Digital Commons Network^™

Epitaxial Growth Of Semiconductors And Chiral Metal Surfaces Using Spin Coating And Electrodeposition, Meagan V. Kelso

Doctoral Dissertations

"The current primary methods for epitaxial growth are energy intensive, requiring high temperature or high vacuum to obtain quality thin films. This dissertation explores the solution process methods of electrodeposition and spin coating for growth of epitaxial thin films. First, a method is developed to directly electrodeposit epitaxial CH₃NH₃PbI₃ perovskite for solar cells on single crystal Au by electrochemically reducing I₂ in organic solution. Perovskite is a newly explored material for solar cells, and its efficiency may be further improved by increasing the crystalline order. Second, a study on epitaxially electrodeposited chiral metal surfaces …

Modeling And Simulation Of Micro/Nano-Rod Distribution In Micro Channel Flows, Saman Monjezi

Doctoral Dissertations

"The behavior of a typical nanorod particle in microscale flows was theoretically investigated, considering the effect of the wall on the rotational and translation motions of the non-spherical particle. Initially, a systematic method using Brownian dynamics simulation of the rotational motion of nanorod was performed to obtain the average orientation distribution of a nanorod in various range of Peclet number and position from the confining wall. Subsequently, the results of the angle distributions simulation were employed to generate a universal mathematical model for the particle orientation distribution, which our model of concentration distribution of high aspect ratio nanorods in the …

The Dynamical State Of A Young Stellar Cluster, Timothy Sullivan

Doctoral Dissertations

"The dynamical state of the young star-forming cluster Rho Ophiuchi is considered, with emphasis on the L1688 cloud. Radial velocities are derived for 32 YSOs, with some being multi-epoch, using Markov-Chain Monte Carlo routines based upon the package emcee. Sources are chosen based upon their spectral index to focus on the earlier stages of star formation, in this case, Class I and Flat spectrum objects, and compared with a sample of Class II and III objects from the same embedded cluster. It is found that the radial velocity dispersion for these younger objects is Δv = 2.8 ± 0:6 …

Privacy Preservation In Social Media Environments Using Big Data, Katrina Ward

Doctoral Dissertations

"With the pervasive use of mobile devices, social media, home assistants, and smart devices, the idea of individual privacy is fading. More than ever, the public is giving up personal information in order to take advantage of what is now considered every day conveniences and ignoring the consequences. Even seemingly harmless information is making headlines for its unauthorized use (18). Among this data is user trajectory data which can be described as a user's location information over a time period (6). This data is generated whenever users access their devices to record their location, query the location of a point …

Investigating Blast Fume Propagation, Concentration And Clearance In Underground Mines Using Computational Fluid Dynamics (Cfd), Raymond Ninnang Tiile

Doctoral Dissertations

"Blasting activities using standard industry explosives is an essential component of underground hard rock mining operations. Blasting operations result in the release of noxious gases, presenting both safety and productivity threats. Overestimation of post-blast re-entry time results in production losses, while underestimation leads to injuries and fatalities. Research shows that most underground mines simply standardize post-blast re-entry times based on experiences and observations. Few underground mines use theoretical methods for calculating post-blast re-entry time. These theoretical methods, however, are unable to account for the variations in the blasting conditions. Literature review shows that: (i) there is currently no means of …

Receiver Function Investigations Of Mantle Transition Zone And Crustal Structure In East Africa And Northeast Asia, Muchen Sun

Doctoral Dissertations

"In spite of numerous geophysical studies have been conducted in East Africa and Northeast Asia, the structure and evolution of the crust, upper mantle, and the mantle transition zone (MTZ) are still controversial. The MTZ discontinuities beneath the study area are imaged by stacking an unprecedented volume of receiver functions (RFs). The normal MTZ thickness beneath the Western Branch of the EARS and Tanzania Craton indicates the absence of present-day thermal upwelling from the lower mantle. In contrast, beneath the Eastern Branch, a significant MTZ thinning reveals the existence of thermal upwelling from either the upper MTZ or the lower …

Underwater Acoustic Communications And Adaptive Signal Processing, Mohammadhossein Behgam

Doctoral Dissertations

"This dissertation proposes three new algorithms for underwater acoustic wireless communications. One is a new tail-biting circular MAP decoder for full tail-biting convolution (FTBC) codes for very short data blocks intended for Internet of Underwater Things (IoUT). The proposed algorithm was evaluated by ocean experiments and computer simulations on both Physical (PHY) and Media access control (MAC) layers. The ocean experimental results show that without channel equalization, the full tail-biting convolution (FTBC) codes with short packet lengths not only can perform similarly to zero-tailing convolution (ZTC) codes in terms of bit error rate (BER) in the PHY layer. Computer simulation …

Provenance And Depositional Environments Of The Upper Permian-Lowermost Triassic Fluvial And Lacustrine Sandstones, Wutonggou Low-Order Cycle, Bogda Mountains, Nw China, Dongyu Zheng

Doctoral Dissertations

"This work integrates petrographic and fieldwork studies and documents the spatial and temporal distributions of compositions and textures of the upper Permian-lowermost Triassic fluvial-lacustrine sandstones, Wutonggou low-order cycle (WTG LC), Bogda Mountains, NW China. In the first part, three petrofacies are identified on the basis of the relative abundances of quartz, feldspar, and lithics and conglomerate compositions and paleocurrent directions are documented. These data indicate that rocks of the eastern North Tianshan Suture (ENTS) and rift shoulders were the provenance lithology. Moreover, the upsection changes of petrofacies and conglomerate compositions suggest that the lithology of ENTS changed. During approximately Wuchiapingian, …

Building Shared Knowledge For Eor Technologies: Screening Guideline Constructions, Dashboards, And Advanced Data Analysis, Na Zhang

Doctoral Dissertations

"Successful implementation of enhanced oil recovery (EOR) technology requires comprehensive knowledge and experiences based on existing EOR projects. EOR screening guidelines and EOR reservoir analog are served as such knowledge which are considered as the first step for a reservoir engineer to determine the next step techniques to improve the ultimate oil recovery from their assets. The objective of this research work is to provide better assistance for EOR selection by using fundamental statistics methods and machine learning techniques.

In this dissertation, a total of 977 worldwide EOR projects with the most uniformed, high-quality, and comprehensive information were collected from …

Electrodeposition Of Epitaxial Metal Thin Films On Silicon For Energy Conversion And Flexible Electronics, Qingzhi Chen

Doctoral Dissertations

"This research focuses on epitaxial electrodeposition of two coinage metals: Au and Ag thin films on the silicon surface and their applications in flexible electronics and energy conversion and storage. The first paper: Photoelectrochemistry of ultrathin, semi-transparent, and catalytic gold films electrodeposited epitaxially onto n-silicon (111) describes the epitaxial electrodeposition of Au thin films on n-type Si using a simple HAuCl4 bath and the photoelectrochemical properties of the Au-Si junction barrier. The effect of the Au layer on the interfacial energetics as well as the stability of the photoelectrode as a function of the Au coverage/thickness is determined in a …

Efficient Estimation And Mitigation For Radio-Frequency Interference, Qiaolei Huang

Doctoral Dissertations

"With rapid innovations in Internet of Things (IoT) and wireless technology, more and more consumer electronic devices around the world are now connected to the internet. In a small form factor electronic device, there are plenty of potential noise sources such as System On Chip (SoC), high speed traces, flexible cables and power converters, etc. Those noise sources can possibly introduce radio frequency interference (RFI) issues. In this dissertation, a transfer function based calculation method is proposed to estimate radio frequency interference (RFI) problems. The derived equations can clearly decompose the RFI problem into two parts: the noise source and …

Non-Invasive Microwave And Millimeter Wave Reflectometry And Imaging For Human Skin Diagnosis And Materials Characterization, Yuan Gao

Doctoral Dissertations

"Microwave and millimeter wave reflectometry and synthetic aperture radar (SAR) imaging techniques have been successfully applied in many applications, such as nondestructive testing and evaluation (NDT&E), security inspection and medical diagnosis. In this dissertation, the feasibility of using microwave and millimeter reflectometry and SAR imaging for burn diagnosis is investigated through both simulations and measurements, with promising results. To correctly model the interaction between electromagnetic waves and skin, the proper knowledge of the complex permittivity of healthy skin is critically important. To this end, the common used measurement methods for in vivo skin complex permittivity are reviewed and analyzed in …

Nanomorphology Dependent Optical And Mechanical Properties Of Aerogels, Chandana Mandal

Doctoral Dissertations

"Aerogels are very low density, light weight open pore materials. A hypothesis that is under intense current investigation by the scientific community states that the mechanical properties of nanostructured polymers depend on their nanomorphology. Aerogels are nanostructured ultra-lightweight nanoporous materials with skeletal frameworks that can display a wide range of nanomorphologies. Thereby aerogels comprise a suitable platform for testing not only that hypothesis but also a wide range of other properties such as light scattering for applications, for example, in thermally insulating windows.

To study the mechanical properties of nanostructured matter as a function of nanomorphology, various shape-memory polyurethane aerogels …

Using Lidar To Measure Subsurface Movement Of Slow-Moving Landslides And Study The Interaction Between The Soil And Lidar Scanning Targets, Chengxun Lu

Doctoral Dissertations

"Terrestrial Laser Scanning (TLS) technology has been used for predicting and researching geological hazards for two decades. This research focuses on using LiDAR (Light Detection And Ranging) to measure the slow-moving displacement of both surface and subsurface soil of landslides. Two kinds of computer simulation software, FLAC3D® and PFC3D® were used to simulate the landslide process to compare with the LiDAR scanning results.

The primary contributions from this research are as follows:

1. Several error tests were done to prove that the three-dimensional LiDAR scanner used in this research can precisely obtain the three-dimensional position, the displacement and the rotational …

Passive Harmonic Generation At Spring Contacts, Sen Yang

Doctoral Dissertations

"In the first paper, the RF passive harmonic generation phenomenon on the spring contact is studied. A spring contact harmonic generation measurement system is developed. The factors that may have an impact on the spring contact harmonic generation, such as contact material, contact force, and contact resistance are characterized by the measurement system. The gold-to-gold contact is found to be much superior to the stainless-steel contacts. It is also found that the passive nonlinearity at the spring contact is the semiconductor-like junction formed by the surface oxide film.

In the second paper, we show that the maximum E-field coupling occurs …

Synthesis And Applications Of Ceramic (Silicon Carbide And Silicon Nitride), Metallic (Cobalt(0)) And Polymeric (Polyurethane) Aerogels, Parwani M. Rewatkar

Doctoral Dissertations

"A new method has been demonstrated for the synthesis of monolithic ceramic and purely metallic aerogels from xerogel powder compacts, and the use of polyurethane aerogels based on cyclodextrins as efficient desiccants.

I. Highly porous ( > 80%) monolithic SiC and Si₃N₄, aerogels were prepared from compressed compacts of polyurea-crosslinked silica xerogel powders. The process is time efficient as solvent-exchange through powders is fast, and energy efficient as it bypasses drying with supercritical fluids. The final ceramic objects were chemically pure, sturdy, with compressive moduli at 37 ±7 MPa and 59 ± 7 MPa, and thermal conductivities …

Hydrodynamics Of Trickle Bed Reactors (Tbrs) Packed With Industrial Catalyst Using Advanced Measurement Techniques, Mohammed Jaber Al-Ani

Doctoral Dissertations

"The impacts of the packing characteristics on the hydrodynamics od a trickle bed reactor (TBR) have been investigated using advanced measurements techniques of Gamma-ray densitometry (GRD) and Optical fiber probe and conventional measurement techniques of high-frequency differential pressure transducer and load cell. Two different reactor sizes of bench and pilot plant scale were used. Bench-scale TBR carried out the experiments to assess phase distribution and catalyst utilization with 1.18 cm inside diameter and 72 cm length at ambient pressure and temperature. The mixture of catalyst and fine particles displayed considerable improvements in the phase distribution, liquid holdup profile, and catalyst …

Polyurea Aerogels: From Nanoscopic To Macroscopic Properties, Tahereh Taghvaee

Doctoral Dissertations

"The morphology of a material is intrinsically a qualitative property and in order to relate nanomorphology to synthetic conditions, it is necessary to express nano/micro-structure quantitatively. In this context, polyurea aerogels were chosen as a model system with demonstrated potential for rich nanomorphology and being guided by a statistical Design-of-Experiments model, a large array of materials (208) with identical chemical composition, but quite different nanostructures were prepared. By reflecting upon the SEM images, it was realized that our first pre-verbal impression about a nanostructure is related to its openness and texture; the former is quantified by porosity (Π), and the …

Multiscale Spatio-Temporal Modeling Of Cell Population In Tissue Architecture And Drug Delivery Nanoparticles, Mohammad Aminul Islam

Doctoral Dissertations

"Multiscale nature of a biological system span at many order of magnitudes in time and space. Molecular interaction at lower scale is connected with the higher scale behavior of tissue or organism. Integrating the dynamics and information at different time and space can give a fundamental physiological understanding of the higher level phenomena. But complex features, functions, interconnectivity between different scales and lack of information on the fundamental physiological property make the model difficult and computationally challenging. The multiscale modeling approach can bridge the gap between different scale by a systemic integration of the complex dynamic behavior.

Here, the focus …

Spatiotemporal Modeling And Model Restructuration Approaches In Studies Of Intracellular Signalling Pathways, Md Shahinuzzaman

Doctoral Dissertations

"The main focus of the research is to understand the complex phenomena of cell transduction pathways and cell biology in a single cell. Mathematical modeling and experimental evaluation are widely used approaches for this kind of research. Firstly, A multiscale framework for protein-protein interaction has been established using Brownian dynamics algorithm. Sit specific feature, steric collision, diffusion, co-localization and complex formation with time and space has been included in this spatial modeling framework. By implementation of the time adaptive feature in this framework, the computation time reduces in an order of magnitude compared with traditional modeling framework. This multiscale Brownian …

Decoding The History Of The Early Solar System Using Comet Volatile Compositions, Nathaniel Xavier Roth

Doctoral Dissertations

"Understanding the evolution of the solar system, as well as its current volatile content, requires knowledge of the initial conditions present in the solar nebula. As some of the first objects to accrete in the solar nebula, cometary nuclei are among the most primitive remnants of solar system formation, and their present-day volatile composition likely reflects the composition and conditions where (and when) they formed. As such, the volatile compositions of cometary nuclei may serve as 'fossils' of solar system formation. High-resolution near-infrared spectroscopy offers a valuable tool for sampling the primary volatile (i.e., ices subliming directly from the nucleus) …

Predictive Analysis Of Real-Time Strategy Games Using Graph Mining, Isam Abdulmunem Alobaidi

Doctoral Dissertations

"Machine learning and computational intelligence have facilitated the development of recommendation systems for a broad range of domains. Such recommendations are based on contextual information that is explicitly provided or pervasively collected. Recommendation systems often improve decision-making or increase the efficacy of a task. Real-Time Strategy (RTS) video games are not only a popular entertainment medium, they also are an abstraction of many real-world applications where the aim is to increase your resources and decrease those of your opponent. Using predictive analytics, which examines past examples of success and failure, we can learn how to predict positive outcomes for such …

Origin Of Periclines In The Ozark Plateau, Missouri: A Field And Numerical Modeling, Chao Liu

Doctoral Dissertations

"A series upright sub-horizontal folds in sandstones of the early Ordovician Roubidoux Formation are exposed in road cuts along US Highway 63 in the northern part of the Salem Plateau of central Missouri for over a distance of approximately 10 km. These folds are in marked contrast to the more typical horizontal to sub-horizontal Ordovician strata of the Ozark Plateau. The origin of those folds remains enigmatic. The inspection of the characteristics of these folds using stereographic analysis revealed a non-cylindrical geometrical pattern than a near cylindrical fold. Structural data of 54 folds indicate an alternating basin and dome pattern. …

Investigating The Performance Of High Viscosity Friction Reducers Used For Proppant Transport During Hydraulic Fracturing, Mohammed Salem Ba Geri

Doctoral Dissertations

"Over the last few recent years, high viscosity friction reducers (HVFRs) have been successfully used in the oil and gas industry across all premier shale plays in North America including Permian, Bakken, and Eagle Ford. However, selecting the most suitable fracture fluid system plays an essential role in proppant transport and minimizing or eliminating formation damage.

This study investigates the influence of the use of produced water on the rheological behavior of HVFRs compared to a traditional linear guar gel. Experimental rheological characterization was studied to investigate the viscoelastic property of HVFRs on proppant transport. In addition, the successful implication …

Characterization Of A Green Electric Solid Propellant For Electric Propulsion, Matthew Scott Glascock

Doctoral Dissertations

"Electric solid propellants are advanced solid chemical rocket propellants that can be controlled (ignited, throttled and extinguished) through the application and removal of an electric current. These propellants are also being considered for use in ablative pulsed plasma thruster and multimode systems. In this work, the behavior and performance of a novel green electric solid propellant operating in an electrothermal ablation-fed pulsed plasma thruster was investigated. Using an inverted pendulum micro-Newton thrust stand, the impulse bit and specific impulse of the device using the electric solid propellant were measured for short-duration and long-duration runs to end-of-life, at energy levels of …

Experimental Study On Enhanced Oil Recovery (Eor) Mechanisms Of Nanogel Combining With Low Salinity Water For Carbonate Reservoirs, Pu Han

Doctoral Dissertations

"Nanomaterials have been widely studied and applied in the oil and gas industry. Among the developed nanomaterials, nano-sized crosslinked polymeric gel particle (nanogel) has shown great potential in recovering residual oil and improving oil recovery. This dissertation carried out their potential EOR mechanisms and the synergetic effect between nanogel and low salinity water. Nanogel used in this study was synthesized through the suspension polymerization process in our lab. The morphology, size distribution, and zeta potential were studied for nanogel dispersed in brine with variable ionic strength. The injectivity of nanogel was elucidated at first to ensure their in-depth penetration ability. …

Development Of Stage-I Tempered High Strength Cast Steel For Ground Engaging Tools, Viraj Ashok Athavale

Doctoral Dissertations

"Ground Engaging Tools (GET) are the expendable replacement parts used in heavy machinery used with mining or construction equipment. GET’s protect the expensive machine components from the wear and tear found common in high-impact or high-abrasion environments. The goal of this project is to develop advanced next-generation alloy choices that outperforms the existing GET materials. A method of predicting tempered hardness of mixed microstructures was formulated. Using this model, two alloy series viz. Cr-Ni-Mo and Mn-Si-Mo-V were proposed and experimented with the goal of obtaining a high strength and impact resistant cast steel. Cast iterations of Cr-Ni-Mo alloy series were …

Applications Of Machine Learning In Nuclear Imaging And Radiation Detection, Shaikat Mahmood Galib

Doctoral Dissertations

"The main focus of this work is to use machine learning and data mining techniques to address some challenging problems that arise from nuclear data. Specifically, two problem areas are discussed: nuclear imaging and radiation detection. The techniques to approach these problems are primarily based on a variant of Artificial Neural Network (ANN) called Convolutional Neural Network (CNN), which is one of the most popular forms of 'deep learning' technique.

The first problem is about interpreting and analyzing 3D medical radiation images automatically. A method is developed to identify and quantify deformable image registration (DIR) errors from lung CT scans …

The Mechanics Of Precision Presplitting, Anthony Joseph Konya

Doctoral Dissertations

"Precision Presplitting is a widely used method of presplit blasting for the mining and construction industries. In recent years considerable effort has gone into the development of empirical equations based on field data to be able to better design the Precision Presplit for various rock types and structural environments. However, the most widely discussed theory about the mechanics of the presplit formation, that of shockwave collisions, does not appear to be applicable for this method of presplitting.

This research has disproven this theory based on insufficient magnitude of the shockwave from modeling with basic wave mechanics. Other authors have suggested …

Deep Understanding Of Degradation In Lithium Ion Batteries Through Experimental And First-Principles Study, Yufang He

Doctoral Dissertations

"The growing interests in Lithium-ion Batteries (LIBs) have significantly accelerated the development of active materials. However, the key challenge is that electrode materials suffer from degradation, which include transition metal dissolution, solid electrolyte interphase (SEI) layer formation, and mechanical fracture. To address these issues, applying an ultrathin coating onto active materials via Atomic Layer Deposition (ALD) is an efficient way. Although numerious works have been done for active material performance improvement via ALD technology, the fundamental enhancement mechanisms of ALD coating on battery performance improvement are not yet known. Therefore, this dissertation consists of four papers, which focused on the …