Digital Commons Network^™

Development Of Intelligent Stimuli-Responsive Biomaterials And Nanodevices, Shuo Yang

Doctoral Dissertations

"Structural DNA nanotechnology utilizes DNA molecules as building blocks to fabricate ordered artificial nanostructures at the molecular level. Among all DNA-based techniques, DNA origami has been considered as one of the most powerful tools for constructing artificial nanostructures with excellent programmability and addressability. Currently, most DNA origami nanostructures are static and do not have the ability to response to environmental stimulation. The development of environmental-responsive DNA origami nanostructures is a critical step towards the realization of intelligent dynamic DNA origami-based nanodevices. This research focuses on the design and fabrication process of both static and dynamic DNA origami nanostructures and their …

Additively Manufactured Metallic Cellular Structures, Okanmisope Aziel Fashanu

Doctoral Dissertations

"Cellular structures are lightweight structures with excellent mechanical, thermal, and acoustic properties. They offer promise in a series of applications, including lightweight applications, sandwich cores, mechanical damping, acoustic absorption, strain isolation, and thermal management. The manufacturing of these complex cellular structures is expensive and time-consuming, which hinders the adoption of these structures in many industries. Advancement in manufacturing technologies, such as additive manufacturing (AM), however, have changed this. AM allows for the rapid and less expensive manufacturing of complex cellular structures. This work aimed to investigate the performance of additively manufactured cellular structures for lightweight and sandwich core applications. In …

Advanced Battery Modeling For Interfacial Phenomena And Optimal Charging, Yaqi Zhu

Doctoral Dissertations

"Lithium-ion batteries are one of the most promising energy storage systems for portable devices, transportation, and renewable grids. To meet the increasing requirements of these applications, higher energy density and areal capacity, long cycle life, fast charging rate and enhanced safety for lithium-ion battery (LIBs) are urgently needed. To solve these challenges, the relevant physics at different length scale need to be understood. However, experimental study is time consuming and limited in small scale’s study. Modeling techniques provide us powerful tools to get a deep understanding of the relevant physics and find optimal solutions. This work focuses on studying the …

Prediction Of Battery Health Dynamics, Damola Martins Ajiboye

Doctoral Dissertations

"The successful market penetration of lithium-ion batteries in the last 30 years has ushered in a new dawn in energy applications. Notwithstanding their widespread use, lithium-ion batteries are affected by a plethora of fundamental issues — safety, cycle life, performance, and cost. In this work, advanced modeling techniques are developed to tackle some of these issues. This dissertation is subdivided into four parts, the first is introduction while the remaining are dedicated to the development of computational techniques for predicting battery health dynamics.

In the second part of this work, we developed fast and accurate algorithms for modeling essential battery …

Studying The Effects Of New Additive Materials For The Improvement Of The Capacity And Cycle Life Performance Of The Lead-Acid Battery, Julian Kosacki

Doctoral Dissertations

"Lead-acid batteries are an established technology with nearly 99% recyclability; however, lead-acid batteries produce only 40% of their theoretical capacity due to poor active mass utilization and PbSO4 pore blockage, and the longevity of the batteries is hampered by secondary reactions during the cycle life such as corrosion and gassing.

Lead-acid batteries were investigated and improved through several different approaches: an alternative electrolyte to mitigate secondary reactions, graphite additives to improve positive active mass (PAM) utilization, and dispersant additives to help the industrial pasting process.

The thermodynamics and chemical reactions of a commercial electrolyte replacement called Tydrolyte^TM were investigated …

Hydromechanical Stress And Internal Erosion Under Earthen Structures, Kerry Allen Magner

Doctoral Dissertations

"Dam failures by seepage and internal erosion have reportedly been attributed to up to 40% of all dam failures in the United States. Backwards piping erosion either through the embankment or foundation soils has been reported to be the major contributing method to seepage and internal erosion dam failures. This proposed research is motivated by the lack of understanding of the complex stress regimes associated with internal erosion in cohesionless soils under earthen structures. The overall goal of this research is to provide a fundamental understanding of internal erosion and the hydromechanical stress conditions necessary for the initiation and continuation …

Sources Of Quality Uncertainty In Laser Powder Bed Fusion Metal Additive Manufacturing, Zachary Young

Doctoral Dissertations

"Powder based additive manufacturing (AM) exhibits tremendous uncertainties, where variations in build quality is present despite utilizing similar build processing parameters. First, this work reports the features and formation mechanisms of five unique types of spatter during the LPBF process by in-situ high-speed, high-energy x-ray imaging. The unique physical characteristics of spatter are determined. The effect of laser scan speed and laser power on spatter formation, ejection, and mitigation are determined. Second, this work addresses the uncertainty challenge by identifying the sources of uncertainty in SLM by in-situ characterization due to variations from the additive manufacturing processing parameters needed for …

Investigating The Impact Of Rock Bridges On The Mechanical Behavior Of Jointed Rock Mass Using Lattice Spring-Based Synthetic Rock Mass (Ls-Srm) Approach, Mariam Salem Alebayat

Doctoral Dissertations

"Rock bridges were defined as a segment of intact rock that separates from discontinuities. Numerous studies are focused on developing methods to quantify their significance in rock mass strength and deformability behavior. This thesis aimed to enhance understanding of the effect of rock bridges on jointed rock masses in both laboratory and slope scales. For this purpose, the lattice spring base Synthetic Rock Mass (LS-SRM) method was adopted to conduct the numerical models, distinguished in computational efficiency, and simulates the brittle failure and roughness of discontinuities.

A robust approach was developed to optimize the calibration procedure to avoid the complex …

Novel Synthetic Methods And Applications Of Porous Materials: Aerogel Foams, Metallic Aerogels, Amorphous And Graphitic Carbon Aerogels, Rushi Soni

Doctoral Dissertations

"We report novel methods for the synthesis of porous materials such as polymeric aerogel foams, pure metallic aerogels, amorphous and graphitic carbon aerogels, and their applications. I. Polyurethane based aerogel foams were synthesized with an aliphatic triisocyanate and ethylene glycol through a pressurized (7 bar) sol-gel method. The foam-like structure is prepared without any chemical foaming agents or templates, resulting in less expensive, more efficient, readily adaptable, and environmentally friendly process. Those materials exhibited lower thermal conductivity (by 25%) and higher oil adsorption capacity (by 36% w/w) than their corresponding aerogels. II. Monolithic, pure metallic Co(0) aerogels were synthesized from …

Thermal Mapping Of Metal Casting Mold Using High Resolution Distributed Fiber-Optic Sensors, Muhammad Roman, Damilola Balogun, Chen Zhu, Laura Bartlett, Ronald J. O'Malley, Rex Gerald, Jie Huang

PSMRC Faculty Research

This article reports a technique to embed optical fiber into a copper mold plate for generating high-density thermal maps of the mold during the process of metal casting. The temperature measurements were based on acquiring and interpreting Rayleigh backscattering (RBS) signals from embedded fiber, using the interrogation technique of optical frequency domain reflectometry (OFDR). The instrumented mold plate was used to perform a cast-iron dip test and a steel dip test in a 200 lb induction furnace. The maximum temperatures recorded by the embedded fiber-optic sensors were 469 degrees C and 388 degrees C in the cast-iron and steel dip …

Novel Piezo Actuators For Surface Cleaning, Yezad H. Anklesaria

Doctoral Dissertations

"Optical cameras are becoming increasingly common and are used in a variety of applications. With recent progress and transition toward more autonomous systems, the usage of optical systems will be common and widespread. Applications of the optical systems range from autonomous vehicles, home security systems, aviation, extraterrestrial vehicles, spacecraft, and satellites. Imaging systems are used in decision-making in many of these applications. Fouling of the field of view of the imaging system can impede the decision process. An active autonomous cleaning method for the optical surface of the optical systems reliably would be advantageous. The research work focuses on developing …

Convective-Diffusive Transport In Krogh Cylinders: A Model For Pharmacokinetics, Xianjie Qiu

Doctoral Dissertations

"Drug delivery to inside of the tumor is the important problem. The dynamics of drug delivery is presented here. Previously and particularly for directed delivery, a stirred tank model has been used, which appears to have worked well when compared to experiments. However, the stirred tank models do not include all the mass transfer resistances and towards that end we have used a distributed system called Krogh cylinder. This study focuses on the Krogh cylinder model simulation, both on the fluid flow and the mass transfer. The capillary network is broken down into cylindrical cells, each containing a capillary and …

Receiver Function Imaging Of The 410 And 660 Km Discontinuities And Seismic Azimuthal Anisotropy Revealed By Shear Wave Splitting Beneath The Australian Continent, Kailun Ba

Doctoral Dissertations

"The Australian continent is composed the of Precambrian cratons in the west and Phanerozolc orogens in the east. Despite numerous seismological studies, controversies remain regarding the structure, evolution, and dynamics of the crust and mantle beneath Australia. In this study, we used two techniques, receiver functions and shear wave splitting analyses, to investigate the topography of the mantle transition zone (MTZ) discontinuities and mantle seismic azimuthal anisotropy, respectively. We utilized P-to-S receiver functions to map the 410 and 660 km discontinuities bordering the MTZ. The discontinuity depths obtained show a systematic apparent uplifting for both discontinuities in central and western …

Information-Based Methods And Models For Particle Flow Filtering, Kari Catherine Ward

Doctoral Dissertations

"Recursive estimation methodologies, such as Kalman and Bayesian filters, typically require models of some kind to perform the estimation. This filtering process seeks to improve knowledge surrounding some quantities of interest, or states, over time by incorporation of imperfect observations. The models required pertain to the state dynamics, sensors from which measurements are obtained, and probabilistic models of the underlying stochastic processes. In addition to any number of necessary models, real-world application of a filter is normally accompanied by at least one, if not several, techniques to promote better performance. These methods vary in purpose from expanding the kinds of …

Swill-Tac: Skill-Oriented Dynamic Task Allocation With Willingness For Complex Job In Crowdsourcing, Riya Samanta, Soumya K. Ghosh, Sajal K. Das

Computer Science Faculty Research & Creative Works

Allocating tasks to the best-fit candidates is a classical problem in crowdsourcing (CS). Most of the existing approaches assume that the task and candidate knowledge is known in advance and ignore the effect of enrolled candidates' willingness on the CS system's selection decision. For instance, an unwilling candidate assigned to a task may quit without completing it, thus depreciating the utility of the CS platform. In practice, a task or candidate may arrive or leave the CS system dynamically. Moreover, a complex task may be broken into smaller sub-tasks, each requiring a variety of computations and expertise. To overcome these …

Quality-Of-Service Architecture For Cloud Computing Networking, Ken R. Owens Jr., Steve Eugene Watkins

Electrical and Computer Engineering Faculty Research & Creative Works

Quality-of-service (QoS) performance is an important consideration for real-time and high-priority traffic on internet protocol (IP) networks. Service differentiation can provide a more efficient and customer-oriented internet. The “best-effort” internet models in use today cannot provide guarantees or service differentiation for end-to-end individual and aggregate data flows. Hardware-based models and software-based models do not completely address the total service-enabled solution. We propose a hybrid architecture that combines software and hardware features to handle network traffic with diverse QoS requirements. Since cloud providers leverage IP networks today, the model is based on a systems engineering approach that uses cloud computing technologies. …

Stress-State Dependency Of The Deformation Ratio Of Quasi-Elastic Granular Soils Under Cyclic Loading -- Supporting Information, Pingxin Xia, Longtan Shao, Wen Deng

Research Data

Poisson’s ratio, besides its transverse-axial strain ratio definition, also plays a significant role in traditional elastic theory as an elastic constant. However, this elastic role of Poisson’s ratio faces a challenge when applied to quasi-elastic granular soils. A so-called “deformation ratio” is therefore introduced and measured in this paper for quasi-elastic granular soils. With the same definition of the transverse-axial strain ratio as Poisson’s ratio, the stress-state dependency of the deformation ratio and the break-down of conversion relationship of elastic constants are investigated under cyclic triaxial tests. The results show that Poisson’s ratio is consistent with deformation ratio only in …

Contributions To The Performance Of Thin Film Capacitors For High Reliability Applications, Daniel Krueger

Doctoral Dissertations

"Capacitors are critical devices in microelectronic assemblies that must be incorporated into electronic systems through a variety of ways such as integrated or discrete devices. This work has developed new thin film capacitors deposited directly onto multichip module or printed circuit board surfaces to benefit from closer integration that enhances system performance for use in high reliability applications. The capacitors serve as filters or provide tuning and energy storage functions. Unexpected performance was observed during development that included low adhesion of the films to the substrates, higher effective dielectric constants than reported in literature, and low yields. Three publications resulted …

Gis And Remote Sensing Groundwater Potentiality Investigation Of Gulu District, Uganda Using Synthetic Aperture Radar And Magnetic Geophysics, Rachel Ann Jones

Doctoral Dissertations

“Developing countries have few resources for ground-based hydrological investigations to determine optimal placement of boreholes for community water access. Remote sensing data are available at a variety of resolutions and sense different parameters, and are useful inputs for hydrologic models, but these data are rarely obtainable in developing countries with the parameters or resolutions necessary for hydrologic applications. This research seeks to use and improve existing remote sensing and GIS techniques to identify areas of optimal water supply in locations with limited geologic or hydrologic information, such as Gulu District, Uganda. Fusing different remotely sensed data sets can produce higher …

Studies On Tornado-Structure Interactions And Guidance On Design Tornadic Wind Loading, Zhi Li

Doctoral Dissertations

“Tornadoes are violent natural hazards that could caused significant property loss and fatalities. Statistical data indicates that most fatalities during tornado incidents were caused by the building failure under tornadoes. For example, in the 2011 Joplin Tornado, 161 people were killed, and 84 percent of the fatalities were related to the failure of buildings. In addition, most of the significant, tornado-induced property loss and fatalities are relevant to the tornadoes passing through the densely populated regions. Besides buildings, bridges were also severely damaged or destroyed by tornadoes in the United States. To reduce the tornado-induced loss, it is imperative to …

Development Of Tripodal And Bipodal Ligand Frameworks And First-Row Transition Metal Reagents For Selective C-N Bond Construction Methodologies, Anshika Kalra

Doctoral Dissertations

"We present a family of anionic Mn(II) reagents supported by trisphenylamido- amlne frameworks that offer guidance with regards to ligand selection for developing C—N bond construction methodologies (extensively used in the synthesis of petrochemicals, household chemicals) through nitrene- transfer chemistry. We subsequently extend the study to include the corresponding Fe(II), Co(II), and Ni(II) reagents, to gain insights in their comparative reactivity/selectivity patterns. Attenuated levels of electrophilicity of anionic complexes proved to be more suitable for discriminating aromatic from aliphatic olefins for aziridination purposes, especially for Mn(II) complexes. However, in the case of Co(II) reagents, we observe that additional stereoelectronic parameters …

Protection Of Modern Distribution Systems, Fahd Amin Hariri

Doctoral Dissertations

“Motivated by the potential for improvements in the electric distribution system’s protection schemes, this work examined the challenges facing protection schemes due to the integration of Distributed Generators (DGs). Traditional protection schemes for radial distribution systems were designed based on the unidirectional power flow from the source down to the loads. Protective devices typically use are overcurrent relays, autoreclosers, fuses, and circuit breakers. However, these protective schemes may no longer be sufficient to ensure correct operation in the new era of distribution systems integrated by DGs. This research investigated the impact of DGs that might mislead the protection schemes in …

An Investigation On The Regulation Of The Tweak–Fn14–Nf-Kb Pathway, Jawahar Khetan

Doctoral Dissertations

“Dysregulation of inflammatory pathways is strongly implicated in cancers and autoimmune diseases. The most consequential of these pathways involves the nuclear translocation of NF-kB, a transcription factor that induces the transcription of multiple proteins associated with cell survival, inflammation, proliferation and death. It is activated when the fibroblast growth factor-inducible 14 kDa protein (Fn14), a trimeric receptor recruits its ligand, TWEAK. Studies have shown that Fn14 is over-expressed in many tumors, the aggressiveness of which is often correlated with the degree of upregulation. Furthermore, TWEAK-Fn14 activation has been shown to result in persistent NF-kB activation. Using a mechanistic model of …

Proper Orthogonal Decomposition: New Approximation Theory And A New Computational Approach, Sarah Katherine Locke

Doctoral Dissertations

“Proper orthogonal decomposition (POD) projection errors and error bounds for POD reduced order models of partial differential equations have been studied by many. In this research we obtain new results regarding POD data approximation theory and present a new difference quotient (DQ) approach for computing the POD modes of the data.

First, we improve on earlier results concerning POD projection errors by extending to a more general framework that allows for non-orthogonal POD projections and seminorms. We obtain new exact error formulas and convergence results for POD data approximation errors, and also prove new pointwise convergence results and error bounds …

Spatial Variations Of Teleseismic P-Wave Attenuation And Scattering Beneath The Southeastern United States And The Malawi And Luangwa Rift Zones In East Africa, Ashutosh Shrivastava

Doctoral Dissertations

"Seismic attenuation is an important physical parameter for characterizing subsurface morphology and the thermal structure of the Earth’s crust and mantle. In this study, teleseismic P-wave amplitude spectra are used to examine the seismic attenuation beneath the southeastern United States and the Malawi and Luangwa rift zones in east African. The resulting seismic attenuation parameters (Δt*) reveal a systematic contrast between the Appalachian Mountains and the Gulf of Mexico Coastal Plain exhibiting high and low attenuation, respectively. Spatial coherency analysis of the Δt* observations suggests that the center of the low-attenuation layer is located within the uppermost mantle at about …

Emi Characterization For Power Supplies And Machine Learning Based Modeling In Emc/Si, Jiayi He

Doctoral Dissertations

"Signal integrity (SI) and electromagnetic interference (EMI) are essential for consumer electronics and high-speed server applications. It is necessary to do EMI and SI modeling at the design stage. In this research, several modeling approaches for EMI and SI problems are proposed. By using measurement-based modeling method, the mechanism of conducted emissions (CE) on ac to dc power supplies in an LED TV is analyzed. A system-level transient simulation model is built to predict the conducted emission (CE). To characterize the equivalent dipole moment sources in RFI and EMI problems, a dipole source reconstruction method based on machine learning techniques …

Using Similitude Theory And Discrete Element Modeling To Understand The Effects Of Digging Parameters On Excavation Performance For Rubber Tire Loaders, Atta Ur Rehman

Doctoral Dissertations

"The large sizes of mining equipment pose challenges for analysis using experiments or simulation. While scaled physical and simulation models can address this challenge, no previous work has explored how similitude theory and modeling can provide valid analysis of large equipment such as rubber tire loaders. The objective of this research was to apply similitude theory and discrete element modeling (DEM) to study the effect of different digging parameters on the penetration and the draft on the buckets of rubber tire loaders. The work sought to (1) test the hypothesis that the geometry of a rubber tire loader bucket and …

Computational Studies Of Carbon Nanocluster Solidification, Chathuri Chandani Silva

Doctoral Dissertations

“A subset of micron-size meteoritic carbon particles formed in red giant atmospheres show a core-rim structure, likely condensed from a vapor phase into super-cooled carbon droplets that nucleated graphene sheets (~40Å) on randomly oriented 5-atom loops during solidification, followed by coating with a graphite rim. Similar particles form during slow cooling of carbon vapor in the lab.

Here we investigate the nucleation and growth of carbon rings and graphene sheets using density functional theory (DFT). Our objectives: (1). explore different computational techniques in DFT-VASP for various carbon structures and compare the results with literature, (2). investigate the nucleation and growth …

The Pilot Knob Magnetite, Pilot Knob Hematite, And Shepherd Mountain Iron Oxide Deposits In Southeast Missouri -- Local Expressions Of A Magmatic-Hydrothermal Plumbing System?, Bolorchimeg N. Tunnell

Doctoral Dissertations

“The Southeast Missouri Iron Metallogenic Province in the Midwestern USA contains seven major and several minor IOA/IOCG-type deposits, all of which are spatially associated with the early Mesoproterozoic (1.50-1.44 Ga) magmatism in the St. Francois Mountains terrane. This Ph.D. project focuses on the Pilot Knob deposits, i.e., the deeper largely massive Pilot Knob Magnetite (PKM) and the shallower Pilot Knob Hematite (PKH) deposits, and the Shepherd Mountain deposit that are located less than 2.1 km distance from one another. The first precise age for the formation of the PKM ore is constrained at 1438±5.8 Ma using apatite U-Pb method. Petrographic …

Instrumentation, Modeling, And Sound Metamodeling Foundations For Complex Hybrid Systems, Natasha Amelia Jarus

Doctoral Dissertations

Many of our critical infrastructures, from power grids to water distribution networks, are complex hybrid systems that use software to control their non-trivial physical dynamics. These systems must be able to capably serve their purpose, while also being reliable, dependable, safe, secure, and efficient. Representation and analysis of these features requires the creation of several distinct models. These models may encode design goals or be derived from collected instrumentation data, reflecting both how a system ought to operate and how it does operate. It is essential to ensure that all of these models consistently and accurately describe the same system. …