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Fluid-Phase Thermodynamics From Molecular-Level Properties And Interactions Based In Quantum Theory, Steven G. Arturo May 2005

Fluid-Phase Thermodynamics From Molecular-Level Properties And Interactions Based In Quantum Theory, Steven G. Arturo

Dissertations

A methodology to predict the thermodynamics of macroscopic fluid systems from quantum chemistry and statistical thermodynamics has been developed. This work extends the group-contribution concepts most utilized in chemical engineering. Computational chemistry software is used to define the geometries and electron density profiles of target molecules. Atoms in Molecules theory and associated software packages are used to calculate rigorous properties of the functional groups within molecules of interest. These properties are incorporated into an intermolecular potential energy function which describes interactions between entire molecules as a set of interactions between functional groups. This information is applied to a lattice-fluid model …


Some Topics On Deterministic Scheduling Problems, Yumei Huo May 2005

Some Topics On Deterministic Scheduling Problems, Yumei Huo

Dissertations

Sequencing and scheduling problems are motivated by allocation of limited resources over time. The goal is to find an optimal allocation where optimality is defined by some problem specific objectives.

This dissertation considers the scheduling of a set of ri tasks, with precedence constraints, on m >= 1 identical and parallel processors so as to minimize the makespan. Specifically, it considers the situation where tasks, along with their precedence constraints, are released at different times, and the scheduler has to make scheduling decisions without knowledge of future releases. Both preemptive and nonpreemptive schedules are considered. This dissertation shows that optimal …


Direct Numerical Simulations And Experimental Investigation Of Dielectrophoresis, Arun Thankamony John-Kadaksham May 2005

Direct Numerical Simulations And Experimental Investigation Of Dielectrophoresis, Arun Thankamony John-Kadaksham

Dissertations

This dissertation deals with the numerical and experimental studies of the phenomenon of dielectrophoresis, i.e., the motion of neutral particles in nonuniform electric fields. Dielectrophoresis is the translatory motion of neutral particles suspended in a dielectric medium when they are subjected to an external nonuniform electric field. The translatory motion occurs because a force called the dielectrophoretic force, which depends on the spatial variation of the electric field, acts on the particles. As the generation of force involves no moving parts and the particles can be moved without touching them, dielectrophoresis can be used in many applications, including manipulation and …


Analysis And Characterization Of The Integrated Dielectric Slab Waveguide-Wedge Antenna Using Iterative Mode-Matching Technique, Chairat Pinthong May 2005

Analysis And Characterization Of The Integrated Dielectric Slab Waveguide-Wedge Antenna Using Iterative Mode-Matching Technique, Chairat Pinthong

Dissertations

A rigorous solution for the TB and TM polarization to the dielectric wedge antenna fed by a slab waveguide of the same material is presented. The method of solution involves modeling the wedge as a sequence of step discontinuities and using an iterative procedure to track forward and backward partial wave fields, expressed as modal expansions, to obtain the rigorous field solution. Radiation patterns of directive gain are presented. All patterns smoothly decrease from a maximum in the endfire direction and exhibit very low side lobes. Longer length wedges are shown to produce higher directivity and smaller half-power beamwidths (HPBW). …


Evaluating Rhizodegradation Of Petroleum Hydrocarbons And Polycyclic Aromatic Hydrocarbons In Wetland Sediments Containing Spartina Patens, Robert J. Lippencott May 2005

Evaluating Rhizodegradation Of Petroleum Hydrocarbons And Polycyclic Aromatic Hydrocarbons In Wetland Sediments Containing Spartina Patens, Robert J. Lippencott

Dissertations

Biodegradation of petroleum hydrocarbons (PHC) and 16 polycyclic aromatic hydrocarbon (PAH) compounds was evaluated in sediments from a stormwater basin that was a former salt marsh at an active oil refinery. Spartina patens were grown in basin sediments during a field study and a greenhouse study over three consecutive growing seasons. Ninety percent (90%) survival was observed in field study plots containing sediments with <12% PHC. In the greenhouse study, planted and bulk sediments were monitored for PHC, PAH, microbial density, nutrients, pH, redox and root biomass at 2.5 and 7.5 cm in sediments with <12% PHC. The sediments contained on average 6.5% to 9.5% PHC and 56 to 124 parts per million (ppm) total PAH. The plants exhibited a 95% survival rate and added from 1% to 2% root biomass to the sediment. Microbial densities in planted sediments were significantly higher than in bulk sediments (p<0.05). Oxidizing conditions were prevalent in all treatments at both depths; however, reducing conditions developed in the planted sediments at 7.5 cm. PHC was 35% to 37% lower in the planted sediments vs. bulk sediment at the end of the study. Planted sediment PAH concentrations were generally lower than in bulk sediments. Low MW PAHs (2 and 3-Rings) were either absent or at relatively low concentrations in all treatments. Phenanthrene concentrations in bulk sediments did not change, but were reduced by 95% in planted sediments (p<0.01), with half-life estimates of 141 to 165 days at 2.5 cm. Temporal changes in high MW PAHs ( 4-Rings) were not observed over the greenhouse study period. Differences in PAH concentrations between planted and bulk sediments exhibited a decreasing trend with PAH molecular weight. Evaluation of differences in planted and bulk sediment PAH concentrations suggests that lower MW PAHs degrade better under oxidizing conditions, and higher MW PAHs under reducing conditions in the planted sediments. Comparison of planted and bulk sediment PAH concentrations links depth and redox conditions to decreases in PAH as a function of PAH MW. Therefore, it was concluded that spatio-temporal variations and cycling of redox conditions should be considered to properly evaluate biodegradation of PAH.


Theory And Algorithms For Swept Manifold Intersections, Yuriy Mileyko May 2005

Theory And Algorithms For Swept Manifold Intersections, Yuriy Mileyko

Dissertations

Recent developments in such fields as computer aided geometric design, geometric modeling, and computational topology have generated a spate of interest towards geometric objects called swept volumes. Besides their great applicability in various practical areas, the mere geometry and topology of these entities make them a perfect testbed for novel approaches aimed at analyzing and representing geometric objects. The structure of swept volumes reveals that it is also important to focus on a little simpler, although a very similar type of objects - swept manifolds. In particular, effective computability of swept manifold intersections is of major concern.

The main goal …


Simulation Of Creep In Nickel Based Single Crystal Superalloys, Yunhong Pang May 2005

Simulation Of Creep In Nickel Based Single Crystal Superalloys, Yunhong Pang

Dissertations

Nickel based single crystal Superalloys are finding wide spread use in high temperature gas turbines and other similar applications because of their superior high-temperature strength and creep properties as compared to the other materials. This is due to two factors: solid solution and precipitation strengthening of the gamma (γ) and gamma prime (γ') phases, and the elimination of grain boundaries. Creep of Nickel based single crystal Superalloys are caused by two primary mechanisms, dislocation creep and diffusion creep. Several factors that affect the creep life of Nickel based single crystal Superalloys are the specific microstructure, stress, temperature and rafting. Also, …


Scheduling Policies For Disks And Disk Arrays, Chang Liu May 2005

Scheduling Policies For Disks And Disk Arrays, Chang Liu

Dissertations

Recent rapid advances of magnetic recording technology have enabled substantial increases in disk capacity. There has been less than 10% improvement annually in the random access time to small data blocks on the disk. Such accesses are very common in OLTP applications, which tend to have stringent response time requirements. Scheduling of disk requests is intended to improve their response time, reduce disk service time, and increase disk access bandwidth with respect to the default FCFS scheduling policy.

Shortest Access Time First policy has been shown to outperform other classical disk scheduling policies in numerous studies. Before verifying this conclusion, …


Image Watermarking, Steganography, And Morphological Processing, Yi-Ta Wu May 2005

Image Watermarking, Steganography, And Morphological Processing, Yi-Ta Wu

Dissertations

With the fast development of computer technology, research in the fields of multimedia security, image processing, and robot vision have recently become popular. Image watermarking, steganogrphic system, morphological processing and shortest path planning are important subjects among them. In this dissertation, the fundamental techniques are reviewed first followed by the presentation of novel algorithms and theorems for these three subjects.

The research on multimedia security consists of two parts, image watermarking and steganographic system. In image watermarking, several algorithms are developed to achieve different goals as shown below. In order to embed more watermarks and to minimize distortion of watermarked …


Collaborative Examinations In Asyncronous Learning Networks : Field Experiments On Collaborative Learning Through Online Assessments, Jia Shen May 2005

Collaborative Examinations In Asyncronous Learning Networks : Field Experiments On Collaborative Learning Through Online Assessments, Jia Shen

Dissertations

With the proliferation of computer networks and the emergence of virtual teams, learning and knowledge sharing in the online environment has become an increasingly important topic. Applying constructivism and collaborative learning theories to assessment, the collaborative online exam is designed featuring students' active participation in various phases of the exam process through small group activities online. A participatory online exam process is designed featuring similar procedures except that students' involvement in each phase of the exam is individual. The collaborative online exam and the participatory online exam are investigated regarding student exam study strategies, group process, exam outcomes, faculty satisfaction, …


Bioinformatics Study Of Mammalian Mrna Polydenylation, Haibo Zhang May 2005

Bioinformatics Study Of Mammalian Mrna Polydenylation, Haibo Zhang

Dissertations

Messenger RNA polyadenylation is one of the key post-transcriptional events in mammalian cells, which have influences on many aspects of mRNA metabolism. Several human diseases have been shown to associate with abnormal polyadenylation, highlighting the importance of this process. The availability of the complete sequence of human and mouse genomes, together with their gene expression data provides valuable resources to study mRNA polyadenylation on a system level. This dissertation addresses the following issues of mammalian mRNA polyadenylation through bioinformatics approaches: (1) the extensive documentation of several key aspects of polyadenylation sites in humans and mice on a genomic level; (2) …


Gas Fluidization Of Nanoparticles, Qun Yu May 2005

Gas Fluidization Of Nanoparticles, Qun Yu

Dissertations

The primary objective of this study is to perform a systematic investigation on the gas fluidization of various nanoparticle agglomerates. Firstly, the gas fluidization characteristics and regime classifications without any additional external force fields are identified using both experimental measurements and modeling. Secondly, the effect of introducing certain external force fields on nanoparticle fluidization is experimentally investigated. Two external force fields were applied: sound waves from a loud speaker (acoustic assistance) and in-bed magnets that were excited by an external oscillating magnetic field (magnetic assistance). Thirdly, exploratory experimental research on the use of nanoparticle agglomerates as a granular filtration media …


Electromagnetic And Acoustic Propagation In Strip Lines And Porous Media, Lin Zhou May 2005

Electromagnetic And Acoustic Propagation In Strip Lines And Porous Media, Lin Zhou

Dissertations

Wave propagation in two physical structures is described and analyzed in this dissertation. In the first problem, the propagation of a normally incident plane acoustic wave through a three dimensional rigid slab with periodically placed holes is modeled and analyzed. The spacing of the holes A and B, the wavelength λ and the thickness of the slab L are order one parameters compared to the characteristic size D of the holes, which is a small quantity. Scattering matrix techniques are used to derive expressions for the transmission and reflection coefficients of the lowest mode. These expressions depend only on the …


Algorithms And Complexity Analyses For Some Combinational Optimization Problems, Hairong Zhao May 2005

Algorithms And Complexity Analyses For Some Combinational Optimization Problems, Hairong Zhao

Dissertations

The main focus of this dissertation is on classical combinatorial optimization problems in two important areas: scheduling and network design.

In the area of scheduling, the main interest is in problems in the master-slave model. In this model, each machine is either a master machine or a slave machine. Each job is associated with a preprocessing task, a slave task and a postprocessing task that must be executed in this order. Each slave task has a dedicated slave machine. All the preprocessing and postprocessing tasks share a single master machine or the same set of master machines. A job may …


Just-In-Time Hypermedia, Li Zhang May 2005

Just-In-Time Hypermedia, Li Zhang

Dissertations

Many analytical applications, especially legacy systems, create documents and display screens in response to user queries "dynamically" or in real time . These documents and displays do not exist in advance, and thus hypermedia must be generated 'just in time" -automatically and dynamically.

This dissertation details the idea of 'just-in-time" hypermedia and discusses challenges encountered in this research area. A fully detailed literature review about the research issues and related research work is given. A framework for the 'just-in-time" hypermedia compares virtual documents with static documents, as well as dynamic with static hypermedia functionality. Conceptual 'just-in-time" hypermedia architecture is proposed …


High-Dimensional Indexing Methods Utilizing Clustering And Dimensionality Reduction, Lijuan Zhang May 2005

High-Dimensional Indexing Methods Utilizing Clustering And Dimensionality Reduction, Lijuan Zhang

Dissertations

The emergence of novel database applications has resulted in the prevalence of a new paradigm for similarity search. These applications include multimedia databases, medical imaging databases, time series databases, DNA and protein sequence databases, and many others. Features of data objects are extracted and transformed into high-dimensional data points. Searching for objects becomes a search on points in the high-dimensional feature space. The dissimilarity between two objects is determined by the distance between two feature vectors. Similarity search is usually implemented as nearest neighbor search in feature vector spaces. The cost of processing k-nearest neighbor (k-NN) queries via a sequential …


Improving Document Representation By Accumulating Relevance Feedback : The Relevance Feedback Accumulation (Rfa) Algorithm, Razvan Stefan Bot May 2005

Improving Document Representation By Accumulating Relevance Feedback : The Relevance Feedback Accumulation (Rfa) Algorithm, Razvan Stefan Bot

Dissertations

Document representation (indexing) techniques are dominated by variants of the term-frequency analysis approach, based on the assumption that the more occurrences a term has throughout a document the more important the term is in that document. Inherent drawbacks associated with this approach include: poor index quality, high document representation size and the word mismatch problem. To tackle these drawbacks, a document representation improvement method called the Relevance Feedback Accumulation (RFA) algorithm is presented. The algorithm provides a mechanism to continuously accumulate relevance assessments over time and across users. It also provides a document representation modification function, or document representation learning …


The Control Of Frequency Of A Conditional Oscillator Simultaneously Subjected To Multiple Oscillatory Inputs, Christina L. Ambrosio May 2005

The Control Of Frequency Of A Conditional Oscillator Simultaneously Subjected To Multiple Oscillatory Inputs, Christina L. Ambrosio

Dissertations

A conditional oscillator is one that requires input to oscillate. An example of such is the gastric mill network of the stomatogastric ganglion of the crab Cancer borealis which requires modulatory input from outside the stomatogastric ganglion and fast input from the pyloric network of the animal in order to become active. This dissertation studies how the frequency of the gastric mill network is determined when it is simultaneously subjected to two different rhythmic inputs whose timing may be mismatched. We derive a mathematical model of the gastric mill network and deduce that the difference in timing between the pyloric …


A Versatile Programming Model For Dynamic Task Scheduling On Cluster Computers, Dejiang Jin May 2005

A Versatile Programming Model For Dynamic Task Scheduling On Cluster Computers, Dejiang Jin

Dissertations

This dissertation studies the development of application programs for parallel and distributed computer systems, especially PC clusters. A methodology is proposed to increase the efficiency of code development, the productivity of programmers and enhance performance of executing the developed programs on PC clusters while facilitating improvement of scalability and code portability of these programs. A new programming model, named the Super-Programming Model (SPM), is created. Programs are developed assuming an instruction set architecture comprised of SuperInstructions (SIs). SPM models the target system as a large Virtual Machine (VM); VM contains functional units which are underlain with sub-computer systems and SIs …


Order Scheduling In Dedicated And Flexible Machine Environments, Haibing Li May 2005

Order Scheduling In Dedicated And Flexible Machine Environments, Haibing Li

Dissertations

Order scheduling models are relatively new in the field of scheduling. Consider a facility with m parallel machines that can process k different products (job types). Each machine can process a given subset of different product types. There are n orders from n different clients. Each order requests specific quantities of the various different products that can be produced concurrently on their given subsets of machines; it may have a release date, a weight and a due date. Preemptions may be allowed. An order can not be shipped until the processing of all the products for the order has been …


Utility Of Remote Sensing Data In Retrieval Of Water Quality Consituents Concentrations In Coastal Water Of New Jersey, Ting Yu May 2005

Utility Of Remote Sensing Data In Retrieval Of Water Quality Consituents Concentrations In Coastal Water Of New Jersey, Ting Yu

Dissertations

Three important optical properties used for monitoring coastal water quality are the concentrations of chlorophyll (CHL), color dissolved organic matter (CDOM) and total suspended materials (TSM). Ocean color remote sensing, a technique to collect color data by detection of upward radiance from a distance (Bukata et al.,1995), provides a synoptic view for determining these concentrations from upwelling radiances. In the open ocean (Case-I), it is not difficult to derive empirical algorithms relating the received radiances to surface concentrations of water quality parameters. In coastal waters (Case-Il), there are serious unresolved problems in extracting chlorophyll concentration because of high concentration of …


Tcp Performance Enhancement In Wireless Networks Via Adaptive Congestion Control And Active Queue Management, Kai Xu May 2005

Tcp Performance Enhancement In Wireless Networks Via Adaptive Congestion Control And Active Queue Management, Kai Xu

Dissertations

The transmission control protocol (TCP) exhibits poor performance when used in error-prone wireless networks. Remedy to this problem has been an active research area. However, a widely accepted and adopted solution is yet to emerge. Difficulties of an acceptable solution lie in the areas of compatibility, scalability, computational complexity and the involvement of intermediate routers and switches.

This dissertation rexriews the current start-of-the-art solutions to TCP performance enhancement, and pursues an end-to-end solution framework to the problem. The most noticeable cause of the performance degradation of TCP in wireless networks is the higher packet loss rate as compared to that …


The Role Of Puf3 Protein Interactions In The Regulation Of Mrna Decay In Yeast Saccharomyces Cerevisiae, Shervin Sean Houshmandi May 2005

The Role Of Puf3 Protein Interactions In The Regulation Of Mrna Decay In Yeast Saccharomyces Cerevisiae, Shervin Sean Houshmandi

Dissertations

The regulation of messenger RNA (mRNA) metabolism is an important step in proper gene expression. In many eukaryotic organisms this regulation can be mediated by a group of highly conserved RNA-binding proteins known as the Puf family of proteins. The yeast Saccharomyces cerevisiae has several proteins that belong to this family. One of the yeast Puf proteins, Puf3p, binds and regulates the COX17 mRNA, which codes for a protein involved in mitochondrial copper transport. Specifically, Puf3p stimulates the decay of COX17 mRNA. However, the precise mechanism of Puf3p binding and decay regulation is yet unknown. The goal of this research …


Confronting The Intra-Racial Gender Gap: A Quantitative Study Of The Impact Of Gender On African American Students' Perceptions Of Campus Climate At A Predominantly White Institution, Tiffany N. Carpenter Edd May 2005

Confronting The Intra-Racial Gender Gap: A Quantitative Study Of The Impact Of Gender On African American Students' Perceptions Of Campus Climate At A Predominantly White Institution, Tiffany N. Carpenter Edd

Dissertations

For the last decade, the attainment gap in college graduation rates between Black males and females has continued to grow, despite the best efforts of researchers interested in identifying both its causes and suggesting possible policy remedies. Although much of the work has focused on the search for cognitive differences between African American males and females, there has been little, if any, research on the different ways that Black males and females may perceive their campus climate. In an attempt to broaden the literature in this area, this study examined the perceptions of 366 undergraduate African American students at a …


Culture And Motivation In Online Learning Environments, Frances A. Clem Edd May 2005

Culture And Motivation In Online Learning Environments, Frances A. Clem Edd

Dissertations

In the past, instructional design of online learning has largely ignored culture in the creation of online learning environments. Because research in the interaction of culture and online learning is very sparse, an exploratory, blended study was conducted to assess whether there is evidence that one measurable aspect of learners’ culture interacts with the online learning environment in ways that can be observed and identified, and whether this interaction impacts learners’ motivation and behavior in those environments. “Culture” is a complex concept consisting of many interrelated behaviors and values. For this reason, the study focused on one single aspect of …


School Counselors' Perceptions About Female Participation In Non-Traditional Secondary Career And Technical Education (Cte) Programs, Rashida Khatoon Malik Apr 2005

School Counselors' Perceptions About Female Participation In Non-Traditional Secondary Career And Technical Education (Cte) Programs, Rashida Khatoon Malik

Dissertations

The purpose of this study was to examine high school counselors' perceptions of female participation in nontraditional secondary Career and Technical Education (CTE) programs. The data for this study was collected from high school counselors in Michigan by sending them a survey containing 25 items. The first section of the survey covered the demographics of the participants. The second section consisted of eight belief statements about counseling femalestudents into nontraditional CTE programs. The third section of the survey had 12 belief statements about female participation in CTE nontraditional programs. The survey responses were based on five-point Likert scales. The belief …


Think First For Kids (Tffk): A Longitudinal Analysis Of A School-Based Injury Prevention Curriculum, Dorothy L. Zirkle Phd Apr 2005

Think First For Kids (Tffk): A Longitudinal Analysis Of A School-Based Injury Prevention Curriculum, Dorothy L. Zirkle Phd

Dissertations

Despite years of legislative and public health efforts, unintentional injury continues to be a serious public health problem and is identified as a major priority on the national health care agenda. The high incidence of unintentional injury in the middle childhood age group is of particular interest due to immaturity of the cognitive, psychosocial, and neurophysical dimensions of the child. The purpose of this study was to examine the effectiveness of a school-based curriculum on improving knowledge and self-reported safety behaviors over time among ethnically and socioeconomically diverse elementary school aged children. The social, cultural, cognitive, and behavioral learning theory …


Understanding Photosynthesis And Plant Cellular Respiration As “Nested Systems”: The Characterization Of Pre-Service Teachers’ Conceptions, Mary H. Brown Apr 2005

Understanding Photosynthesis And Plant Cellular Respiration As “Nested Systems”: The Characterization Of Pre-Service Teachers’ Conceptions, Mary H. Brown

Dissertations

This dissertation project focused on pre-service elementary teachers' conceptions of the plant processes of photosynthesis and cellular respiration as being connected, occurring at multiple ecological levels, and working within "nested systems." Participants enrolled in a biology course designed for elementary education majors provided their views of the processes through a series of tasks with a peer, a semi-structured interview, and clarified both photosynthesisand plant cellular respiration directly following classroom instruction on the two topics. The instructor of the course was interviewed after a preliminary analysis of the participants' responses. Data were analyzed using the qualitative analysis computer program The Ethnograph …


Who Voted?: Social Class And Participation In United States Presidential Elections, Uisoon Kwon Apr 2005

Who Voted?: Social Class And Participation In United States Presidential Elections, Uisoon Kwon

Dissertations

Low turnout remains a persistent problem in American politics. The decline in turnout has been studied in various ways. In some cases scholars analyze aggregate turnout data and compare turnout in election districts with high and low concentrations o f particular ,social groups (Neimi and Weisberg, 1993). In other cases, surveys provide an opportunity to examine the causes and correlates o f turnout at the individual level. Various researchers find that socio-economic factors are related to turnout. People with more education vote at much higher rates than those with less education, higher income and middle class people are more likely …


Global Optimality Conditions In Mathematical Programming And Optimal Control, Pariwat Pacheenburawana Apr 2005

Global Optimality Conditions In Mathematical Programming And Optimal Control, Pariwat Pacheenburawana

Dissertations

We derive new first-order necessary and sufficient optimality conditions characterizing global minimizers in mathematical programming and optimal controlproblems. These conditions are based on level sets of an objective functional and they do not assume special structure of a problem (convexity, linearity, etc.). For a mathematical programming problem of minimization of a smooth functional on some compact convex set with equality nonlinear constraints, we derive first-order optimality conditions in the form of a generalized Lagrange multiplier rule. This rule should hold for any point from the level set of the objective functional corresponding to a global minimizer. We demonstrate that these …