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Excess Lifetime Cancer Risk Due To Natural Radioactivity In Gümüşhane Province, Ne Turkey, Nafiz Maden, Enver Akaryali, Mehmet Ali̇ Gücer
Excess Lifetime Cancer Risk Due To Natural Radioactivity In Gümüşhane Province, Ne Turkey, Nafiz Maden, Enver Akaryali, Mehmet Ali̇ Gücer
Turkish Journal of Earth Sciences
In this study, 162 in situ measurements of 238U, 232Th, and 40K radionuclide concentrations dataset taken by the gamma-ray spectrometer in Gümüşhane, Turkey are presented. The gamma ray measurements were performed by a 512-channel, three-window gamma-ray spectrometry equipment made by GF Instruments. We first observed the radionuclides of the 238U, 232Th, and 40K values in Gümüşhane. We then calculated the hazard indices of gamma radiation such as annual effective dose equivalent (AEDE), internal and external hazard index (Hin, Hex), and excess lifetime cancer risk (ELCR) based on the radionuclide abundances of 238U, 232Th, and 40K for the first time. In …
Msap Analysis Reveals Diverse Epigenetic Statuses In Opium Poppy Varieties With Different Benzyisoquinoline Alkaloid Content, Betül Bulut, Zehra Aydinli, Mi̇ne Türktaş
Msap Analysis Reveals Diverse Epigenetic Statuses In Opium Poppy Varieties With Different Benzyisoquinoline Alkaloid Content, Betül Bulut, Zehra Aydinli, Mi̇ne Türktaş
Turkish Journal of Biology
DNA methylation is one of the major epigenetic modifications influencing the regulation of gene expression. The opium poppy is an important medicinal plant. Its latex contains opium, which is a rich source of pharmaceutical benzyisoquinoline alkaloids (BIA). Here, the methylation-sensitive amplification polymorphism (MSAP) profiling technique using 21 MSAP molecular markers was applied in order to compare levels of DNA methylation between 6 opium poppy varieties. MSAP profiling reflected the different methylation statuses among opium poppy varieties having divergent BIA content. Moreover, different organ-specific epigenetic profiles were observed between the samples. Differential epigenetic profiles of capsules and shoots from the leaves …
Covid-19: Current Knowledge, Disease Potential, Prevention And Clinical Advances, Aftab Alam, Mohd Faizan Siddiqui, Nikhat Imam, Rafat Ali, Mushtaque Mushtaque, Romana Ishrat
Covid-19: Current Knowledge, Disease Potential, Prevention And Clinical Advances, Aftab Alam, Mohd Faizan Siddiqui, Nikhat Imam, Rafat Ali, Mushtaque Mushtaque, Romana Ishrat
Turkish Journal of Biology
The top priority of any nation is to lead the nation towards prosperity, progress, and economic growth, confronting several challenges and concerns arisen from global situations. The sudden outbreak of any disease defies the health care systems and economy of nations. COVID-19 is one of the viral diseases which broke out in Wuhan city of China in 2019. COVID-19 outbreak intermittently prevailed all over the world. It exposes the fragility of the established health care systems across the world in spite of comprising modern science and technology. Unfortunately, there is no chemotherapeutic agent in the regimen of antiviral drugs or …
Effect Of Mound Size On Intranest Thermoregulation In The Red Wood Ants Formicarufa And F. Polyctena (Hymenoptera, Formicidae), Stanislav Stukalyuk, Yuri Radchenko, Maksym Netsvetov, Alexey Gilev
Effect Of Mound Size On Intranest Thermoregulation In The Red Wood Ants Formicarufa And F. Polyctena (Hymenoptera, Formicidae), Stanislav Stukalyuk, Yuri Radchenko, Maksym Netsvetov, Alexey Gilev
Turkish Journal of Zoology
Red wood ants are capable of active thermoregulation in the nest, which allows them to achieve a high number of workers and a dominant position in biocenoses. We investigated the features of the spring warm-up and the ability for active thermoregulation of the mounds of the ants Formica polyctena and F. rufa in the vicinity of Kyiv, Ukraine. We have proposed a model of thermoregulation of the mound, which takes into account the heat flow from the sun, heat exchange with air and soil, and endogenous heat generated by the antcolony. The calculation of the model for specific values showed …
First Record Of Ahaetulla Mycterizans (Linnaeus, 1758) (Serpentes: Colubridae) From The Lesser Sunda Region, Indonesia, Based On Molecular And Morphological Identification, Lilin Ika Nur Indahsari, Fatchiyah Fatchiyah, Eric Nelson Smith, Nia Kurniawan
First Record Of Ahaetulla Mycterizans (Linnaeus, 1758) (Serpentes: Colubridae) From The Lesser Sunda Region, Indonesia, Based On Molecular And Morphological Identification, Lilin Ika Nur Indahsari, Fatchiyah Fatchiyah, Eric Nelson Smith, Nia Kurniawan
Turkish Journal of Zoology
Previous studies on the distribution of the Ahaetulla snake across Indonesia only focused on morphological characters without any molecular data. This study was aimed at analyzing phylogenetic relationships among the genus Ahaetulla in Indonesia based on partial mitochondrial DNA sequences of 16 specimens collected from the Sundaland and Lesser Sunda regions. The 12S-rDNA gene was PCR-amplified and sequenced to analyze phylogenetic relationships and to estimate the divergence time between the 2 Ahaetulla populations of the Sundaland and Lesser Sunda regions. Morphological characters of 3 Ahaetulla specimens from Lesser Sunda and Sundaland have also been analyzed to confirm the results based …
Microfossil Assemblages (Diatoms, Calcareous Nannofossils, And Silicoflagellates),Paleoenvironment, And Hydrocarbon Source Rock Potential Of The Oligocene Ruslarformation At Karadere, Bulgaria, Emilia Tulan, Reinhard F. Sachsenhofer, Jakub Witkovski, Gabor Tari, Stjepan Coric, Achim Bechtel
Microfossil Assemblages (Diatoms, Calcareous Nannofossils, And Silicoflagellates),Paleoenvironment, And Hydrocarbon Source Rock Potential Of The Oligocene Ruslarformation At Karadere, Bulgaria, Emilia Tulan, Reinhard F. Sachsenhofer, Jakub Witkovski, Gabor Tari, Stjepan Coric, Achim Bechtel
Turkish Journal of Earth Sciences
The Oligocene Ruslar Formation, an equivalent of the Maykop Suite, is a potential hydrocarbon source rock in the western Black Sea Basin. In contrast to the offshore areas, the depositional environment and hydrocarbon source rock potential of onshore Bulgaria sediments are largely unknown. Hence, a 14-m-thick section of the Ruslar Formation, exposed near Karadere (Black Cape) along the Black Sea coast, provides an excellent opportunity to study the upper part of the Ruslar Formation. Here, laminated diatomrich mudstones with frequent thin sandstone beds and a prominent concretion horizon are exposed. Furthermore, the fossil diatom assemblages provide a key component to …
The Ypresian To Lutetian Marine Record In Nw Turkey: A Revised Biostratigraphy Andchronostratigraphy And Implications For Eocene Paleogeography, Ercan Özcan, Zahi̇de Özcan, Aral I. Okay, Kenan Akbayram, Aynur Hakyemez
The Ypresian To Lutetian Marine Record In Nw Turkey: A Revised Biostratigraphy Andchronostratigraphy And Implications For Eocene Paleogeography, Ercan Özcan, Zahi̇de Özcan, Aral I. Okay, Kenan Akbayram, Aynur Hakyemez
Turkish Journal of Earth Sciences
The Eocene sedimentary units in the Kocaeli and Armutlu peninsulas and İznik-Geyve region (northwest Turkey) consist of marine siliciclastic and carbonate deposits, locally intercalated with volcaniclastic rocks and tuffs (Middle Eocene Magmatic Rocks-MEMR). The record of larger benthic fauna (LBF) and pelagic microfossils, such as planktonic foraminifera and calcareous nannoplankton, combined with lithological description, indicate a wide spectrum of depositional environments ranging from shallowto deep-marine. These deposits contain in situ and/or allochthonous assemblages of orthophragminids, nummulitids, subordinate rotaliids, and sparse alveolinids. The in situ assemblages (mainly orthophragminids) point to several episodes of shallow marine depositional conditions during a) early Ypresian …
Possible Implications Of Weather Variation On Reproductive Phenology Of Europeancommon Toad In Southeastern Europe, Bogdan Jovanovic, Ethan J. Kessler, Marija Ilic, Jelena Corovic, Natasa Tomasevic-Kolarov, Christopher A. Phillips, Jelka Crnobrnja Isailovic
Possible Implications Of Weather Variation On Reproductive Phenology Of Europeancommon Toad In Southeastern Europe, Bogdan Jovanovic, Ethan J. Kessler, Marija Ilic, Jelena Corovic, Natasa Tomasevic-Kolarov, Christopher A. Phillips, Jelka Crnobrnja Isailovic
Turkish Journal of Zoology
We tracked yearly variation in breeding phenology in relation to weather parameters in a common European toad population from the southeastern part of its range. Phenological data were collected from 2001 to 2003 and from 2011 to 2017 and compared to open-access daily weather data from a nearby weather station. Data analysis revealed no significant effect of weather on initiation of breeding and a negative relationship between mean daily humidity and mean cloud cover on the duration of breeding season (P = 0.03). Further analysis showed a decreasing trend in breeding season humidity in the past 70 years. Our results …
Genetic Structure And Population Dynamics Of The Silver Pheasant(Lophura Nycthemera) In Southern China, Chaoying Zhu, Wenjing Lu, Guanglong Sun, Jiang Chen, Zhen Zhang, Liangjie Yu, Peng Chen, Yuqing Han, Zhifeng Xu, Junpeng Bai, Dongqin Zhao, Luzhang Ruan
Genetic Structure And Population Dynamics Of The Silver Pheasant(Lophura Nycthemera) In Southern China, Chaoying Zhu, Wenjing Lu, Guanglong Sun, Jiang Chen, Zhen Zhang, Liangjie Yu, Peng Chen, Yuqing Han, Zhifeng Xu, Junpeng Bai, Dongqin Zhao, Luzhang Ruan
Turkish Journal of Zoology
In southern China, the silver pheasant (Lophura nycthemera) is a widespread species due to complex topography and sufficient habitats and food resources. We investigated the microsatellite and mitochondrial DNA control region sequence of 115 individuals from 7 locations in China to study population dynamics of the silver pheasant during the Pleistocene. The neutrality test and mismatch distribution analyses showed that population expansion began in the interglacial period (76,053 years ago), and the latest common ancestor appeared approximately 970,300 years ago. Most populations exhibited a high level of genetic diversity as well as gene flow. Results of phylogenetic trees and network …
Fireanalyst: An Effective System For Detecting Fire Geolocation And Fire Behavior In Forestsusing Mathematical Modeling, Yücel Güllüce, Rahmi̇ Nurhan Çeli̇k
Fireanalyst: An Effective System For Detecting Fire Geolocation And Fire Behavior In Forestsusing Mathematical Modeling, Yücel Güllüce, Rahmi̇ Nurhan Çeli̇k
Turkish Journal of Agriculture and Forestry
This study proposes an effective new fire detection method and monitoring software for an early-warning fire detection system aimed at valuable forested areas, such as botanical parks or high conservation value forests, particularly those with boundaries. These critical forested areas need to be appropriately managed because they contain large concentrations of biological diversity, including threatened or endangered species, which are very susceptible to fire outbreaks; thus, early detection of fire and rapid response have a very important place in the fight against fire in those areas. In this proposed system, special detectors with state-of-the-art multispectral infrared technology and mathematical modeling …
Alluvial-Lacustrine Sedimentation And Volcaniclastic Deposition In An Intracontinental Tectonic Graben: Paleoenvironmental Evolution Of The Neogene Sinanpaşa Basin, West-Central Turkey, Eli̇f Akiska, Baki̇ Erdoğan Varol
Alluvial-Lacustrine Sedimentation And Volcaniclastic Deposition In An Intracontinental Tectonic Graben: Paleoenvironmental Evolution Of The Neogene Sinanpaşa Basin, West-Central Turkey, Eli̇f Akiska, Baki̇ Erdoğan Varol
Turkish Journal of Earth Sciences
This study reports on the Sinanpaşa Basin, a typical example of the Miocene tectonic intracontinental grabens formed in West Anatolia, Turkey. The study reconstructs the paleoenvironmental and paleogeographic history of the graben based on a detailed sedimentological analysis of basin-fill deposits exposed mainly near the graben's northern and southern margins. The sedimentary paleoenvironments in the graben range from basin-margin alluvial fan systems and basin-axis fluvial distributary system to an intrabasinal shallow lake environment surrounded by peat-forming mires, changing from carbonate to more clayey, episodically evaporitic, and shifting its shorelines considerably. The spatial distribution and stratigraphic stacking of these paleoenvironments indicate …
Petrology Of The Late Triassic Mafic Volcanic Rocks From The Antalya Complex, Southernturkey: Evidence For Mantle Source Characteristics During The Neotethyan Rifting, Utku Bağci, Tamer Rizaoğlu, Güzi̇de Önal, Osman Parlak
Petrology Of The Late Triassic Mafic Volcanic Rocks From The Antalya Complex, Southernturkey: Evidence For Mantle Source Characteristics During The Neotethyan Rifting, Utku Bağci, Tamer Rizaoğlu, Güzi̇de Önal, Osman Parlak
Turkish Journal of Earth Sciences
The Antalya Complex in southern Turkey comprises a number of autochthonous and allochthonous units that originated from the Southern Neotethys. Late Triassic volcanic rocks are widespread in the Antalya Complex and are important for the onset of the rifting stage of the southern Neotethys. The studied Late Triassic volcanic rocks within the Antalya Complex are exposed in the southern part of Saklıkent (Antalya) region. They are represented by pillow, massive, and columnar-jointed lava flows with volcaniclastic breccias and pelagic limestone intercalations. Spilitic basalts exhibit intersertal, microlithic porphyritic, and ophitic textures and are represented by plagioclase, pyroxene, and olivine. Secondary phases …
Hyracoidea From The Middle Miocene Hominoid Locality Of Paşalar (Nw Turkey), Martin Pickford, Serdar Mayda, Berna Alpagut, Fatma Arzu Demi̇rel, Ayşegül Şarbak, Tümel Tanju Kaya
Hyracoidea From The Middle Miocene Hominoid Locality Of Paşalar (Nw Turkey), Martin Pickford, Serdar Mayda, Berna Alpagut, Fatma Arzu Demi̇rel, Ayşegül Şarbak, Tümel Tanju Kaya
Turkish Journal of Earth Sciences
Previously available samples of Hyracoidea from Paşalar (MN 6, Middle Miocene), Turkey, have indicated the presence of Pliohyracidae at the site, but the material was too scanty for confident identification. The single upper molar, an upper molar ectoloph fragment and an ascending ramal fragment were too uninformative for determining the taxonomic identity of the fossils, although several names have been proposed in the literature. Additional fossils collected from Paşalar include upper and lower premolars, which help to tie down the affinities of this hyracoid. They are attributed to the genus Prohyrax, but were not named specifically, even though they are …
When Did The Drainage System Of The Kızılırmak River Form In Cappadocia (Anatolia,Turkey)? A Revised Geological And Geomorphological Stratigraphy, Uğur Doğan, Çeti̇n Şenkul
When Did The Drainage System Of The Kızılırmak River Form In Cappadocia (Anatolia,Turkey)? A Revised Geological And Geomorphological Stratigraphy, Uğur Doğan, Çeti̇n Şenkul
Turkish Journal of Earth Sciences
The Kızılırmak is the longest river in Turkey, extending from the western part of eastern Anatolia to the Black Sea, and crossing the orogenic Central Anatolian Plateau (CAP) and Black Sea Mountains. This study focuses on the formation period of the drainage system of the Kızılırmak River in the Cappadocia region, which is situated in the middle of the CAP. The Upper Pliocene-Quaternary geological and geomorphological stratigraphy of the Cappadocia region was revised with new findings and those of previous studies. In this study, the oldest terrace (Sünnetli Tepe Terrace, T0) of the Kızılırmak River was identified 214 m above …
Assessment Of Element Concentrations In Surface Sediment Samples Fromsığacık Bay (Eastern Aegean), Özde Bakak, Fi̇li̇z Küçüksezgi̇n, Fai̇k Erdeni̇z Özel
Assessment Of Element Concentrations In Surface Sediment Samples Fromsığacık Bay (Eastern Aegean), Özde Bakak, Fi̇li̇z Küçüksezgi̇n, Fai̇k Erdeni̇z Özel
Turkish Journal of Earth Sciences
Concentrations of Al, Fe, As, Co, Cr, Cu, Mn, Ni, Pb, Zn, Hg, and organic carbon, and grain size distribution were investigated in the surface sediments of 7 sampling stations in the Sığacık Bay (western Anatolia) in December 2016. At all of the sampling stations, the concentrations of Pb, Ni, Cr, and As were higher than the average shale values. The highest concentrations of Pb, Cu, Zn, As, and Hg were found at stations near Doğanbey Cape. The possible sources of pollution were evaluated using several parameters: the enrichment factor (Ef), contamination factor (Cf), and contamination degree (Cd). The Ef …
Review Of Late Cretaceous Volcanogenic Massive Sulfide Mineralization In The Easternpontides, Ne Turkey, Mustafa Kemal Revan
Review Of Late Cretaceous Volcanogenic Massive Sulfide Mineralization In The Easternpontides, Ne Turkey, Mustafa Kemal Revan
Turkish Journal of Earth Sciences
The production of Cu-Zn from volcanogenic massive sulfide (VMS) deposits in the eastern Pontides began in the early 1900s, with the exploitation of high-grade ores scattered across the district. The district still possesses economically important blind VMS and associated sulfide deposits. Careful descriptive documentation of the typical features of these VMS ores illustrated the geological characteristics that are important in identifying ore localities and can be used to define exploration targets. The eastern Pontide VMS deposits are examples of volcanic-hosted massive sulfide deposits that exhibit many of the characteristics typical of bimodal-felsic-type VMS mineralization. Nearly all known VMS deposits in …
Latest Priabonian Larger Benthic Foraminiferal Assemblages At The Demise Of Thesoğucak Carbonate Platform (Thrace Basin And Black Sea Shelf, Nw Turkey):Implications For The Shallow Marine Biostratigraphy, Ali̇ Osman Yücel, Ercan Özcan, Ümi̇tcan Erbi̇l
Latest Priabonian Larger Benthic Foraminiferal Assemblages At The Demise Of Thesoğucak Carbonate Platform (Thrace Basin And Black Sea Shelf, Nw Turkey):Implications For The Shallow Marine Biostratigraphy, Ali̇ Osman Yücel, Ercan Özcan, Ümi̇tcan Erbi̇l
Turkish Journal of Earth Sciences
The Eocene-Oligocene transition corresponds to a significant biotic turnover globally. In shallow marine realms, the larger benthic foraminifera (LBF) belonging to most nummulitids and all orthophragminids became extinct at or near the Eocene/Oligocene boundary, reflecting the environmental deterioration. We here record the advanced developmental stages of midlatitude LBF from the Soğucak Carbonate Platform in NW Turkey on the brink of their extinction in the Tethys. The LBF assemblages in the uppermost part of the platform, exposed in Gökçetepe and Karaburun in the Thrace Basin and Black Sea shelf, are represented by the dominant occurrence of Heterostegina d'Orbigny, 1826, Spiroclypeus Douville, …
Pyrene-Bodipy-Substituted Novel Water-Soluble Cyclotriphosphazenes: Synthesis,Characterization, And Photophysical Properties, Seda Çeti̇ndere, Serkan Yeşi̇lot, Adem Kiliç
Pyrene-Bodipy-Substituted Novel Water-Soluble Cyclotriphosphazenes: Synthesis,Characterization, And Photophysical Properties, Seda Çeti̇ndere, Serkan Yeşi̇lot, Adem Kiliç
Turkish Journal of Chemistry
In the present work, pyrene-boron-dipyrromethene (BODIPY)-substituted novel water-soluble cyclotriphosphazene derivatives (6 and 7) were synthesized by click reactions between a cyclotriphosphazene derivative with a hydrophilic glycol side group (2) and BODIPYs (4 and 5). All of the new compounds (2, 6, and 7) were characterized by Fourier-transform infrared and nuclear magnetic resonance spectroscopy, as well as mass spectrometry and elemental analysis. The photophysical properties of the BODIPY-substituted cyclotriphosphazenes (6 and 7) were investigated by UV-Vis and fluorescence emission spectroscopy in water and water/solvent mixtures. It was found that the target compounds were soluble in water and could be potential candidates …
Synthesis And Spectroscopic Properties Of (N/O) Mono- Anddispirocyclotriphosphazene Derivatives With Benzyl Pendant Arms: Study Ofbiological Activity?, Özlem İşcan, Reşi̇t Cemaloğlu, Nuran Asmafi̇li̇z, Zeynel Kiliç, Leyla Açik, Peli̇n Özbeden, Tuncer Hökelek
Synthesis And Spectroscopic Properties Of (N/O) Mono- Anddispirocyclotriphosphazene Derivatives With Benzyl Pendant Arms: Study Ofbiological Activity?, Özlem İşcan, Reşi̇t Cemaloğlu, Nuran Asmafi̇li̇z, Zeynel Kiliç, Leyla Açik, Peli̇n Özbeden, Tuncer Hökelek
Turkish Journal of Chemistry
The Cl replacement reactions of hexachlorocyclotriphosphazene (trimer; N3 P3 Cl6) with sodium (N-benzyl)- aminopropanoxides (1 and 2) produced monospiro- (3 and 4), cis-, and trans-dispirocyclotriphosphazenes (13-16). The monospiro tetrakis-aminocyclotriphosphazenes (5-12) were obtained by the Cl substitutions of 3 and 4 with different secondary amines. The cis- (13 and 14) and trans-dispirophosphazenes (15 and 16) possessed 2 chiral P centers, and they were able to present meso and racemic forms, respectively. Moreover, the structures of compounds 5 and 14 were designated using X-ray data. The absolute configuration of compound 14 was found as SR in the solid state. Analytical and spectroscopic …
Synthesis Of New Cyclotriphosphazene Derivatives Bearing Schiff Bases And Theirthermal And Absorbance Properties, Semi̇h Doğan, Süreyya Oğuz Tümay, Ceylan Mutlu Balci, Serkan Yeşi̇lot, Serap Beşli̇
Synthesis Of New Cyclotriphosphazene Derivatives Bearing Schiff Bases And Theirthermal And Absorbance Properties, Semi̇h Doğan, Süreyya Oğuz Tümay, Ceylan Mutlu Balci, Serkan Yeşi̇lot, Serap Beşli̇
Turkish Journal of Chemistry
In this study, a series of cyclotriphosphazene derivatives containing a Schiff base (3a-3d) were synthesized by the reactions of hexachlorocyclotriphosphazene (1) with bis-aryl Schiff bases (2a-2d) having different terminal groups (H, F, Cl, and Br). The products (3a-3d) were characterized by elemental and mass analyses, FT-IR, and $^{1}$H, $^{13}$C, and 31 P NMR spectroscopies. Furthermore, the structure of compound 3a was also determined by X-ray crystallography. The thermal behaviors and the spectral properties of the new cyclotriphosphazene compounds (3a-3d) were investigated and the results were compared in the series.
Synthesis, Optical, And Structural Properties Of Bisphenol-Bridgedaromatic Cyclic Phosphazenes, Bünyemi̇n Çoşut, Burcu Topaloğlu Aksoy, Süreyya Oğuz Tümay, Ahmet Şenocak, Serkan Yeşi̇lot
Synthesis, Optical, And Structural Properties Of Bisphenol-Bridgedaromatic Cyclic Phosphazenes, Bünyemi̇n Çoşut, Burcu Topaloğlu Aksoy, Süreyya Oğuz Tümay, Ahmet Şenocak, Serkan Yeşi̇lot
Turkish Journal of Chemistry
Phenoxy- and naphthoxy-substituted bisphenol-bridged cyclic phosphazenes were synthesized in 2 steps and their thermal, photophysical, and electrochemical properties were investigated. The structures of the cyclic phosphazene compounds were determined by ESI-MS mass spectrometry and $^{1}$H, $^{13}$C, and $^{31}$P NMR spectroscopies. The photophysical studies of phenoxy- and naphthoxy-substituted bridged cyclophosphazenes were investigated by means of absorption and fluorescence spectroscopies in different solvents. Thermal and electrochemical properties of the target compounds were also studied. Furthermore, the excimer emissions through intramolecular interactions in solution and in solid state were investigated by fluorescence spectroscopy and the theoretical calculations were performed in detail using DFT.
Chemosensor Properties Of 7-Hydroxycoumarin Substituted Cyclotriphosphazenes?, Gönül Yeni̇lmez Çi̇ftçi̇, Sergen Yilmaz, Nagi̇han Bayik, Eli̇f Şenkuytu, Esra Nur Kaya, Mahmut Durmuş, Mustafa Bulut
Chemosensor Properties Of 7-Hydroxycoumarin Substituted Cyclotriphosphazenes?, Gönül Yeni̇lmez Çi̇ftçi̇, Sergen Yilmaz, Nagi̇han Bayik, Eli̇f Şenkuytu, Esra Nur Kaya, Mahmut Durmuş, Mustafa Bulut
Turkish Journal of Chemistry
The newly synthesized cyclotriphosphazene cored coumarin chemosensors 5, 6, and 7 were successfully characterized by $^{1}$H NMR, $^{31}$P NMR, and MALDI-TOF mass spectrometry. Additionally, the photophysical and metal sensing properties of the targeted compounds were determined by fluorescence spectroscopy in the presence of various metals (Li$^{+}$, Na$^{+}$ , K$^{+}$ , Cs$^{+}$ , Mg2$^{+}$ , Ca2$^{+}$ , Ba2$^{+}$ , Cr3$^{+}$ , Mn2$^{+}$ , Fe3$^{+}$ , Co2$^{+}$ , Al3$^{+}$ , Hg$^{+}$ , Cu2$^{+}$ , Zn2$^{+}$ , Ag$^{+}$ , and Cd2$^{+}$) . The fluorescence titration results showed that compounds 5, 6, and 7 could be employed as fluorescent chemosensors for Fe3$^{+}$ ions with …
Novel Bodipy-Bridged Cyclotriphosphazenes, Hande Eserci̇, Ezel Öztürk, Eli̇f Okutan
Novel Bodipy-Bridged Cyclotriphosphazenes, Hande Eserci̇, Ezel Öztürk, Eli̇f Okutan
Turkish Journal of Chemistry
Three new 2-component unsubstituted (4P), diiodo- (5P), and dibromo- (6P) distyryl-BODIPY-bridged cyclotriphosphazene dimers were designed and synthesized. The newly synthesized BODIPY-cyclotriphosphazene systems were characterized by $^{1}$H, $^{13}$C, and $^{31}$P NMR spectroscopy. The photophysical properties of the distryl-BODIPYs (4-6) and BODIPY-cyclotriphosphazene dyads (4P-6P) were studied by UV-Vis absorption and fluorescence emission spectroscopy. In these derivatives, the bino-type cyclotriphosphazene derivative bearing unsubstituted BODIPY unit 4 P exhibited high fluorescence and no singlet oxygen generation due to the lack of spin converter. The attachment of heavy atoms (iodine and bromine) enabled the production of singlet oxygen. The bino-type BODIPY-cyclotriphosphazenes (5P and 6P) were …
Nucleophilic Substitution Reactions Of Monofunctional Nucleophilic Reagents Withcyclotriphosphazenes Containing 2,2-Dioxybiphenyl Units, Esra Tanriverdi̇ Eçi̇k, Hani̇fe İbi̇şoğlu, Gönül Yeni̇lmez Çi̇ftçi̇, Gi̇zem Demi̇r, Eda Erdemi̇r, Fatma Yüksel
Nucleophilic Substitution Reactions Of Monofunctional Nucleophilic Reagents Withcyclotriphosphazenes Containing 2,2-Dioxybiphenyl Units, Esra Tanriverdi̇ Eçi̇k, Hani̇fe İbi̇şoğlu, Gönül Yeni̇lmez Çi̇ftçi̇, Gi̇zem Demi̇r, Eda Erdemi̇r, Fatma Yüksel
Turkish Journal of Chemistry
The nucleophilic substitution reactions of mono- and bis-spiro-2,2' -dioxybiphenyl cyclotriphosphazenes (3 and 4) with cyclopropanemethylamine (5) and aniline (6) were performed in the presence of trimethylamine in THF. Five novel cyclopropanemethylamino- and anilino-substituted spiro-2,2' -dioxybiphenyl cyclotriphosphazene derivatives (7-11) were obtained from these reactions. The molecular structures of the new cyclotriphosphazene derivatives (7- 11) were characterized by elemental analysis, MALDI-TOF MS, FT-IR, and NMR ( $^{31}$P and $^{1}$H) spectroscopies. The structure of the spiro-(2,2' -dioxybiphenyl)-bis-(anilino)-cyclotriphosphazene (11) was also determined by single-crystal X-ray crystallography.
Highly Sensitive Fluorometric Method Based On Nitrogen-Doped Carbon Dotclusters For Tartrazine Determination In Cookies Samples, Abi̇di̇n Gümrükçüoğlu, Aysel Başoğlu, Sevgi̇ Kolayli, Sali̇ha Di̇nç, Meryem Kara, Mi̇raç Ocak, Ümmühan Ocak
Highly Sensitive Fluorometric Method Based On Nitrogen-Doped Carbon Dotclusters For Tartrazine Determination In Cookies Samples, Abi̇di̇n Gümrükçüoğlu, Aysel Başoğlu, Sevgi̇ Kolayli, Sali̇ha Di̇nç, Meryem Kara, Mi̇raç Ocak, Ümmühan Ocak
Turkish Journal of Chemistry
Nitrogen-doped carbon nanodots (CDs) were prepared via the solvothermal method, using urea and triethylene glycol as the starting materials. The as-prepared CDs had individual diameters of approximately 100 nm and were in clusters of different sizes. The surface composition and optical properties of the as-prepared CDs were characterized. They exhibited multicolor emission properties in the visible range when excited with a wide wavelength range. The aqueous solution of the CDs was used in highly sensitive tartrazine determination. The fluorescence quenching of the CDs was in a linear relationship with the concentrations of tartrazine in the range of 0.5-30.0 μM. The …
One-Pot Synthesis Of Vox /Al2 O3 As Efficient Catalysts For Propanedehydrogenation, Guangjian Wang, Hao Xu, Kai Lu, Zhihao Ding, Liancheng Bing
One-Pot Synthesis Of Vox /Al2 O3 As Efficient Catalysts For Propanedehydrogenation, Guangjian Wang, Hao Xu, Kai Lu, Zhihao Ding, Liancheng Bing
Turkish Journal of Chemistry
Vanadium oxides, as highly efficiently catalysts, are widely applied in various catalytic reactions, such as the dehydrogenation of light alkanes and epoxidation of alkenes. In this paper, a series of VO$_{x}$ /Al$_{2}$O$_{3}$ catalysts were fabricated by the 1-pot method for catalytic propane dehydrogenation. The results indicated that the VO$_{x}$ /Al$_{2}$O$_{3}$ catalysts with loading of 10 wt.% vanadium exhibited optimized catalytic performance. The as-prepared catalysts were characterized by N$_{2}$ adsorption-desorption, XRD, TEM, H$_{2}$ -TPR, and XPS to explore the texture properties, morphology, and electronic environment of vanadium. In addition, several vanadium catalysts were also prepared by the incipient wetness impregnation (IWI) …
Highly Improved Electrocatalytic Oxidation Of Dimethylamine Borane On Silvernanoparticles Modified Polymer Composite Electrode, Çağri Ceylan Koçak, Süleyman Koçak, Şükri̇ye Karabi̇beroğlu, Zekerya Dursun
Highly Improved Electrocatalytic Oxidation Of Dimethylamine Borane On Silvernanoparticles Modified Polymer Composite Electrode, Çağri Ceylan Koçak, Süleyman Koçak, Şükri̇ye Karabi̇beroğlu, Zekerya Dursun
Turkish Journal of Chemistry
Dimethylamine borane (DMAB) is a promising fuel alternative for fuel cell applications. In this work cyclic voltammetric behavior of DMAB was investigated on the polymerized aminophenol film decorated with Ag nanoparticles in alkaline media. The polymer film was formed on the glassy carbon electrode by electrochemical technique and then, the surface was modified with Ag nanoparticles. The surface of the modified electrode was identified by scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and electrochemical impedance spectroscopy techniques. The developed electrode has displayed high electrocatalytic activity for DMAB oxidation in alkaline media depending on the supporting electrolyte concentration. Experimental …
Entrapment Of Organic Fluorophores In Calcium Phosphate Nanoparticles Withslow Release, Laila Sadallah, Aicha Boukhriss, Hassan Hannache, Said Gmouh
Entrapment Of Organic Fluorophores In Calcium Phosphate Nanoparticles Withslow Release, Laila Sadallah, Aicha Boukhriss, Hassan Hannache, Said Gmouh
Turkish Journal of Chemistry
Two organic fluorophores, fluorescein (F) and rhodamine B (Rd), were entrapped in calcium phosphate nanoparticles. The as-obtained nanoparticles can be used for biological release applications. For this aim, calcium phosphate nanoparticles were synthesized using the precipitation method. Structural analysis of these nanoparticles was performed using XRD, FTIR, and Raman spectroscopy, confirming that the synthesized nanoparticles were hydroxyapatite. TEM and SEM analyses demonstrated that these nanoparticles had a size of 20 nm and a well-defined morphology. F and Rd (about 0.5 wt.%) were entrapped in these nanoparticles and their release, as a function of time, was studied via UV-Vis spectroscopy. The …
Ranolazine-Functionalized Cuo Nps: Efficient Homogeneous And Heterogeneouscatalysts For Reduction Of 4-Nitrophenol, Gul Naz Laghari Baloch, Sarfaraz Ahmed Mahesar, Sirajuddin Khan, Jan Nisar, Syed Tufail Hussain Sherazi
Ranolazine-Functionalized Cuo Nps: Efficient Homogeneous And Heterogeneouscatalysts For Reduction Of 4-Nitrophenol, Gul Naz Laghari Baloch, Sarfaraz Ahmed Mahesar, Sirajuddin Khan, Jan Nisar, Syed Tufail Hussain Sherazi
Turkish Journal of Chemistry
In the present study copper oxide nanoparticles (CuO NPs) were synthesized using a hydrothermal method with ranolazine as a shape-directing agent. Ranolazine-functionalized CuO NPs were characterized by various analytical techniques such as scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). The SEM pattern confirmed the morphology of ranolazine-functionalized CuO NPs with well-defined rice-like structures. FTIR spectroscopy confirmed the interaction between CuO NPs and ranolazine. The XRD analysis indicated that the structure of ranolazine-functionalized CuO NPs was monoclinic crystalline and the size ranged between 9 and 18 nm with an average particle size of 12 nm. …