Digital Commons Network^™

Extended Inter-Laboratory Characterization Of The New Coastal Seawater Dissolved Organic Matter Reference Material Trm-0522, Alexander J. Craig, Lydia Babcock-Adams, Maxime C. Bridoux, Charlotte Brun, Juliana D'Andrilli, Aleksandar I. Goranov, Patrick G. Hatcher, Oliver Lechtenfeld, Hang Li, Rebecca Matos, Garrett Mckay, Amy M. Mckenna, Madelyn Miller, Sasha Wagner, Margot E. White, Alexander Zherebker, Jeffrey A. Hawkes

Chemistry & Biochemistry Faculty Publications

Dissolved organic matter (DOM) reference materials are critical to ensuring reliable comparability of measurements across experiments and between labs. TRM-0522, isolated in 2022 from 45 m deep seawater off of Sweden’s west coast, fills the niche of a previously unavailable coastal marine DOM reference material. After its isolation, we detailed a limited number of metrics for TRM-0522, initially disclosing Orbitrap high-resolution mass spectrometry, nuclear magnetic resonance, carbon proportion, absorbance, and fluorescence data. With TRM-0522 becoming more widely used, a variety of labs have generated different metrics that help to characterize and define the chemical properties of this coastal reference material. …

Co₂ Isotopologues From The Ace Satellite, D. English, P. Bernath, C. Boone

Chemistry & Biochemistry Faculty Publications

Carbon dioxide isotopologues have been studied thoroughly in the troposphere. In the stratosphere, the minor oxygen CO₂ isotopologues have anomalous abundances due to their exchange reactions with isotopically fractionated ozone, differentiating them from tropospheric CO₂. Previously a model predicted that this anomalous isotopic abundance continues into the mesosphere but lacked verification from experimental observations. Here we use the Atmospheric Chemistry Experiment Fourier Transform Spectrometer which records infrared transmittance spectra of the Earth's limb from low Earth orbit using solar occultation. These infrared spectra provide measurements of global CO₂ isotopologue volume mixing ratios (VMRs) from the upper troposphere to the lower …

Analysis Of Aerosols In The Asian Monsoon Anticyclone As Observed By The Atmospheric Chemistry Experiment, M. Lecours, R. Dodangodage, C. D. Boone, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

During the Asian summer monsoon season, pollutants from the lower troposphere are transported through deep convection to the upper troposphere and lower stratosphere. Surface pollutants such as CO are transported upward and trapped in the anticyclone during this unique atmospheric phenomenon. Associated with the anticyclone is a layer of enhanced aerosols located near the tropopause often referred to as the Asian tropopause aerosol layer (ATAL). The chemical and physical properties of aerosols in the ATAL are not yet fully understood as direct observations of the aerosols are limited. The Atmospheric Chemistry Experiment (ACE) is a satellite mission that provides high-resolution …

From Biophysics To Cellular Function: Neural Telcs-Membrane-Anions Capacitor Transmembrane Potential, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

Based on the transmembrane-electrostatically localized protons/cations charges (TELCs) theory, neural transmembrane potential including both resting and action potential is now well elucidated as the voltage contributed by the TELCs-membrane-anions capacitor biophysics in a neuron. Accordingly, neural transmembrane potential has an inverse relationship with TELCs surface density, which may represent a substantial progress in bettering the fundamental understanding of neuroscience. In this article, I will present a review on the latest development of the TELCs neural transmembrane potential theory and address Silverstein’s interesting arguments regarding the TELCs model that may constitute a complementary development to both the Hodgkin-Huxley classic cable theory …

Metathesis Or Isomerization: Counteranion Directed Reactivity Of Grubbs I, Paul D. Miller, Joe B. Calkins, Craig A. Bayse, Trandon A. Bender

Chemistry & Biochemistry Faculty Publications

Catalytic isomerization of alkenes has garnered interest for many years, but there are remaining challenges when it comes to thermodynamic selectivity and uncontrolled isomerization. Nonbiased substrates, be it sterically or thermodynamically, remain challenging for many catalysts, with a few examples available in the more modern literature. Herein, we present the controlled isomerization of linear alkenes with a cocatalytic mixture of commercially available catalyst and reagents: Grubbs I, tris(pentafluorophenyl)borane, and triethylsilane. DFT calculations indicate that an observed alkylidyne hydride intermediate is in rapid equilibrium with an alkylidene that binds the alkene substrate. This combination results in a pi-acidic metal and a …

Stack Bonding In Pentacene And Its Derivatives, Craig A. Bayse

Chemistry & Biochemistry Faculty Publications

Understanding the nature of π-stacking interactions is important to molecular recognition, self-assembly, and organic semiconductors. The stack bonding order (SBO) model of π-stacking has shown that the conformations of dimers occur when the combinations of monomer MOs are overall stack bonding in character. DFT calculations show that minima found on the potential energy surface for the π-stacked dimers of pentacene and perfluoropentacene occur when the dimer MOs are constructed from combinations of monomer MOs with an allowed SBO. An ex-amination of the MOs of π-stacked dimers extracted from X-ray structures of alkynyl derivatives like TIPS-pentacene pack at one or more …

Molecular Characterization Of Humic And Fulvic Acids On Watterlogged And Well-Drained Amazonian Podzols, Amanda M. Tadini, Aleksandar I. Goranov, Stéphane Mounier, Débora M.B.P. Milori, Célia R. Montes, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The Amazon rainforest is the largest tropical rainforest in the world. Amazonian Podzol soils, characteristic of this region, are known to store substantial amounts of organic carbon in both their surface and deep horizons. Despite decades of research, the molecular-level composition of these soils remains uncharacterized. This study addresses this knowledge gap by employing ultrahigh resolution mass spectrometry, namely, Fourier transform–ion cyclotron resonance–mass spectrometry (FT-ICR-MS), to determine the molecular composition of humic acid (HA) and fulvic acid (FA) fractions from two Amazonian Podzol profiles of varying levels of groundwater exposure (waterlogged vs well-drained). In the waterlogged soil compounds containing nitrogen, …

Protonic Capacitor Cell Energetics: Transmembrane-Electrostatically Localized Protons/Cations, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

The transmembrane-electrostatically localized protons/cations charges (TELPs/TELCs) theory can serve as a theoretical framework to better explain cell electrophysiology and elucidate bioenergetic systems including both delocalized and localized protonic coupling. According to the TELCs model, the excess positive charges of TELCs at one side of the membrane are balanced by the excess negative charges of transmembrane-electrostatically localized hydroxides anions (TELAs) at the other side of the membrane. Through the TELCs-membrane-TELAs capacitor model, the energetics of oxidative phosphorylation have recently been better elucidated in mitochondria and alkalophilic bacteria, leading to the identification of a novel Type-B energetic process. Both the TELCs model …

Deciphering The Chemistry Of Condensed Aromatic "Black" Carbon And Nitrogen In Amazonian Anthrosols, João Vitor Dos Santos, Aleksandar I. Goranov, Laís G. Fregolente, Marcia C. Bisinoti, Zhenhuan Sun, Klaus Schmidt-Rohr, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Amazonian anthrosols are renowned for their high fertility and dark color, properties primarily attributed to the abundance of condensed aromatic carbon (ConAC) in the soil organic matter. ConAC, commonly referred to as black carbon, play a key role in the stability and nutrient retention of these soils. However, the processes governing the formation of ConAC and its transformation into oxygenated derivatives remain poorly understood. In this study, we used multiple analytical platforms to investigate the chemistry of ConAC-rich humic acids (HA) extracted from Terra Mulata de Indio, a type of Amazonian anthrosol. The results reveal that ConAC are predominantly …

Formation Of Pyramidal Palladium Enhanced By B(C₆F₅)₃ Additive Enabling Selective Alkene Monoisomerization, Paul D. Miller, Trandon A. Bender

Chemistry & Biochemistry Faculty Publications

The addition of a strong Lewis acid, tris(pentafluorophenyl)borane, facilitates the reduction of Pd(cod)Cl₂ with Et₃SiH to form palladium nanoparticles in organic solvents. It was found that these palladium nanoparticles are capable of selective monoisomerization of linear alkenes. This heterogeneous palladium catalyst is tolerant of a wide variety of functional groups, confirmed by substrate and robustness screenings. It is also possible to utilize poly(methylhydro)siloxane, an industrial waste byproduct, as the reductant to enable similar isomerization chemistry.

Experimental Demonstration And Study Of Transmembrane-Electrostatically Localized Protons Prevail, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

In this review in relation to some interesting arguments from Silverstein, it is now reaffirmed that the experimental demonstration of transmembrane-electrostatically localized protons (TELPs) was successfully accomplished through 1) using an aluminum film as a TELPs sensor in a biomimetic anode water-membrane-water cathode system, 2) analyzing the water-electrolysis current curve, and 3) measuring bulk liquid phase pH. Formation of induced TELPs was subsequently discovered in an anode water-membrane-water-membrane-water cathode system. The discovery of induced TELPs enabled clean experimental tests on the cation-TELPs exchange process by using sodium bicarbonate or potassium bicarbonate solution in the central liquid chamber. The sodium/TELPs exchange …

Application Of Telc Model To Better Elucidate Neural Stimulation By Touch, James Weifu Lee

Chemistry & Biochemistry Faculty Publications

Aim: This study is to better understand how the transient ion transport activity of touch receptors could change the graded potential to stimulate an action potential firing.

Methods: The latest transmembrane-electrostatically localized protons/cations charges (TELC) theory is employed for numerical analysis to calculate the neural touch signal transduction responding time required to fire an action potential spike.

Results: A neural action potential spike was constructed successfully using newly developed time-dependent TELC-based neural transmembrane potential integral equations (Equations 5, 6, and 7). The results explicated that the TELC curve has an inverse relationship with neural transmembrane potential since its curve appears …

The B³Π–A³Δ And B³Π–X¹Σ+ Band Systems Of Zro, Manish Bhusal, Peter F. Bernath, Jacques Liévin, Léo Lavy

Chemistry & Biochemistry Faculty Publications

The zirconium oxide (ZrO) b³Π–a³Δ system is a prominent source of opacity in the atmospheres of S-type stars in the near-infrared region. The emission spectra of ZrO, obtained at the National Solar Observatory located at Kitt Peak in Arizona, have been utilized to analyze this band system. A reanalysis of the 0–0 vibrational band of the b³Π–a³Δ transition has been carried out. For the first time, the vibrational bands with 1 ⩽ v ′ ⩽ 3 and v″ ≤ 4 for the same electronic transition have been rotationally analyzed using PGOPHER. Additionally, the 0–0 and 1–1 bands of the spin-forbidden …

Identification Of Π-Stacking Motifs In Naphthalene Diimides Via Solid-State Nmr, Jennifer E. Mejia, Hannah E. Butler-Au, Nalaya E. Thompson, Karcher D. Goodman, Elizabeth R. Zengel, Robert D. Pike, Jingdong Mao, Craig A. Bayse

Chemistry & Biochemistry Faculty Publications

Organic electronics, featuring π-conjugated small molecules and polymers, have gained significant attention for their potential in flexible, lightweight devices. However, characterization of the ordered, π-stacking domains within these materials using microscopy or X-ray diffraction (XRD) is challenging with complex systems or when crystallography is impractical. This study applied 1D ¹³C multiple cross-polarization magic angle spinning (multiCP/MAS) and 2D ¹H-¹³C heteronuclear correlation (HetCor) solid-state nuclear magnetic resonance (ssNMR) to systematically characterize π-stacking motifs in a series of N,N'-dialkyl naphthalene diimides (NDIs). These techniques were shown to distinguish between the electronic environments attributed to different π-stacking motifs adopted in these NDIs, such …

Assemblage Structure Of Large Carnivorous Coral Reef Fishes At Shallow And Mesophotic Depths In Two Of The Largest And Most Isolated Marine Protected Areas In The Philippines, Rene A. Abesamis, Mikaela L. Salvador, Ryan Murray, Kymry Delijero, Segundo F. Conales, Jean T. Utzurrum, Christopher E. Bird, David T. Gauthier

Biological Sciences Faculty Publications

Overfishing remains a threat to coral reef fishes globally, with large carnivores often the most vulnerable. Marine protected areas (MPAs) can restore fish populations and biodiversity, but their impact has been understudied in mesophotic coral ecosystems (MCEs – extensions of shallow reefs from 30 to 150 m). We analyzed baited remote underwater videos recorded in 2016 to investigate the assemblage structure of large carnivorous fishes at shallow (4–12 m) and mesophotic (45–96 m) depths in two of the largest and most isolated MPAs in the Philippines: Tubbataha Reefs Natural Park (TRNP), a fully no-take MPA enacted in 1988; and Cagayancillo, …

Building Heat-Resilient Caribbean Reefs: Integrating Thermal Thresholds And Coral Colonies Selection In Restoration, Macarena Blanco Pimentel, Johanna Calle-Triviño, Daniel J. Barshis, Sancia E. T. Van Der Meij, Megan K. Morikawa

Biological Sciences Faculty Publications

Caribbean reefs face increasingly frequent and intense bleaching events, adding to the numerous other threats impacting these ecosystems. Addressing these challenges requires global action to reduce climate drivers, along with local efforts like reef restoration. Active restoration using thermotolerant coral colonies offers a potential strategy to alleviate these impacts; however, gaps remain in identifying context-specific temperature thresholds to guide colony selection and standardize thermotolerance assessment methods. This study addressed these gaps in two phases. First, by determining practical thresholds to differentiate species responses to heat stress; and second, by developing a framework to identify and prioritize resilient colonies for restoration. …

Oxidation Camouflages Terrestrial Organic Matter To Appear Marine-Like, Aleksandar I. Goranov, Susan J. Carter, Ann Pearson, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

The export of terrestrial organic matter (TOM) to the ocean has been traditionally viewed to be minimal or only of significance in near-coastal continental margins. The broadly accepted explanation for the widespread loss of terrestrial lignin biomarkers and apparent disappearance of the <-25‰ stable carbon isotopic signature (δ¹³C) of TOM is that TOM is almost fully degraded before reaching the open ocean. Oceanic carbon (δ¹³C value ≥ -22‰) is therefore thought to be derived primarily from algae. However, an alternative explanation for the different molecular and δ¹³C signatures in terrestrial and marine environments may be that oxidative processing transforms TOM to appear marine-like. To test this hypothesis, we subjected eight TOM samples to a strong oxidation gradient. At carbon losses typical of TOM degradation during transport and sedimentation (above 60%), the differentiators of provenance disappeared, leaving a residue that was marine-like both chemically (aliphatic- and nitrogen-rich) and isotopically (δ¹³C enrichment of 4 to 9‰). This challenges the validity of conventional two-endmember mixing models, suggesting that a much larger fraction than previously estimated of the organic matter found in the ocean may originate from terrestrial sources, impacting global models of carbon cycling and sequestration.

Amphiphilic Tripodal Metalloligands: Synthesis, Coordination Chemistry And Preliminary Catalysis, Austin W. Medley, Paul D. Miller, Craig A. Bayse, Robert D. Pike, Trandon A. Bender

Chemistry & Biochemistry Faculty Publications

Triscatecholate binding has been widely studied in the context of biological systems, supramolecular chemistry, and weak aggregate interactions. However, the utilization of the triscatecholate binding motif for the preparation of metalloligands remains unexplored. Herein, we report the synthesis, structural characterization, and functional studies of a triscatecholate ligand with an appended pyridyl residue as a candidate for such applications. Our findings reveal that the selective formation of cis-triscatecholate-based metalloligands is influenced by electronic effects on the catecholate anions, enabling the targeted synthesis of Al(III), Ga(III), and In(III) triscatecholate metalloligands capable of binding Zn(II) and Ru(II) at the appended pyridyl moiety for …

Twenty Years Of Global Stratospheric Fluorine Inventories From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements, N. Raymond, P. Bernath, C. Boone, M. Chipperfield

Chemistry & Biochemistry Faculty Publications

We present fluorine inventories calculated for twenty years (2004–2023) and five latitude bands (82°–60°N, 60°–30°N, 30°N–30°S, 30°–60°S, and 60°–82°S) at altitudes from the surface up to 55 km. The inventories were calculated using the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE‐FTS) version 5.2 retrievals of the volume mixing ratios (VMRs) of 15 fluorine‐containing species. Of these 15 species, 3 are product gases: HF, COF₂, COCIF, and 12 are source gases: SF₆, PFC-14 (CF₄), CFC-11 (CCl₃F), CFC-12 (CCl₂F₂), CFC-113 (CCIF₂CCl₂F), HCFC-22 (CHF₂CL), HCFC-141b(C₂H₃Cl₂F), HCFC-142b ( …

The Influence Of Shopping Context And Anthropocentric Bias On Consumer Preferences For Human And Ai Designers In Fashion, Dooyoung Choi, Ha Kyung Lee, Christina Soyoung Song, Ji Young Lee

Educational Leadership & Workforce Development Faculty Publications

This study explores how shopping contexts (hedonic vs. utilitarian) influence consumer preferences for AI- vs. human-designed fashion products. In Study 1, participants with hedonic motivations preferred human-designed items, while those with utilitarian motivations preferred AI-designed products, supporting the hypothesis that shopping context affects designer preferences. Study 2 further investigates the mediation of competence-warmth traits in designer preferences and the moderation of anthropocentric bias. It finds that hedonic shopping contexts increase the desire for warmth-related traits, leading to a preference for human designers, while utilitarian contexts favor competence-related traits and AI designs. Additionally, individuals with higher anthropocentric biases showed stronger preferences …

Artificial Intelligence In Achieving Sustainable Development: Expectations Of Undergraduate Students, Jinhee Kim

STEMPS Faculty Publications

While there has been ample discussion regarding Artificial Intelligence (AI)’s contributions and challenges on the development agenda at the policy level, little is known about how students translate the potential and barriers of AI in achieving Sustainable Development Goals (SDGs). Drawing upon various qualitative data, including class observation, focus group interviews, and learning activity outcomes generated by 240 students across 7 different majors, this case study explores the expected roles of AI as well as barriers to AI adoption for sustainable development perceived by undergraduate students. The study revealed that students anticipated AI to play diverse roles, including data analyst, …

The Strategic And Governance Implications Of Solar Radiation Modification: Perspectives From Delegates Of International Climate Negotiations, Todd L. Cherry, Steffen Kallbekken, David M. Mcevoy, Wai Yan Siu

ODU Articles

The lack of progress in addressing climate change has led to increased interest in solar radiation modification (SRM)—a collection of large-scale interventions that cool the planet by managing the amount of solar radiation that reaches the earth. SRM complicates climate change governance because, in addition to advancing collective action to reduce greenhouse gas emissions, governance needs to restrain unilateral SRM action while balancing diverging actor interests, ethical risks and scientific uncertainty. We survey international climate policy experts for their assessments of the potential for effective global governance of SRM and the likelihood of possible international responses to unilateral SRM scenarios. …

Coastal Flooding And Housing Market Liquidity: Policy Implications For Eastern U. S. Communities, Wai Yan Siu, Rex Sitti

ODU Articles

Coastal flooding poses an escalating threat to communities across the U.S East Coast, where rising sea levels and intensifying storms increasingly overwhelm existing infrastructure and natural defenses. These events generate complex economic consequences that extend beyond immediate property damage to affect community stability and long-term development patterns. The real estate industry in particular, faces increasing levels of flood risk. Existing research on climate risk and real estate markets focuses predominantly on price capitalization effects, overlooking the critical dimension of housing market liquidity. This study examines the causal impact of coastal flooding on days-on-market (DOM), a metric of liquidity in the …

High-Resolution Modeling Of Extreme Heat Events With Socioeconomic Consideration: A Real-Case Wrf-Les Approach, Maryam Golbazi, Frank Liu, Yin-Hsuen Chen, Timothy W. Juliano, Heather Richter

ODU Articles

The overarching goals of this work is to explore best practices for micro-scale modeling of a real case, identify relevant phenomena by using high-resolution modeling, and to explore their implications for public health, and climate resilience strategies in Hampton Roads, VA, USA. This project employs the Weather Research and Forecasting (WRF) model to conduct a comprehensive study of Hampton Roads, utilizing a coupled mesoscale to microscale modeling capable of resolving boundary layer turbulence. This study has three primary objectives: (1) to establish the optimal mesoscale to Large-Eddy Simulation (LES) configurations for complex geographical regions such as the Hampton Roads (HR) …

Using Virtual Reality To Assist Students At Academic Risk In Human Anatomy, Michael Foley, Lauren T. Lilley, Lindsay Meyers, Robert Armstrong, Lisa Fore-Arcand, Kelly Mccoy, Chad Eitel, Tod R. Clapp, Natascha Heise

Department of Pathology & Anatomy Faculty Publications

Learning human anatomy presents a significant challenge for health profession students due to the difficulty in visualizing structures in three dimensions. Virtual reality (VR) has been reported to aid in understanding these relationships. In this study, students at academic risk attended VR sessions alongside their gross anatomy course. Data from post-surveys, observations, and examinations indicated VR participants performed similarly to peers, except in head/neck and pelvis/lower limb exams where performance was lower. Students valued VR for enhancing confidence and understanding. VR shows promise in supplementing anatomy education, particularly for less complex regions, and bridging gaps in traditional learning methods.

Analysing Nontraditional Students' Chatgpt Interaction, Engagement, Self-Efficacy And Performance: A Mixed-Methods Approach, Mohan Yang, Shiyan Jiang, Belle Li, Kristin Herman, Tian Luo, Shanan Chappell Moots, Nolan Lovett

STEMPS Faculty Publications

Generative artificial intelligence brings opportunities and unique challenges to nontraditional higher education students, stemming, in part, from the experience of the digital divide. Providing access and practice is critical to bridge this divide and equip students with needed digital competencies. This mixed-methods study investigated how nontraditional higher education students interact with ChatGPT in multiple courses and examined relationships between ChatGPT interactions, engagement, self-efficacy and performance. Data were collected from 73 undergraduate and graduate students through chat logs, course reflections and artefacts, surveys and interviews. ChatGPT interactions were analysed using four metrics: prompt number, depth of knowledge (DoK), prompt relevance and …

Improving Understanding And Connections For Preparedness, Mitigation, Response, And Recovery For Tornado And Straight-Line Wind Events In Virginia: Summary Of The Inaugural Virginia Tornado And Straight-Line Wind Summit, Wie Yusuf, Monica Arul, Joshua Behr, Kaleen Lawsure, An Huy Pham, Henry Attivor

School of Public Service Faculty Publications

Background

The Virginia Tornado and Straight-Line Wind Summit, the first of its kind in the Commonwealth, was held on October 15, 2025 in Isle of Wight County, Virginia. The Summit had several goals, including:

• Understanding Virginia’s wind risk and learning the science behind it.
• Hearing lessons learned from emergency managers who have experienced extreme wind events.
• Learning about practical steps to prepare, mitigate, and respond to severe wind events.
• Learning best practices for timely and actionable communication with the public before and after events.
• Strengthening interagency coordination and connecting with others to share resources, align priorities, and coordinate resilience planning. …

Ai-Generated Messaging For Life Events Using Structured Prompts: A Comparative Study Of Gpt With Human Experts And Machine Learning, Christopher Lynch, Erik Jensen, Ross Gore, Virginia Zamponi, Kevin O'Brien, Brandon Feldhaus, Katherine Smith, Joseph Martínez, Madison H. Munro, Timur E. Ozkose, Tugce B. Gundogdu, Ann Marie Reinhold, Hamdi Kavak, Barry Ezell

VMASC Publications

Large Language Models (LLMs) play an increasingly integrated and pivotal role in generating diverse types of texts, such as social media messages, emails, narratives, and technical reports, among other textual communication forms. As AI-generated messaging filters into human communication, a systematic exploration of their effectiveness for mimicking human-like communication of life events is needed. In this study, we employ a zero-shot structured narrative prompt to generate 24,000 life event messages for birth, death, hiring, and firing events using OpenAI's GPT-4. From this dataset, we manually classify 2880 messages and evaluate their validity in conveying these life events through the form …

Guiding Evolutionary Algorithms With Large Language Models To Learn Fuzzy Cognitive Maps, Ryan Schuerkamp, Philippe J. Giabbanelli

VMASC Publications

Fuzzy Cognitive Maps (FCMs) are interpretable simulation models that represent causal relationships between concepts as a weighted digraph with labeled nodes. They serve to examine a system’s structure (e.g., what concepts are critical to spreading an intervention’s effects?) and long-term behavior (e.g., if we increase fruit availability, how will its consumption change?). When modelers build FCMs by leveraging participants’ knowledge, the resulting participant-built FCMs can be analyzed and interpreted since participants report perceived causality. However, engaging enough knowledgeable participants to construct an FCM can be challenging. Alternatively, machine learning algorithms derive FCMs from data by selecting relationships to maximize a …

Utilizing Artificial Intelligence As A Strategic Risk Management Tool For Public Sector Operations And Auditing Processes, Oğuz Ümit Tamer, Bruce D. Mcdonald Iii, Farouk Hemici, Georgia Kontogeorga

School of Public Service Faculty Publications

Symbolizing a significant turning point in the historical landscape, AI is becoming an effective tool in today's public administration, not only for increasing capacity, quality, and speed in services, but also for strategic risk management. Regulators and algorithmic auditing play a central role in implementing fairness, transparency, and persistent controls against risks in AI systems. Discussing modern applications of AI, such as anomaly-based fraud detection, resource estimation, and continuous auditing, and their respective strengths and weaknesses, this study concludes that AI significantly enhances efficiency and oversight but also poses the risk of enshrining bias, opacity, and accountability gaps. By considering …