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Investigation Of The Octene-Decane-Urea Adduct Equilibrium System, Frederick Charles Guest

Theses

Concentrations of equilibrium mixtures formed by adding increments of octene to a solution of urea in methanol to form adduct are reported.

Calorimetric studies indicate that the addition of octene to a urea-methanol solution shows an endothermic heat effect prior to the formation of solid adduct. The heat effect becomes exothermic as solid adduct is formed.

Addition of decane to an equilibrium octene-urea adduct system increased octene concentration in the supernatent liquid, indicating an octene release from the original adduct as decane adduct was formed.

The order in which decane and octene were added to form the decane-octene-urea adduct system …

Activity Coefficient For Infinite Dilute Solution By Gas-Liquid Chromotography, Suresh Jivabhai Patel

Theses

Gas-liquid partition chromatography has been used to determine the activity coefficient for very dilute solutions of solute in non-volatile solvents.

Other, more classical methods of determining the activity coefficient are laborious and are neither as accurtate nor as precise as desired.

The systems studied were:

(1) Benzene-Dinonyl Phthalate

(2) Cyclohexane-Dinonyl Phthalate

(3) Benzene-Squalane

(4) Cyclohexane-Squalane

All systems were studied over the column temperature range of 50° to 110°C with constant pressure and sample size. A study was also made on the effect of column pressure at constant temperature and sample size. One system was studied with variable sample size but …

Nucleus 1965, Newark College Of Engineering

Yearbooks

This is a digitized, downloadable version of the Newark College of Engineering Nucleus.

Planning And Scheduling Software Programs With Pert, Henry E. Mielo

Theses

The use of the Program Evaluation and Review Technique (PERT) in planning and scheduling software programs was discussed in this thesis. A real world program, referred to as the Wrap-Around Simulation or WAS Project, was selected to illustrate that complex efforts in the software domain can respond favorably to modern planning and scheduling techniques

The WAS Project included the provision of a digital simulation of the shipboard environment in which a Digital Fire Control Computer (DFCC) would operate as part of a Digital Fire Control System. The digital simulation afforded a well controlled and conclusive checkout of the operational program …

Newark College Of Engineering Graduate Courses 1965-1966, New Jersey Institute Of Technology

Course Catalogs

No abstract provided.

The Bulletin: Newark College Of Engineering Bulletin Of Undergraduate Day And Evening Programs 1965-1966, New Jersey Institute Of Technology

Course Catalogs

No abstract provided.

Interphase Gas-Liquid Mass Transfer Study In A Horizontal Channel, Bruce R. Marx

Theses

The rate of transfer of hydrogen sulfide and of carbon dioxide from an atmosphere of the gas saturated with water to a flowing stream of water in a horizontal channel was investigated over a range of water flow velocities and absolute pressures.

Mathematical models describing the system in terms of the penetration and boundary layer theories were inadequate when used to calculate the diffusivity of each gas in water at various conditions. The results of the hydrogen sulfide-water system study shows a relationship between the diffusivity, the interfacial concentration and the liquid flow rate. The calculated diffusivity of the carbon …

Decomposition Of Diacetone Alcohol In Packed Beds Of Ion Exchange Resins, Arthur Donald Lahr, Rafael Juan Puente-Duany

Theses

A study was made of the rate of decomposition of diacetone alcohol by anion exchange resins in a packed bed under adiabatic and isothermal conditions. Two different resins were compared: a conventional type gel structure resin, Amberlite IRA-400, and a newly marketed maorore-ticular resin, Amberlyst A-26.

In a substrate with low water content, the rate of decomposition of diacetone alcohol by Amberlite IRA-400 vas controlled by intraparticle diffusion. This vas due to shrinkage of the polymer chain matrix of the resin. When dry diacetone alcohol feed was introduced the amount of decomposition was not measurable.

It was found that the …

Gas Phase Fugacity Coefficients, Harvey Joel Klee

Theses

A method is presented for calculation of fugacity coefficients in gas mixtures. This work is based on a recent paper by Leland, Gamson, and Chappelear, wherein they presented a new method for evaluation of ideal K values. The information required for the method presented here includes pure component physical properties, and generalized tables or equations for compressibility factors, fugacity coefficients, and real gas enthalpy departure terms. Pseudo-critical temperatures and pressures for the mixture are calculated using the expressions presented by Leland and Mueller.

Five different binary systems consisting of paraffin hydro-carbon and CO₂ mixtures containing 318 separate points were …

Salt Effects In Liquid-Liquid Equilibria, Edwin Otto Eisen

Dissertations

The effect of lithium chloride, sodium chloride and potassium chloride on the distribution of acetic acid, propionic acid and butyric acid between benzene and water at 25° C has been studied. The method of Hand, which has previously been used to correlate tie line data in salt-free ternary systems, has now been successfully employed to correlate distribution data for quaternary systems containing salt.

The slope and intercept of the Hand equations have been expressed as linear functions of the salt concentration in each system studied. Equations for slope and intercept possessing high statistical significance have been formulated using a linear …

Nucleus 1964, Newark College Of Engineering

Yearbooks

This is a digitized, downloadable version of the Newark College of Engineering Nucleus.

The Bulletin: Newark College Of Engineering Bulletin Of Graduate Courses 1964-1965, New Jersey Institute Of Technology

Course Catalogs

No abstract provided.

The Bulletin, Newark College Of Engineering Undergraduate Courses 1964-1965, New Jersey Institute Of Technology

Course Catalogs

No abstract provided.

Prediction Of Extruder Performance For Thermoplastic Materials, Aldo Bergonzoni

Theses

The object of this thesis was to predict the output of an extruder, for thermoplastic materials, by using simplified equations relating output to screw speed and screw geometry.

Three different extruders were used for this purpose and several addition-type polymers were studied. These materials included: stabilized and unstabilized polypropylene, low-density and high-density polyethylene, general-purpose polystyrene and rubber-modified poly-styrene.

The results obtained show that, by using relatively low screw speeds (up to 140 r.p.m.), shallow screw channels and back pressures at the die up to 2000 psig., a theoretical output can be calculated with a maximum deviation from the experimental data …

Application Of Transient Response Analysis To An Automatically Controlled Liquid Level System, Armando Anthony Gregoli

Theses

System instability or poor control are problems which occur in commercial automatically controlled liquid level installations. A simple level control system was constructed to define the parameters which affect a level control system response. Special problems which occur in commercial installations were evaluated.

The system parameters were defined. To simplify the mathematical analysis, a negligible measurement and controller time constant were assumed. These were later shown to be reasonable assumptions. Transfer functions were derived for each component and were used to describe the system response. The system response was predicted by transient response analysis and compared with experimental results. An …

A Correlation Of Viscosity Of N-Paraffin Hydro-Carbons, Sheldon Krueger

Theses

A linear relationship between the Log viscosity and the Log vapor pressure is shown to exist for each n-paraffin hydrocarbon from C₃ to C₂₀. The average error of these equation e is ± 1.5 per cent of the American Petroleum Institute's¹ experimental values. The use of individual slopes for each equation is shown to be store accurate than one alone for all the viscosity data. These slopes e:thibit an unusual behavior by having a minimum value at undecane.

The slopes and intercepts are correlated with carbon number (the number of atoms in a n-paraffin Chain). These …

Viscosity Of A Three Component System : Benzene-Ethanol-Acetic Acid At 20 Degrees C., 25 Degrees C., And 30 Degrees C, Alan Alvin Schetelich

Theses

The viscosity for the ternary system benzene-ethanol-acetic acid, has been determined. The viscosity maximum shown in the ethanol-acetic acid system is clearly distinguished in the ternary system as well. The viscosity minima which occur in the benzene-ethanol, and benzene-acetic acid systems are too slight to be readily apparent in the ternary system.

The ternary system viscosity was determined at temperatures of 20, 25, and 30° C. The effect of increasing the temperature from 20° C for the ternary system was to produce corresponding curves of lower viscosity. The maximum viscosity noted in the ternary system as well as the maximum …

Equations Of State For Propyne, Thomas Marshall Stark

Theses

P-V-T data for propyne have been fit using the Martin-Hou and the Benedict-Webb-Rubin equations of state. The Martin-Hou equation, with its constants calculated from the critical properties and a vapor pressure point for the gas, fit up to 1.1 to 1.5 times the critical density with deviations of less than 1%. The Benedict-Webb-Rubin equation, with its constants calculated by the method of Joffe, resulted in greater deviations in the low pressure region than did the Martin-Hou equation; however, it also provided a better approximation of the data at high pressures and lower temperatures. The best over-all fit was obtained using …

Nucleus 1963, Newark College Of Engineering

Yearbooks

This is a digitized, downloadable version of the Newark College of Engineering Nucleus.

The Investigation Of Frequency Response And Stability Of A Heat Exchanger Under Condensate Control, Louis F. Fornoff

Theses

Control of a condensing steam heat exchanger by condensate throttling was investigated theoretically by a frequency response analysis. The theoretical analysis was verified by experimental operation of the heat exchanger.

The system was characterized by heat transfer calculations and Laplace transform functions. The transfer functions were used to complete a frequency response analysis of the system which predicted the controller settings, the stability of the system and its response to a step set point change. The calculations were verified by experimental operation and reasonable agreement was obtained.

It was calculated that condensate throttling can be used to obtain stable control …

Prediction Of Ternary Azeotropes From Binary Data, Eric Lustig

Theses

The Margules equation as modified by Wohl for ternary liquid-vapor systems, is used to develop ternary activity coefficients at different concentrations and varying temperatures. Corresponding binary experimental data are necessary to mathematically obtain these ternary activity coefficients. A trial and error graphical technique is used to examine the ternary data for azeotropic conditions. Convergence on ternary graph paper can be easily detected after the first two trials. Divergence is an indication that the system under consideration is nonazeotropic.

Most of the azeotropic systems investigated agreed quite well with published data. The range of disagreement of concentrations for component a in …

Isobaric Vapor-Liquid Equilibria System : Benzene, Chlorobenzene, Phenol, Larry Madestau

Theses

Isobaric vapor-liquid equilibria were determined experimentally for the three binary systems benzene-chlorobenzene, benzene-phenol, and chlorobenzene-phenol; and for the corresponding ternary system benzene-chlorobenzene-phenol. Constants for the Chao modified Redlich-Kistler equations were calculated from the experimental data by the method of least squares. These constants were then used to predict vapor-liquid equilibria for the ternary system. The predicted values showed satisfactory agreement with those found experimentally.

A modified Ellis still was used for obtaining equilibrium data. Samples of vapor and liquid phases were analyzed by means of the F & M Model 720 vapor phase chromatograph. Benzene, chlorobenzene, and phenol used in …

The Bulletin, Newark College Of Engineering Undergraduate Courses 1963-1964, New Jersey Institute Of Technology

Course Catalogs

No abstract provided.

The Bulletin: Newark College Of Engineering Bulletin Of Graduate Courses 1963-1964, New Jersey Institute Of Technology

Course Catalogs

No abstract provided.

Vapor-Liquid Equilibria System : Carbon Tetra-Chloride, Toluene, N-Heptane, Joel Philip Pearlstein

Theses

A study was made of the vapor-liquid equilibria of the ternary system: carbon tetrachloride (CCl₄), n-Heptane (C₇H₁₆) and Toluene (C₇H₈). An Othmer still was used for the determination of the equilibria and the liquid and vapor compositions were ascertained by refractive index and density measurements. A comparison between experimental values and theoretical values was made using the Margules 3-suffix ternary equations for the correlation. Although the Margules equations did not correlate the experimental data very well, this is most likely due to the fact that the ternary solution was close …

The Stability And Response Of An Automatically Controlled Liquid Level System, Milton Kalman Rosen

Theses

Stability and response of automatically controlled liquid level systems was investigated theoretically by transient and frequency response analysis and experimentally on a laboratory liquid level system.

Transfer functions were derived for each component and were used to describe the response of the experimental system. The effect of measurement time constants on system performance was experimentally investigated. Poor control, but not instability, resulted from an increase in measurement time constant. The behavior of the system at various operating loads was determined experimentally. The system was unstable at the maximum measureable flow rate, but stable at all other loads. Theoretical response curves …

Program Evaluation And Review Technique, Anthony Immaculate Agresta

Theses

The problem of planning, controling and evaluating complex projects both engineering and non-engineering has existed as long as the projects themselves. In the past the approach of management to this problem has been one which was based heavily on the use of historical information. There have been very few attempts to predict and control the occurrence of the objective event of these projects.

This thesis deals with a review of this problem and a new approach to the planning, control, and evaluation of these complex projects. This new approach is the Program Evaluation and Review Technique (PERT) which was developed …

The Evaluation Of A Three Mode Temperature Controller By Pulse Techniques, Sanford Allen Schram

Theses

Work was performed to evaluate a commercial three mode temperature controller by pulse techniques. The extensive calculations were performed on an I. B. M. 1620 general purpose computer. Bode diagrams are presented to graphically show the instrument's dynamic response. The conclusions reached are as follows:

1. Pulse tests provide a quick method of testing the dynamic response of instruments.

2. A computer should be used for the efficient calculation of results from pulse tests.

3. Limitations of pulse tests are not yet defined but it appears that an increase in the energy of the input pulse leads to an increase …

Modified Coates-Orr Vapor-Liquid Equilibrium Still : The Effect Of Pressure On Binary Azeotropes, John K. Jacob

Theses

In order to test the effect of pressure on binary azeotropes, an all stainless steel Coates-Orr vapor-liquid equilibrium still was constructed and then tested at atmospheric and superatmospheric pressure. To overcome operating difficulties at superatmospheric pressures, it was necessary to modify the original still design by (1) coiling a Nichrome resistance wire around the entire still body and insulating heavily over the coil, (2) substituting a "canned" seal-less pump in place of the original centrifugal pump.

A survey of the literature shows that the difficult-to-operate Jones-type equilibrium stills, from which the Coates-Orr still was developed, approach true phase equilibrium. Therefore, …

Properties Of Non-Newtonian Fluids, George Robert Ferment

Theses

The purpose of this work was to investigate the fluid properties of non-Newtonian solutions.

The effect of temperature on the viscometric properties, flow behavior index (n) and fluid consistency index (K), was investigated. It was established that the flow behavior index was temperature dependent, tending to approach Newtonian behavior as the temperature was raised. The fluid consistency index was also temperature dependent; a plot of K vs temperature will yield a straight line on semilogarithmic coordinates.

The specific heats of non-Newtonian solutions were also determined. For systems containing large mass fractions of water, it was established that the presence of …