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Twisted Sasaki Metric On The Unit Tangent Bundle And Harmonicity, Liana Lotarets
Twisted Sasaki Metric On The Unit Tangent Bundle And Harmonicity, Liana Lotarets
Turkish Journal of Mathematics
The paper deals with the twisted Sasaki metric on the unit tangent bundle of n–dimensional Riemannian manifold Mn . The main purpose of the research is to find deformations that preserve the existence harmonic left-invariant unit vector fields on 3-dimensional unimodular Lie groups G with the left invariant metric and harmonic maps G → T1G in case of twisted Sasaki metric on the unit tangent bundle. The necessary and sufficient conditions for harmonicity of left-invariant unit vector field and map Mn → T1Mn are obtained. The necessary and sufficient conditions for harmonicity of left-invariant unit vector field and map M2 …
Langevin Delayed Equations With Prabhakar Derivatives Involving Two Generalized Fractional Distinct Orders, Mustafa Aydin
Langevin Delayed Equations With Prabhakar Derivatives Involving Two Generalized Fractional Distinct Orders, Mustafa Aydin
Turkish Journal of Mathematics
This paper is devoted to defining the delayed analogue of the Mittag-Leffler type function with three parameters and investigating a representation of a solution to Langevin delayed equations with Prabhakar derivatives involving two generalized fractional distinct orders, which are first introduced and investigated, by means of the Laplace integral transform. It is verified by showing the solution satisfies the introduced system. Special cases which are also novel are presented as examples. The findings are illustrated with the help of the RLC circuits.
Combinatorial Results For Semigroups Of Orientation-Preserving Transformations, Ayşegül Dağdevi̇ren, Gonca Ayik
Combinatorial Results For Semigroups Of Orientation-Preserving Transformations, Ayşegül Dağdevi̇ren, Gonca Ayik
Turkish Journal of Mathematics
Let Xn denote the chain {1, 2, . . . , n} under its natural order. We denote the semigroups consisting of all order-preserving transformations and all orientation-preserving transformations on Xn by On and OPn , respectively. We denote by E(U) the set of all idempotents of a subset U of a semigroup S . In this paper, we first determine the cardinalities of Er(On) = {α ∈ E(On) : |im(α)| = |fix(α)| = r}, E ∗ r (On) = {α ∈ Er(On) : 1, n ∈ fix(α)}, Er(OPn) = {α ∈ E(OPn) : |fix(α)| = r}, E ∗ r …
On The Reconstruction Of An Integro-Differential Dirac Operator With Parameter-Dependent Nonlocal Integral Boundary Conditions From The Nodal Data, Baki Keskin, Yu Ping Wang
On The Reconstruction Of An Integro-Differential Dirac Operator With Parameter-Dependent Nonlocal Integral Boundary Conditions From The Nodal Data, Baki Keskin, Yu Ping Wang
Turkish Journal of Mathematics
We consider the integro-differential Dirac operator with parameter-dependent nonlocal integral boundary conditions. We derive the asymptotic expressions for the eigenvalues and the zeros of eigenfunctions (nodal points or nodes) and develop a constructive procedure for solving the inverse nodal problem for this operator.
Isometries Of Length 1 In Purely Loxodromic Free Kleinian Groups And Trace Inequalities, İlker Savaş Yüce, Ahmet Nedi̇m Narman
Isometries Of Length 1 In Purely Loxodromic Free Kleinian Groups And Trace Inequalities, İlker Savaş Yüce, Ahmet Nedi̇m Narman
Turkish Journal of Mathematics
In this paper, we prove a generalization of a discreteness criteria for a large class of subgroups of PSL2(C) . In particular, given a finitely generated purely loxodromic free Kleinian group Γ = ⟨ξ1, ξ2, . . . , ξn⟩ for n ≥ 2, we show that |trace2(ξi) − 4| + |trace(ξiξjξ −1 i ξ −1 j ) − 2| ≥ 2 sinh2 ( 1 4 log αn ) for some ξi and ξj for i ̸= j in Γ provided that certain conditions on the hyperbolic displacements given by ξi , ξj and their length 3 conjugates formed by …
On The Oscillation And Asymptotic Behavior Of Solutions Of Third Order Nonlineardifferential Equations With Mixed Nonlinear Neutral Terms, Shaimaa Salem, Mohamed M. A. El-Sheikh, Ahmed Mohamed Hassan
On The Oscillation And Asymptotic Behavior Of Solutions Of Third Order Nonlineardifferential Equations With Mixed Nonlinear Neutral Terms, Shaimaa Salem, Mohamed M. A. El-Sheikh, Ahmed Mohamed Hassan
Turkish Journal of Mathematics
This paper is concerned with the oscillation and asymptotic behavior of solutions of third-order nonlinear neutral differential equations with a middle term and mixed nonlinear neutral terms in the case of the canonical operator. We establish several oscillation criteria that guarantee that all solutions are oscillatory or converge to zero. The given results are obtained by applying the comparison method, the Riccati transformation and the integral averaging technique. The results improve significantly and extend existing ones in the literature. Finally, illustrative examples are given.
Modules Over Invertible 1-Cocycles, José Manuel Fernández Vilaboa, Ramon Gonzalez Rodriguez, Brais Ramos Pérez, Ana Belén Rodríguez Raposo
Modules Over Invertible 1-Cocycles, José Manuel Fernández Vilaboa, Ramon Gonzalez Rodriguez, Brais Ramos Pérez, Ana Belén Rodríguez Raposo
Turkish Journal of Mathematics
In this paper, we introduce in a braided setting the notion of left module for an invertible 1-cocycle and we prove some categorical equivalences between categories of modules associated to an invertible 1-cocycle and categories of modules associated to Hopf braces.
An Extension Of The Definition On The Compositions Of The Singular Distributions, Emi̇n Özçağ
An Extension Of The Definition On The Compositions Of The Singular Distributions, Emi̇n Özçağ
Turkish Journal of Mathematics
Gelfand and Shilov give the definition of the composition δ(g(x)) for an infinitely differentiable function g(x) having any number of simple roots. In the paper, we consider their definition for an infinitely differentiable function having any number of multiple roots by using the method of the discarding of unwanted infinite quantities from asymptotic expansions and give some examples. Further, we define the compositions δ(g+) and δ(g−) for a locally summable function g(x).
Qualitative Results For A Generalized 2-Component Camassa-Holm System With Weak Dissipation Term, Nurhan Dündar
Qualitative Results For A Generalized 2-Component Camassa-Holm System With Weak Dissipation Term, Nurhan Dündar
Turkish Journal of Mathematics
Our main aim in the current study is to examine the mathematical properties of a generalized 2-component Camassa-Holm system with a weakly dissipative term. Firstly, we acquire the theorem of well-posedness in locally for the generalized system with weak dissipation. Then, we demonstrate that this system can reveal the blow-up phenomenon. Finally, we acquire the theorem of global existence utilizing a method of the Lyapunov function.
Lightcone Framed Curves In The Lorentz-Minkowski 3-Space, Liang Chen, Masatomo Takahashi
Lightcone Framed Curves In The Lorentz-Minkowski 3-Space, Liang Chen, Masatomo Takahashi
Turkish Journal of Mathematics
For a nonlightlike nondegenerate regular curve, we have the arc-length parameter and the Frenet-Serret type formula by using a moving frame like a regular space curve in the Euclidean space. If a point of the curve moves between spacelike and timelike regions, then there is a lightlike point. In this paper, we consider mixed types of not only regular curves but also curves with singular points. In order to consider mixed type of curves with singular points, we introduce a frame, so-called the lightcone frame, and lightcone framed curves. We investigate differential geometric properties of lightcone framed curves.
Timelike Surfaces With Parallel Normalized Mean Curvature Vector Field In The Minkowski 4-Space, Victoria Bencheva, Velichka Milousheva
Timelike Surfaces With Parallel Normalized Mean Curvature Vector Field In The Minkowski 4-Space, Victoria Bencheva, Velichka Milousheva
Turkish Journal of Mathematics
In the present paper, we study timelike surfaces with parallel normalized mean curvature vector field in the four-dimensional Minkowski space. We introduce special isotropic parameters on each such surface, which we call canonical parameters, and prove a fundamental existence and uniqueness theorem stating that each timelike surface with parallel normalized mean curvature vector field is determined up to a rigid motion in the Minkowski space by three geometric functions satisfying a system of three partial differential equations. In this way, we minimize the number of functions and the number of partial differential equations determining the surface, thus solving the Lund-Regge …
Special Subdiagrams Of Young Diagrams And Numerical Semigroups, Meral Süer, Mehmet Yeşi̇l
Special Subdiagrams Of Young Diagrams And Numerical Semigroups, Meral Süer, Mehmet Yeşi̇l
Turkish Journal of Mathematics
In this study, Young diagrams and their corresponding numerical sets are considered, and a new notion called special subdiagrams is described. Characterizations of special subdiagrams and their corresponding numerical sets, as well as the conditions when they are numerical semigroups, are provided. Young diagrams of symmetric, almost symmetric and Arf numerical semigroups are also considered and properties of their special subdiagrams are given.
Duality And Norm Completeness In The Classes Of Limitedly Lwc Anddunford–Pettis Lwc Operators, Ömer Şafak Alpay, Eduard Emelyanov, Svetlana Gorokhova
Duality And Norm Completeness In The Classes Of Limitedly Lwc Anddunford–Pettis Lwc Operators, Ömer Şafak Alpay, Eduard Emelyanov, Svetlana Gorokhova
Turkish Journal of Mathematics
We study the duality and norm completeness in the new classes of limitedly L-weakly compact and Dunford–Pettis L-weakly compact operators from Banach spaces to Banach lattices.
Laguerre Type Twice-Iterated Appell Polynomials, Nesli̇han Bi̇ri̇ci̇k, Mehmet Ali̇ Özarslan, Bayram Çeki̇m
Laguerre Type Twice-Iterated Appell Polynomials, Nesli̇han Bi̇ri̇ci̇k, Mehmet Ali̇ Özarslan, Bayram Çeki̇m
Turkish Journal of Mathematics
In this study, we use discrete Appell convolution to define the sequence of Laguerre type twice-iterated Appell polynomials. We obtain explicit representation, recurrence relation, determinantal representation, lowering operator, integro-partial raising operator and integro-partial differential equation. In addition, the special cases of this new family are investigated using Euler and Bernoulli numbers. We also state their corresponding characteristic properties.
Existence Of Solutions By Coincidence Degree Theory For Hadamard Fractionaldifferential Equations At Resonance, Martin Bohner, Alexander Domoshnitsky, Seshadev Padhi, Satyam Narayan Srivastava
Existence Of Solutions By Coincidence Degree Theory For Hadamard Fractionaldifferential Equations At Resonance, Martin Bohner, Alexander Domoshnitsky, Seshadev Padhi, Satyam Narayan Srivastava
Turkish Journal of Mathematics
Using the coincidence degree theory of Mawhin and constructing appropriate operators, we investigate the existence of solutions to Hadamard fractional differential equations (FRDEs) at resonance { − (HDγu ) (t) = f(t, u(t)), t ∈ (1, e), u(1) = 0, u(e) = ∫ e 1 u(t)dA(t), where 1 < γ < 2, f : [1, e]×R2 → R satisfies Carathéodory conditions, ∫ e 1 u(t)dA(t) is the Riemann–Stieltjes integration, and (HDγu ) is the Hadamard fractional derivation of u of order γ . An example is included to illustrate our result.
The Effect Of Partial Substitution Of Noble Metal (Pd) At The B Site Of La0.6sr0.4feo3 As A Supercapacitor Electrode Material, Nagihan Deli̇baş, Turgut Süleymanoğlu
The Effect Of Partial Substitution Of Noble Metal (Pd) At The B Site Of La0.6sr0.4feo3 As A Supercapacitor Electrode Material, Nagihan Deli̇baş, Turgut Süleymanoğlu
Turkish Journal of Chemistry
Sol-gel combustion was used to produce the perovskite-type La0.6Sr0.4FeO3 (LSF) and La0.6Sr0.4Fe0.9Pd0.1O3 (LSFP) materials and assessed as supercapacitor electrodes. The synthesized materials’ crystal structure, morphology, and electrochemical performance were thoroughly analyzed. The partial substitution of Pd in the B site of the LSF structure affected the electrochemical properties of this compound and improved its performance. In fact, the greatest effect of Pd substitution was on the content of oxygen vacancies, which are known as the active sites of the perovskite surface in the supercapacitor cell. The specific capacitance obtained for the sample containing Pd was about 80 F.g–1 at a …
Reheating Constraints To Palatini Coleman-Weinberg Inflation, Nilay Bostan
Reheating Constraints To Palatini Coleman-Weinberg Inflation, Nilay Bostan
Turkish Journal of Physics
In this work, we examine the reheating constraints to symmetry-breaking mechanism, which is associated with Coleman-Weinberg inflation in the early universe. We consider the Coleman-Weinberg inflation potential, where the inflaton has a v ̸= 0 after inflation. Setting Treh = 105 GeV, we first show wreh dependency on ns , r , and N∗ for AV case. Then, we demonstrate the results of ns , r , N∗ , α = dns/d ln k for different reheating temperatures and compare the results with the latest BICEP/Keck data. We also present that ns −r and ns −N∗ planes and the effect …
Detection And Characterization Of The Pichia Manshurica Biofilm On The Traditionally Produced Homemade Apple Vinegar, Zeynep İşlek Koklu, Pınar Akkuş Süt, Esra Eskihoran Üçüncüoğlu, Sadık Kalayci, Fikrettin Şahi̇n
Detection And Characterization Of The Pichia Manshurica Biofilm On The Traditionally Produced Homemade Apple Vinegar, Zeynep İşlek Koklu, Pınar Akkuş Süt, Esra Eskihoran Üçüncüoğlu, Sadık Kalayci, Fikrettin Şahi̇n
Turkish Journal of Chemistry
Pichia yeasts are capable of forming biofilms during vinegar production and causing spoilage in various beverages. In addition, there exists a significant likelihood of encountering yeast contamination which can prevent vinegar production. The present study investigates the detection and characterization of the Pichia manshurica (P. manshurica) biofilm on traditionally produced homemade apple vinegar. The unique characteristics of vinegar were analyzed with a focus on the constituent, known as the “mother of vinegar”, whose composition is comprised of cellulosic biofilm and acetic acid bacteria, including Gluconobacter oxydans (G. oxydans) Briefly, P. manshurica was isolated from apple vinegar and characterized in terms …
Exploration Of Novel 6,8,9-Trisubstituted Purine Analogues: Synthesis, In Vitro Biological Evaluation, And Their Effect On Human Cancer Cells, Muhammed Fatih Polat, İrem Durmaz Şahi̇n, Rengül Atalay, Meral Tunçbi̇lek
Exploration Of Novel 6,8,9-Trisubstituted Purine Analogues: Synthesis, In Vitro Biological Evaluation, And Their Effect On Human Cancer Cells, Muhammed Fatih Polat, İrem Durmaz Şahi̇n, Rengül Atalay, Meral Tunçbi̇lek
Turkish Journal of Chemistry
Cancer, a leading global cause of mortality, demands continuous advancements in therapeutic strategies. This study focuses on the design and synthesis of a novel series of purine derivatives, specifically 6-(substituted phenyl piperazine)-8-(4-phenoxyphenyl)-9-cyclopentyl purine derivatives (5–11). The motivation behind this endeavor lies in addressing acquired resistance mechanisms in cancer cells, a significant hurdle in current treatment modalities. The synthesis, starting from 4,6-dichloro-5-nitropyrimidine, involves a multi-step process, resulting in seven new purine derivatives. Biological evaluation against human liver, colon, and breast cancer cells (Huh7, HCT116, and MCF7, respectively) was performed using the SRB assay. Among the synthesized analogs, compounds 5 and 6, …
Nonoxidative Dehydrogenation Of Propane Using Boron-Incorporated Silica-Supported Pt Sites Synthesized By Atomic Layer Deposition, Gokhan Çeli̇k
Nonoxidative Dehydrogenation Of Propane Using Boron-Incorporated Silica-Supported Pt Sites Synthesized By Atomic Layer Deposition, Gokhan Çeli̇k
Turkish Journal of Chemistry
Nonoxidative dehydrogenation of propane to propylene using Pt-based supported catalysts is an active research area in catalysis because catalyst attributes of Pt sites can be controlled by careful design of active sites. One way to achieve this is by the addition of a second metal that may impart a change in the electron density of active sites, which in turn affects catalytic performance. In this study, bimetallic Pt and B sites were deposited on powder SiO2 using atomic layer deposition (ALD). Boron was first deposited on SiO2 via half-cycle ALD using triisoproplyborate as the B source. Following calcination, Pt deposition …
Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün
Low Fine-Tuning With Heavy Higgsinos In Yukawa Unified Susy Guts, Cem Salih Ün
Turkish Journal of Physics
The work presented considers a class of minimally constructed Yukawa unified SUSY GUTs - NUHM2 - and explores their implications when their soft supersymmetry breaking Lagrangian is generalized by the nonholomorphic terms which provide extra contributions to the Higgsino mass and couple the supersymmetric scalar fields to the wrong Higgs doublets. With such a simple extension, it can be found several regions with interesting implications which cannot be realized in the usual restricted models. It is observed that the Yukawa unification solutions can be compatible with a relatively light mass spectrum and acceptable low fine-tuning measurements. In the restricted models …
Sustainable Bio-Based Solid Phase Extraction Adsorbent For The Determination Of Various Types Of Organic Compounds, Mustafa Zafer Ozel, James H. Clark, Avtar S. Matharu
Sustainable Bio-Based Solid Phase Extraction Adsorbent For The Determination Of Various Types Of Organic Compounds, Mustafa Zafer Ozel, James H. Clark, Avtar S. Matharu
Turkish Journal of Chemistry
A sustainable, bio-based, mesoporous material, Starbon A800, was explored for use as an adsorbent in solid phase extraction (SPE). A solution containing seven nitrosamines was first used as a standard to optimise conditions for extraction efficiency with Starbon A800. After optimising conditions, 25 compounds of varying polarity (terpenes, phenolics, pesticides, PAHs, amines, and nitrosamines) were extracted with SPE using either Starbon® A800, C18 or Porous Graphitic Carbon (PGC) as the adsorbent, for comparison purposes. At the same time, 3 different elution solvents (heptane, dichloromethane, and ethanol) were used for each type of adsorbent. Hansen solubility parameters can be used to …
Hydroxyl- Terminated Dendrimers With Sulfonimide Linkers As Binders For Metals Of Industrial Significance, Khaleel Abu Sbeih, Mohammad Al Harahsheh
Hydroxyl- Terminated Dendrimers With Sulfonimide Linkers As Binders For Metals Of Industrial Significance, Khaleel Abu Sbeih, Mohammad Al Harahsheh
Turkish Journal of Chemistry
First- and second-generation hydroxyl- terminated dendrimers were prepared starting from a 1,3-diaminopropane core and sulfonimide linkers. A first-generation mesitylene-derived dendrimer was also prepared with the same terminals. The dendrimers were then reacted with Fe3+, Al3+, and UO22+ separately in order to apply the dendrimers for binding these metals, which have important industrial applications and pose environmental problems simultaneously. The prepared dendrimers were also shown to bind Fe3+ selectively from mixtures with Al3+.
Palladium (0) Nanoparticles Distributed On Lanthanum (Iii) Oxide As An Effective Catalyst For The Methanolysis Of Hydrazine-Borane To Produce Hydrogen, Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan
Palladium (0) Nanoparticles Distributed On Lanthanum (Iii) Oxide As An Effective Catalyst For The Methanolysis Of Hydrazine-Borane To Produce Hydrogen, Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan
Turkish Journal of Chemistry
Pd (0) nanoparticles (NPs) distributed on lanthanum (III) oxide were ex situ generated from the reduction of Pd2+ ions using NaBH4 as reducing agent. The Pd/La2O3 displayed good catalytic activity in H2(g) releasing from the hydrazine-borane (HB) methanolysis reaction and it was identified by advanced techniques. Pd/La2O3 was found to be an active catalyst procuring three equiv. H2(g) per mole of HB. The results from TEM images represent the formation of Pd (0) NPs with an average particle size of 1.94 ± 0.1 nm on the surface of La2O3. Moreover, Pd/La2O3 with various Pd loadings were prepared and tested as …
N-(2-Aminobenzoyl)Benzotriazole Mediated Synthesis Of 3- Acyl-2-Alkyl(Aryl)-4-Hydroxyquinolines And 3-Acylamino-4(3h) Quinazolinones, İlbilge Merve Şenol, Sevtem Gökbulut Satioğlu, İlhami Çeli̇k
N-(2-Aminobenzoyl)Benzotriazole Mediated Synthesis Of 3- Acyl-2-Alkyl(Aryl)-4-Hydroxyquinolines And 3-Acylamino-4(3h) Quinazolinones, İlbilge Merve Şenol, Sevtem Gökbulut Satioğlu, İlhami Çeli̇k
Turkish Journal of Chemistry
New methods have been developed for the synthesis of the substituted quinolines and quinazolinones derivatives by utilizing N-(2-aminobenzoyl)benzotriazoles under mild reaction conditions. 3-Acyl-2-alkyl(aryl)-4-hydroxyquinolines were obtained in modarete yields by the reaction of N-(2-aminobenzoyl)benzotriazoles and diketones in the presence of tert-BuOK. 3-Acylamino-4(3H) quinazolinones were obtained in good yields via N-(2-aminobenzoyl)benzotriazoles, orthoester and hyrazides in one-pot.
Synthesis And Characterization Of Surface-Modified Magnetic Mesoporous Silicate Materials For Phosphate Adsorption, Ayşegül Gençer, Burcu Uysal Karataş, Önder Topel, Nadir Ki̇raz
Synthesis And Characterization Of Surface-Modified Magnetic Mesoporous Silicate Materials For Phosphate Adsorption, Ayşegül Gençer, Burcu Uysal Karataş, Önder Topel, Nadir Ki̇raz
Turkish Journal of Chemistry
The magnetic mesoporous silica material, Mag-MCM-41, was synthesized by coating magnetite (Fe3O4) nanoparticles with a mesoporous material called MCM-41. Mag-MCM-41 and modified nanomaterials Mag-MCM-41-NN and Mag-MCM-41-NN-Fe+3 which were modified with aminopropyl functional groups. In water and wastewater, phosphate anions are considered significant contaminants due to their detrimental impact on the environment. They promote the growth of algae, leading to eutrophication. The purpose of this study is to investigate the removal of phosphate anions from aqueous solutions using modified magnetic silica particles. The Mag-MCM-41 material exhibits hexagonal properties and belongs to the class of “mesoporous” materials. It has a surface area …
An Efficient One-Pot And Simple Multicomponent Approach To The Synthesis Of Highly Functionalized Furans Containing Dialkyl Phenol, Fourogh Jalili Milani, Mahmoud Nassiri, Jaber Salehzadeh
An Efficient One-Pot And Simple Multicomponent Approach To The Synthesis Of Highly Functionalized Furans Containing Dialkyl Phenol, Fourogh Jalili Milani, Mahmoud Nassiri, Jaber Salehzadeh
Turkish Journal of Chemistry
In this study, arylglyoxals, acetylacetone, and 2,6-dimethyl phenol or 2,6-di-tert-butyl phenol are combined to efficiently synthesize a series of 1-(4-(3,5-dialkylphenyl)-2-methyl-5-phenylfuran-3-yl) ethan-1-one derivatives in excellent yields. These reactions were carried out in acetone at reflux under catalyst-free conditions in the presence of triethylamine as a base for 3 h. NMR, FT-IR, EI-MS, and elemental studies were used to characterize the products' structural characteristics. The present study has also several benefits, such as excellent yields and the ease of workup procedure, making it an appealing, practical, and acceptable one-pot method for producing functionalized derivatives of dialkyl furan.
Copolymerization Of Pyrrole And Carbazole Onto Polyester Textile, Mehmet Akif Küçükkaya, Utku Ustamehmetoğlu, Esma Sezer, Belkıs Ustamehmetoğlu
Copolymerization Of Pyrrole And Carbazole Onto Polyester Textile, Mehmet Akif Küçükkaya, Utku Ustamehmetoğlu, Esma Sezer, Belkıs Ustamehmetoğlu
Turkish Journal of Chemistry
The purpose of this study was the polymerization of carbazole (Cz), pyrrole (Py) and copolymerization of them onto polyester (PES) textile with chemical oxidative method by using FeCl3. First, in order to determine the optimum conditions, the effect of polymerization steps, the immersion order of the PES to the oxidant and monomer solutions, time, monomer, oxidant, and surfactant concentrations and types on the conductivities of PES/PCz composite were investigated and at this conditions, conductive composite, PES/P[Py-co-Cz] was obtained. The highest conductivities were obtained as 12.4 mS/cm and 9.0 mS/cm for PES/PCz and PES/P[Py-co-Cz], respectively. Further characterization of PES/P[Py-co-Cz] was performed …
Voltammetric Measurement Of Catechol-O-Methyltransferase Inhibitor Tolcapone In The Pharmaceutical Form On The Boron-Doped Diamond Electrode, Musa Kiran, Yavuz Yardim
Voltammetric Measurement Of Catechol-O-Methyltransferase Inhibitor Tolcapone In The Pharmaceutical Form On The Boron-Doped Diamond Electrode, Musa Kiran, Yavuz Yardim
Turkish Journal of Chemistry
This study presents an electroanalytical approach to measure the catechol-O-methyltransferase (COMT) inhibitor tolcapone (TOL) using a boron-doped diamond (BDD) electrode. The application of cyclic voltammetry (CV) technique revealed that TOL exhibited a distinct, diffusion-controlled, irreversible anodic peak at a potential of approximately +0.71 V (vs. Ag/AgCl) in a 0.1 mol L–1 phosphate buffer solution (PBS) with a pH of 2.5. The oxidation of TOL is highly dependent on the pH and supporting electrolytes. Based on the data obtained from the pH investigation, a proposed mechanism for the electro-oxidation of TOL is suggested. Using the square wave voltammetry (SWV) technique, a …