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Articles 31111 - 31140 of 40092
Full-Text Articles in Entire DC Network
A Reintroduction Experiment Involving Mated Pairs Of Parent-Reared Greater Sandhill Cranes In Northern Arizona, Daniel P. Mummert, David H. Ellis, Carol L. Chambers
A Reintroduction Experiment Involving Mated Pairs Of Parent-Reared Greater Sandhill Cranes In Northern Arizona, Daniel P. Mummert, David H. Ellis, Carol L. Chambers
Proceedings of the North American Crane Workshop
In April 1997, 4 mated pairs of adult greater sandhill cranes (Grus canadensis tabida) were abrupt-released at Monnon Lake, Arizona. Five of 8 adult cranes died within 10 days of release. One crane flew from the release area within 10 days after release and was never relocated. One pair of cranes, with 1 pair member sustaining a broken wing 4 days after release, survived for 4 months and demonstrated the importance of maintaining pair bonds after release. The cause of death of at least 5 birds was predation. The high immediate mortality and complete long-term mortality experienced in …
Minimum Survival Rates For Mississippi Sandhill Cranes: A Comparison Of Hand-Rearing And Parent-Rearing, David H. Ellis, George F. Gee, Glenn H. Olsen, Scott G. Hereford, Jane M. Nicolich, Nancy J. Thomas, Meenakshi Nagendran
Minimum Survival Rates For Mississippi Sandhill Cranes: A Comparison Of Hand-Rearing And Parent-Rearing, David H. Ellis, George F. Gee, Glenn H. Olsen, Scott G. Hereford, Jane M. Nicolich, Nancy J. Thomas, Meenakshi Nagendran
Proceedings of the North American Crane Workshop
Hand-reared (56) and parent-reared (76) juvenile Mississippi sandhill cranes (Grus canadensis pulla) were produced at the Patuxent Wildlife Research Center (patuxent), Laurel, Maryland over a 4-year period (1989-92) and released at the Mississippi Sandhill Crane National Wildlife Refuge (Refuge), Gautier, Mississippi in a controlled experiment. Hand-reared survival rates proved higher than for parent-reared survival for each time category: 6 months, 86% versus 75%; 1 year, 77% versus 68%; 2 years, 66% versus 53%; 3 years, 55% versus 43%: partial data for fourth and fifth years were 57% versus 31 % and 48% versus 37%.
Developing A Migratory Whooping Crane Flock, Robert H. Horwich
Developing A Migratory Whooping Crane Flock, Robert H. Horwich
Proceedings of the North American Crane Workshop
Research on crane reintroductions within the last 15 years has produced information necessary to effect a successful reintroduction of a migratory whooping crane (Grus americana) flock. There are 4 main problems to solve for such a reintroduction: (1) inducing a high survival rate of the reintroduced cranes, (2) encouraging normal reproduction with conspecifics, (3) teaching the reintroduced cranes the migration route, and (4) inducing fear of humans in the reintroduced cranes. Use of an isolation-rearing method by the author, using puppets, sounds, and costumes, has led to a consistent, over 80%, survival rate for the reintroduced young cranes …
The Effects Of Semen Collection On Fertility In Captive, Naturally Fertile, Sandhill Cranes, Guojun Chen, George F. Gee, Jane M. Nicolich, Joanna A. Taylor
The Effects Of Semen Collection On Fertility In Captive, Naturally Fertile, Sandhill Cranes, Guojun Chen, George F. Gee, Jane M. Nicolich, Joanna A. Taylor
Proceedings of the North American Crane Workshop
We tested to see if semen collection interferes with fertility in naturally fertile pairs of cranes. We used 12 naturally fertile, Florida sandhill crane (Grus canadensis pratensis) pairs for this study, 6 control and 6 experimental. All pairs had previously produced fertile eggs. Semen was collected on Tuesday mornings and Friday afternoons from 26 February 1993 to 4 June 1993. We used standard artificial insemination methods to collect and to evaluate the semen and spermatozoa. Semen collection had minimal effect on semen quality and semen quantity. Semen volume, sperm density, sperm motility, sperm morphology, sperm viability, sperm number …
Multiple Spatial Scale Analysis Of Whooping Crane Habitat In Nebraska, Amy L. Richert, Kevin E. Church
Multiple Spatial Scale Analysis Of Whooping Crane Habitat In Nebraska, Amy L. Richert, Kevin E. Church
Proceedings of the North American Crane Workshop
Geographic Information System (GIS) and remote sensing technologies were used to evaluate whooping crane stopover habitat in Nebraska. The goal of the research was to investigate habitat selection at multiple spatial scales. The GIS database consisted of all confirmed whooping crane sightings reported in Nebraska from 1975-1996 and land cover information delineated from color infrared aerial photographs and Landsat Thematic Mapper data. Results suggest that whooping cranes select roost habitat by recognizing site-level and landscape-scale land cover composition. Wetland is the most strongly selected habitat type at all spatial scales examined. This presentation emphasizes methods used to analyze habitat selection …
Whooping Cranes Breeding At White Lake, Louisiana, 1939: Observations By John J. Lynch, U. S. Bureau Of Biological Survey, Roderick C. Drewien, John Tautin, Mary Lynch Courville, Gay M. Gomez
Whooping Cranes Breeding At White Lake, Louisiana, 1939: Observations By John J. Lynch, U. S. Bureau Of Biological Survey, Roderick C. Drewien, John Tautin, Mary Lynch Courville, Gay M. Gomez
Proceedings of the North American Crane Workshop
On 15 May 1939, Jo1m J. Lynch of the U.S. Bureau of Biological Survey located l3 whooping cranes (Grus americana), including 2 prefledged young, during an aerial survey near White Lake in southwestern Louisiana. His observation was the last historic record of whooping cranes breeding in the wild in the United States, and it confinned the presence of a nonmigratory breeding population along the Gulf Coast. While reviewing old U.S. Fish and Wildlife Service files at the National Archives in 1999, we located Lynch's original 1939 field note, 2 letters, 5 photographs, and a draft manuscript describing the …
Results Of The Utah–Arizona Stage-By-Stage Migrations, David H. Ellis, Carolee Mellon, Matthew Kinloch, Tressa Dolbeare, Damien P. Ossi
Results Of The Utah–Arizona Stage-By-Stage Migrations, David H. Ellis, Carolee Mellon, Matthew Kinloch, Tressa Dolbeare, Damien P. Ossi
Proceedings of the North American Crane Workshop
In an effort to find a safer means of teaching cranes new migration routes, each year (in 1998 and 1999) we transported a group of greater sandhill cranes (Grus canadensis tabida) stage-by-stage, in a horse trailer, with stops for brief flights at about 30-km intervals, along a 1300-1400-km fall migration route from Fish Springs National Wildlife Refuge (Fish Springs) in west-central Utah to the vicinity of Gila Bend, Arizona. Thereafter, we released them into a wild flock of sandhill cranes. All stage-by-stage birds were hand-reared with both a plastic crane decoy (to encourage them to roost in water) …
Using Ivermectin To Increase Survival Of Sandhill Crane Colts At Malheur National Wildlife Refuge, Oregon, Gary L. Ivey, Caroline P. Herziger
Using Ivermectin To Increase Survival Of Sandhill Crane Colts At Malheur National Wildlife Refuge, Oregon, Gary L. Ivey, Caroline P. Herziger
Proceedings of the North American Crane Workshop
Parasitic gapeworms (Cyathostoma sp.) caused 5.6% of mortalities of219 radiomarked greater sandhill crane (Grus canadensis tabida) colts at Malheur National Wildlife Refuge (NWR) in Oregon from 1991-98. From 1993-98 we tested the efficacy of ivennectin, an antihelmenthic drug, as a means of increasing colt survival by reducing gapewonn infestations. We selected pairs of siblings for the study, injecting 1 colt with ivennectin and not the other. We found significantly shorter survival times for untreated birds compared to those treated with ivennectin (P = 0.06). We conclude that in areas with gapewonn infestations in young cranes, the …
Proceedings Of The Eighth North American Crane Workshop, 11–14 January 2000, Preface And Contents
Proceedings Of The Eighth North American Crane Workshop, 11–14 January 2000, Preface And Contents
Proceedings of the North American Crane Workshop
This volume includes reports from the January 2000 conference in Albuquerque, New Mexico, 2 papers not included in the previous proceedings, and a small number of invited papers intended to broaden the scope of the volume and to replace the few papers presented at the conference but withdrawn from publication. In serving as Editor, I wish, first of all, to express thanks to the many authors, reviewers, and associate editors, and to Gary Lingle who hosted the conference and was the intended Chief Editor: Gary underwent an employment change early in 2001 and so passed the task to me. I …
Increased Egg Conservation: Is It Essential For Recovery Of Whooping Cranes In The Aransas/Wood Buffalo Population?, James C. Lewis
Increased Egg Conservation: Is It Essential For Recovery Of Whooping Cranes In The Aransas/Wood Buffalo Population?, James C. Lewis
Proceedings of the North American Crane Workshop
The whooping crane (Grus americana) is in a race for survival against adversities (genetic, demographic, and environmental) that are only partially understood. There is increasing evidence of genetic problems (drift, inbreeding, and loss of heterozygosity) in the captive population that likely also exist in the wild Aransas-Wood Buffalo Population (A WP), a consequence of the 1940s population bottleneck. Small populations are vulnerable to extinction through catastrophic events and random changes in productivity or survival. Negative environmental effects faced by whooping cranes include upstream diversion which diminish freshwater (nutrient) inflow into Texas wintering habitats, and expanding human activities along …
Continuing Studies Of Ultralight Aircraft Applications For Introducing Migratory Populations Of Endangered Cranes, Kent R. Clegg, James C. Lewis
Continuing Studies Of Ultralight Aircraft Applications For Introducing Migratory Populations Of Endangered Cranes, Kent R. Clegg, James C. Lewis
Proceedings of the North American Crane Workshop
This research tested whether captive-reared cranes led by an ultralight aircraft (UL) along a migration route, would, after release on a wintering area, integrate with wild cranes and migrate in spring to their natal area without human assistance. This was the historical first motorized migration involving an endangered species. In 1997, whooping cranes (Grus americana) and greater sandhill cranes (Grus canadensis tabida) were group-reared in species-specific pens and 80% fledged. Beginning 13 October, 4 whooping cranes and 8 sandhill cranes were led along a 1, 133-km migration route from Grace, Idaho, to Bosque del Apache National …
Promoting Wildness In Sandhill Cranes Conditioned To Follow An Ultralight Aircraft, Joseph W. Duff, William A. Lishman, Dewitt A. Clark, George F. Gee, Daniel T. Sprague, David H. Ellis
Promoting Wildness In Sandhill Cranes Conditioned To Follow An Ultralight Aircraft, Joseph W. Duff, William A. Lishman, Dewitt A. Clark, George F. Gee, Daniel T. Sprague, David H. Ellis
Proceedings of the North American Crane Workshop
During the 1998 field season, we developed and tested a new protocol to teach sandhill cranes (Grus canadensis) to follow ultralight aircraft yet avoid humans. Although successful in teaching the cranes a migration route, our previous migration (1997) resulted in birds that were overly tame and sought association with humans. For this study, 16 sandhill cranes were costume-reared at USGS Patuxent Wildlife Research Center and transported to Ontario shortly before fledging. After the birds learned to follow the aircraft, 14 were transported to an isolated wintering site in South Carolina, 1300 km south of the training area. Twelve …
Use Of Satellite Telemetry To Identify Temporal And Spatial Distribution Of The Midcontinent Sandhill Crane Population Throughout The Annual Cycle, Gary L. Krapu, David A. Brandt
Use Of Satellite Telemetry To Identify Temporal And Spatial Distribution Of The Midcontinent Sandhill Crane Population Throughout The Annual Cycle, Gary L. Krapu, David A. Brandt
Proceedings of the North American Crane Workshop
Effective management of the midcontinent sandhill crane (Grus canadensis) population requires having detailed information available on the distribution of subspecies and subpopulations throughout the annual cycle. The current study is being undertaken in partnership with several federal and state agencies and private organizations to obtain key information not currently available. We are monitoring crane movements throughout the year by attaching Platform Transmitting Terminals (PTTs) to plastic leg bands and with the aid of equipment on board orbiting NOAA weather satellites relocating the radiomarked individuals at 4-10 day intervals throughout the year. Twenty-one cranes were captured and radio-marked in …
Water Conditioning And Whooping Crane Survival After Release In Florida, George F. Gee, Jane M. Nicolich, Stephen A. Nesbitt, Jeff S. Hatfield, David H. Ellis, Glenn H. Olsen
Water Conditioning And Whooping Crane Survival After Release In Florida, George F. Gee, Jane M. Nicolich, Stephen A. Nesbitt, Jeff S. Hatfield, David H. Ellis, Glenn H. Olsen
Proceedings of the North American Crane Workshop
About 50% of the whooping cranes (Grus americana) released in Florida die within the first year of release. Most of these deaths and those in subsequent years result from bobcat (Lynx rufus) predation. Choosing release sites in open marshes away from bobcat habitat has improved survival. We hypothesized that exposure to ponds (water conditioning) at the rearing site would encourage birds to roost in deeper water marshes after release and such exposure would thereby reduce bobcat predation. In this study, we moved young birds (ca 50 days of age) to netted pens with large (I5-m diameter), deep (30--60 …
Mortality Of Whooping Crane Colts In Wood Buffalo National Park, Canada, 1997–99, Douglas G. Bergeson, Brian W. Johns, Geoffrey L. Holroyd
Mortality Of Whooping Crane Colts In Wood Buffalo National Park, Canada, 1997–99, Douglas G. Bergeson, Brian W. Johns, Geoffrey L. Holroyd
Proceedings of the North American Crane Workshop
Twenty-two whooping crane (Grus americana) pairs with 2 young were monitored in Wood Buffalo National Park (WBNP) over 3 years to determine causes of colt mortality. The family groups were monitored from the ground, air, and with the aid ofradioteiemetry. We attached transmitters to 18 colts: 5 (28%) fledged, 5 (28%) succumbed to cumulative effects (head trauma, stress, exposure and/or infection), 4 (22%) were lost to unknown causes (3 of these went missing after they had lost their transmitters), 2 (11%) were taken by foxes (Vulpes vulpes), 1 (5.5%) was lost to raven (Corvus corax …
Egg Collection And Recruitment Of Young Of The Year In The Aransas/Wood Buffalo Population Of Whooping Cranes, John R. Cannon, Brian W. Johns, Thomas V. Stehn
Egg Collection And Recruitment Of Young Of The Year In The Aransas/Wood Buffalo Population Of Whooping Cranes, John R. Cannon, Brian W. Johns, Thomas V. Stehn
Proceedings of the North American Crane Workshop
We present data for 61 years (1938 to 1998) on the recruitment of juvenile (i.e., young-of-the-year) whooping cranes (Grus americana) for the 1 natural wild population that nests in the vicinity of Wood Buffalo National Park (WBNP) in Canada and migrates annually to wintering grounds in the vicinity of Aransas National Wildlife Refuge (ANWR) on the Gulf coast of Texas in the United States. We divide these years into 2 data sets: years during which 1 of 2 eggs was collected from WBNP nests (to develop captive populations and to conduct reintroduction experiments), and years during which no …
Status Of Sandhill Cranes In Indiana, John S. Castrale, James Bergens
Status Of Sandhill Cranes In Indiana, John S. Castrale, James Bergens
Proceedings of the North American Crane Workshop
Historically, the sandhill crane (Grus canadensis) was considered a common migrant throughout Indiana and a locally abundant breeding bird in northwestern Indiana until 1929. Most of the Eastern Population of greater sandhill cranes (G. c. tabida) is thought to congregate each fall at Jasper-Pulaski Fish and Wildlife Area before migrating to Florida and Georgia. Systematic weekly fall counts began in 1967 and annual peak numbers have increased from 2,500 in 1967 to 27,600 in 1997, with a record count of 32,600 in 1991. Fall migrants are noticeable by late September, peak in mid-October through mid-November, and …
Tracking Sandhill Crane Migration From Saskatchewan To The Gulf Coast, Dale G. Hjertaas, David H. Ellis, Brian W. Johns, Stacie L. Moon
Tracking Sandhill Crane Migration From Saskatchewan To The Gulf Coast, Dale G. Hjertaas, David H. Ellis, Brian W. Johns, Stacie L. Moon
Proceedings of the North American Crane Workshop
Four adult sandhill cranes (Grus canadensis rowani) were captured in east-central Saskatchewan, equipped with transmitters, and tracked by satellite to detennine if their migration routes and wintering areas would allow their use as guide birds to establish a new migratory flock of whooping cranes (G. americana). Two birds captured near Yorkton died or their transmitters were lost before migration. Two adults from the Overflowing River moved to staging areas in southern Saskatchewan in September. By 29 September, Crane A left Saskatchewan and moved to North Dakota where it remained until late October. By 21 December, it …
Fish & Wildlife News: January/February/March 2001
Fish & Wildlife News: January/February/March 2001
Fish and Wildlife News
Contents:
Norton Takes the Interior Helm 2
Experts Recommend Hatchery Changes 3
Landowners Take Charge to Save Wetlands 6
A Great Experiment at Aransas NWR 8
Anchors Aweigh: The Navy Helps Out 9
Lead Shot Ban Proven Good for Birds 11
A New Cup of Coffee at DOI 13
Pelican Island: Preserving a Legacy 14
Realizing a Decade-Old Dream 16
Jones Looks at Challenges Ahead 17
The First Name on “the Wall” 30
Fish and Wildlife...In Brief 35
Manipulating Dna Conformation Using Intertwined Conducting Polymer Chains, Ramaswamy Nagarajan, Wei Liu, Jayant Kumar, Sukant K. Tripathy, Ferdinando F. Bruno, Lynne A. Samuelson
Manipulating Dna Conformation Using Intertwined Conducting Polymer Chains, Ramaswamy Nagarajan, Wei Liu, Jayant Kumar, Sukant K. Tripathy, Ferdinando F. Bruno, Lynne A. Samuelson
United States Army: Publications
In the field of inherently conducting polymers, polyaniline (Pani) has elicited tremendous interest due to its promising electrical properties and unique redox tunability. Synthetic routes involving the use of polyelectrolytes have significantly improved the processability of polyaniline. Recently, a template guided synthesis catalyzed by an enzyme, horseradish peroxidase (HRP), has provided a means of polymerizing aniline under milder pH conditions (pH 4.3) and subsequently widened the choice of templates to more delicate biological macromolecules. Here we report a strategy that exploits the inherent molecular order as well as the polyelectrolyte behavior of DNA to enzymatically synthesize and biologically assemble conducting …
Lab Fattening And Non-Invasive Estimates Of Body Composition In Deer Mice, Edward T. Unangst, Michael J. Blair, Matthew W. Granger, David W. Hale
Lab Fattening And Non-Invasive Estimates Of Body Composition In Deer Mice, Edward T. Unangst, Michael J. Blair, Matthew W. Granger, David W. Hale
United States Air Force: Publications
Total body electrical conductivity measurements and lipid composition were determined for the deer mouse (Peromyscus maniculatus) to derive species specific calibration equations for use with EM-SCAN estimates of lean and fat tissue. For each individual, total body electrical conductivity was measured by EM-SCAN, and actual lipid content was determined by chemical extraction. Then, using estimated and actual lipid values, separate calibration equations were generated for freshly captured (lean) and laboratory maintained (fat) individuals, and a combined equation was derived for all individuals. These equations were variable in the accuracy of lipid estimates; the lowest relative error estimate (percent …
Effect Of Extraction Buffer On Estimating Calpain And Calpastatin Activity In Postmortem Ovine Muscle, E. Veiseth, M. Koohmaraie
Effect Of Extraction Buffer On Estimating Calpain And Calpastatin Activity In Postmortem Ovine Muscle, E. Veiseth, M. Koohmaraie
Roman L. Hruska U.S. Meat Animal Research Center: Reports
The effect of extraction buffer on extractable calpain and calpastatin activity in postmortem muscles was examined. Muscles were removed from ovine carcasses 24 h after slaughter and extracted with three volumes of two extraction buffers containing 20 (pH 7.5) and 100 (pH 8.3) mM Tris. There was a significant difference in pH of the muscle homogenates, having a pH of 5.84 and 7.58 for 20 and 100 mM Tris base, respectively. Calpastatin, μ-calpain and m-calpain all had signifcantly reduced activity in extracts made with 20 mM Tris (pH 7.5) buffer compared to 100 mM Tris (pH 8.3) buffer, showing a …
A Porcine Bac Library With Tenfold Genome Coverage: A Resource For Physical And Genetic Map Integration, Scott C. Fahrenkrug, Gary A. Rohrer, Brad A. Freking, Timothy P. L. Smith, Kazutoyo Oswoegawa, Chung Li Shu, Joseph J. Catanese, Pieter J. De Jong
A Porcine Bac Library With Tenfold Genome Coverage: A Resource For Physical And Genetic Map Integration, Scott C. Fahrenkrug, Gary A. Rohrer, Brad A. Freking, Timothy P. L. Smith, Kazutoyo Oswoegawa, Chung Li Shu, Joseph J. Catanese, Pieter J. De Jong
Roman L. Hruska U.S. Meat Animal Research Center: Reports
Recent advances in porcine genomics have identified quantitative trait loci (QTL) that influence pork production traits such as carcass traits, meat quality, and reproductive efficiency (Rohrer 2000; Cassady 1999). The low resolution to which most of these loci have been defined precludes the accurate application of markerassisted selection (MAS) strategies for increasing production efficiency. Large-insert genomic libraries are an excellent resource for marker development aimed at increasing the resolution of QTL and for the development of contiguous physical maps (contigs) of the chromosomal regions containing them.
Impact 2001, Jim Peterson, David J. Goeller, Keith Glewen, David R. Smith, James E. Specht, Kenneth Vogel, Mark Svoboda, Blair D. Siegfried, Terry L. Mader, Terry J. Klopfenstein, Richard Perrin
Impact 2001, Jim Peterson, David J. Goeller, Keith Glewen, David R. Smith, James E. Specht, Kenneth Vogel, Mark Svoboda, Blair D. Siegfried, Terry L. Mader, Terry J. Klopfenstein, Richard Perrin
Institute of Agriculture and Natural Resources: News Releases
Index
Competitive Agricultural Systems in a Global Economy ............................................................. 1
Safe and Secure Food and Fiber Systems ............................................................. 20
Healthy, Well-Nourished Population ............................................................. 28
Greater Harmony Between Agriculture and the Environment ............................................................. 38
Economic Development and Quality of Life for People and Communities ............................................................. 46
Society-Ready Graduates ............................................................. 55
G01-1434 Controlling Beaver Damage, Dallas R. Virchow, John M. Hobbs, Ronald Fryda, Scott E. Hygnstrom
G01-1434 Controlling Beaver Damage, Dallas R. Virchow, John M. Hobbs, Ronald Fryda, Scott E. Hygnstrom
University of Nebraska-Lincoln Extension: Historical Materials
This NebGuide describes beaver biology and behavior and characterizes the types of damage caused by them. It suggests control methods and equipment and describes legal restrictions.
The beaver (Castor canadensis) is the largest rodent in North America. Adults weigh about 40 pounds and have been known to weigh up to 60 pounds or more. Beavers are admired for being industrious, curious, and social. Historically, both the American beaver and the European beaver (Castor fiber) were overharvested to near extinction. In recent decades, however, both species have been rapidly increasing.
Arbovirus Infection Increases With Group Size, Charles R. Brown, Nicholas Komar, Sunita B. Quick, Rajni A. Sethi, Nicholas A. Panella, Mary Bromberger Brown, Martin Pfeffer
Arbovirus Infection Increases With Group Size, Charles R. Brown, Nicholas Komar, Sunita B. Quick, Rajni A. Sethi, Nicholas A. Panella, Mary Bromberger Brown, Martin Pfeffer
Zoonotics and Wildlife Disease: Publications
Buggy Creek (BCR) virus is an arthropod-borne alphavirus that is naturally transmitted to its vertebrate host the cliff swallow (Petrochelidon pyrrhonota) by an invertebrate vector, namely the cimicid swallow bug (Oeciacus vicarius). We examined how the prevalence of the virus varied with the group size of both its vector and host. The study was conducted in southwestern Nebraska where cliff swallows breed in colonies ranging from one to 3700 nests and the bug populations at a site vary directly with the cliff swallow colony size. The percentage of cliff swallow nests containing bugs infected with BCR …
Biotransformation Of Ni-Substituted Hydrous Ferric Oxide By An Fe(Iii)-Reducing Bacterium, James K. Fredrickson, John M. Zachara, Ravi K. Kukkadapu, Yuri A. Gorby, Steven C. Smith, Christopher F. Brown
Biotransformation Of Ni-Substituted Hydrous Ferric Oxide By An Fe(Iii)-Reducing Bacterium, James K. Fredrickson, John M. Zachara, Ravi K. Kukkadapu, Yuri A. Gorby, Steven C. Smith, Christopher F. Brown
United States Department of Energy: Publications
The reductive biotransformation of a Ni2+-substituted (5 mol %) hydrous ferric oxide (NiHFO) by Shewanella putrefaciens, strain CN32, was investigated under anoxic conditions at circumneutral pH. Our objectives were to define the influence of Ni2+ substitution on the bioreducibility of the HFO and the biomineralization products formed and to identify biogeochemical factors controlling the phase distribution of Ni2+ during bioreduction. Incubations with CN32 and NiHFO were sampled after 14 and 32 d, and both aqueous chemistry and solid phases were characterized. By comparison of these results with a previous study (Fredrickson, J. K.; Zachara, J. M.; …
Dissimilatory Bacterial Reduction Of Al-Substituted Goethite In Subsurface Sediments, Ravi K. Kukkadapu, John M. Zachara, Steven C. Smith, James K. Fredrickson, Chongxuan Liu
Dissimilatory Bacterial Reduction Of Al-Substituted Goethite In Subsurface Sediments, Ravi K. Kukkadapu, John M. Zachara, Steven C. Smith, James K. Fredrickson, Chongxuan Liu
United States Department of Energy: Publications
The microbiologic reduction of a 0.2 to 2.0 µm size fraction of an Atlantic coastal plain sediment (Eatontown) was investigated using a dissimilatory Fe(III)-reducing bacterium (Shewanella putrefaciens, strain CN32) to evaluate mineralogic controls on the rate and extent of Fe(III) reduction and the resulting distribution of biogenic Fe(II). Mössbauer spectroscopy and X-ray diffraction (XRD) were used to show that the sedimentary Fe (III) oxide was Al-substituted goethite (13–17% Al) that existed as 1- to 5-µm aggregates of indistinct morphology. Bioreduction experiments were performed in two buffers [HCO3‑; 1,4-piperazinediethansulfonic acid (PIPES)] both without and with 2,6-anthraquinone …
Kinetics And Mechanism Of Birnessite Reduction By Catechol, Christopher J. Matocha, Donald L. Sparks, James E. Amonette, Ravi K. Kukkadapu
Kinetics And Mechanism Of Birnessite Reduction By Catechol, Christopher J. Matocha, Donald L. Sparks, James E. Amonette, Ravi K. Kukkadapu
United States Department of Energy: Publications
The complex interactions of oxidizable organic ligands with soil Mn(III,IV) (hydr)oxide minerals have received little study by in situspectroscopic techniques.We used a combination of an in situ electron paramagnetic resonance stopped-flow (EPR-SF) spectroscopic technique and stirred-batch studies to measure the reductive dissolution kinetics of birnessite (δ-MnO2), a common Mn mineral in soils, by catechol (1,2-dihydroxybenzene). The reaction was rapid, independent of pH, and essentially complete within seconds under conditions of excess catechol at pH 4 to 6. The overall empirical second-order rate equation describing the reductive dissolution rate was d[Mn(II)]/dt = k[CAT]1.0[SA]1.0 where …
Kinetic Analysis Of The Bacterial Reduction Of Goethite, Chongxuan Liu, John M. Zachara, James K. Fredrickson, Cynthia Brinkman
Kinetic Analysis Of The Bacterial Reduction Of Goethite, Chongxuan Liu, John M. Zachara, James K. Fredrickson, Cynthia Brinkman
United States Department of Energy: Publications
The kinetics of dissimilatory reduction of goethite (RFeOOH) was studied in batch cultures of a groundwater bacterium, Shewanella putrefaciens, strain CN32 in pH 7 bicarbonate buffer. The rate and extent of goethite reduction were measured as a function of electron acceptor (goethite) and donor (lactate) concentrations. Increasing goethite concentrations increased both the rate and extent of Fe(III) reduction when cell and lactate concentrations were held constant. However, constant initial reduction rates were observed after normalization to the Fe(II) sorption capacity of FeOOH, suggesting that the bacterial reduction rate was first order with respect to surface site concentration. Increasing …