Digital Commons Network^™

Session 3b: Sediments, Kentucky Water Research Institute

Kentucky Water Resources Annual Symposium

• Sediment Degradation Experiments for a Low Gradient Stream Suggest the Watershed’s Connectivity Regime Exhibits Control on Stream Biogeochemistry
• Does Sediment Organic Matter Content Mediate the Effects of Chironomid Larvae on Benthic Nitrous Oxide Flux
• Drivers of Variability in Annual Sediment Accretion Rates Within Wetland Easements of Western Kentucky

Poster Session, Kentucky Water Research Institute

Kentucky Water Resources Annual Symposium

• Evaluating the Effects of Beaver Dam Removal on the Hydrology, Water Quality, and Bioindicators of a Restored Wetland
• Predictive Sediment Flux Modeling of a Karst Spring Using High Resolution Sensors and Stable Carbon and Nitrogen Isotopes
• Development and Validation of qPCR Assays for Use in eDNA Detection of Four Species of Semiaquatic Salamanders .
• Analyzing Recent Spatio-Temporal Rainfall Erosivity Patterns and Trends Across Kentucky
• Development of eDNA Protocols for Detection of Four Darter (Percidae: Etheostomatinae) Species in Central Kentucky Streams
• Assessing Change in the Seasonality of Stable Isotopes δ18O and δ2H for Meteoric and Terrestrial Waters of Central Kentucky
• Coupling …

Session 2: Water And The Community, Kentucky Water Research Institute

Kentucky Water Resources Annual Symposium

• Development of Human Health Criteria for Surface Waters of the Commonwealth of Kentucky
• Kentucky Workforce Survey Results
• Modeling, Managing, and Mitigating Stormwater Flooding using a Real-time Monitoring Network and Environmental Equity Approach

Session 1a: Watershed Management, Kentucky Water Research Institute

Kentucky Water Resources Annual Symposium

• Motivations and Barriers to the Implementation of Riparian Buffer Zones on Central Kentucky Horse Farms
• Engaging Urban Watershed Stewards in Stormwater Management
• Efficacy Examination of Urban Reforestation Efforts on Streams in Lexington, KY: Macroinvertebrates and Water Quality Assessments
• Over a Decade of Monitoring Water Quality at McConnell Springs – What Have We Learned?
• Glenns Creek Watershed Characterization Efforts

Session 1b: Contaminant Exposure And Treatment, Kentucky Water Research Institute

Kentucky Water Resources Annual Symposium

• Cyanobacteria, Cyanotoxin Synthetase Genes, and Cyanotoxin Occurrence Among Selected Large River Sites in the Lower Ohio River Basin, 2020–21
• Emerging Contaminant Exposure Following WWTP Processes to Surface Waters
• Reactive Membrane Synthesis for Capture and Degradation of Toxic Water Contaminants
• Implications to Tap and Stream Water Chemistry Due to Variations in Sampling Location and Watershed Land Use
• Examining Toxicity of 2D Nanomaterial Phosphorene, Free-Standing and Embedded onto Membranes, and Its Application for Removal of Per-and Polyfluoroalkyl Substances (PFAS)

Plenary Session: 2022 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

No abstract provided.

Proceedings Of 2022 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

This symposium was planned and conducted as a part of the state water resources research institute annual program that is supported by Grant/Cooperative Agreement Number G21AP10631-00 from the United States Geological Survey (USGS). The contents of this proceedings document and the views and conclusions presented at the symposium are solely the responsibility of the individual authors and presenters and do not represent the official views of the USGS or of the symposium organizers and sponsors. This publication is produced with the understanding that the United States Government is authorized to reproduce and distribute reprints for government purposes. Mention of trade …

Reactivity Of Aminophenols In Forming Nitrogen-Containing Brown Carbon From Iron-Catalyzed Reactions, Hind A. Al-Abadleh, Fatemeh Motaghedi, Wisam Mohammed, Md Sohel Rana, Kotiba A. Malek, Dewansh Rastogi, Akua A. Asa-Awuku, Marcelo I. Guzman

Chemistry Faculty Publications

Nitrogen-containing organic carbon (NOC) in atmospheric particles is an important class of brown carbon (BrC). Redox active NOC like aminophenols received little attention in their ability to form BrC. Here we show that iron can catalyze dark oxidative oligomerization of o- and p-aminophenols under simulated aerosol and cloud conditions (pH 1–7, and ionic strength 0.01–1 M). Homogeneous aqueous phase reactions were conducted using soluble Fe(III), where particle growth/agglomeration were monitored using dynamic light scattering. Mass yield experiments of insoluble soot-like dark brown to black particles were as high as 40%. Hygroscopicity growth factors (κ) of these …

Landslide Susceptibility Map Of Johnson County, Kentucky, Matt M. Crawford, Hudson J. Koch, Jason M. Dortch, William C. Haneberg

Contract Reports--KGS

The purpose of this map is to identify landslide-prone areas in Johnson County in order to provide the public, as well as local and state government agencies, with information about where landslides are likely to occur. This map represents geomorphic-based susceptibility modeling that focuses on physical slope characteristics and morphology, the quality of which is dependent on data accuracy and resolution of terrain models. The availability of high-resolution (5-ft digital elevation model) lidar derived datasets allows for the generation of terrain elevation derivatives such as hillshades, slope, aspect, curvature, and roughness, as well as identification of existing landslide deposits. These …

Landslide Susceptibility Map Of Floyd County, Kentucky, Matt M. Crawford, Hudson J. Koch, Jason M. Dortch, William C. Haneberg

Contract Reports--KGS

The purpose of this map is to identify landslide-prone areas in Floyd County in order to provide the public, as well as local and state government agencies, with information about where landslides are likely to occur. This map represents geomorphic-based susceptibility modeling that focuses on physical slope characteristics and morphology, the quality of which is dependent on data accuracy and resolution of terrain models. The availability of high-resolution (5-ft digital elevation model) lidar derived datasets allows for the generation of terrain elevation derivatives such as hillshades, slope, aspect, curvature, and roughness, as well as identification of existing landslide deposits. These …

Landslide Susceptibility Map Of Magoffin County, Kentucky, Matt M. Crawford, Hudson J. Koch, Jason M. Dortch, William C. Haneberg, Ashton A. Killen

Contract Reports--KGS

The purpose of this map is to identify landslide-prone areas in Magoffin County, Kentucky, in order to provide the public, as well as local and state government agencies, with information about where landslides are likely to occur. This map represents geomorphic-based susceptibility modeling that focuses on physical slope characteristics and morphology, the quality of which is dependent on data accuracy and resolution of terrain models. The availability of high-resolution (5-ft digital elevation model) lidar derived datasets allows for the generation of terrain elevation derivatives such as hillshades, slope, aspect, curvature, and roughness, as well as identification of existing landslide deposits. …

Landslide Susceptibility Map Of Pike County, Kentucky, Matt M. Crawford, Hudson J. Koch, Jason M. Dortch, William C. Haneberg

Contract Reports--KGS

The purpose of this map is to identify landslide-prone areas in Pike County in order to provide the public, as well as local and state government agencies, with information about where landslides are likely to occur. This map represents geomorphic-based susceptibility modeling that focuses on physical slope characteristics and morphology, the quality of which is dependent on data accuracy and resolution of terrain models. The availability of high-resolution (5-ft digital elevation model) lidar derived datasets allows for the generation of terrain elevation derivatives such as hillshades, slope, aspect, curvature, and roughness, as well as identification of existing landslide deposits. These …

Landslide Susceptibility Map Of Martin County, Kentucky, Matt M. Crawford, Hudson J. Koch, Jason M. Dortch, William C. Haneberg

Contract Reports--KGS

The purpose of this map is to identify landslide-prone areas in Martin County in order to provide the public, as well as local and state government agencies, with information about where landslides are likely to occur. This map represents geomorphic-based susceptibility modeling that focuses on physical slope characteristics and morphology, the quality of which is dependent on data accuracy and resolution of terrain models. The availability of high-resolution (5-ft digital elevation model) lidar derived datasets allows for the generation of terrain elevation derivatives such as hillshades, slope, aspect, curvature, and roughness, as well as identification of existing landslide deposits. These …

Cell-Intrinsic Melanin Fails To Protect Melanocytes From Ultraviolet-Mutagenesis In The Absence Of Epidermal Melanin, Tirzah J. Weiss, Emma R. Crawford, Valentina Posada, Hafeez Rahman, Tong Liu, Brandon M. Murphy, Tiffany E. Arnold, Shannon Gray, Zhexuan Hu, Rebecca C. Hennessey, Lianbo Yu, John August D'Orazio, Craig J. Burd, Jonathan H. Zippin, Douglas Grossman, Christin E. Burd

Markey Cancer Center Faculty Publications

Melanin is a free-radical scavenger, antioxidant, and broadband absorber of ultraviolet (UV) radiation which protects the skin from environmental carcinogenesis. However, melanin synthesis and UV-induced reactive melanin species are also implicated in melanocyte genotoxicity. Here, we attempted to reconcile these disparate functions of melanin using a UVB- sensitive, NRAS-mutant mouse model, TpN. We crossed TpN mice heterozygous for an inactivating mutation in Tyrosinase to produce albino and black littermates on a C57BL/6J background. These animals were then exposed to a single UVB dose on postnatal day three when keratinocytes in the skin have yet to be melanized. Approximately one-third (35%) …

Low-Cost Compact Optical Spectroscopy And Novel Spectroscopic Algorithm For Point-Of-Care Real-Time Monitoring Of Nanoparticle Delivery In Biological Tissue Models, Zahid Hasan, Jing Yan, Zhongchao Yi, Madison O. Korfhage, Sheng Tong, Caigang Zhu

Markey Cancer Center Faculty Publications

Objective: Real-time monitoring of nanoparticle delivery in biological models is essential to optimize nanoparticle- mediated therapies. However, few techniques are available for convenient real-time monitoring of nanoparticle concentrations in tissue samples. This work reported novel optical spectroscopic approaches for low-cost point-of-care real-time quantification of nanoparticle concentrations in biological tissue samples.

Methods: Fiber probe measured diffuse reflectance can be described with a simple analytical model by introducing an explicit dependence on the reduced scattering coefficient. Relying on this, the changes on the inverse of diffuse reflectance are proportional to absorption change when the scattering perturbation is negligible. We developed this model …

Investigation Of Illegal Weigh Station Bypassing, Mallory Brown, Andrew Martin, David Leddy, Jennifer Walton

Kentucky Transportation Center Research Report

This study recommends best practices to curb illegal weigh station bypassing by commercial motor vehicles (CMVs). Analysis of historical data collected by Kentucky State Police – Commercial Vehicle Enforcement (KSP-CVE) for 2017-2021 revealed that CMV drivers were charged with illegally bypassing weigh stations 2,616 times. Drivers were charged with an average of two other violations when cited for illegal bypassing — most often violations related to credentialing, vehicle safety, or driver safety. Site visits to three permanent weigh stations in Kentucky revealed that CMVs regularly bypass weigh stations illegally, including those authorized to use preclearance systems (Drivewyze and PrePass). A …

2022 Safety Belt Usage Survey In Kentucky, Erin Lammers-Staats, Derek S. Young, Eric Green, Kenneth R. Agent

Kentucky Transportation Center Research Report

Each year Kentucky Transportation Center researchers conduct a safety belt usage survey to estimate Kentucky’s statewide safety belt usage rate. In 2022, the safety belt usage rate in Kentucky was 86.72 percent, which represents a 3.06 decline over 2021. Safety belt usage peaked in 2018 at 89.99 percent. Declines in safety belt usage rate over the past couple years may be attributable in part to changes in driver behaviors and traffic dynamics following the COVID-19 pandemic. If Kentucky wants to increase safety belt usage rates, the state may need ramp up enforcement of safety belt laws or bolster educational outreach …

The Role Of Crystal Packing On The Optical Response Of Trialkyltetrelethynyl Acenes, Ling-Yi Huang, Qianxiang Ai, Chad Risko

Chemistry Faculty Publications

The electronic and optical responses of an organic semiconductor (OSC) are dictated by the chemistries of the molecular or polymer building blocks and how these chromophores pack in the solid state. Understanding the physicochemical nature of these responses is not only critical for determining the OSC performance for a particular application, but the UV/visible optical response may also be of potential use to determine aspects of the molecular-scale solid-state packing for crystal polymorphs or thin-film morphologies that are difficult to determine otherwise. To probe these relationships, we report the quantum-chemical investigation of a series of trialkyltetrelethynyl acenes (tetrel = silicon …

Removal Of Selenium And Heavy Metals From Coal Combustion Residuals Wastewater Using Surface Modified Iron Based Media, Madan Tandukar, Alex Korff, Andrew Vincent, Chris Hardin

World of Coal Ash Proceedings

No abstract provided.

The Gospel Of Freedom, Alicestyne Turley

Civil Rights

Wilbur H. Siebert published his landmark study of the Underground Railroad in 1898, revealing a secret system of assisted slave escapes. A product of his time, Siebert based his research on the accounts of northern white male abolitionists. While useful in understanding the northern boundaries of the slaves' journey, Siebert's account leaves out the complicated narrative of assistance below the Mason-Dixon Line. In The Gospel of Freedom: Black Evangelicals and the Underground Railroad, author Alicestyne Turley positions Kentucky as a crucial "pass through" territory for escaping slaves and addresses the important contributions of white and black antislavery southerners who united …

Maternal Proximity To Mountain-Top Removal Mining And Birth Defects In Appalachian Kentucky, 1997–2003, Daniel B. Cooper, Courtney J. Walker, W. Jay Christian

Epidemiology and Environmental Health Faculty Publications

Extraction of coal through mountaintop removal mining (MTR) alters many dimensions of the landscape. Explosive blasts, exposed rock, and coal washing have the potential to pollute air and water. Previous research suggests that infants born to mothers living in areas with MTR have a higher prevalence of birth defects. In this cross-sectional study, we further examine the relationship between MTR activity and several types of birth defects. Maternal exposure to MTR was assessed using remote sensing data from Skytruth, which captures MTR activity in the Central Appalachian region of the United States. Active MTR area was quantified within a five-kilometer …

Krs And Kar Review Of Models As A Legal Contract Document, Bryan Gibson, Pam Clay-Young, Rachel Catchings, Chris Van Dyke

Kentucky Transportation Center Research Report

State departments of transportation (DOTs) are expanding the use of electronic engineering data (EED) throughout highway projects — from design and construction through asset management. Included under the umbrella of EED are technologies such as building information modelling (BIM), digital terrain models (DTMs), and 3D models and plan sets. The Kentucky Transportation Cabinet’s (KYTC) Digital Project Delivery (DPD) Initiative is spearheading the transition to EED in the state. While digital delivery promises to streamline project development and management it does not come without hurdles. This report discusses methods for agency wide implementation of EED and highlights best practices for managing, …

Southeastern Law Librarian Summer 2022, Seaall

Newsletters

No abstract provided.

Moral Distress During Covid-19: The Importance Of Perceived Organizational Support For Hospital Nurses, Abigail Latimer, Melanie D. Otis, Gia Mudd-Martin, Debra K. Moser

UK CARES Faculty Publications

Moral distress, or the inability to act congruent with moral beliefs, has been of concern for healthcare professionals especially since the COVID-19 pandemic. Hospital nurses are particularly affected in their roles with mounting administrative pressures and demands. We examined whether general and COVID- specific support in employing healthcare organizations predicted moral distress in a sample of inpatient hospital nurses. A total of 248 nurses completed the Measure of Moral Distress for Healthcare Professionals, Survey of Perceived Organizational Support, COVID Organizational Support survey, and the Hospital Ethical Climate Scale. We found that general and COVID-related organizational support were predictors of moral …

Urban Utopia Or Pipe Dream? Examining Chinese-Invested Smart City Development In Southeast Asia, Yujia He, Angela Tritto

Patterson School of Diplomacy and International Commerce Faculty Publications

With increasing public–private partnership and international cooperation in smart city development across the Global South, Chinese firms are poised to take advantage of growing business opportunities, a situation that few studies have examined. This empirical case study of the Forest City, a Chinese-invested greenfield smart city project in Iskandar Malaysia, begins to fill that gap. This megaproject represents the coming together of overlapping economic development interests of the local authorities and the profit motivations of the Chinese investor. However, the project’s use of the ‘smart city’ discourse contrasts with the reality of limited technology adoption. Its visibility and considerable socio-economic …

An Acid Baking Approach To Enhance Heavy Rare Earth Recovery From Bituminous Coal-Based Sources, Ahmad Nawab, Xinbo Yang, Rick Q. Honaker

Mining Engineering Faculty Publications

The recovery of rare earth elements (REEs) from secondary resources, particularly coal-based materials, has recently received attention due to supply and demand imbalance. Research reported to date indicates that a high REE recovery can be realized when treating bituminous coal sources using strong acid solutions of approximately100 g/L or higher. This study introduces an approach to enhance the total rare earth recovery (TREE), especially for heavy rare earth elements (HREEs), from these coal sources at significantly lower acid concentrations. Based on the presence of REE minerals like monazite and xenotime, a detailed investigation was undertaken to quantify three pre-leach treatment …

Non-Solvent Induced Phase Separation (Nips) For Fabricating High Filtration Efficiency (Fe) Polymeric Membranes For Face Mask And Air Filtration Applications, Ebuka A. Ogbuoji, Lauren Stephens, Amber Haycraft, Eric Woodridge, C. Escobar

Chemical and Materials Engineering Faculty Publications

Protection against airborne viruses has become very relevant since the outbreak of SARSCoV-2. Nonwoven face masks along with heating, ventilation, and air conditioning (HVAC) filters have been used extensively to reduce infection rates; however, some of these filter materials provide inadequate protection due to insufficient initial filtration efficiency (FE) and FE decrease with time. Flat sheet porous membranes, which have been used extensively to filter waterborne microbes and particulate matter due to their high FE have the potential to filter air pollutants without compromising its FE over time. Therefore, in this study, single layer polysulfone (PSf) membranes were fabricated via …

A Simplified Model For The Intermediate Structure Of Strong Fire Whirls, Forman A. Williams

Progress in Scale Modeling, an International Journal

A model is described for the overall structure of intense fire whirls, based on a spatially evolving vortex, with circulation enhancement driven by the axial acceleration of low-density gas in the core through the axial pressure gradient. The axial acceleration increases the entrainment rate into the core which, through mass conservation, increases the circulation if the angle between the tangential and radial velocity components remains fixed. The two-zone model employs general balance equations for regions inside and outside a cylinder of fixed radius, each inviscid, the inside region being presumed to have a constant density small compared with the (constant) …

Reduced-Scale Experiments And Numerical Simulations Of Informal Settlement Dwelling Fires, Vigneshwaran Narayanan, Antonio Cicicone, Ayden D. Botha, Richard Shaun Walls

Progress in Scale Modeling, an International Journal

Informal settlement dwellings (ISDs) house approximately one billion people in the developing world and this number is expected to double by the year 2030. Contemporary research on ISD fires has focused on understanding the fire dynamics within individual dwellings (micro-scale) and fire spread in settlements consisting of multiple dwellings (macro-scale). This paper aims to do two primary things: investigate if scaling methods that were derived for compartments with thermally thick boundaries can be applied to ISDs (compartments with thermally thin boundaries), and if they can adequately represent the most important phenomena associated with full-scale ISD fires; and demonstrate Fire Dynamics …

Specialized Safety Training And Tracking For Kytc Construction And Maintenance Personnel, Gabriel Dadi, Ashtarout Ammar, Seth Atkins, Martha Horseman

Kentucky Transportation Center Research Report

High-quality safety training is critical for educating employees in the highway construction and maintenance industry about workplace hazards and giving them tools to remove and/or minimize associated risks. But researchers and state transportation agencies have not committed enough resources to develop safety trainings that address the unique needs of this sector. This report fills in this gap for the Kentucky Transportation Cabinet (KYTC) by cataloguing safety training resources available through other state and federal transportation agencies, documenting trainings available to Cabinet staff, identifying and prioritizing training gaps, and critically evaluating the content, quality, and duration of training resources. A web-based …