Digital Commons Network^™

Selected First Row Transition Metal Coordination Compounds Of 2-(N-Aminomethyl)-3-Quinuclidinone Chelates, Richard Cecil Dickinson

Doctoral Dissertations

"As part of a project directed towards elucidating the characteristics of ligands which coordinate to give complexes having tetrahedral structures, a study of chelates containing the bulky quinuclidine group has been made. With 2-(N-morpholinylmethyl)-3-quinuclidinone (MQN), complexes having the general formula M(MQN)X₂ were prepared where the metal ion was Co(II), Ni(II), Fe(II), Cu(II), and Mn(II). The ligands 2-(N-piperidinylmethyl)-3-quinuclidinone (PQN) and 2-(N-dimethylaminomethyl)-3-quinuclidinone (DQN) were prepared along with the analogous cobalt(II) chloride complexes. The series of complexes Co(MQN)X₂ where X = Cl, Br, or I were prepared, and magnetic susceptibilities and spectral data obtained. They have room temperature magnetic moments in the range …

The Utilization Of High Sensitivity Noble Gas Mass Spectrometry In The Detection Of Iodine-129 And Plutonium-244, Mervet S. Boulos

Doctoral Dissertations

"Mass spectrometric analysis of the xenon isotopes in natural gas wells demonstrates that radioactive isotopes of element number 53 (I) and element number 94 (Pu) were present at the time of the Earth's formation. Evidence for the now extinct nuclide¹²⁹I (t_1/2 = 17 x 10⁶ years) was found in CO₂ -rich gas while evidence for the now extinct ²⁴⁴Pu (t_1/2 = 82 x 10⁶ years) was discovered in other natural gas wells. The amounts of ¹²⁹I in thyroids was measured by combining neutron activation analysis with noble gas mass spectrometry. The current …

Statistical Studies Of Various Time-To-Fail Distributions, James Addison Eastman

Doctoral Dissertations

"Three models are considered that have U-shaped hazard functions, and a fourth model is considered that has a linear hazard function. Several methods for estimating the parameters are given for each of these models. Also, various tests of hypotheses are considered in the case of the model with the linear hazard function. One of the models with a U-shaped hazard function has a location and a scale parameter, and it is proved in general that any other parameters in a distribution of this type are distributed independently of the location and scale parameters.

A new method used to estimate the …

Modal Truncation Of Substructures Used In Vibration Analysis, Suresh Kumar Tolani

Doctoral Dissertations

"The objective of this study is to describe in a unified manner a group of structural dynamics analyses using the substructures technique. An additional effort is to provide a consistent basis for the selection of substructure principal modes as required by this method. Substructure principal mode frequency roots and strain energy are two criteria evaluated for the selection of substructure principal modes. System eigenvalues and system strain energy are investigated for the comparison of results in the principal modes. System strain energy should provide more rational results since it is proportional to the stress times the strain in the system …

Stratigraphy, Genesis, And Economic Potential Of The Southern Part Of The Florida Land-Pebble Phosphate Field, Dean Stanley Clark

Doctoral Dissertations

"The important and highly productive Florida land-pebble phosphate field is located in west central peninsular Florida in portions of Hillsborough, Polk, Hardee, and Manatee counties. The Pine Level phosphate area, described in detail in this report, is south of the previously known and mined deposits and occurs in portions of Manatee, Sarasota, and De Soto counties. Results of the current geologic study of the Pine Level phosphate deposit and the evaluation of the overall potential of this southern part of the land-pebble field are presented.

The entire southern part of the phosphate field is underlain by more than 15,000 feet …

The Mio-Eugeosynclinal Thrust Interface And Related Petroleum Implications In The Sason-Baykan Area, Southeast Turkey, Ismail Özkaya

Doctoral Dissertations

"A detailed investigation of the stratigraphy, structure and petroleum geology of the Sason-Baykan region in 600 square km area of the thrust belt of southeast Turkey was completed at a scale 1: 25 000. Geosynclinal sediments within the area were redated.

Results of field study indicate a massive plate of metamorphic rocks and crystalline limestones was thrust southward over geosynclinals sediments. These in turn were thrust over the southern marginal basin deposits. A stratigraphic sequence of the allochthonous geosynclinals sediments was reconstructed and correlated with the autochthonous Tertiary section. Contrary to earlier views the allochthonous sediments and accompanying igneous rocks …

The Effect And Compensation Of Time-Base Perturbations In Analog Recording Systems, Clifford D. Skouby

Doctoral Dissertations

"The mean square error between recorded and reproduced signals is used as an error measure to determine the effects of time-base perturbations on an analog singal. The mean square error caused by time-base perturbations is shown to be proportional to the product of the square of the signal bandwidth and the time-base error variance for the case of low pass signal. When the signal is band pass, there is shown to be an additional error term which is proportional to the square of the signal center frequency and the time-base error variance.

Calculations are also carried out to determine the …

A Learning Receiver For Communication In Three-Component Multipath Channels, Richard Paul Brueggemann

Doctoral Dissertations

"An adaptive receiver is designed for transmissions through a time-varying multipath channel which may include both specular and diffuse components. The design is based on the theory of unsupervised learning machines and the receiver is a recursive structure which does not grow in complexity with each new observation, but is Bayes' optimal at each instant of time. The multipath medium is modelled as an aggregate of L conditionally independent transmission paths, each consisting of random and/or fixed reflections, and is identified in terms of three components: (1) indirect diffuse scatter, (2) indirect specular reflection, and (3) direct transmission. The channel …

Iicads--Integrated Interactive Computer Aided Design System, Archie Golden Lambert

Doctoral Dissertations

"This research has three goals. The first goal is to develop a software interface (supervisor) to support and control a variety of interactive subsystem modules; thus eliminating manual scheduling of interactive jobs. The second goal is to develop a common methodology for interactive subsystem design. The third goal is to develop a linear systems analysis package using the facilities developed under the first two goals. A software interface (supervisor) to support and control a variety of interactive subsystem modules is described. The supervisor operates under the constraints of a large multiprogramming variable task operating system as opposed to a time …

Radiative And Predissociative Lifetimes Of The A²Σ⁺ State Of Oh, Robert Allen Sutherland

Doctoral Dissertations

"Lifetime measurements have been made on the A²Σ⁺ state of OH by the delayed coincidence technique in conjunction with an interrupted rf discharge through water vapor. Lifetimes are reported for rotational states up to K = 29 and K = 20 in the v = 0 and v = 1 vibrational levels respectively and on the unresolved levels of v =2. A predissociation, previously predicted from relative intensity measurements, resulting from a curve crossing by the repulsive 4 Σˉ state, was observed for the rotational states above K = 23 of v = 0, for those above K = 14 …

Substituent Effects On The Magnetic Resonance Spectra Of 1, 4-Disubstituted Benzenes, Holger Er-Chah Chen

Doctoral Dissertations

"The Nuclear Magnetic Resonance spectra of five complete series of para-substituted benzenes have been investigated: the benzoic acids, benzonitriles, benzoyl chlorides, methyl benzoates and nitrobenzenes. Precise values of aromatic proton chemical shifts and coupling constants were obtained from LAOCOON3 computer analyses of the spectra. Using the relative internal chemical shift technique of Beachell and Beistel, excellent linear correlations among all five series were found. All substituents gave proton shifts which lay on the least-squares line, so it is concluded that all substituents are well behaved. Using the correlation plots the chemical shifts of the aromatic ring protons can be predicted …

Condensation And Sublimation Of Carbon Dioxide And Water Molecules At Cryogenic Temperatures, Victor Cazcarra

Doctoral Dissertations

"Measurements of the condensation coefficient of CO₂ and H₂O have been made using a molecular beam and quartz crystal microbalances. The dependence of the condensation coefficient on variables such as population density on the substrate, temperature of the substrate, molecular beam intensity and temperature of the molecular beam, was investigated. The results are explained using heterogeneous nucleation theory for low density population, and a new approach for high density population is presented. The rate of sublimation of these two gases was measured directly. The results are reported in terms of vapor pressure in the range 10⁻⁹ to 10⁻⁴ Torr. The …

Wall Rock Geochemistry Of The Chester Vein, Sunshine Mine, Kellogg, Idaho, Nicholas Howard Tibbs

Doctoral Dissertations

"The Chester vein has been the major source of ore from the Sunshine mine, largest single producer of silver in the world. 425 samples of quartzite and argillite wall rocks were collected in 13 traverses across this vein on the 4400, 4600, and 4800 mining levels. These samples were analyzed for aluminum, magnesium, calcium, sodium, potassium, manganese, iron, lead, copper, and zinc by atomic absorption spectroscopy, and for silicon and sulfur by x-ray emission spectroscopy. Element distribution plots, linear correlation coefficient matrices, varimax factor analysis, and cluster analysis were employed to determine the geochemical processes that occurred in the wall …

The Scattering Of Elastic Waves By Void Cavities, Jerry Lee Davis

Doctoral Dissertations

"Elastodynamic multipole theory, the theory of least squares, and the theory of integral representation of solutions are employed in solving certain problems involving an elastic solid containing a source and a scatterer. Both the source and scatterer are of finite geometrical extent; they occupy non-intersecting regions. The source is separable, i.e., its mathematical specification consists of an arbitrary vector function of position multiplied by a time function, which is further assumed to be a sinusoid. The scatterer emphasized is a finite void cavity of arbitrary shape; however, scatterers composed of rigid material may also be treated. The calculation of a …

Synthesis And Properties Of Cadmium Manganese Ferrites, B. W. Jong

Doctoral Dissertations

"The formation sequence of (Cd,Mn,Fe) (Mn,Fe)₂O₄ from the individual oxides,x CdO + (1-x) MnCO₃ + α-Fe₂O₃,was found by X-Ray diffraction. Cd(Mn,Fe)₂O₄ was formed completely from CdO·Fe₂O₃ and CdO·Fe₂O₄ at 900°C and reacted with MnFe₂O₄ for 0 < x < 0.5 and with α-Fe₂O₃ for 0.5 < x < 1.0 to form a single phase of (Cd,Mn,Fe) (Mn,Fe)₂O₄ at 1150°C. This is the first time that the details involved in the formation sequence of CdMn-ferrite have been shown. A mixture of 0.5 CdO + 0.5 MnCO₃ + α-Fe₂O₃ was calcined at 900°C for 2 hrs forming Cd(Mn,Fe)₂O₄ with no Cd present in the other phases. Sintering was accomplished at 1150°C for 30 minutes forming a single phase of Cd₀.₅Mn₀.₅Fe₂O₄ with a bulk sintered density of 98-99% of the X-Ray density. The rate of changing density followed the relationship, p = K ln t + c, at temperatures between 1050°C and 1300°C. Magnetic properties of CdₓMn₁₋ₓFe₂O₄ were affected by composition x. A relationship, B = gx + h, was found between maximum magnetic flux density B and composition x at room temperature for 0 <̲ x <̲ 0.3. This was rationalized by a modification of Néel's theory. The maximum magnetic flux density decreased with increasing cadmium concentration for 0.3 < x <̲ 0.5. This decrease was attributed to the changing direction of the magnetic moment in the octahedral site sub-lattice according to the superexchange theory. No magnetic properties were observed due to the formation of a compensated antiferromagnetic phase for 0.5 < x <̲ 1.0. Maximum magnetic flux density increased with bulk density, while the coercive force decreased with the grain growth and the initial permeability increased with the bulk density and grain size. A stator core used for a-c electric motor application was formed by pre-sintering at 900⁰C for 2 hrs. Slots were then sawed with a tungsten carbide blade and final sintering was accomplished at 1150⁰C for 1 hr"--Abstract, pages iii-iv.

The Effect Of Impurities And Additives On The Electrowinning Of Zinc, Haruhisa Fukubayashi

Doctoral Dissertations

"The effect of various impurities, commonly found in zinc electro-winning solutions, on the surface morphology of deposited zinc was investigated. Individual additions of the impurities Al, Ag, Cd, Co, Cr, Cu, Ge, Mn, Ni, Sb, Sn, Ti, PbO₂ , PbSO₄, and HCl were studied. In a few cases additives of animal glue, gum arabic, and Na₂SiO₃, were used individually or in combination, to determine their effect on the surface structure of the deposited zinc. Comparisons were then made with deposits from a pure electrolyte consisting of H₂SO₄ and Zn⁺², 200 and 65 g/l, respectively. The zinc was deposited on a …

Time Resolved Measurements Of Droplet Growth In A Wilson Cloud Chamber, Michael Anthony Vietti

Doctoral Dissertations

"The growth rates of water drops in a Wilson expansion cloud chamber are measured with air, argon and helium as the carrier gas, in the size range of .5 to 10 microns. The drops growing in the supersaturated chamber exhibit oscillations in the scattered intensity as predicted by Mie theory. Scattered intensity is measured at 30 degrees to the He-Ne laser beam. Supersaturation ratios during growth range from S =1.2 to S = 3.5 for all three gases. The initial temperature is measured and the pressure is monitored continuously so that droplet growth theory can be compared with experiment. Three …

Secondary Techniques For Increasing Fault Coverage Of Fault Detection Test Sequences For Asynchronous Sequential Networks, Lewis Ronald Hoover

Doctoral Dissertations

"The generation of fault detection sequences for asynchronous sequential networks is considered here. Several techniques exist for the generation of fault detection sequences on combinational and clocked sequential networks. Although these techniques provide closed solutions for combinational and clocked networks, they meet with much less success when used as strategies on asynchronous networks. It is presently assumed that the general asynchronous problem defies closed solution. For this reason, a secondary procedure is presented here to facilitate increased fault coverage by a given fault detection test sequence. This procedure is successful on all types of logic networks but is, perhaps, most …

An Exact Analysis Of Two-Dimensional Radiative Transfer In An Absorbing And Emitting Gray Medium, William F. Breig

Doctoral Dissertations

"The exact formulations for the radiative flux and the emissive power are presented for a two-dimensional, finite, planar, absorbing and emitting, gray medium in radiative equilibrium. Exact expressions are obtained for the medium subjected to the following types of boundary conditions: (1) cosine varying diffuse, (2) cosine varying collimated, (3) constant temperature strip, and (4) the strip illuminated by a uniform collimated flux. The solutions for the physically unrealistic cosine varying models are used to construct the solutions for the more practical finite strip models. The two-dimensional equations are reduced to one-dimensional equations by the method of separation of variables. …

Ionization Mechanisms In Cesium, Yu Bong Hahn

Doctoral Dissertations

"Autoionizing states in Cs between 12 and 20 eV have been studied by electron impact. The retarding-potential-difference(RPD) method was used to obtain an electron beam with energy spread of about 0.1 eV. To determine the threshold energies, inelastically scattered electrons were analyzed by the trapped-electron method. We have been able to identify about 20 levels, and the agreement with spectroscopic data is excellent. A peak appearing at 12.80 eV is probably due to the quartet states observed by Feldman and Novick"--Abstract, page 2. "The structure in the electron impact ionization cross section in cesium can be partially accounted for by …

The Eikonal Distorted Wave Born Approximation For The Excitation Of Hydrogen By Impact With Hydrogen And Helium In The Intermediate Energy Range, Richard Homer Shields

Doctoral Dissertations

"An eikonal approximation is applied to atom-atom scattering in the intermediate energy range. The theory and the form of the eikonal approximation are reviewed. Also a brief survey of previous theoretical methods for all energy ranges is included.

In particular, the differential and total cross sections for the excitation of hydrogen to the 2s and 2p states by impact on hydrogen and helium atoms have been calculated using the eikonal distorted wave Born approximation (DWBA) for the incident energy range of 2.25-100 keV. The eikonal DWBA differential cross sections are compared to the differential cross sections given by the first …

Deformation And Fracture Of Concrete Under Uniaxial Impact Loading, Esteban Eulogio Miranda

Doctoral Dissertations

"Stress wave propagation and interaction in plain concrete leading up to spall fracture was investigated experimentally with a computer numerical analysis of the bar-geometry axial-impact loading. The critical normal fracture strain energy U and mechanical energy W criteria are proposed for the spatial and time dependence explanation of spallation in concrete. The energy criteria are special cases of a more generalized cumulative damage model of the form:....

Finite-difference analyses of the wave propagation and interactions in the split Hopkinson bar showed that early failure in brittle materials limits the application of the conventional method of analysis because equilibrium in the …

Quasi-Pseudometrics Over Tikhonov Semifields And Fixed Point Theorems, Ronald Evans Satterwhite

Doctoral Dissertations

"It has been shown that topological spaces are characterized as quasi-pseudometric spaces over some Tikhonov semifield.

Sufficient conditions are given for a T₁ space to be metrizable over some Tikhonov semifield.

Completely regular (uniform) spaces are characterized as pseudornetric spaces over some Tikhonov semifield.

Certain metric, pseudornetric, quasi-metric, quasipseudometric spaces over a Tikhonov semifield are shown to be respectively metric, pseudometric, quasi-metric, quasipseudometric spaces in the usual sense.

Several results from fixed point theory in the metric space setting are generalized to the setting of completely regular (uniform) Hausdorff spaces."--Abstract, page ii.

Elementary Length Topologies Constructed Using Pseudo-Norms With Values In Tikhohov Semi-Fields, Jackie Ray Hamm

Doctoral Dissertations

"Elementary length topologies defined on normed and pseudo-normed linear spaces are studied. It is shown that elementary length topologies constructed with different pseudo-norms are never equivalent. Elementary length topologies are constructed on certain topological spaces and some of their properties are investigated. It is shown that certain "measuring devices" (i.e., norms, pseudo-norms, semi-norms, and pseudo-metrics) which take their values in Tikhonov semifields may be used to construct elementary length topologies on any topological linear space. Relationships between two elementary length topologies generated with different measuring devices are considered.

Let (X,t) be a topological linear space such that t is determined …

A Method For Generating Uts Assignments With An Iterative State Transition Algorithm, Dattatraya Govind Raj-Karne

Doctoral Dissertations

"There is a lack of systematic procedures that can be used to find uni-code totally sequential (UTS) assignments from a flow table description of an asynchronous sequential circuit. Presented here is an iterative internal state assignment method. This method consists of three algorithms. The first generates a minimum variable initial assignment from a flow table description. The second tests the validity of this assignment by constructing minimum length transition paths without crossover and the third augments this assignment by adding an internal state variable in the event that all transition paths cannot be constructed without crossover. The second and the …

The Morphology Of Cellular Precipitation In Aluminum Rich Aluminum-Silver Alloys, Santiago Ibarra Jr.

Doctoral Dissertations

"The morphology of cellular precipitation in Al-29.8wt%Ag alloy has been investigated in bulk specimens by transmission electron microscopy and in solution treated specimens by means of hot stage microscopy. Both cellular and general precipitation were observed to occur simultaneously in quench-aged and isothermally aged alloys. By studying the early stages of precipitation in the hot stage, the mechanism for the growth of cells in Al-Ag alloys was developed. According to this mechanism, the grain boundary allotriomorphs begin to form, the boundary then interacts with the allotriomorphs by bowing, and then either trailing precipitation forms on the allotriomorphs or new lamellae …

An Asynchronous Circuit Design Language System, Gregory Martin Bednar

Doctoral Dissertations

"This paper presents a system for specifying the behavior of asynchronous sequential circuits. The system consists of a special purpose Asynchronous Circuit Design Language (ACDL), a translator and a flow table generation algorithm. The language includes many special features which permit quick and precise specification of terminal behavior. It is best suited for problems originating from a word description of the circuit's operation. The translator is written with the XPL Translator Writing System and is a syntax-directed compilation method. From the translated ACDL specifications, the flow table algorithm generates a primitive flow table which is the required input for the …

Determination Of Thermal Contact Resistance Between Metals Using A Pulse Technique, William Edward Stewart Jr.

Doctoral Dissertations

"This dissertation reports the results of an experimental and analytical investigation to determine the thermal contact resistance of several metal specimen pairs using a relatively new pulse technique. Metal specimens were aluminum 2024-T3, aluminum 6061-T6, aluminum 7075-T6, copper 110, stainless steel 304, molybdenum, and Armco iron. Thermal contact resistance was also determined for dissimilar metal specimen pairs of aluminum 6061-T6 - copper 110 and aluminum 7075-T6 - copper 110. Aluminum 7075-T6, copper 110, and stainless steel 304 specimens were tested to determine the variance of contact resistance with time after loading.

Specimens were circular cylindrical disks between .033 and .061 …

Distributed-Network Realizations For The Simulation Of Partial Differential Equations, Roy Dale Hensley

Doctoral Dissertations

"A method is developed for the simulation of the partial differential equation

-u_xx + k_ou_tt + k_lu_t +k₂u = g(t)

for various boundary conditions. The boundary conditions are used to classify the problems into types and the Laplace transformed solution of the most general problem of each type is obtained.

Synthesis techniques are presented for the realization of circuits containing distributed networks that can be used to simulate the partial differential equation for given boundary conditions. Several heat flow and vibrating string examples are included to illustrate the application of the …

Mass Transfer With Second-Order Chemical Reaction Inside Circulating Fluid Droplets, Roy James Brunson

Doctoral Dissertations

"The solution of a mathematical model is presented which describes mass transfer accompanied by a second-order chemical reaction inside a circulating, fluid sphere for the laminar flow region. The values for eight different mass transfer indices are presented as a function of the Peclet number, reaction number, diffusivity ratio, concentration ratio, and the dimensionless contact time. The results of this work are compared with the film and penetration theories for mass transfer with reaction as modified to apply inside a fluid sphere. This work corrects the three factors which limit the accuracy of applying previous theories to fluid spheres: geometrical …