, time-dependent anisotropies that …

Transport Of Heat And Momentum In Non-Equilibrium Wall-Bounded Flows, Alireza Ebadi

Doctoral Dissertations

Transport of momentum and heat in non-equilibrium wall-bounded flows is studied analytically and experimentally to better understand the underlying physics, transition dynamics, and appropriate flow scaling in non-equilibrium flows. Non-equilibrium flows, in which the mean flow time scales are comparable to turbulent flow time scales, do not exhibit universal behaviors and cannot be characterized only in terms of local parameters. Pressure gradients, fast transients and complex geometries are among the sources that can perturb a flow from an equilibrium state to a non-equilibrium state. Since all or some of these perturbation sources are present in many engineering application relevant flow …

Computationally Efficient Specifications Of Spatial Point Process Models And Spatio-Temporal Gaussian Models: Combining Remote Sensing Drivers With Geospatial Disease Case Data To Enhance Geographic Epidemiology, Beth Louise Ziniti

Doctoral Dissertations

In this dissertation, the flexibility of Bayesian hierarchical models specified using a latent Gaussian Markov Random Field (GMRF) are evaluated for use in analyzing large complex spatial and spatio-temporal data with the goal of contributing to an interdisciplinary effort of developing an eco-epidemiological model that quantifies the relationship between remotely sensed water quality and the incidence of ALS (Amyotrophic Lateral Sclerosis or Lou Gehrig’s Disease) over large areas such as Northern New England (NNE).

In particular, a Log-Gaussian Cox Process (LGCP) specified by the logarithm of a GMRF on a regular lattice is shown to allow for simultaneous estimation of …

On Tensor Autoequivalences Of Graded Fusion Categories, Ian Swenson Marshall

Doctoral Dissertations

Fusion categories generalize the representation theory of finite groups. The simplest examples of fusion categories come from finite groups, their representations, and their cohomology. In general, it is useful to examine group theoretical features of fusion categories such as groups of (isomorphism classes of) tensor invertible objects, and gradings by finite groups. Indeed, every fusion category has a maximal pointed subcategory (generated by tensor invertible objects) and a universal grading by a finite group. We use such features to study tensor autoequivalences.

Pointed fusion categories: categories for which all simple objects are tensor invertible, provide our prototype for graded fusion …

Impedance Characterization Of Ysz Based Nox Sensors, Ling Cui

Doctoral Dissertations

Yttria-stabilized zirconia has been utilized as an electrolyte of SOFC (Solid Oxide Fuel Cell) studies for years. It is also preferred as the electrolyte for solid state electrochemical sensor which is able to measure nitrogen oxides in the exhaust system. Electrochemical Impedance Spectroscopy method yields the change in impedance which is caused by an electron exchange of NO x gases at the sensing electrodes. From the EIS data, the fractional change in the phase angle is calculated for detecting sensor sensitivity.

Considering the fabrication of a sensor, several variables have been investigated which include the choice of electrolyte processing, sensing …

Modular And Dynamic Approaches To The Formation Of Single-Chain Polymer Nanoparticles, Bryan Tyler Tuten

Doctoral Dissertations

The methodology towards the creation of nanoscale polymeric objects by way of the folding of single polymer chains has been enjoying success in the field of polymer chemistry and materials science. By synthesizing polymer chains with built in functionality either through functional side groups, or direct incorporation into the polymer backbone, polymer chemists are able to fold single polymer chains onto themselves through a broad range of covalent and non-covalent interactions in dilute solution. These compact, nano-sized objects can now be used in a wide arrange of functions and applications.

The aim of this dissertation is to provide first, a …

Ontology Of Close Human-Nature Relationships, Neil H. Kessler

Doctoral Dissertations

The world’s environmental problems call out for solutions. At root, many of the solutions currently being offered revolve around how modern humans relate to the environment. An array of theorists have offered perspectives and prescriptions for improvement of this relationship, with many seeking to promote a sense of closeness between human and nonhuman. But, in attempting to offer perspectives on how this might be achieved, theorists tend to neglect the relational structure and dynamics that produce closeness or, if exploring it, tend to characterize the nonhuman as incapable of participating in it as a truly close, relational partner. In this …

Global And Regional Assessments Of Unsustainable Groundwater Use In Irrigated Agriculture, Danielle S. Grogan

Doctoral Dissertations

Groundwater is an essential input to agriculture world-wide, but it is clear that current rates of groundwater use are unsustainable in the long term. This dissertation assesses both current use of groundwater for country- to global-scale agriculture, and looks at the future of groundwater. The focus is on 1) quantifying food directly produced as a result of groundwater use across spatially-varying agricultural systems, 2) projecting future groundwater demands with consideration of climate change and human decision-making, and 3) understanding the system dynamics of groundwater re-use through surface water systems. All three are addressed using a process-based model designed to simulate …

Polyacrylamide And Its Derivatives For Oil Recovery, Zun Chen

Doctoral Dissertations

"Polyacrylamide is an umbrella term used to describe the homo-polymer of acrylamide and the copolymer of acrylamide with a small amount of other monomers. Owing to their superior property on increasing viscosity and gelling ability in the presence of crosslinkers, polyacrylamides has become the primarily selection for polymer flooding and gel treatment agent in enhanced oil recovery. Recent developments, performance, applications and limitations of polyacrylamides and its derivatives, including copolymers and hydrogels for enhancing oil recovery are reviewed.

A water-free suspension system was developed to synthesize PAMs and PAMs-microgel. Products are dry particle powder and ready to disperse in water. …

Adaptive Consensus Based Formation Control Of Unmanned Vehicles, Haci Mehmet Guzey

Doctoral Dissertations

"Over the past decade, the control research community has given significant attention to formation control of multiple unmanned vehicles due to a variety of commercial and defense applications. Consensus-based formation control is considered to be more robust and reliable when compared to other formation control methods due to scalability and inherent properties that enable the formation to continue even if one of the vehicles experiences a failure. In contrast to existing methods on formation control where the dynamics of the vehicles are neglected, this dissertation in the form of four papers presents consensus-based formation control of unmanned vehicles-both ground and …

Thorium-Based Mixed Oxide Fuel In A Pressurized Water Reactor: A Feasibility Analysis With Mcnp, Lucas Powelson Tucker

Doctoral Dissertations

"This dissertation investigates techniques for spent fuel monitoring, and assesses the feasibility of using a thorium-based mixed oxide fuel in a conventional pressurized water reactor for plutonium disposition. Both non-paralyzing and paralyzing dead-time calculations were performed for the Portable Spectroscopic Fast Neutron Probe (N-Probe), which can be used for spent fuel interrogation. Also, a Canberra ³He neutron detector's dead-time was estimated using a combination of subcritical assembly measurements and MCNP simulations. Next, a multitude of fission products were identified as candidates for burnup and spent fuel analysis of irradiated mixed oxide fuel. The best isotopes for these applications were …

A Moving Imagination In Spaces Of Distress: Teacher And Student Agency In A Science Classroom, Annie Sunshine Adamian

Doctoral Dissertations

This qualitative study explored the ways in which our classroom community (students and teacher) engaged with humanizing pedagogy in a seventh grade science classroom, toward the full development (e.g. personal, social, emotional, academic) of our classroom community, and the dismantling of inequitable practices and unjust policies that we recognized in our science classroom, school and/or community while utilizing the process of teacher and student participatory action research (tsPAR) (Adamian, 2015) and Critical Race Praxis for Educational Research (CRP-Ed) (Jayakumar & Adamian, 2015).

This study examined the complexities of mutually engaging across differing positionalities while intentionally working in spaces of distress …

Modeling Of Rheological Properties For Entangled Polymer Systems, Nilanjana Banerjee

Doctoral Dissertations

"The study of entangled polymer rheology both in the field of medicine and polymer processing has their major importance. Mechanical properties of biomolecules are studied in order to better understand cellular behavior. Similarly, industrial processing of polymers needs thorough understanding of rheology so as to improve process techniques. Work in this dissertation has been organized into three major sections. Firstly, numerical/analytical models are reviewed for describing rheological properties and mechanical behaviors of cytoskeleton. The cytoskeleton models are classified into categories according to the length scales of the phenomena of interest. The main principles and characteristics of each model are summarized …

Modeling Daily Electricity Load Curve Using Cubic Splines And Functional Principal Components, Abdelmonaem Salem Jornaz

Doctoral Dissertations

"Forecasting electricity load is very important to the electric utilities as well as producers of power because accurate predictions can cut down costs by avoiding power shortages or surpluses. Of specific interest is the 24-hour daily electricity load profile, which provides insight into periods of high demand and periods where the use of electricity is at a minimum. Researchers have proposed many approaches to modeling electricity prices, real-time load, and day-ahead demand, with varying success. In this dissertation three new approaches to modeling and forecasting the 24-hour daily electricity load profiles are presented. The application of the proposed methods is …

Construction Of Multi-State Potential Energy Surfaces For Spectroscopy And Dynamics, Phalgun Lolur

Doctoral Dissertations

"This dissertation is about construction and visualization of multi-state Born-Oppenheimer potential energy surfaces which are essential for studying spectroscopy and dynamics. A potential energy surface is a mathematical function that represents the energy of a system as a function of its molecular geometry. The Born-Oppenheimer approximation enables us to solve the Schrödinger equation by separating the nuclear and electronic motions. Construction of potential energy surfaces has become a basic and crucial operation for chemists in order to compute various electronic states of molecules for understanding the spectroscopy, kinetics and dynamics of molecules. These methods have been used to successfully (i) …

A Control Theoretic Approach For Security Of Cyber-Physical Systems, Haifeng Niu

Doctoral Dissertations

"In this dissertation, several novel defense methodologies for cyber-physical systems have been proposed. First, a special type of cyber-physical system, the RFID system, is considered for which a lightweight mutual authentication and ownership management protocol is proposed in order to protect the data confidentiality and integrity. Then considering the fact that the protection of the data confidentiality and integrity is insufficient to guarantee the security in cyber-physical systems, we turn to the development of a general framework for developing security schemes for cyber-physical systems wherein the cyber system states affect the physical system and vice versa. After that, we apply …

Multiphase Field Modeling Of The Formation Path Of Delta Hydrides In Zirconium, Jacob Luke Bair

Doctoral Dissertations

"Zirconium alloys are commonly used in nuclear fuel rod claddings due to their high ductility, good corrosion resistance, and low neutron absorption cross section. Among the most important weaknesses of zirconium alloys is their affinity for hydrogen, resulting in formation of hydrides in the cladding, and leading to embrittlement and mechanical failure. Despite numerous studies on hydride precipitation in zirconium alloys, the nucleation and formation path of stable δ hydrides in α zirconium matrix are not yet fully understood.

In this Ph.D. research project, two novel quantitative phase-field models were developed and utilized to advance our understanding of mechanisms of …

Mechanisms For Improving Information Quality In Smartphone Crowdsensing Systems, Francesco Restuccia

Doctoral Dissertations

"Given its potential for a large variety of real-life applications, smartphone crowdsensing has recently gained tremendous attention from the research community. Smartphone crowdsensing is a paradigm that allows ordinary citizens to participate in large-scale sensing surveys by using user-friendly applications installed in their smartphones. In this way, fine-grained sensing information is obtained from smartphone users without employing fixed and expensive infrastructure, and with negligible maintenance costs.

Existing smartphone sensing systems depend completely on the participants' willingness to submit up-to-date and accurate information regarding the events being monitored. Therefore, it becomes paramount to scalably and effectively determine, enforce, and optimize the …

Identifying Shallow Subsurface Stratigraphy And Voids Using Dispersive Characteristics Of Electromagnetic And Surface Waves, Payman Hajiani

Doctoral Dissertations

"This dissertation presents the results of three manuscripts on spectral analysis of electromagnetic and seismic surface waves to detect subsurface stratigraphy and voids. In the first manuscript, a new technique was developed by utilizing spectral analysis of surface waves to detect subsurface openings. This technique applied the concept of group delay to evaluate the effects of subsurface voids on the phase shift domain. Seismic data sets were acquired at different sites where the shape, size, and depth of the void varied. In all surveys, the time delay technique precisely identified the locations of the subsurface openings. The second manuscript presents …

Blended Learning In Chemistry Laboratory Courses: Enhancing Learning Outcomes And Aligning Student Needs With Available Resources, Shayna Brianne Burchett

Doctoral Dissertations

"Freshman science courses are intended to prepare students for the rigor and expectations of subsequent college science. While secondary education aims to prepare students for the college curriculum, many incoming freshman lack the sense of responsibility for their own learning that is essential for success in a college-level course. The freshman general-chemistry laboratory course at Missouri University of Science and Technology (Missouri S&T) was identified as a bottleneck course with a demand beyond accommodation capacity. To address the bottleneck and develop a sense of learner responsibility, a decision was made to investigate laboratory course delivery strategies. As a result of …

Dynamic Impact Of Ageing Dump Truck Suspension Systems On Whole-Body Vibrations In High-Impact Shovel Loading Operations, Saeid R. Dindarloo

Doctoral Dissertations

"Surface mining operations typically deploy large shovels, with 100+ tons per pass capacity, to load dump trucks in a phenomenon described as high-impact shovel loading operations (HISLO). The HISLO phenomenon causes excessive shock and vibrations in the dump truck assembly resulting in whole body vibration (WBV) exposures to operators. The truck suspension system performance deteriorates with time; therefore their effectiveness in attenuating vibrations reduces. No research has been conducted to study the impact of ageing suspension mechanisms on the magnitudes of WBV in HISLO operations.

This study is a pioneering effort to provide fundamental and applied knowledge for understanding the …

Continuous Flow Reactor For Carbonic Acid Hydrolysis/Pretreatment Of Microalgal Biomass To Produce Bioethanol, Nicholas Dudenhoeffer

Doctoral Dissertations

"In order to maximize bioethanol production an efficient pretreatment method for the hydrolysis of polysaccharides to fermentable sugars is necessary. Commonly used pretreatment methods are the slow enzymatic hydrolysis and the corrosive mineral acid hydrolysis process that requires a post-treatment neutralization step and generates waste stream. We investigated the high temperature water with carbonic acid catalyst as an alternative method. Carbonic acid generated from dissolved CO₂ is inexpensive and environmentally benign, and easily removed by decompression. A high pressure continuous flow reactor that can continuously process the wet biomass stream and perform the carbonic acid hydrolysis in-situ using the …

Contribution Of New Thiol Antioxidant In The Treatment Of Acetaminophen Toxicity, Ahdab Naeem Khayyat

Doctoral Dissertations

"Acetaminophen (N-acetyl-p-aminophenol, APAP) is one of the most widely used over-the-counter antipyretic analgesic medications. It is safe at therapeutic doses, but an overdose can result in severe hepato-nephrotoxicity, a leading cause of drug-induced acute liver failure in the U.S. Although a few different mechanisms have been proposed for APAP-induced toxicity, a significant amount of evidence has pointed to the potential involvement of oxidative stress in acetaminophen toxicity. Depletion of glutathione (GSH) is one of the initiating steps in APAP-induced toxicity; therefore, one strategy for restricting organ damage is to restore GSH levels by using GSH prodrugs like N-acetylcysteine (NAC). Although …

Azimuthal Anisotropy Beneath North Central Africa From Shear Wave Splitting Analysis, Awad Abdussalam Henish Lemnifi

Doctoral Dissertations

"This study represents the first multi-station investigation of azimuthal anisotropy beneath the interior of north central Africa, including Libya and adjacent regions, using shear wave splitting (SWS) analysis. Data used in the study include recently available broadband seismic data obtained from 15 stations managed by the Libyan Center for Remote Sensing and Space Science, and those from five other stations at which data are publicly accessible. A total of 583 pairs of high-quality SWS measurements utilizing the PKS, SKKS, and SKS phases demonstrate primarily N-S fast orientations with an average splitting delay time of approximately 1.2 s. An absence of …

Modeling, Analysis, And Simulation For Aqueous-Based Ceramic Pastes In Freeze-Form Extrusion Fabrication Process, Mingyang Li

Doctoral Dissertations

"During the freeze-form extrusion fabrication process, both the extrusion and freezing processes are complex due to the aqueous-based ceramic pastes' non-Newtonian behavior, large latent heat of the water contained in the paste, and the small temperature difference between the ambient and the paste. In this study, the steady-state relationship between plunger velocity and extrusion force is developed based on a modified Herschel-Bulkley viscosity model and the Navier-Stokes equations, and the dynamic response of the extrusion force is described by a first-order nonlinear equation when plunger velocity is taken as an input. It is shown that the extrusion response time depends …

Geophysical Imaging Of Karst Features In Missouri, Jeremiah Chukwunonso Obi

Doctoral Dissertations

"Automated electrical resistivity tomography (ERT) supported with multichannel analysis of surface waves (MASW) and boring data were used to map karst related features in Missouri in order to understand karst processes better in Missouri. Previous works on karst in Missouri were mostly surficial mapping of bedrock outcrops and joints, which are not enough to define the internal structure of karst system, since most critical processes in karst occur underground. To understand these processes better, the density, placement and pattern of karst related features like solution-widened joints and voids, as well as top of bedrock were mapped. In the course of …

Existence And Classification Of Nonoscillatory Solutions Of Two Dimensional Time Scale Systems, Özkan Özturk

Doctoral Dissertations

"During the past years, there has been an increasing interest in studying oscillation and nonoscillation criteria for dynamic equations and systems on time scales that harmonize the oscillation and nonoscillation theory for the continuous and discrete cases in order to combine them in one comprehensive theory and eliminate obscurity from both.

We not only classify nonoscillatory solutions of dynamic equations and systems on time scales but also guarantee the (non)existence of such solutions by using the Knaster fixed point theorem, Schauder - Tychonoff fixed point theorem, and Schauder fixed point theorem. The approach is based on the sign of nonoscillatory …

Multi-Level Evolutionary Algorithms Resource Allocation Utilizing Model-Based Systems Engineering, Bhanuchander Reddy Poreddy

Doctoral Dissertations

"This research presents an innovative approach to solve the resource allocation problems using Multi-level Evolutionary Algorithms. Evolutionary Algorithms are used to solve resource allocation problems in different domains and their results are then incorporated into a higher level system solution using another Evolutionary Algorithm to solve base camp planning problems currently faced by the U.S. Department of Defense.

Two models are introduced to solve two domain specific models: a logistics model and a power model. The logistic model evaluates routes for logistics vehicles on a daily basis with a goal of reducing fuel usage by delivery trucks. The evaluation includes …