Digital Commons Network^™

Neuroengineering Of Clustering Algorithms, Leonardo Enzo Brito Da Silva

Doctoral Dissertations

"Cluster analysis can be broadly divided into multivariate data visualization, clustering algorithms, and cluster validation. This dissertation contributes neural network-based techniques to perform all three unsupervised learning tasks. Particularly, the first paper provides a comprehensive review on adaptive resonance theory (ART) models for engineering applications and provides context for the four subsequent papers. These papers are devoted to enhancements of ART-based clustering algorithms from (a) a practical perspective by exploiting the visual assessment of cluster tendency (VAT) sorting algorithm as a preprocessor for ART offline training, thus mitigating ordering effects; and (b) an engineering perspective by designing a family of …

Biofuel Supply Chain Restructuring -- An Economic Viability And Environmental Sustainability Investigation For Enhancing Second Generation Biofuel Adoption, Rajkamal Kesharwani

Doctoral Dissertations

"Biofuel is a promising clean alternative to fossil fuels. Currently, first generation biofuels are commercially produced by using corn grain as biomass feedstock. However, the use of edible matter of crops, may lead to a competition between food and fuel. Therefore, there is a significant push in both industry and academia to commercialize second generation biofuel manufacturing technology, which uses non-edible matter from crops. Most research focuses on individual manufacturing processes for producing second generation biofuel, but the economic and environmental impacts of a large-scale adoption of second generation biofuel manufacturing have been less widely reported.

This work investigates the …

Multi-Body Dynamic And Finite Element Modeling Of Ultra-Large Dump Truck - Haul Road Interactions For Machine Health And Haul Road Structural Integrity, Bruno Ayaga Kansake

Doctoral Dissertations

"Haul truck capacities have increased due to their economies of scale in large-scale surface mine production systems. Ultra-large trucks impose high dynamic loads on haul roads. The dynamic loads are exacerbated by road surface roughness and truck over-loading. The dynamic forces also subject trucks to high torsional stresses, which affect truck health. Current haul road response models are 2D and use static truckloads for low capacity trucks. Existing 3D models consider the road as a two-layer system. No models capture the truck dynamic effects on haul roads and predict strut pressures during haulage.

Lagrangian mechanics was used to formulate the …

Application Of Computational Intelligence To Explore And Analyze System Architecture And Design Alternatives, Gene Lesinski

Doctoral Dissertations

"Systems Engineering involves the development or improvement of a system or process from effective need to a final value-added solution. Rapid advances in technology have led to development of sophisticated and complex sensor-enabled, remote, and highly networked cyber-technical systems. These complex modern systems present several challenges for systems engineers including: increased complexity associated with integration and emergent behavior, multiple and competing design metrics, and an expansive design parameter solution space. This research extends the existing knowledge base on multi-objective system design through the creation of a framework to explore and analyze system design alternatives employing computational intelligence. The first research …

Development And Demonstration Of Sampling Techniques For A Chirped Pulse Fourier Transform Microwave Spectrometer, Frank Edward Marshall

Doctoral Dissertations

"With the introduction of the Chirped Pulse-Fourier Transform Microwave Spectrometer in the past decade, it has become possible to rapidly study the rotational spectra of molecules in the gas phase. It is possible to study molecules that are not normally in the gas phase through the use of various sourcing techniques. The development of both the heated nozzle and the laser ablation sourcing techniques allow for the study of liquids and solids, respectively. The design and performance of these sources will be presented in detail and discussed. Additionally, the development of a Multi-Antennae detection scheme, useful in improving overall sensitivity …

Dendrites Or Lambda-Dendroids As Generalized Inverse Limits, Faruq Abdullah Mena

Doctoral Dissertations

"This research centers on the study of generalized inverse limits. We show that all members of an infinite family of inverse limit spaces are homeomorphics to one particularly complicated inverse limit space known as "The Monster". Further, properties of factor spaces and graphs of bonding functions which are preserved in generalized inverse limit spaces with upper semi-continuous bonding functions with appropriate restrictions are investigated. Some of the properties are locally connectedness, hereditary decomposability, hereditary indecomposability, hereditary unicoherence, arc-likeness, and tree-likeness. The theorems are illustrated by several examples"--Abstract, page iv.

Decoupling Methods For The Time-Dependent Navier-Stokes-Darcy Interface Model, Changxin Qiu

Doctoral Dissertations

"In this research, several decoupling methods are developed and analyzed for approximating the solution of time-dependent Navier-Stokes-Darcy (NS-Darcy) interface problems. This research on decoupling methods is motivated to efficiently solve the complex Stokes-Darcy or NS-Darcy type models, which arise from many interesting real world problems involved with or even dominated by the coupled porous media flow and free flow. We first discuss a semi-implicit, multi-step non-iterative domain decomposition (NIDDM) to solve a coupled unsteady NS-Darcy system with Beavers-Joseph-Saffman-Jones (BJSJ) interface condition and obtain optimal error estimates. Second, a parallel NIDDM is developed to solve unsteady NS-Darcy model with Beavers-Joseph (BJ) …

Study Of Optical Propulsion Concepts And Techniques For Small-Satellites, Jaykob Neil Maser

Doctoral Dissertations

"The first objective of this research is to manufacture and investigate the characteristics and use of asymmetric, metallic, nanostructures for plasmonic force propulsion, a developing method of nano-/picosatellite thrust generation. This project developed a higher-fidelity model of a recently envisioned small spacecraft propulsion system for precision pointing and proximity control. Plasmonic force propulsion harnesses solar light focused onto plasmon reactive sub-wavelength nanostructures to generate polarized oscillations of electrons on the surface of metallic nanostructures which accelerate and expel nanoparticle propellant via strong optical forces. This research also explores how material selection affects the electromagnetic response of the closely positioned asymmetric …

Modeling Of Hiv, Sir And Sis Epidemics On Time Scales And Oscillation Theory, Gülşah Yeni

Doctoral Dissertations

"We study higher dimensional systems of first order dynamic equations on time scales together with their applications. In particular, we focus on epidemic models such as HIV (Human Immunodeficiency Virus), SIS (Susceptible-Infected-Susceptible) and SIR (Susceptible-Infected-Recovered).

First, we generalize the early studied continuous three dimensional linear model of drug therapy for HIV-1 decline on time scales in order to derive new discrete models that predict the total concentration of plasma virus as a function of time. We compare these models to explore the impact of the theory of time scales. After fitting the models to the data collected at a clinical …

Smart Control Architecture For Microgrid Application, Vikram Roy Chowdhury

Doctoral Dissertations

"This research proposes non-linear control architectures dedicated towards improving transient response, reliability and computational burden for grid connected inverters applicable for ac micro-grids. Also this work proposes an optimization procedure applied to a small microgrid to reduce the billing cost for power incorporating battery degradation mechanism.

Three works are discussed in this research that discusses methodologies to improve the operation of a three phase grid connected inverters. The first work discusses a globally stable estimation architecture for estimating the plant parameters for a grid connected inverter during its operation. Then a Lyapunov based control architecture is utilized and online parameter …

Accurate Monitoring Of X, Y, And Z Magnetization For Analysis Of Hardware And Pulse Sequence Performance In Nmr Spectroscopy, Emmalou Theresa Schmittzehe

Doctoral Dissertations

"A new nuclear magnetic resonance (NMR) imaging protocol has been developed to independently record the x, y, and z components of the nuclear net magnetization at any point in a pulse sequence while eliminating the observation of the other components. This protocol provides an experimental method of tracking magnetization which then can be used in conjunction with theoretical models to scrutinize the predicted outcome of each step in an NMR pulse sequence and potentially find further improvements to their effectiveness and efficiency. The protocol utilizes a rapid rotating-frame imaging pulse-train technique to obtain RF-field (B₁) and resonance-offset (ΔB …

The Behavior Of Suas Under Explosive Loading Conditions And Implications For Safe Operating Procedures, Ashok Em Sudhakar

Doctoral Dissertations

"Drones are increasingly being used for tasks previously unimagined and the beneficial uses are evolving. The United States Congress has envisioned the possible uses of drones for both combating and conveying explosive threats and other harmful and destructive activities. Congress' intent is reflected in new laws (2018) and policies (2019).

All civilian available Small Unmanned Aerial Systems sUASs (Drones), weighing less than 55 pounds, in the current market are not designed for operations in explosive environments. This first of a kind research focuses on further understanding of sUASs response to explosive loading and the public policy implications. This research measured …

Thermomechanical Analysis Of Rock Asperity In Fractures Of Enhanced Geothermal Systems, Chao Zeng

Doctoral Dissertations

"Enhanced Geothermal Systems (EGS) offer great potential for dramatically expanding the use of geothermal energy and become a promising supplement for fossil energy. The EGS is to extract heat by creating a subsurface system to which cold water can be added through injection wells. Injected water is heated by contact with rock and returns to the surface through production well. Fracture provides the primary conduit for fluid flow and heat transfer in natural rock. Fracture is propped by fracture roughness with varying heights which is called asperity. The stability of asperity determines fracture aperture and hence imposes substantial effect on …

Remanufacturing Of Precision Metal Components Using Additive Manufacturing Technology, Xinchang Zhang

Doctoral Dissertations

"Critical metallic components such as jet engine turbine blades and casting die/mold may be damaged after servicing for a period at harsh working environments such as elevated temperature and pressure, impact with foreign objects, wear, corrosion, and fatigue. Additive manufacturing has a promising application for the refurbishment of such high-costly parts by depositing materials at the damaged zone to restore the nominal geometry. However, several issues such as pre-processing of worn parts to assure the repairability, reconstructing the repair volume to generate a repair tool path for material deposition, and inspection of repaired parts are challenging. The current research aims …

Improvements In Digital Image Correlation And Application In Material Mechanical Test, Yunlu Zhang

Doctoral Dissertations

"Digital image correlation (DIC) is a non-contact full-field optical measurement method. With the advantages of high accuracy, low cost, and simple implementation, it has been widely applied in the area of experimental mechanics. In this study, DIC algorithm has been improved in the aspects of the pixel-level searching method and reference frame update strategy. The feature matching based method is proposed to provide an initial guess for all points of interest with semi-subpixel level accuracy in cases with small or large translation, deformation, or rotation. The bisection searching strategy is presented to automatically adjust the frame step for varying practical …

A Computational Study Of Sleep And The Hemispheres Of The Brain, Tera Ashley Glaze

Doctoral Dissertations

"Sleep and sleep cycles have been studied for over a century, and scientists have worked on modeling sleep for nearly as long as computers have existed. Despite this extensive study, sleep still holds many mysteries. Larger and more extensive sleep-wake models have been developed, and the circadian drive has been depicted in numerous fashions, as well as incorporated into scores of studies. With the ever-growing knowledge of sleep comes the need to find more ways to examine, quantify, and define it in the context of the most complex part of the human anatomy -- the brain. Presented here is the …

Paleoenvironment And Paleoclimate Of Ne Pangea In Early Permian-Linking Chemo- And Cyclo-Stratigraphy, Bogda Mountains, Nw China, Xin Zhan

Doctoral Dissertations

"The overall objective of this study is to understand physical and chemical responses of Earth Systems to environmental and climatic perturbations of diverse magnitudes and time scales in Bogda Mountains, NE Pangea. Field investigations, petrographic observations, and geochemical analyses have been used to interpret paleoenvironment and paleoclimate in cm-m-scale high-order cycles (HCs: 0.1-100 kyrs), low-order cycles (LCs: 1-10 Myr), and critical events of late Paleozoic ice age (LPIA: 320-260 Myr ago). Four organo-facies are one-to-one correlated with the four lithofacies in the meter-scale HCs, suggesting litho- and organo-facies are genetically linked and fundamentally controlled by environmental changes associated with lake …

Long Period Fiber Grating, Thin Coating Of Graphene And Silver Nanowires, And Corrosion Sensing For Life-Cycle Assessment Of Steel Structures, Chuanrui Guo

Doctoral Dissertations

"This study aims to develop and validate a compact, integrated lab-on-sensor system for simultaneous measurement of strain, temperature and corrosion-induced mass loss in steel structures and concrete reinforcement elements in order to assess their life-cycle performance. The sensing system operates based on the principle of long period fiber gratings (LPFG) that are responsive to both thermal and mechanical deformation, and the change in refractive index of any medium surrounding the optical fiber. To fabricate a LPFG sensor for strain and temperature measurement, a CO₂ laser aided fiber grating system was assembled. To enable mass loss measurement, a low pressure …

New Reproducing Kernel Hilbert Spaces On Plane Regions, Their Properties, And Applications To Partial Differential Equations, Jabar S. Hassan

Doctoral Dissertations

"We introduce new reproducing kernel Hilbert spaces W₂^(m,n) (D) on unbounded plane regions D. We study linear non-homogeneous hyperbolic partial differential equation problems on D with solutions in various reproducing kernel Hilbert spaces. We establish existence and uniqueness results for such solutions under appropriate hypotheses on the driver. Stability of solutions with respect to the driver is analyzed and local uniform approximation results are obtained which depend on the density of nodes. The local uniform approximation results required a careful determination of the reproducing kernel Hilbert spaces on which the elementary …

Development Of Functional Ionic Liquids For Separation And Recovery Of Rare Earth Elements, Mostafa Khodakarami

Doctoral Dissertations

“This research focused on the design and synthesis of task-specific ionic liquids for enhanced extraction and separation of rare earth elements (REEs). Two novel ammonium-based functional ionic liquids (FILs) with oxygen donating groups: trioctyl(2-ethoxy-2-oxoethyl)ammonium dihexyl diglycolamate, [OcGBOEt][DHDGA], and tricaprylmethylammonium dihexyl diglycolamate, [A336][DHDGA] were synthesized and tested for the recovery and separation of selected REEs from aqueous solutions. Functionalities with different denticities were incorporated into both anionic and cationic parts of ionic liquids, which are solely composed of incinerable atoms including C, H, O, and N. The structural, physical, and chemical properties of the synthesized FILs were studied using nuclear magnetic …

Design, Synthesis, Characterization And Anti-Cancer Effects Evaluation Of Interchain Cysteine Linked Antibody Drug Conjugates, Ke Li

Doctoral Dissertations

"Antibody drug conjugates (ADCs) are emerging therapeutic products specially designed for the treatment of cancers. Potent cytotoxic agents are linked to antibodies via linkers. Antibody drug conjugates, which take advantage of both antibodies and cytotoxic agents, showed high selectivity towards cancer cells. Cytotoxic agents are delivered to the cancer cells selectively and kill them from inside while leaving low or non-toxicity towards normal cells. Antibody drug conjugates are actually heterogeneous mixtures. The major heterogeneities mainly lie in the drug to antibody ratio (DAR) and drug linking positions, both of which potentially affect the therapeutic index of ADCs. In this research, …

Mass Spectrometry Analysis Of Contaminants Of Emerging Concern: Nanoparticles, Algal Toxins, And Cyanotoxins In Natural Waters And Their Potential Health Impacts, Ariel R. Donovan

Doctoral Dissertations

“The analysis of contaminants of emerging concern is critical to protecting environmental health. In the presented dissertation, two groups of contaminants of emerging concern were assessed using mass spectrometry methods: nanoparticles and algal and cyanotoxins.

Analysis of metal oxide nanoparticles in environmental matrices has been a challenging issue, as most traditional methods require complicated sample preparation methods or that can alter or destroy the nanoparticles in the system. Single particle inductively coupled plasma mass spectrometry (SP-ICP-MS) methods were used to detect metal oxide nanoparticles in surface waters and their removal through drinking water treatment simulations while retaining all information regarding …

Design And Performance Of Fiber-Reinforced Concrete With Adapted Rheology For Construction And Repair Of Bridge Structures, Ahmed Abdelrazik

Doctoral Dissertations

“The objective of this document is to design high-performance fiber-reinforced self-consolidating concrete (FR-SCC) for infrastructure repair and fiber-reinforced super-workable concrete (FR-SWC) for bridge construction. The investigated fibers included propylene synthetic fibers, hooked steel fibers, double and triple hooked steel fibers, hybrid crimped steel fiber and polypropylene multifilament fibers, and micro-macro steel fibers. The fiber volume varied between 0 and 0.75%. An expansive agent (EA) was incorporated to compensate for shrinkage and induce compression in the concrete at early age. Two types of EA (G and K) were employed at 0 to 8%, by mass of binder. The investigated FRSCC and …

Exploring Transition Metal Chalcogenides For Bio Sensing And Environmental Remediation, Bahareh Golrokh Amin

Doctoral Dissertations

“Electrocatalysts play an inevitable role in many applications including energy storage, energy conversion, and biosensing. The state-of-the-art noble metal-based electrocatalysts have long been used in full water splitting, non-enzymatic glucose sensing, and supercapacitors. However, scarcity and high cost of noble metals restrict utilization of such electrocatalysts in large-scale implementations. Transition metal-based electrodes have been considered as a potential solution to address these drawbacks as well as to enhance the electrocatalytic performance. In this work, applicability of non-oxidic transition metal based electrocatalysts is evaluated. Transition metal chalcogenides are expected to have high catalytic performance owing to their facilitated electron cloud delocalization …

Feasibility And Assessment Of Using Recycled Rubber For Infrastructure Applications, Ahmed A. Gheni

Doctoral Dissertations

“The United States needs to mine billions of tons of raw natural aggregate each year. At the same time, millions of scrap tires are stockpiled every year. Therefore, replacing natural aggregate with recycled crumb rubber aggregate will be beneficial to the construction industry and environment. This research aimed to investigate the feasibility of using recycled rubber in new construction applications. Based on size, recycled rubber was selected to match its natural counterpart. Different ratios of recycled crumb rubber were used as a fine aggregate replacement in concrete masonry units (CMUs) where the rubberized units showed a lower unit weight, higher …

Design, Fabrication, And Characterization Of Functionally Graded Materials, Sreekar Karnati

Doctoral Dissertations

“The aim of this research was to investigate the feasibility of fabricating custom designed, graded materials using Laser Metal Deposition (LMD) that will cater for functionality and unconventional repair. The ultimate goal of the project is to establish the versatility of LMD for fabricating advanced materials and tackling problems that have been conventionally difficult or in cases infeasible. In order to accomplish these goals, this research involved investigations into, the feasibility of using elemental powders as modular feedstocks, the feasibility of fabricating tailored gradients with these custom compositions, and finally leveraging the advantages of grading materials using LMD to successfully …

Three-Dimensional Nanotube Arrays For Solar Energy Harvesting And Production Of Solar Fuels, Wipula P. R. Liyanage

Doctoral Dissertations

"Over the past decade extensive research has been carried out on photovoltaic semiconductors to provide a solution towards a renewable energy future. Fabricating high-efficiency photovoltaic devices largely rely on nanostructuring the photoabsorber layers due to the ability of improving photoabsorption, photocurrent generation and transport in nanometer scale. Vertically aligned, highly uniform nanorods and nanowire arrays for solar energy conversion have been explored as potential candidates for solar energy conversion and solar-fuel generation owing to their enhanced photoconversion efficiencies.

However, controlled fabrication of nanorod and especially nanotube arrays with uniform size and shape and a pre-determined distribution density is still a …

Nanoscale Solidification Of Metals By Atomistic Simulations: From Nucleation To Nanostructural Evolution, Avik Mahata

Doctoral Dissertations

"Homogeneous nucleation during solidification in Al (fcc), Fe (bcc) and Mg (hcp) is studied by million-atom molecular dynamics (MD) utilizing the second nearest neighbor modified embedded atom method (2NN-MEAM) potentials. Spontaneous homogenous nucleation from the melt was produced without any influence of pressure, free surface effects and impurities. We also study the effect on the simulation size on homogenous nucleation and the heterogeneity in homogenous nucleation. The heterogeneity in homogenous nucleation originates from the twins, grain boundaries and short range order in the liquid during the initial stages of solidification.

To study the solid-liquid coexistence in binary Al alloys, interatomic …

Development Of A Switchable Radioisotope Generator, Kyle Mitchell Paaren

Doctoral Dissertations

The Switchable Radioisotope Generator utilizes alpha-induced reactions to produce a combination of photons, neutrons, and protons with varying fluxes dependent on target materials and source geometry. The activity/strength of the secondary radiation is further controlled by manipulating the number of alpha particles that can interact with the target material(s). Analytical equations were solved to confirm secondary radiation production from target materials using average cross sections from TENDL data. TENDL and JENDL data was confirmed by analytically solving for the total alpha-induced cross sections. This information was used to produce the provisional and utility Patent No: US20190013109A1. TENDL data was then …

The Effects Of Silica On The Properties Of Vitreous Enamels, Signo Tadeu Dos Reis, Mike Koenigstein, Liang Fan, Genda Chen, Luka Pavic, Andrea Mogus-Milankovic

Materials Science and Engineering Faculty Research & Creative Works

Ground coat enamels for low carbon steel that contain silica as a mill addition have been developed to study the changes of their properties. Acid-resistant commercial enamel where silica addition was varied from 0 to 10.0 wt % was used for this investigation. The effects of the addition on the corrosion resistance, thermal properties, electrical properties, and mechanical adherence of the enamel to low carbon steel were studied. The corrosion resistance of the steel enameled coupons was tested using a salt spray (fog) apparatus for time periods reaching 168 h at room temperature. It was found that, although the density …