Digital Commons Network^™

Magnetic Control Of Transport Of Particles And Droplets In Low Reynolds Number Shear Flows, Jie Zhang

Doctoral Dissertations

“Magnetic particles and droplets have been used in a wide range applications including biomedicine, biological analysis and chemical reaction. The manipulation of magnetic microparticles or microdroplets in microscale fluid environments is one of the most critical processes in the systems and platforms based on microfluidic technology. The conventional methods are based on magnetic forces to manipulate magnetic particles or droplets in a viscous fluid.

In contrast to conventional magnetic separation method, several recent experimental and theoretical studies have demonstrated a different way to manipulate magnetic non-spherical particles by using a uniform magnetic field in the microchannel. However, the fundamental mechanism …

Integrated Approach To Investigate The Wellbore Integrity Under Downhole Conditions, Weicheng Zhang

Doctoral Dissertations

“The integrity of the cement sheath is the key part to maintain zonal isolation and prevent the inter-zonal communication. Loads arising from multiple stages of wellbore life span may induce various modes of cement failure within the cement (disking and radial cracks) and at the cement-casing and the cement-formation interfaces (debonding fractures). This research utilizes the integrated laboratory and numerical approach to investigate the cement hardening process, to predict the cement failure under various loading conditions. An innovative experimental setup is established to measure the cement pore pressure variation during the hardening process under downhole conditions, and a staged 3D …

Combustion And Emission Characteristics Of Ic Engines Fueled By Hydrogen And Hydrogen/Diesel Mixtures And Multi-Objective Optimization Of Operating Parameters, Abdulhakim Issa Jabbr

Doctoral Dissertations

“The present study considers combustion of hydrogen in IC engines. In general, the work focuses on simulating the engine performance and emissions at different operation parameters, and using optimization techniques. Task I work deals with the engine performance and emissions of a single cylinder spark-ignition (SI) engine fueled by hydrogen. The engine was simulated at different equivalence ratios, exhaust gas recirculation (EGR) and ignition timing. The results indicate that NOx emissions, engine power, and efficiency are reduced by increasing EGR level, and increased with increasing equivalence ratio and advanced ignition timing. The best operating conditions for hydrogen engines were obtained …

Development Of A System Architecture For The Prediction Of Student Success Using Machine Learning Techniques, Tatiana A. Cardona

Doctoral Dissertations

“ The goals of higher education have evolved through time based on the impact that technology development and industry have on productivity. Nowadays, jobs demand increased technical skills, and the supply of prepared personnel to assume those jobs is insufficient. The system of higher education needs to evaluate their practices to realize the potential of cultivating an educated and technically skilled workforce. Currently, completion rates at universities are too low to accomplish the aim of closing the workforce gap. Recent reports indicate that 40 percent of freshman at four-year public colleges will not graduate, and rates of completion are even …

Applications Of Information Theory In Filtering And Sensor Management, Matthew James Gualdoni

Doctoral Dissertations

“A classical sensor tasking methodology is analyzed in the context of generating sensor schedules for monitoring resident space objects (RSOs). This approach, namely maximizing the expected Kullback-Leibler divergence in a measurement update, is evaluated from a probabilistic perspective to determine the accuracy of the conventional approach. In this investigation, a newdivergence-based approach is proposed to circumvent themyopic nature of the measure, forecasting the potential information contribution to a time of interest and leveraging the system dynamics and measurement model to do so. The forecasted objective exploits properties of a batch measurement update to frequently exhibit faster optimization times when compared …

Geo-Engineered Induced Seismicity And The Effects On Federal Infrastructure, Merissa L. Zuzulock

Doctoral Dissertations

“The study of human-induced seismicity and the effects on civil engineering systems are not completely understood or often studied. Moreover, existing studies are focused on the cause of the seismicity and not on the potential damage to infrastructure from these seismic events. There are recent studies that are beginning to focus on shallow induced seismic activity and the effects on infrastructure by establishing innovative ways to quantify that damage. These studies that focus on the potential damage neglect to included considerations for small magnitude cluster events. As geo-induced seismic events increase, soil fatigue becomes of greater concern to structures within …

An Approach To System Of Systems Resiliency Using Architecture And Agent-Based Behavioral Modeling, Paulette Bootz Acheson

Doctoral Dissertations

”In today’s world it is no longer a question of whether a system will be compromised but when the system will be compromised. Consider the recent compromise of the Democratic National Committee (DNC) and Hillary Clinton emails as well as the multiple Yahoo breaches and the break into the Target customer database. The list of exploited vulnerabilities and successful cyber-attacks goes on and on. Because of the amount and frequency of the cyber-attacks, resiliency has taken on a whole new meaning. There is a new perspective within defense to consider resiliency in terms of Mission Success.

This research develops a …

A Molecular Dynamics Study Of Temperature Dependent Wetting In Alkane-Water Systems, Pauf Neupane

Doctoral Dissertations

“The wetting behavior of aqueous organic systems is of great importance in several environmental and industrial processes such as the formation and growth of atmospheric aerosols, crude oil recovery from an oil field, onsite cleaning of natural gas, and clean-up of oil spills. In this work, we employed molecular dynamics (MD) simulations to explore the temperature dependent wetting behavior of octane and nonane on water in planar interfaces as well as in nanodroplets using PYS alkane and SPC/E and TIP4P/2005 water models.

For planar interfaces, we found unusual wetting behavior of octane and nonane on SPC/E water, but generally not …

Development Of A Modeling Algorithm To Predict Lean Implementation Success, Richard Charles Barclay

Doctoral Dissertations

”Lean has become a common term and goal in organizations throughout the world. The approach of eliminating waste and continuous improvement may seem simple on the surface but can be more complex when it comes to implementation. Some firms implement lean with great success, getting complete organizational buy-in and realizing the efficiencies foundational to lean. Other organizations struggle to implement lean. Never able to get the buy-in or traction needed to really institute the sort of cultural change that is often needed to implement change. It would be beneficial to have a tool that organizations could use to assess their …

A Spectroscopic And Photometric Survey Of The W4 Hii Region And Its Young Stellar Population, Matt Wentzel-Long

Doctoral Dissertations

”The W4 HII region is home to a large number of O and B-type stars as well as the young open cluster IC 1805. OB-type produce intense photoionizing radiation and stellar winds that can induce star formation in surrounding molecular clouds and sometimes carve out large regions of decreased particle density called superbubbles. During the star- formation process, young stellar objects (YSOs) are initially surrounded by circumstellar disks made of gas and dust which naturally dissipate after several million years. The dissipation of the disk is thought to occur for a variety of reasons, including photoevaporation by the encompassed protostar …

Enabling Flexibility Through Strategic Management Of Complex Engineering Systems, Walter Louis Barnes Ii

Doctoral Dissertations

”Flexibility is a highly desired attribute of many systems operating in changing or uncertain conditions. It is a common theme in complex systems to identify where flexibility is generated within a system and how to model the processes needed to maintain and sustain flexibility. The key research question that is addressed is: how do we create a new definition of workforce flexibility within a human-technology-artificial intelligence environment?

Workforce flexibility is the management of organizational labor capacities and capabilities in operational environments using a broad and diffuse set of tools and approaches to mitigate system imbalances caused by uncertainties or changes. …

Fuzzy Logistic Regression For Detecting Differential Dna Methylation Regions, Tarek M. Bubaker Bennaser

Doctoral Dissertations

“Epigenetics is the study of changes in gene activity or function that are not related to a change in the DNA sequence. DNA methylation is one of the main types of epigenetic modifications, that occur when a methyl chemical group attaches to a cytosine on the DNA sequence. Although the sequence does not change, the addition of a methyl group can change the way genes are expressed and produce different phenotypes. DNA methylation is involved in many biological processes and has important implications in the fields of biomedicine and agriculture.

Statistical methods have been developed to compare DNA methylation at …

History Of Natural And Anthropogenic Activities In Lake Izabal, Eastern Guatemala: Using Geochemical Evidence To Record Recent Contamination, Elisandra Hernandez

Doctoral Dissertations

”Water is essential for human subsistence. Stable freshwater supplies are needed as a source of food, drinking water, for transportation, recreation and economic development. Despite their recognized importance, anthropogenic activities have altered freshwater ecosystems around the world. Lake Izabal is the habitat for diverse aquatic species of flora and fauna, some of which are endemic and endangered. Its importance notwithstanding, anthropogenic activities developed in Lake Izabal’s catchment in recent years have compromised its status. This study used paleolimnological techniques to link past and recent anthropogenic activities such as mining operations and recent tilapia aquaculture. Relative abundances and concentrations of Pb, …

Modification Of The Optical Response Of Alpha Quartz Via The Deposition Of Gold Nanoparticles In Etched Ion Tracks, Maria C. Garcia Toro

Doctoral Dissertations

”This study addresses the experimental methods used to develop and characterize plasmonic devices capable of modifying the optical response of alpha quartz via the deposition of gold nanoparticles in etched ion tracks. In the first part of the research, the microstructural characterization of latent and etched ion tracks produced in alpha quartz (α-SiO₂) is presented. Single crystals of α-SiO₂ were irradiated with two highly energetic ions to different nominal fluences. As expected, the morphology of the resulting ion tracks depends on the energy of the incident ion and their stopping powers within the target material. Subsequent chemical …

Removal Of Non-Metallic Inclusions From Molten Steel By Ceramic Foam Filtration, Soumava Chakraborty

Doctoral Dissertations

”Ceramic filters are routinely used in steel foundries to remove non-metallic inclusions from steel melt. Removal efficiency for both solid and liquid inclusions by magnesia-stabilized zirconia foam filters (10ppi) were evaluated and distribution of the captured inclusions through the filter thickness was also investigated. A mold design was developed using a commercial computational fluid dynamics software package to produce two castings that fill simultaneously, one with a filter and the other without a filter, from a single ladle pour, while also matching the fill rates and avoid turbulence and reoxidation during pouring. An industrial-scale experiment was also performed to investigate …

Studying The Effects Of Various Process Parameters On Early Age Hydration Of Single- And Multi-Phase Cementitious Systems, Rachel Cook

Doctoral Dissertations

”The hydration of multi-phase ordinary Portland cement (OPC) and its pure phase derivatives, such as tricalcium silicate (C₃S) and belite (ß-C₂S), are studied in the context varying process parameters -- for instance, variable water content, water activity, superplasticizer structure and dose, and mineral additive type and particle size. These parameters are studied by means of physical experiments and numerical/computational techniques, such as: thermodynamic estimations; numerical kinetic-based modelling; and artificial intelligence techniques like machine learning (ML) models. In the past decade, numerical kinetic modeling has greatly improved in terms of fitting experimental, isothermal calorimetry to kinetic-based modelling …

Tools To Evaluate Nanodiamond-Mediated Delivery Of Tiopronin For Cataract Prevention, Justin Beltz

Doctoral Dissertations

”There is a growing demand for non-surgical means of cataract treatment. This dissertation presents three bodies of work that reflect the early-stage development of eye drop formulations aimed at delaying cataract progression. These formulations consist of the antioxidant 2-mercaptopropionylglycine (MPG) loaded onto nanodiamond particles.

Cataractogenesis is linked to oxidative damage to lens proteins. To investigate the potential of MPG for protection against oxidative damage, A549 cells were incubated in 0.6 mM tert-butylhydroperoxide (tBHP). Cells exposed to tBHP without MPG exhibited elevated levels of reactive oxygen species, which led to the depletion of the vital antioxidant glutathione and, ultimately, apoptosis. Co-administration …

Modeling And Optimization Of Froth Flotation Of Low-Grade Phosphate Ores: Experiments And Machine Learning, Ashraf Alsafasfeh

Doctoral Dissertations

”In this research work, bench-scale and micro-scale flotation tests were conducted to separate “minerals from silicate minerals using direct and reverse flotation approaches, respectively. Experiments were conducted at different flotation conditions including reagents’ type, reagents’ dosages, pulp’s pH, and flotation time.

In the direct flotation process, two polymers were selected to promote the depression of silicates: hybrid polyacrylamide-based polymers (Hy-PAM) and chitosan. Results indicated that the highest recovery of P₂O₅ (86.82%) was obtained when the Hy-PAM polymer was used compared with 66.7% and 40% when chitosan and commercial inorganic depressant were used, respectively. The experimental datasets obtained …

Critical Success Factors And Risk Mitigation Strategy For New Product Development, Rodney A. Ewing

Doctoral Dissertations

”Success in new product development (NPD) offers a competitive and comparative advantage in the marketplace. A primary objective in an NPD project is to launch world class products with minimal risk. To deliver the superior quality and performance customers require, a company must develop the right NPD structure and framework for seamless execution by the NPD project teams throughout the product lifecycle. Companies must understand how to identify and mitigate risk to enable the success of their NPD projects. The costs to develop new products are often a considerable portion of an organization’s budget; however, studies have shown only 60 …

Predictive Geohazard Mapping Using Lidar And Satellite Imagery In Missouri And Oklahoma, Usa, Olufeyisayo B. Ososami

Doctoral Dissertations

”Light Detection and Ranging (LiDAR) and satellite imagery have become the most utilized remote sensing technologies for compiling inventories of surficial geologic conditions. Point cloud data obtained from multi-spectral remote sensing methods provide a detailed characterization of the surface features, in particular, the detailed surface manifestations of underlying geologic structures. When combined, point clouds eliminate bias from visual inconsistencies and/or statistical values. This research explores the competence of point clouds derived from LiDAR and Unmanned Aerial Systems (UAS) as a predictive tool in evaluating various geohazards. It combines these data sets with other remote sensing techniques to evaluate the sensitivity …

Strategies To Improve The Electrochemical Performance Of Lithium-Ion Batteries By Stabilizing The Interface Of Electrode/Electrolyte, Ye Jin

Doctoral Dissertations

”Lithium-ion batteries (LIBs) provide great potential for electric vehicles, and smart grids as future energy-storage devices. However, there are many challenges in the development of the LIB industry, including low energy and power density of electrode materials, poor rate performance, short cycle life of electrode materials, and safety issues caused by the flammability of the conventional organic liquid electrolytes.

In this research, we were committed to using general approach to efficiently and economically synthesize or modify LIB materials by stabilizing the interface between electrode and electrolyte. Atomic layer deposition (ALD) method was used to coat metal oxide thin films on …

Improved Attenuation And Crosstalk Modeling Techniques For High-Speed Channels, Shaohui Yong

Doctoral Dissertations

”As digital systems are moving in the direction of faster data transmission rate and higher density of circuits, the problem of the far-end crosstalk (FEXT) and frequency-dependent attenuation are becoming the major factors that limit signal integrity performance. This research is focusing on providing several more comprehensive and accurate modeling approaches for striplines on fabricated printed circuit board (PCB). By characterizing the dielectric permittivity of prepreg and core, dielectric loss tangent, and copper foil surface roughness using measurement data, a better agreement between the stripline model and measurement is achieved. First, a method is proposed to extract dielectric loss tangent …

Fabrication Of Micro-/Nanofluidic Models And Their Applications For Enhanced Oil Recovery Mechanism Study, Yandong Zhang

Doctoral Dissertations

”Micro-/nanofluidic model, as a potential powerful tool, has been used for decades for investigating fluid flow at pore-scale in energy field. It is still increasingly imperative nowadays to use different micromodels to direct observe pore-level fluid flow and analyze mechanisms of different enhanced oil recovery methods. In this work, three main tasks including three dimensional micromodels (1D,2D,3D) are proposed to fabricate and use for investigating different mechanisms of different enhanced oil recovery methods. For 1D capillary tube micromodel, we fabricate and use it to investigate the dynamics of a trapped oil droplet under seismic vibration. Seismic stimulation is a promising …

Development Of Horizontal Axis Hydrokinetic Turbine Using Experimental And Numerical Approaches, Abdulaziz Abutunis

Doctoral Dissertations

“Hydrokinetic energy conversion systems (HECSs) are emerging as viable solutions for harnessing the kinetic energy in river streams and tidal currents due to their low operating head and flexible mobility. This study is focused on the experimental and numerical aspects of developing an axial HECS for applications with low head ranges and limited operational space. In Part I, blade element momentum (BEM) and neural network (NN) models were developed and coupled to overcome the BEM’s inherent convergence issues which hinder the blade design process. The NNs were also used as a multivariate interpolation tool to estimate the blade hydrodynamic characteristics …

Seismic Behavior Of Composite Bridge Columns, Mohanad M. Abdulazeez

Doctoral Dissertations

“This study investigates experimentally and numerically the seismic behavior of large-scale hollow-core fiber-reinforced polymer-concrete-steel (HC-FCS) innovative bridge columns as a sustainable approach to endure and rapidly recover from natural disasters such as earthquakes. The HC-FCS column consisted of a concrete shell sandwiched between an outer fiber-reinforced polymer (GFRP) tube and an inner steel tube to provided continuous confinement for the concrete shell along with the height of the column. The columns have a slender inner steel tube with diameter-to-thickness (D_s/t_s) ratios ranged between 85 to 254. Each steel tube was embedded into the footing, while the …

Geophysical Characteristics Of Nickel And Copper Deposits In Wadi Al Khadra Prospect, Southwestern Of Saudi Arabia, Abdulrahman Ahmed Aljabbab

Doctoral Dissertations

“Three geophysical datasets (self-potential, magnetics, and time - domain electromagnetics) were acquired at Wadi Al Khadra Ni-Cu prospect in southwest Saudi Arabia, and were processed and interpreted for the Saudi Geological Survey. The primary objectives were to map the distribution of metallic mineralization, map structures, verify the integration of the geophysical interpretations and its signatures in conjunction with boreholes information, distinguish the similarities and differences in the integrated interpretation of geophysical data, and design optimal processing and interpretation data parameters. The self-potential tool was used to map the variation in natural surface potential differences to map lateral variations in the …

Balancing Labor Requirements In A Manufacturing Environment, Patrick Bernard Dwyer

Doctoral Dissertations

“This research examines construction environments within manufacturing facilities, specifically semiconductor manufacturing facilities, and develops a new optimization method that is scalable for large construction projects with multiple execution modes and resource constraints. The model is developed to represent real-world conditions in which project activities do not have a fixed, prespecified duration but rather a total amount of work that is directly impacted by the level of resources assigned. To expand on the concept of resource driven project durations, this research aims to mimic manufacturing construction environments by allowing a non-continuous resource allocation to project tasks. This concept allows for resources …

Development Of Novel Materials And Processes For Direct Conversion Of Co₂ Flue Gas To Chemicals And Fuels, Ahmed Al-Mamoori

Doctoral Dissertations

“This research focused on addressing the pressing issues of greenhouse gas emissions that greatly contribute to climate change. Specifically, the focus was given to the reduction of anthropogenic CO₂ emission and its subsequent conversion to commodity chemicals and fuels. In the first part of the research, a series of novel high temperature CO₂ adsorbents including double salts (K-Ca and Na-Ca) and metal-doped calcium oxide (Fe_x@CaO and Ga_x@CaO) was developed and evaluated. Both sets of materials exhibited high CO₂ capacity, fast kinetics, and long-term stability. In particular, at 650 °C, the doped adsorbents comprising …

Pattern Selection Models: From Normal To Anomalous Diffusion, Hatim K. Khudhair

Doctoral Dissertations

“Pattern formation and selection is an important topic in many physical, chemical, and biological fields. In 1952, Alan Turing showed that a system of chemical substances could produce spatially stable patterns by the interplay of diffusion and reactions. Since then, pattern formations have been widely studied via the reaction-diffusion models. So far, patterns in the single-component system with normal diffusion have been well understood. Motivated by the experimental observations, more recent attention has been focused on the reaction-diffusion systems with anomalous diffusion as well as coupled multi-component systems. The objectives of this dissertation are to study the effects of superdiffusion …

Behavior Of Negative Stiffness Metamaterial Systems In Structural Engineering Applications, Yasser Darwish

Doctoral Dissertations

“Metamaterial systems with negative stiffness behavior became a point of interest in many energy dissipation applications due to their ability to dissipate high levels of energy. Negative stiffness metamaterial elements can dissipate energy through non-linear elastic behavior when transferred from one stable mode of buckling to another. Hence, the ability of such elements to be reusable for multiple loading cycles exists. Such unique properties made the metamaterial systems a perfect candidate for structural applications such as impact protection of bridges against collision. This research provides innovative metamaterial shell structure that can exhibit negative stiffness behavior by deforming from one shape …