Digital Commons Network^™

Functionalized Nanoporous Carbon Scaffolds For Hydrogen Storage Applications, Christopher L. Carr

Doctoral Dissertations

"Recent efforts have demonstrated confinement in porous scaffolds at the nanoscale can alter the hydrogen sorption properties of metal hydrides, though not to an extent feasible for use in onboard hydrogen storage applications, proposing the need for a method allowing further modifications. The work presented here explores how the functionalization of nanoporous carbon scaffold surfaces with heteroatoms can modify the hydrogen sorption properties of confined metal hydrides in relation to non-functionalized scaffolds (FS). Investigations of nanoconfined LiBH₄ and NaAlH₄ indicate functionalizing the carbon scaffold surface with nitrogen can shift the activation energy of hydrogen desorption in excess of …

Critical Buckling And Post-Buckling Behavior Of Thin-Walled Liners Encased By Underground Pipelines In Saturated Soils, Zhaochao Li

Doctoral Dissertations

"This study aims to investigate the structural stability of thin-walled liners encased in functionally-obsolete underground pipelines in saturated soil under external hydrostatic pressure, a concentrated load, temperature change or their combination, and develop a simplified circular arch model of thin-walled liners when not constrained by the pipelines. The friction and adhesion on the interface between a liner and its constraining surface (pipeline or grouting), and the pressure gradient on deeply-buried pipelines are neglected. The critical buckling load of elastic liners is analytically derived under a plane strain condition using the principle of minimum potential energy. The analytical solution is either …

Crustal Structure Beneath The Eastern Margin Of The Tibetan Plateau And Adjacent Areas From Receiver Function Stacking And Gravity Modeling, Yunxin Peng

Doctoral Dissertations

"To provide constraints on the mechanisms responsible for the uplift and crustal thickening of the eastern Tibetan Plateau, the thickness and Vp/Vs values of the Moho beneath 153 seismic stations are obtained by stacking P-to-S converted phases from the Moho and gravity modeling. The resulting crustal thickness generally decreases from the northwest to the south-east, from about 60 km in the Bayan Har Block to 30 km in the Sichuan Basin. The crustal Vp/Vs measurements in the Qinling Orogenic Belt, Bayan Har Block, Chuxiong Basin, and Yangtze Platform indicate an overall intermediate to felsic crustal composition. With a relatively thick …

Engineering Zeolite Catalysts Through Porosity And Surface Acidity Control For Selective Production Of Light Olefins, Xin Li

Doctoral Dissertations

"Zeolites are broadly used as heterogeneous catalysts in various chemical and petrochemical industries to produce value-added chemicals and fuels, mainly due to their large surface area, acid-base properties, high thermal stability, and excellent shape-selectivity. In this dissertation, various zeolite catalysts were engineered through fine-tuning micro-meso-macro-porosity and surface acidity. The engineered zeolites were used as heterogeneous catalysts for production of light olefins such as ethylene and propylene through alcohol dehydration and hydrocarbon cracking reactions.

To control the zeolite porosity and acidity, SAPO-34@ZSM-5 and SAPO-34@Silicalite-1 composites with core-shell structure were synthesized and evaluated in ethanol dehydration reaction. Analysis of catalytic performance revealed …

Long-Term Behavior Of Fiber Reinforced Polymer (Frp) Confined Concrete Cylinders Subjected To Severe Weather And Seawater Solution Conditions, Song Wang

Doctoral Dissertations

"This study presents an experimental investigation on durability of fiber-reinforced polymer (FRP) confined concrete cylinders subjected to various environmental conditions. Two types of cylinders were tested in this experiment: concrete-filled FRP tube (CFFT) and hollow-core FRP-concrete-steel (HC-FCS), with FRP tubes having two different constitutive resin components: polyester and epoxy. The specimens were subjected to three different environmental conditions: combined freeze/thaw, wet/dry and heating/cooling cycles with options of continuous water immersion and sustained axial load in an environmental chamber, UV exposure in an UV chamber, and seawater immersion in water tanks with sustained axial load. Mechanical and material characterization tests were …

Atomic Layer Deposition Prepared Nanostructured Materials For Various Catalytic Reactions, Xiaofeng Wang

Doctoral Dissertations

"Atomic layer deposition (ALD) has been widely used for thin film coating and metal nanoparticles (NPs) preparation. In this report, the applications of ALD prepared nanostructured materials in catalysis were examined.

Highly dispersed Pt monometallic catalysts with different substrates and multi-walled carbon nanotubes (MWCNTs) supported Pt-Co bimetallic catalysts were synthesized by ALD for selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols (UA). Pt/MWCNTs showed the highest selectivity of UA in selective hydrogenation of citral, as compared to Pt/SiO₂, Pt/ALD-Al₂O₃, and Pt/γ-Al₂O₃. After adding Co, the highest selectivity was achieved …

Design For Optical Metamaterial Design For Optical Metamaterial Absorber, Huixu Deng

Doctoral Dissertations

“Optical metamaterlal (MM) absorbers in the visible or near-infrared range have been widely investigated in these years since they are crucial in many promising applications, such as solar energy harvesting systems, thermo-photovoltaic energy conversion devices, thermal imaging and emissivity control. This dissertation aims to design and investigate various optical metamaterial absorbers based on different mechanisms and theories, such as cavity resonance, impedance match, equivalent circuit model and waveguide stop light mode. First, via utilizing the cavity resonance, a tunable narrowband MM absorber/emitter for thermophotovoltaic (TPV) is designed and analyzed based on gold nanowire cavities to improve the overall efficiency of …

Micro-Slotting Technique For Measurement Of Local Residual Stress In Metallic Materials, Elizabeth Anne Burns

Doctoral Dissertations

"Micro-slotting, a micro-scale relaxation residual stress measurement technique, has been shown in recent years to be a reliable method for measuring local residual stresses in metallic materials. This technique employs an SEM-focused ion beam system for milling and imaging, digital image correlation software to track displacements due to residual stress relaxation, and finite element analysis for interpolation of the original local stress state. In this research, a micro-slotting procedure was established using finite element models and was used to obtain sub-surface residual stress measurements on machined and shot peened planar Ti-6Al-4V samples. These measurements were compared to macro-scale XRD residual …

Design And Characterization Of Multi-Spectral Underwater Beam-Port For Pool-Type Research Reactors, Meshari Mesfer Alqahtani

Doctoral Dissertations

“The beam-port is a cardinal facility at research reactors necessary for dry irradiation, testing and measurement experiments. The Missouri University of Science and Technology Reactor (MSTR) is one such reactor with a beam-port. Installation of additional beam-port in such reactor facilities can be prohibitive. A novel remedy to this is an underwater beam-port for pool-type reactors. The design and characterization of a conceptual underwater multi-spectral beam-port for neutron and gamma fluxes were completed for the MSTR. The neutron spectra from the MSTR were simulated using the Monte Carlo N-particle (MCNP). The determined neutron spectra were experimentally validated using SAND-II. The …

Quantitative Phase-Field Modeling Of Crack Propagation In Multi-Phase Materials, Arezoo Emdadi

Doctoral Dissertations

”Research presented in this dissertation is focused on developing and validating a computational framework for study of crack propagation in polycrystalline composite ceramics capable of designing micro-architectures of phases to improve fracture toughness and damage tolerance of ZrB₂-based ultra-high temperature ceramics (UHTCs). A quantitative phase-field model based on the regularized formulation of Griffith’s theory is presented for crack propagation in homogenous and heterogeneous brittle materials. This model utilizes correction parameters in the total free energy functional and mechanical equilibrium equation within the crack diffusive area to ensure that the maximum stress in front of the crack tip is …

Synthesis And Comprehensive Studies Of Nanogels For Enhanced Oil Recovery, Jiaming Geng

Doctoral Dissertations

“Nanomaterials have been developed and applied for enhanced oil recovery (EOR) in oil industry. Among the developed nanomaterials, nano-sized crosslinked polymeric gel particles (nanogels) have shown the potential in improving both the macro- and micro-displacing efficiency. This dissertation focuses on the synthesis and the potential EOR mechanisms of nanogels. Nanogels with positive, negative, and neutral charges were synthesized through suspension polymerization. The morphology, size distribution, and zeta potential of nanogels were elucidated by corresponding technologies, such as scanning electron microscopy and dynamic light scattering. The ability of nanogels in oil-water interfacial tension (IFT) reduction and oil-in-water (o/w) emulsion stabilization was …

Exploring The Use Of A Time-Frequency Domain Technique For The Filtering Of Acoustic Emission/Microseismic Data, Charles Mborah, Maochen Ge, Zhigang Wang

Mining Engineering Faculty Research & Creative Works

The performance of acoustic emission/micro seismic (AE/MS) monitoring systems in mines is greatly impacted by background noise interference. Mine trucks/vehicles, fans, blasting and electrical spikes generate noise which negatively affect AE/MS signal quality. Using such datasets without filtering may lead to inaccurate determination of first arrivals and hence wrong source location. Also, data contaminated with noise makes manual identification and picking of the first arrivals impossible or difficult to achieve. This paper explored the use of stationary discrete wavelet transform as a filter to augment noise reduction on mine AE/MS data. The output of a test run on both noisy …

Inorganic Biodegradable Substrates For Devices And Systems, Chang-Soo Kim, Richard K. Brow, D. E. Day

Electrical and Computer Engineering Faculty Research & Creative Works

Disclosed are biodegradable glass substrates that are useful as functional elements of solid-state devices. In particular, biodegradable glass substrates having a rapidly degradable glass and a slowly degradable glass provide a structural platform that completely dissolves following a desired operational lifetime of devices such as implanted electronic devices, implanted sensor devices, and optical fibers.

Agenda For The Fifth Meeting Of The Forum On Soil Dynamics, Shamsher Prakash

Forum for Promotion of Soil Dynamics in India

No abstract provided.

Membership Of Forum For Promotion Of Soil Dynamics In India, Shamsher Prakash

Forum for Promotion of Soil Dynamics in India

No abstract provided.

Minutes Of The Fifth Meeting Of The Forum For Promotion Of Soil Dynamics In India, Shamsher Prakash

Forum for Promotion of Soil Dynamics in India

No abstract provided.

Infrastructure, Urban Sprawl, And Naturally-Occurring Asbestos: An Ontological Thought Model For Wicked And Saving Technologies, Shane Ray Epting

Arts, Languages and Philosophy Faculty Research & Creative Works

Recently, geologists in Southern Nevada discovered new deposits of naturally occurring asbestos and microscopic fibers in rocks and soil. The danger is that inhaling them can lead to mesothelioma. One problem is that this rare cancer often takes decades to manifest. This discovery abruptly stalled a highway project near Las Vegas. Due to this condition, management developed numerous protocols to keep workers safe. Using this case as a "thought model," the author challenges an established way of categorizing kinds of technologies as they relate to the concept of being. In turn, this thought model reveals that climate change alters the …

Tensorviz: Visualizing The Training Of Convolutional Neural Network Using Paraview, Xinyu Chen, Qiang Guan, Xin Liang, Li-Ta Lo, Simon Su, Trilce Estrada, James Ahrens

Computer Science Faculty Research & Creative Works

Deep Convolutional Networks have been very successful in visual recognition tasks recently. Previous works visualize learned features at different layers o help people to understand how CNNs learn visual recognition tasks. However they do not help to accelerate the training process. We use Paraview to provides both qualitative and quantitative visualization that help understand the learning procedure, tune the learning parameters and direct merging and pruning of neural networks.

The Effect Of Z-Binding Yarns On The Electrical Properties Of 3d Woven Composites, Mohamed Nasr Saleh, Arief Yudhanto, Gilles Lubineau, Constantinos Soutis

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Electrical resistance monitoring (ERM) has been used to study the effect of the z-binding yarns on the initial electrical resistance (ER) and its change of three architectures of 3D woven carbon fiber composites namely (orthogonal "ORT", layer-to-layer "LTL" and angle interlock "AI") when tested in tension. Specimens are loaded in on-axis "warp" and off-axis "45°" directions. In situ ERM is achieved using the four-probe technique. Monotonic and cyclic "load/unload" tests are performed to investigate the effect of piezo-resistivity and residual plasticity on resistance variation. The resistance increases for the off-axis loaded specimens (∼90%) is found to be higher than that …

Tensorviz: Visualizing The Training Of Convolutional Neural Network Using Paraview (Poster), Xinyu Chen, Qiang Guan, Xin Liang, Li-Ta Lo, Simon Su, Trilce Estrada, James Ahrens

Computer Science Faculty Research & Creative Works

Deep Convolutional Networks have been very successful in visual recognition tasks recently. Lots of previous works aimed to help people to get senses of why those biology-inspired networks achieved such good performances. Deconvnet[1], Guided propagation[2] and a comprehensive visualization tool box[3] can help people to see features learned at different layers of the networks. These works in some extent provided understanding and support for the biology origin of how convolutional networks emulate visual recognition tasks. However, due to the complexity of searching in very high dimensional parameter space, the whole training remains in black-boxes. Normally a large network needs weeks …

Drone-Enabled Remote Sensing For Transportation Infrastructure Assessment, Colin Brooks

INSPIRE Archived Webinars

Unmanned aerial systems (UAS or “drones”) are a rapidly developing technology that can help meet the needs of transportation agencies for reliable, repeatable data that can save money and increase safety for the data collection process. By taking advantage of flexible platforms that can deploy a variety of sensors, transportation agencies and their information suppliers can help meet these data needs for operations, asset management, and other areas. Location-specific data on infrastructure condition and distresses can help with improved management of assets.

In this presentation, recent applied research led by a Michigan Technological University team is reviewed, with a focus …

Factors Affecting The Evolution Of Inclusion Populations During Steelmaking And Casting Processes, Obinna Adaba, Laura Bartlett, Mingzhi Xu, Ronald J. O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Investigations into the evolution of inclusion populations during ladle processing and continuous casting are reviewed. Details of the steelmaking practices employed in BOP and EAF steelmaking have been observed to have a strong influence on the size distribution, quantity, composition, phases and morphology of the final inclusion population delivered to the caster. Examples of the effects of different processing paths on the evolution of inclusion populations are presented. The importance of preexisting inclusion populations on the formation and removal of new inclusion populations is also reviewed and discussed.

Faculty Senate Minutes Dec. 7, 2017, Missouri University Of Science And Technology Faculty Senate

Minutes & Agendas

No abstract provided.

Metabolism And Photolysis Of 2,4-Dinitroanisole In Arabidopsis, Hunter W. Schroer, Xueshu Li, Hans Joachim Lehmler, Craig L. Just

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

New insensitive munitions explosives, including 2,4-dinitroanisole (DNAN), are replacing traditional explosive compounds to protect soldiers and simplify transport logistics. Despite the occupational safety benefits of these new explosives, feasible strategies for cleaning up DNAN from soil and water have not been developed. Here, we evaluate the metabolism of DNAN by the model plant Arabidopsis to determine whether phytoremediation can be used to clean up contaminated sites. Furthermore, we evaluate the role of photodegradation of DNAN and its plant metabolites within Arabidopsis leaves to determine the potential impact of photolysis on the phytoremediation of contaminants. When exposed to DNAN for three …

The Toxicity Of Nanoparticles Depends On Multiple Molecular And Physicochemical Mechanisms, Yue-Wern Huang, Melissa Cambre, Han-Jung Lee

Biological Sciences Faculty Research & Creative Works

Nanotechnology is an emerging discipline that studies matters at the nanoscale level. Eventually, the goal is to manipulate matters at the atomic level to serve mankind. One growing area in nanotechnology is biomedical applications, which involve disease management and the discovery of basic biological principles. In this review, we discuss characteristics of nanomaterials, with an emphasis on transition metal oxide nanoparticles that influence cytotoxicity. Identification of those properties may lead to the design of more efficient and safer nanosized products for various industrial purposes and provide guidance for assessment of human and environmental health risk. We then investigate biochemical and …

Amplification Of Earthquake Ground Motions In Washington, Dc, And Implications For Hazard Assessments In Central And Eastern North America, Thomas L. Pratt, J. Wright Horton Jr., Jessica Munoz, Susan E. Hough, Martin C. Chapman, C. Guney Olgun

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The extent of damage in Washington, DC, from the 2011 M_W 5.8 Mineral, VA, earthquake was surprising for an epicenter 130 km away; U.S. Geological Survey “Did-You-Feel-It” reports suggest that Atlantic Coastal Plain and other unconsolidated sediments amplified ground motions in the city. We measure this amplification relative to bedrock sites using earthquake signals recorded on a temporary seismometer array. The spectral ratios show strong amplification in the 0.7 to 4 Hz frequency range for sites on sediments. This range overlaps with resonant frequencies of buildings in the city as inferred from their heights, suggesting amplification at frequencies to …

Scholars' Mine Quick Facts December 2017, James Roger Weaver

Scholars’ Mine Statistics

Scholars' Mine statistical quick facts for December 2017.

Shockwave Interaction With A Cylindrical Structure, Phillip R. Mulligan

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

An increased understanding of the shockwave interaction with a cylindrical structure is the foundation for developing a method to explosively seal a pipe similar to the Deepwater Horizon accident in the Gulf of Mexico. Shockwave interactions with a cylindrical structure have been a reoccurring focus of energetics research. Some of the most notable contributions of non-destructive tests are described in ``The Effects of Nuclear Weapons'' (Glasstone, 1962). The work presented by Glasstone examines shockwave interaction from a 20-megaton bomb with a cylindrical structure. However, the data is limited to a peak overpressure of less than 25 psi, requiring several miles …

A Humidity-Controlled Fast Integrated Mobility Spectrometer (Hfims) For Rapid Measurements Of Particle Hygroscopic Growth, Tamara Pinterich, Steven R. Spielman, Yang Wang, Susanne V. Hering, Jian Wang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

We present a humidity-controlled fast integrated mobility spectrometer (HFIMS) for rapid particle hygroscopicity measurements. The HFIMS consists of a differential mobility analyzer (DMA), a relative humidity (RH) control unit and a water-based FIMS (WFIMS) coupled in series. The WFIMS (Pinterich et al., 2017) combines the fast integrated mobility spectrometer (Kulkarni and Wang, 2006a, b) with laminar flow water condensation methodologies (Hering and Stolzenburg, 2005; Spielman et al., 2017). Inside the WFIMS, particles of different electrical mobilities are spatially separated in an electric field, condensationally enlarged and imaged to provide 1 Hz measurements of size distribution spanning a factor of ∼3 …

Special Section On Wireless Emc And Wireless Ota Measurements, Jun Fan, Y. Qi

Electrical and Computer Engineering Faculty Research & Creative Works

No abstract provided.